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1. 发明授权

US5552549A Process for the dechlorination of chlorinated aromatic compounds 失效
标题翻译：氯化芳烃化合物脱氯工艺
公开(公告)号：US5552549A
公开(公告)日：1996-09-03
申请号：US315001
申请日：1994-09-29
申请人： Christian Rasp , Helmut Waldmann , Hans-Joachim Traenckner
发明人： Christian Rasp , Helmut Waldmann , Hans-Joachim Traenckner
IPC分类号： A62D3/32 , A62D101/22 , C07B35/06 , C07B61/00 , C07C1/26 , C07C15/04 , C07C17/23 , C07C25/02 , C07D213/06 , C07D213/61 , C07D215/18 , C07D217/22 , C07D319/24 , C07D217/00 , C07C1/20 , C07C22/00 , C07D309/00
CPC分类号： A62D3/32 , A62D2101/22
摘要： Chlorinated aromatic compounds are dechlorinated in a simple and inexpensive manner by heating them to 300.degree. to 450.degree. C. in a salt melt in the presence of water and/or water vapor and carbon.
摘要翻译：氯化芳族化合物以简单且便宜的方式通过在水和/或水蒸气和碳的存在下在盐熔体中加热至300-450℃进行脱氯。

2. 发明授权

US5401798A Gypsum-based materials, process for their preparation and their use 失效
标题翻译：基于石膏的材料，其制备方法及其应用
公开(公告)号：US5401798A
公开(公告)日：1995-03-28
申请号：US101326
申请日：1993-08-02
申请人： Christian Rasp , Jan Mazanek , Ulrich von Gizycki
发明人： Christian Rasp , Jan Mazanek , Ulrich von Gizycki
IPC分类号： C04B28/14 , C08J5/10 , C08K3/30 , C08L71/00
CPC分类号： C04B28/14 , C04B2111/00836 , C04B2111/27
摘要： Materials based on gypsum and organic additives are improved if they contain polyethers and, if desired, polymers. They can be used in a wide range of areas, for example as slabs in the building sector and for improving plasters, mortars, insulating materials and other construction compositions, casts and/or moulds.
摘要翻译：基于石膏和有机添加剂的材料如果含有聚醚，并且如果需要，则改进聚合物。它们可以用于广泛的领域，例如建筑部门的板坯，以及用于改善灰泥，迫击炮，绝缘材料和其他建筑组合物，铸件和/或模具。

3. 发明授权

US4304922A Process for the preparation of urethane 失效
标题翻译：氨基甲酸酯的制备方法
公开(公告)号：US4304922A
公开(公告)日：1981-12-08
申请号：US125395
申请日：1980-02-27
申请人： Robert Becker , Johann Grolig , Christian Rasp , Gunter Stammann
发明人： Robert Becker , Johann Grolig , Christian Rasp , Gunter Stammann
IPC分类号： C07C239/00 , C07C67/00 , C07C271/06 , C07C125/065 , C07C125/073
CPC分类号： C07C271/06
摘要： Production of urethanes by the oxycarbonylation reaction of N,N'-disubstituted ureas and organic compounds containing at least one hydroxyl group with carbon monoxide in the presence of molecular oxygen and/or organic nitro compounds and a catalyst system comprising (a) a noble metal and/or noble metal compound of the eighth subgroup of the periodic system of elements and (b) a compound of an element and/or elements of the third to fifth main group and/or first to eighth subgroup of the periodic system of elements characterized in that said compounds are capable of undergoing Redox reactions under the reaction conditions.
摘要翻译：在分子氧和/或有机硝基化合物的存在下通过N，N'-二取代的脲和含有至少一个羟基的有机化合物与一氧化碳的羰基化反应制备氨基甲酸酯和包含（a）贵金属和/或元素周期性系统的第八子群的贵金属化合物和（b）元素周期系统的元素和/或元素的第三至第五主族和/或第一至第八亚组的化合物，其特征在于因为所述化合物能够在反应条件下进行氧化还原反应。

4. 发明授权

US4094811A Process for the preparation of silver dispersions for filter layers and antihalation layers 失效
标题翻译：用于制备过滤层和防晕层的银分散体的方法
公开(公告)号：US4094811A
公开(公告)日：1978-06-13
申请号：US753093
申请日：1976-12-21
申请人： Artur Botta , Anita VON Konig , Franz Moll , Christian Rasp , Johannes Hartl
发明人： Artur Botta , Anita VON Konig , Franz Moll , Christian Rasp , Johannes Hartl
IPC分类号： G03C1/06 , C07D235/00 , C07D239/00 , G03C1/825 , B01J13/00 , G03C1/84
CPC分类号： G03C1/8255
摘要： The process for the preparation of silver dispersions for antihalation and filter layers in photographic material by reducing silver salts in the presence of a heterocyclic 5-membered or 6-membered compound which has a ##STR1## group in its 1,2,3-position and a 2-aminoalkyl or 2-hydroxyalkyl group or an alkylene chain which is linked through the 1- and 2-position. The process provides neutral grey silver dispersions without using cadmium salts, for the reduction of the silver salts.
摘要翻译：通过在杂环5元或6元化合物的存在下还原银盐制备用于防光晕和过滤层的银分散体的方法，该化合物在其1,2,3位上具有基团和2-氨基烷基或2-羟基烷基或通过1-和2-位连接的亚烷基链。该方法提供不使用镉盐的中性灰色银分散体，用于还原银盐。

5. 发明授权

US06933409B1 Amination of aromatic hydrocarbons and heterocyclic analogs thereof 失效
标题翻译：芳烃和其杂环类似物的胺化
公开(公告)号：US06933409B1
公开(公告)日：2005-08-23
申请号：US09571567
申请日：2000-05-15
申请人： Damodara M. Poojary , Ramesh Borade , Alfred Hagemeyer , Xiao Ping Zhou , Christopher E. Dube , Ulrich Notheis , Ralph Armbrust , Christian Rasp , David M. Lowe
发明人： Damodara M. Poojary , Ramesh Borade , Alfred Hagemeyer , Xiao Ping Zhou , Christopher E. Dube , Ulrich Notheis , Ralph Armbrust , Christian Rasp , David M. Lowe
IPC分类号： C07C209/00 , C07C209/02 , C07C211/46
CPC分类号： C07C209/02 , Y02P20/582 , C07C211/46
摘要： Noble metal/reducible metal oxide catalysts effective for the direct amination of aromatic hydrocarbons and heterocyclic analogs thereof are disclosed. In one embodiment, the cataloxidant comprises a noble metal selected from Pd, Rh, Ir and/or Ru and a reducible metal oxide. In another embodiment, the cataloxidant comprises a noble metal and a reducible oxide of a metal selected from Ni, Mn, V, Ce, Th, Pr, Te, Re, Co, Fe, Cu and/or Bi. A preferred cataloxidant comprises one or more noble metals selected from Pd, Rh, Ir and/or Ru, in combination with nickel oxide and/or manganese oxide. In preferred applications, benzene can be aminated in the presence of the cataloxidants to form aniline. A benzene conversion of at least 5% is achieved, with more than 90% selectivity for aniline. Significantly, the cataloxidant can be regenerated without a substantial loss of performance.
摘要翻译：公开了对芳烃和其杂环类似物的直接胺化有效的贵金属/可还原金属氧化物催化剂。在一个实施方案中，所述催化剂包含选自Pd，Rh，Ir和/或Ru的贵金属和可还原的金属氧化物。在另一个实施方案中，所述催化剂包含贵金属和选自Ni，Mn，V，Ce，Th，Pr，Te，Re，Co，Fe，Cu和/或Bi的金属的可还原氧化物。优选的催化剂包含一种或多种选自Pd，Rh，Ir和/或Ru的贵金属，与氧化镍和/或氧化锰组合。在优选的应用中，苯可以在催化剂存在下胺化形成苯胺。达到至少5％的苯转化率，对苯胺具有超过90％的选择性。值得注意的是，可以再生催化剂，而没有显着的性能损失。

6. 发明授权

US4297501A Process for the preparation of urethanes 失效
标题翻译：制备聚氨酯的方法
公开(公告)号：US4297501A
公开(公告)日：1981-10-27
申请号：US125394
申请日：1980-02-27
申请人： Robert Becker , Johann Grolig , Christian Rasp
发明人： Robert Becker , Johann Grolig , Christian Rasp
IPC分类号： B01J27/10 , B01J21/00 , B01J23/00 , B01J23/56 , B01J23/89 , B01J27/00 , B01J31/00 , B01J31/28 , C07C67/00 , C07C239/00 , C07C269/04 , C07C125/065
CPC分类号： C07C269/04
摘要： A process for producing urethanes by reacting primary amines, carbon monoxide and organic hydroxyl compounds in the presence of molecular oxygen and/or organic nitro compounds as oxidizing agents and a catalyst system comprising a noble metal and/or a compound of a noble metal of the 8th subgroup of the Periodic System of Elements and a compound capable of undergoing Redox reactions under reaction conditions of the 3rd to 5th main group and/or 1st to 8th subgroup of the Periodic System of Elements.
摘要翻译：在分子氧和/或有机硝基化合物作为氧化剂存在下使伯胺，一氧化碳和有机羟基化合物反应制备氨基甲酸酯的方法和包含贵金属和/或贵金属的化合物的催化剂体系元素周期元素第8族和能够在元素周期表第3至第5主族和/或第1至第8族的反应条件下进行氧化还原反应的化合物。

7. 发明授权

US4262130A Process for the production of urethanes 失效
标题翻译：生产聚氨酯的工艺
公开(公告)号：US4262130A
公开(公告)日：1981-04-14
申请号：US112780
申请日：1980-01-17
申请人： Robert Becker , Johann Grolig , Christian Rasp
发明人： Robert Becker , Johann Grolig , Christian Rasp
IPC分类号： C07B61/00 , B01J23/00 , B01J23/44 , B01J23/74 , B01J23/89 , B01J27/10 , B01J27/128 , B01J31/02 , C07C67/00 , C07C239/00 , C07C269/00 , C07C125/065 , C07C125/073
CPC分类号： B01J23/8906 , B01J27/10
摘要： The present invention relates to an improved process for the production of urethanes (carbamic acid esters) by the reaction of organic nitro compounds with carbon monoxide and organic compounds containing at least one hydroxy group in the presence of palladium and/or palladium compounds and a cocatalyst which consists of a mixture of one or more iron oxides and/or iron hydroxides and activating chloride-containing additives.
摘要翻译：本发明涉及通过有机硝基化合物与一氧化碳和含有至少一个羟基的有机化合物在钯和/或钯化合物和助催化剂的存在下反应制备氨基甲酸酯（氨基甲酸酯）的改进方法其由一种或多种氧化铁和/或氢氧化铁和活化的含氯化物的添加剂的混合物组成。

8. 发明授权

US4151262A Process for the catalytic conversion of organic chlorine compounds 失效
标题翻译：有机氯化合物的催化转化工艺
公开(公告)号：US4151262A
公开(公告)日：1979-04-24
申请号：US868551
申请日：1978-01-11
申请人： Christian Rasp , Gerhard Scharfe
发明人： Christian Rasp , Gerhard Scharfe
IPC分类号： B01J23/00 , C01B7/01 , C01B32/50 , C01B7/00 , B01J8/00 , C01B7/08
CPC分类号： C01B7/01
摘要： A process has been developed for the catalytic conversion of organic chlorine compounds into carbon dioxide and hydrogen chloride, using molecular oxygen, in which process the catalyst system is provided by using platinum in a first catalyst zone and palladium in a second catalyst zone.
摘要翻译：已经开发了一种使用分子氧将有机氯化合物催化转化成二氧化碳和氯化氢的方法，在该方法中，通过在第一催化剂区中使用铂和在第二催化剂区中使用钯来提供催化剂体系。

9. 发明授权

US4209583A Corrosion preventative for two-bath stabilizer baths 失效
标题翻译：双浴稳定剂浴的防腐蚀
公开(公告)号：US4209583A
公开(公告)日：1980-06-24
申请号：US901640
申请日：1978-05-01
申请人： Werner Berthold , Artur Botta , Anita von Konig , Christian Rasp
发明人： Werner Berthold , Artur Botta , Anita von Konig , Christian Rasp
IPC分类号： C23F11/04 , G03C5/29 , G03C5/39 , G03C5/38
CPC分类号： G03C5/39
摘要： Stabilizing baths used in rapid reproduction processes of photographic elements which comprise stabilizers, hardening additives and corrosion preventatives are improved in that certain heterocyclic compounds are incorporated in the baths. Excellent protection against corrosion is attained without a deleterious effect on the quality of the photographic material.
摘要翻译：改进了包含稳定剂，硬化添加剂和防腐剂的照相材料的快速再生过程中使用的稳定浴，因为某些杂环化合物被并入浴中。不会对照相材料的质量造成有害的影响，从而获得良好的耐腐蚀性。

10. 发明授权

US4048174A Process for preparing 1,2-fused-1,3-dinitrogen-heterocyclic compounds 失效
标题翻译：制备1,2-稠合-1,3-二氮杂环化合物的方法
公开(公告)号：US4048174A
公开(公告)日：1977-09-13
申请号：US591789
申请日：1975-06-30
申请人： Artur Botta , Christian Rasp
发明人： Artur Botta , Christian Rasp
IPC分类号： C07D471/04 , C07D471/14 , C07D487/04 , C07D487/06 , C10N30/12 , C23F11/14
CPC分类号： C07D471/04 , C07D471/14 , C07D487/04 , C07D487/06 , C23F11/149
摘要： 1,2-FUSED FIVE-MEMBERED OR SIX-MEMBERED 1,3-DINITROGEN-HETEROCYCLIC COMPOUNDS, USFUL AS ANTI-CORROSION AGENTS, HAVING THE FORMULA ##STR1## wherein A is an optionally substituted, optionally polynuclear orth- or peri-arylene radical andB is an optionally substituted alkylene chain ##STR2## WHEREIN R.sup.1 and R.sup.2 individually represent hydrogen and/or optionally substituted aliphatic, cycloaliphatic, araliphatic or aromatic radicals andn represents a number from 3 to 6,OrB is an optionally substituted 1,8-naphthylene, 2,2'-diphenylene or 4,5-phenanthrylene radical,Are prepared by splitting a five-membered or six-membered 1,3- dinitrogen-heterocyclic compound, which contains a 2-(.omega.-amino group) side chain, having the formula ##STR3## wherein A and B have the meanings indicated above andR.sup.3 and R.sup.4 are hydrogen, lower alkyl, cycloalkyl or aralkyl but at least one of the two radicals R.sup.3 and R.sup.4 must represent hydrogen.
摘要翻译：其中A是任选取代的，任选多核的orth或peri的1,2-二烯或六元共轭三元杂环化合物，作为抗腐蚀剂，具有式（I）亚芳基，B是任选取代的亚烷基链，其中R 1和R 2各自表示氢和/或任选取代的脂族，脂环族，芳脂族或芳族基团，并且N代表从3至6的数字，或B是任选取代的 1,8-亚萘基，2,2'-二亚苯基或4,5-菲亚基，是通过分离五元或六元共轭三元杂环化合物制备的，其包含2-（ω-氨基）组合式），具有式（II）其中A和B具有上述含义，R 3和R 4是氢，低级烷基，环烷基或芳烷基，但两个基团R 3和R 4中的至少一个必须表示氢。

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