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11. 发明申请

US20070179301A1 BISPHOSPHINES AS BIDENTATE LIGANDS 失效
公开(公告)号：US20070179301A1
公开(公告)日：2007-08-02
申请号：US11609559
申请日：2006-12-12
申请人： Armin Boerner , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten Schneider , Uwe Dingerdissen , Karlheinz Drauz
发明人： Armin Boerner , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten Schneider , Uwe Dingerdissen , Karlheinz Drauz
IPC分类号： C07F9/572 , C07F9/547
CPC分类号： B01J31/1658 , B01J31/24 , B01J31/2433 , B01J31/2476 , B01J2231/321 , B01J2231/645 , B01J2531/16 , B01J2531/80 , B01J2531/822 , C07B53/00 , C07C45/505 , C07C45/72 , C07C67/303 , C07C231/18 , C07F9/5027 , C07F9/5537 , C07F9/6506 , C07F9/650994 , C07F9/65515 , C07F9/65683 , C07C69/34
摘要： The present invention relates to ligands of the general formula (I). In addition, a process for the production thereof and the use thereof are demonstrated.

12. 发明授权

US06884887B1 Method for producing amines by homogeneously catalyzed reductive amination of carbonyl compounds 失效
标题翻译：通过羰基化合物的均匀催化还原胺化制备胺的方法
公开(公告)号：US06884887B1
公开(公告)日：2005-04-26
申请号：US10030946
申请日：2000-06-29
申请人： Thomas Riermeier , Karl-Josef Haack , Uwe Dingerdissen , Armin Boerner , Vitali Tararov , Renat Kadyrov
发明人： Thomas Riermeier , Karl-Josef Haack , Uwe Dingerdissen , Armin Boerner , Vitali Tararov , Renat Kadyrov
IPC分类号： C07D295/02 , B01J31/18 , B01J31/24 , C07B53/00 , C07B61/00 , C07C209/26 , C07C211/08 , C07C211/27 , C07C213/02 , C07C215/50 , C07C227/08 , C07C229/08 , C07C229/14 , C07C229/36 , C07D295/023 , C07D295/14 , C07D295/15 , C07D265/30
CPC分类号： C07D295/15 , B01J31/1875 , B01J31/2404 , B01J31/2409 , B01J2231/341 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C209/26 , C07C227/08 , C07D295/023 , C07C211/27 , C07C229/14
摘要： The invention relates to the preparation of chiral or achiral amines by reaction of aldehydes or ketones with ammonia or primary or secondary amines in the presence of hydrogen and in the presence of homogeneous metal catalysts under mild conditions. Metal catalysts which can be used are complexes of late transition metals with chiral or achiral phosphorus-containing ligands.
摘要翻译：本发明涉及通过醛或酮与氨或伯胺或仲胺在氢气存在下和在温和条件下在均相金属催化剂存在下反应来制备手性或非手性胺。可以使用的金属催化剂是后过渡金属与手性或非手性含磷配体的络合物。

13. 发明授权

US08501975B2 Method for manufacturing ruthenium carbene complexes 有权
标题翻译：制备钌卡宾配合物的方法
公开(公告)号：US08501975B2
公开(公告)日：2013-08-06
申请号：US12937046
申请日：2009-04-08
申请人： Renat Kadyrov , Anna Rosiak
发明人： Renat Kadyrov , Anna Rosiak
IPC分类号： C07F15/00
CPC分类号： B01J31/2447 , B01J31/2269 , B01J31/2273 , B01J31/2278 , B01J31/24 , B01J31/2404 , B01J31/2414 , B01J31/248 , B01J2231/543 , B01J2531/821 , C07F15/0046
摘要： A method of manufacturing ruthenium carbene complexes and novel aryl alkylidene ruthenium complexes based on the method, the complexes able to used as catalysts in metathesis reactions.
摘要翻译：基于该方法制备钌卡宾络合物和新型芳基亚烷基钌配合物的方法，该复合物能够用作复分解反应中的催化剂。

14. 发明申请

US20070213540A1 Process for the hydrogenation of imines 审中-公开
标题翻译：亚胺氢化方法
公开(公告)号：US20070213540A1
公开(公告)日：2007-09-13
申请号：US11371084
申请日：2006-03-09
申请人： Juan Jose Perea , Thomas Riermeier , Axel Monsees , Renat Kadyrov
发明人： Juan Jose Perea , Thomas Riermeier , Axel Monsees , Renat Kadyrov
IPC分类号： C07D333/42 , C07C209/44
CPC分类号： C07C209/52 , C07B2200/07 , C07C211/48
摘要： The present invention relates to a process for the hydrogenation of an imines with hydrogen in the presence of iridium catalysts. In particular, the present invention relates to a process for the hydrogenation of imines with hydrogen under elevated pressure in the presence of an iridium catalyst and with or without an inert solvent, wherein the reaction mixture comprises a phosphonium chloride, bromide or iodide in the presence of an acid, which can be an organic or inorganic acid soluble or insoluble in the reaction mixture. Suitable imines are especially those that contain at least one group. If the groups are substituted asymetrically and are thus compounds having a prochiral ketitine group, it is possible in the process according to the invention for mixtures of optical isomers or pure optical isomers to be formed if enantioselective or diastereoselective iridium catatalysts are used.
摘要翻译：本发明涉及在铱催化剂存在下用氢氢化亚胺的方法。特别地，本发明涉及在铱催化剂和惰性溶剂的存在下在高压下用氢气氢化亚胺的方法，其中反应混合物在存在下包含氯化鏻，溴化物或碘化鏻的酸，其可以是可溶于或不溶于反应混合物的有机或无机酸。合适的亚胺尤其是含有至少一个基团的亚胺。如果这些基团被非对称取代，并且因此是具有前手性酮亚胺基团的化合物，则在本发明的方法中，如果使用对映选择性或非对映选择性铱催化剂，则可以形成光学异构体或纯的光学异构体的混合物。

15. 发明授权

US07230134B2 Method for the production of amines by reductive amination of carbonyl compounds under transfer-hydrogenation conditions 失效
标题翻译：通过羰基化合物在转移氢化条件下还原胺化制备胺的方法
公开(公告)号：US07230134B2
公开(公告)日：2007-06-12
申请号：US10484900
申请日：2002-08-06
申请人： Armin Borner , Uwe Dingerdissen , Renat Kadyrov , Thomas Riermeier , Vitali Tararov
发明人： Armin Borner , Uwe Dingerdissen , Renat Kadyrov , Thomas Riermeier , Vitali Tararov
IPC分类号： C07C209/28
CPC分类号： C07C231/08 , C07C209/28 , C07C213/02 , C07C231/02 , C07C2601/14 , C07C2602/08 , C07D213/38 , C07C211/03 , C07C211/27 , C07C211/29 , C07C211/35 , C07C211/42 , C07C215/50 , C07C217/58 , C07C237/22
摘要： This application claims the benefit of German priority Application No. 10138140.9, filed on Aug. 9, 2001, and International Application No. PCT/EP02/08748, filed on Aug. 6, 2002. The invention relates to the production of amines by the reaction of aldehydes or ketones with ammonia or primary or secondary amines in the presence of a hydrogen-donor and the presence of homogeneous metal catalysts of the eighth sub-group under mild conditions.
摘要翻译：本申请要求于2001年8月9日提交的德国优先权申请号10138140.9和2002年8月6日提交的国际申请号PCT / EP02 / 08748的优先权。本发明涉及由在氢供体存在下，醛或酮与氨或伯胺或仲胺的反应，以及在温和条件下第八子基团的均相金属催化剂的存在。

16. 发明授权

US09890108B2 Catalytic hydrogenation for the preparation of amines from amide acetals, ketene N, O-acetals or ester imides 有权
公开(公告)号：US09890108B2
公开(公告)日：2018-02-13
申请号：US15034135
申请日：2014-10-15
申请人： Renat Kadyrov
发明人： Renat Kadyrov
IPC分类号： C07C209/52 , C07B43/04 , C07C209/68 , C07C213/00 , C07C253/30 , C07D295/023 , C07D295/027 , C07D295/03 , C07C213/02
CPC分类号： C07C209/52 , C07B43/04 , C07C209/68 , C07C213/00 , C07C213/02 , C07C253/30 , C07C2601/14 , C07D295/023 , C07D295/027 , C07D295/03 , C07C211/04 , C07C211/08 , C07C215/08 , C07C211/48 , C07C211/07 , C07C211/27 , C07C255/30
摘要： The present invention relates to a process for the preparation of amines, comprising the following steps: Reaction of a (i) amide acetal of the general formula (I), or (ii) ketene N,O-acetal of the general formula (II), or (iii) ester imide of the general formula (III) with H2 in the presence of a hydrogenation catalyst, where catalyst and amide acetal or ketene N,O-acetal or ester imide are used in a molar ratio of from 1:10 to 1:100 000 and where a hydrogen pressure of from 0.1 bar to 200 bar is established and where a temperature in the range of from 0° C. to 250° C. is established.

17. 发明申请

US20080287713A1 Halophospholanes And Their Preparation 失效
标题翻译： Halophospholanes及其制备
公开(公告)号：US20080287713A1
公开(公告)日：2008-11-20
申请号：US12091410
申请日：2006-10-04
申请人： Armin Borner , Jens Holz , Juan Almena , Renat Kadyrov , Axel Monsees , Thomas Riermeier
发明人： Armin Borner , Jens Holz , Juan Almena , Renat Kadyrov , Axel Monsees , Thomas Riermeier
IPC分类号： C07F9/6568
CPC分类号： C07F9/65683 , B01J31/2433
摘要： The present invention is directed to a process for preparing compounds of the general formula (I). Compounds of the general formula (I) are advantageous precursors for preparing phospholane catalysts, especially bisphospholane catalysts. The invention therefore likewise provides for the use of the substances in question for preparing these catalysts.
摘要翻译：本发明涉及制备通式（I）化合物的方法。通式（I）的化合物是制备磷脂催化剂，特别是双
磷脂催化剂的有利前体。因此，本发明同样提供了所讨论的物质用于制备这些催化剂的用途。

18. 发明授权

US07015342B2 Ferrocenyl ligands and method for the production of such ligands 失效
标题翻译：二茂铁基配体及其制备方法
公开(公告)号：US07015342B2
公开(公告)日：2006-03-21
申请号：US10511439
申请日：2003-04-17
申请人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
发明人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
IPC分类号： C07F17/00 , B01J31/00 , C07C5/02
CPC分类号： C07F17/02 , C07B53/00 , C07C67/303 , C07C231/18 , C07C233/47 , C07C69/67 , C07C69/34
摘要： The invention relates to ferrocenyl ligands of general formula (II), the Sfc,S-enantiomer or the Rfc,R-enantiomer of the ferrocenyl ligands of formula (II) being enriched, and a method for producing such ligands.
摘要翻译：本发明涉及通式（II）的二茂铁基配体，式（II）的二茂铁基配体的S-对映异构体或RΨC，），以及这种配体的制造方法。

19. 发明授权

US07009065B2 Ferrocenyl ligands and the use thereof in catalysis 失效
标题翻译：二茂铁基配体及其在催化中的应用
公开(公告)号：US07009065B2
公开(公告)日：2006-03-07
申请号：US10506255
申请日：2003-03-10
申请人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
发明人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
IPC分类号： C07F17/00 , B01J31/00 , C07C5/02
CPC分类号： C07F17/02
摘要： The invention relates to bidentate organophosphorous ferrocenyl ligands containing ligands of formula (I), to their complex compounds and to their utilization in catalytic processes.
摘要翻译：本发明涉及含有式（I）配位体的双齿有机亚磷酸二茂铁基配体，其复合化合物及其在催化过程中的应用。

20. 发明授权

US08618328B2 Cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions 有权
标题翻译：环戊二烯基，茚基或芴基取代的膦化合物及其在催化反应中的应用
公开(公告)号：US08618328B2
公开(公告)日：2013-12-31
申请号：US13437415
申请日：2012-04-02
申请人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
发明人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
IPC分类号： C07F9/02
CPC分类号： C07C2/88 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2231/4227 , B01J2231/4266 , B01J2231/4283 , B01J2531/824 , C07C17/26 , C07C41/30 , C07C45/62 , C07C201/12 , C07C209/68 , C07C253/30 , C07D213/16 , C07D213/22 , C07D213/73 , C07D265/30 , C07F9/5022 , C07F9/5442
摘要： Disclosed herein are phosphine compounds represented by the general formula (4): and corresponding phosphonium salts represented by the general formula (4a): Also disclosed are processes for the preparation of these phosphines and phosphonium salts as well as their use as ligands in catalytic reactions.
摘要翻译：本文公开了由通式（4）表示的膦化合物：和由通式（4a）表示的相应的鏻盐：还公开了制备这些膦和鏻盐以及它们在催化反应中作为配体的用途的方法。

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