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11. 发明授权

US08987517B2 Process for preparing cycloaliphatic amines 有权
标题翻译：脂环族胺的制备方法
公开(公告)号：US08987517B2
公开(公告)日：2015-03-24
申请号：US12863137
申请日：2009-01-14
申请人： Joachim Pfeffinger , Willi Doell
发明人： Joachim Pfeffinger , Willi Doell
IPC分类号： C07C211/35 , C07C211/36 , C08K5/14 , C07C209/72 , C07C211/44
CPC分类号： C08K5/14 , C07C209/72 , C07C211/44 , C07C2601/14 , C08K5/17 , Y02P20/582 , C07C211/35 , C07C211/36
摘要： A process for preparing cycloaliphatic amines by hydrogenating the corresponding aromatic compounds with hydrogen-comprising gas at a temperature of from 30 to 280° C. and a pressure of 50-350 bar, in the presence of ruthenium catalysts. The hydrogenation is performed in the presence of from 1% by weight to 500% by weight, based on the catalyst calculated as elemental ruthenium (Ru), of suspended inorganic additives, and to the use of the cycloaliphatic amines as a synthesis unit.
摘要翻译：在钌催化剂存在下，在30〜280℃的温度和50〜350巴的压力下，用含氢气体氢化相应的芳族化合物，制备环脂族胺的方法。基于以元素钌（Ru）计算的催化剂，悬浮的无机添加剂的1重量％至500重量％的存在，以及使用脂环族胺作为合成单元进行氢化。

12. 发明申请

US20120289747A1 CATALYSTS FOR THE HYDROGENATION OF AROMATIC AMINES 审中-公开
标题翻译：催化剂用于加氢芳族氨基酸
公开(公告)号：US20120289747A1
公开(公告)日：2012-11-15
申请号：US13468689
申请日：2012-05-10
申请人： Lucia Königsmann , Thomas Heidemann , Martin Bock , Joachim Pfeffinger , Benjamin Koch
发明人： Lucia Königsmann , Thomas Heidemann , Martin Bock , Joachim Pfeffinger , Benjamin Koch
IPC分类号： C07C209/72 , B01J21/08
CPC分类号： C07C209/72 , B01J21/08 , B01J23/462 , B01J35/0013 , B01J35/006 , B01J35/0066 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J37/0205 , B01J37/18 , C07C2601/14 , C07C211/35 , C07C211/36
摘要： The present invention relates to a catalyst comprising 4% by weight of ruthenium (Ru) or more and a support material comprising silicon dioxide, wherein the nitrogen content of the catalyst after the last drying or calcination is in the range from 1 to 3% by weight, and also catalyst precursors thereof. The present patent application further relates to a process for producing an Ru-comprising catalyst, which comprises the steps impregnation, drying, calcination and reduction. In addition, the present patent application relates to a process for hydrogenating organic substances in the presence of catalysts of the invention or catalysts produced according to the invention, and also a process for producing downstream products from cycloaliphatic amines prepared according to the invention.
摘要翻译：本发明涉及包含4重量％的钌（Ru）或更多的催化剂和包含二氧化硅的载体材料，其中在最后的干燥或煅烧之后的催化剂的氮含量在1至3％的范围内由重量，以及它们的催化剂前体。本专利申请还涉及一种制备含Ru催化剂的方法，该方法包括浸渍，干燥，煅烧和还原的步骤。此外，本专利申请涉及在本发明的催化剂或根据本发明制备的催化剂存在下氢化有机物的方法，以及由根据本发明制备的脂环族胺生产下游产物的方法。

13. 发明授权

US06790995B2 Preparation of primary and secondary amines from nitriles 失效
标题翻译：从腈制备伯胺和仲胺
公开(公告)号：US06790995B2
公开(公告)日：2004-09-14
申请号：US10033912
申请日：2002-01-03
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C213/02 , C07C209/48 , C07C211/11 , C07C215/08
摘要： Mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) where X is C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycloalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino. C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 50 to 250° C. and pressures of from 5 to 350 bar in the presence of a Pd-containing catalyst comprising, based on the total weight of the catalyst, from 0.1 to 10% by weight of Pd on a support.
摘要翻译：式（I）的伯胺和式（II）的仲胺的混合物，其中X是可以未被取代或被C 1-20烷基取代的C 1-20 - 烷基，C 2-20 - 烯基或C 3-8 - 环烷基，C 3-8 - 环烷基，C 4-20 - 烷基环烷基，C 4-20 - 环烷基烷基，C 2-20烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20羟烷基，氨基，C 1-20烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基。 C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，C 3-8 - 环烷氧基，芳氧基和/或C 2-8烷氧基羰基，（III）与氢气在50-250℃下反应，压力为5-350巴，在含Pd催化剂的存在下，基于催化剂的总重量计，为0.1-10重量％的Pd 在支持上。

14. 发明授权

US06525223B2 Preparation of secondary amines from nitriles 失效
标题翻译：从腈制备仲胺
公开(公告)号：US06525223B2
公开(公告)日：2003-02-25
申请号：US10026900
申请日：2001-12-27
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/11
摘要： Secondary amines of the formula (II) (X—CH2—)2NH (II) where X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl group which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycoalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino, C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl, are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 20 to 250° C. and pressures of from 60 to 350 bar in the presence of an Rh-containing catalyst comprising from 0.1 to 5% by weight, based on the total weight of the catalyst, of Rh on a support to give mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) and returning at least part of the primary amines separated from the mixtures obtained to the reaction.
摘要翻译：式（II）的仲胺，其中X是可以是未取代的或被C 1-20 - 烷基，C 3-8 - 环烷基，C 4 -C 18环烷基，C 3-8 - C 20-20烷基烷基，C 2-20 - 烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20 - 羟基烷基，氨基， C 1-20 - 烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基，C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，环烷氧基，芳氧基和/或C 2-8 - 烷氧基羰基，通过在含Rh的催化剂存在下，使式（III）的腈与20至250℃的压力和60至350巴的压力反应来制备包含基于催化剂总重量的0.1至5重量％的Rh在载体上以得到式（I）的伯胺和式（II）的仲胺的混合物，并使至少部分从获得的混合物中分离出伯胺反应。

15. 发明授权

US5788743A Selective separation and recovery of chlorine from gas mixtures 失效
标题翻译：从气体混合物中选择性分离和回收氯
公开(公告)号：US5788743A
公开(公告)日：1998-08-04
申请号：US711907
申请日：1996-09-12
申请人： Otto Watzenberger , Joachim Pfeffinger
发明人： Otto Watzenberger , Joachim Pfeffinger
IPC分类号： C01B7/01 , C01B7/04 , C01B7/07 , B01D53/047 , B01D53/14
CPC分类号： C01B7/04 , B01D3/141 , C01B7/0743 , Y02P20/22
摘要： A process for separating chlorine of high purity from a chlorine-containing feed gas by absorption of the chlorine using an inert absorbent and downstream desorption of the chlorine from the absorbent/chlorine mixture drawn off from the absorption stage by the supply of mixture to a desorption distillation column which is coupled to a chlorine separation column in such a way that the top of the chlorine separation column and an upper section of the desorption distillation column and a lower section of the desorption distillation column and the bottom of the chlorine separation column are connected to one another on both the gas and the liquid side, the absorbent/chlorine mixture being supplied exclusively to the desorption distillation column, and high-purity chlorine being drawn off from a middle region of the chlorine separation column.
摘要翻译：通过使用惰性吸收剂吸收氯和从吸收阶段从吸收阶段排出的吸收/氯混合物的氯的下游解吸，通过将混合物供给到解吸附物中，从高氯气进料气体中分离出高纯度氯的方法蒸馏塔，其与氯分离塔结合，使得氯分离塔的顶部和解吸蒸馏塔的上部以及解吸蒸馏塔的下部和氯分离塔的底部相连接在气体和液体两侧彼此相连，吸收/氯混合物专门提供给解吸蒸馏塔，并且高纯度氯从氯分离塔的中间区域排出。

16. 发明申请

US20100292510A1 PROCESS FOR PREPARING CYCLOALIPHATIC AMINES 有权
标题翻译：制备环磷酰胺的方法
公开(公告)号：US20100292510A1
公开(公告)日：2010-11-18
申请号：US12863137
申请日：2009-01-14
申请人： Joachim Pfeffinger , Willi Doell
发明人： Joachim Pfeffinger , Willi Doell
IPC分类号： C07C211/44
CPC分类号： C08K5/14 , C07C209/72 , C07C211/44 , C07C2601/14 , C08K5/17 , Y02P20/582 , C07C211/35 , C07C211/36
摘要： A process for preparing cycloaliphatic amines by hydrogenating the corresponding aromatic compounds with hydrogen-comprising gas at a temperature of from 30 to 280° C. and a pressure of 50-350 bar, in the presence of ruthenium catalysts. The hydrogenation is performed in the presence of from 1% by weight to 500% by weight, based on the catalyst calculated as elemental ruthenium (Ru), of suspended inorganic additives, and to the use of the cycloaliphatic amines as a synthesis unit.
摘要翻译：在钌催化剂存在下，在30〜280℃的温度和50〜350巴的压力下，用含氢气体氢化相应的芳族化合物，制备环脂族胺的方法。基于以元素钌（Ru）计算的催化剂，悬浮的无机添加剂的1重量％至500重量％的存在，以及使用脂环族胺作为合成单元进行氢化。

17. 发明授权

US06750365B2 Thermal dissociation of allophanates 有权
标题翻译：脲基甲酸酯的热解离
公开(公告)号：US06750365B2
公开(公告)日：2004-06-15
申请号：US10133329
申请日：2002-04-29
申请人： Gerhard Laqua , Matthias Klötzer , Volker Krase , Peter Pfab , Joachim Pfeffinger , Andreas Schmidt
发明人： Gerhard Laqua , Matthias Klötzer , Volker Krase , Peter Pfab , Joachim Pfeffinger , Andreas Schmidt
IPC分类号： C07C26100
CPC分类号： C07C263/00 , C07C269/00 , C07C265/04 , C07C271/12
摘要： The present invention relates to a process for the dissociation of allophanates, in which a thermal dissociation is carried out in a reaction vessel and the gaseous dissociation products obtained are removed from the reaction vessel using an inert carrier gas or the vapor of a liquid as stripping medium and are condensed.
摘要翻译：本发明涉及一种用于解离脲基甲酸酯的方法，其中在反应容器中进行热解离，并且使用惰性载气或液体的蒸气作为汽提从所述反应容器中除去所得的气体解离产物中等浓度。

18. 发明授权

US06723880B2 Preparation of secondary amines from primary amines 有权
标题翻译：从伯胺制备仲胺
公开(公告)号：US06723880B2
公开(公告)日：2004-04-20
申请号：US10173774
申请日：2002-06-19
申请人： Peter Neumann , Johann-Peter Melder , Christoph Benisch , Arthur Höhn , Joachim Pfeffinger
发明人： Peter Neumann , Johann-Peter Melder , Christoph Benisch , Arthur Höhn , Joachim Pfeffinger
IPC分类号： C07D41702
CPC分类号： C07C209/64 , C07C211/13
摘要： A process for producing secondary amines of the formula R1R2N—A—NH—A—NR1R2, where R1 and R2 are linear or branched C1-20-alkyl radicals, optionally substituted with from 1 to 5 phenyl groups; or cyclohexyl radicals; or together with the nitrogen atom to which they are bound, form a 3 to 7 membered saturated ring, optionally containing further hetero atoms selected from the group consisting of N, O and S, and optionally substituted with from 1 to 5 C1-2-alkyl groups. The group A is a linear or branched C2-20-alkylene group, optionally containing from 1 to 5 phenylene groups; or a radical of the formula —CH(R3)—[CH2]k—X—[CH(R3)—[CH2]k—X]m—CH(R3)—[CH2]k—, where R3 is H or CH3, X is O, S or NR4, R4 is H or a linear or branched C1-4-alkyl group, k is 1 or 2, and m is an integer from 0 to 4; or a group of the formula where n, o, p, and q are, independently, integers from 1 to 4. In this process, primary amines of the formula R1R2N—A—NH2 are reacted in the presence of hydrogen and a catalyst comprising at least one element or compound of an element of groups VIII and IB of the Periodic Table, preferably group IB, and in particular, Cu. Through this process, a high selectivity of the desired amines can be achieved.
摘要翻译：一种制备式R 1 R 2 NA-NH-A-NR 1 R 2的仲胺的方法，其中R 1和R 2是直链或支链C 1-20 - 任选被1至5个苯基取代的烷基; 或环己基; 或与其结合的氮原子一起形成3至7元饱和环，任选地含有选自N，O和S的另外的杂原子，并且任选被1至5个C 1-2 - 烷基。基团A是任选含有1至5个亚苯基的直链或支链C 2-20 - 亚烷基; 或式-CH（R 3） - [CH 2] k X- [CH（R 3） - [CH 2] k X] m -CH（R 3） - [CH 2] k - 的基团，其中R 3是H或CH 3，X是O，S或NR 4，R 4是H或直链或支链C 1-4 - 烷基，k是1或2，m是整数从0到4; 或一组式n，o，p和q独立地为1至4的整数。在该方法中，式R 1 R 2 NA-NH 2的伯胺在存在下反应氢和包含元素周期表第VIII和IB族元素的至少一种元素或化合物的催化剂，优选IB族，特别是Cu。通过该方法，可以实现所需胺的高选择性。

19. 发明授权

US06576788B1 METHOD FOR PRODUCING MIXTURES CONSISTING OF DIPHENYLMETHANE DIISOCYANATES AND POLYPHENYLENE-POLYMETHYLENE-POLYISOCYANATES CONTAINING A REDUCED AMOUNT OF CHLORINATED SECONDARY PRODUCTS AND WITH A REDUCED IODINE COLOR INDEX 有权
标题翻译：生产含二苯甲基二异氰酸酯的混合物的方法和含有减少的氯化二次产物和减少的碘颜色指数的聚苯乙烯 - 聚乙烯 - 聚异氰酸酯
公开(公告)号：US06576788B1
公开(公告)日：2003-06-10
申请号：US09673326
申请日：2000-10-13
申请人： Ulrich Penzel , Volker Scharr , Dieter Starosta , Hilmar Boesel , Eckhard Ströfer , Joachim Pfeffinger , Frank Poplow , Jürgen Dosch , Hans Volkmar Schwarz , Fritz Näumann , Peter van den Abeel , Jan Jacobs , Filip Nevejans , Willy van Pee
发明人： Ulrich Penzel , Volker Scharr , Dieter Starosta , Hilmar Boesel , Eckhard Ströfer , Joachim Pfeffinger , Frank Poplow , Jürgen Dosch , Hans Volkmar Schwarz , Fritz Näumann , Peter van den Abeel , Jan Jacobs , Filip Nevejans , Willy van Pee
IPC分类号： C07C24914
CPC分类号： C07C263/10 , C07C263/20 , C07C265/14
摘要： In a process for preparing mixtures of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates having a reduced content of chlorinated by-products and a reduced iodine color number by two-stage reaction of the corresponding mixtures of diphenylmethanediamines and polyphenylpolymethylenepolyamines with phosgene in the presence of at least one inert organic solvent at elevated temperature, separation of the excess phosgene and solvent after the phosgenation is complete and thermal treatment of the reaction product, the mass ratios of phosgene to hydrogen chloride in the residence time apparatus of the second stage of the phosgenation are at the same time 10-30:1 in the liquid phase and 1-10:1 in the gas phase.
摘要翻译：在二氯甲烷二异氰酸酯和多苯基聚亚甲基多异氰酸酯的混合物的制备方法中，其中氯化副产物含量降低，碘色数降低，二苯基甲烷二胺与多苯基多亚甲基多胺与光气的相应混合物在至少一种惰性的存在下进行两步反应高温下的有机溶剂，光气化后过剩的光气和溶剂的分离完成，反应产物的热处理，光气化第二阶段的停留时间装置中光气与氯化氢的质量比相同时间为10-30：1，液相为1-10：1。

20. 发明授权

US06403845B1 Preparation of pentanediols from alkoxydihydropyrans 失效
标题翻译：从烷氧基二氢吡喃制备戊二醇
公开(公告)号：US06403845B1
公开(公告)日：2002-06-11
申请号：US09625487
申请日：2000-07-25
申请人： Joachim Pfeffinger , Peter Wahl , Jan Nouwen , Karsten Eller , Arthur Höhn , Jürgen Hunger
发明人： Joachim Pfeffinger , Peter Wahl , Jan Nouwen , Karsten Eller , Arthur Höhn , Jürgen Hunger
IPC分类号： C07C2700
CPC分类号： C07C29/132 , C07C29/141 , C07C31/20
摘要： are prepared by single-stage reaction of alkoxydihydropyrans of the formula (II) with water and hydrogen in the presence of a catalyst comprising oxides of nickel, zirconium and copper. In the formulae (I) and (II), R, R′, R″, R′″ can be identical or different and are each hydrogen or a linear or branched saturated hydrocarbon radical having from 1 to 20 carbon atoms in which the hydrocarbon chain may contain O, S and N as heteroatoms and which may be monosubstituted or polysubstituted by hydroxy, thiol or amino groups or halogens.
摘要翻译：在式（I）和（II）的催化剂存在下，通过式（II）的烷氧基二氢吡喃与水和氢的单步反应制备。在式（I）和（II）中，R，R' R“，R”可以相同或不同，并且各自为氢或具有1至20个碳原子的直链或支链饱和烃基，其中烃链可以含有O，S和N作为杂原子，并且其可以是被羟基，硫醇或氨基或卤素单取代或多取代。

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