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11. 发明授权

US06855764B2 Method for producing self- emulsifiable aqueous polyurethane resins having improved characteristics 失效
标题翻译：具有改进特性的自乳化水性聚氨酯树脂的制造方法
公开(公告)号：US06855764B2
公开(公告)日：2005-02-15
申请号：US10129291
申请日：2000-12-07
申请人： Alois Maier , Stefan Ingrisch , Alfred Kern
发明人： Alois Maier , Stefan Ingrisch , Alfred Kern
IPC分类号： C08G18/08 , C08G18/12 , C08G18/66 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/6674 , C08G18/0823 , C08G18/12 , C08G18/348
摘要： A method for producing self-emulsifiable, aqueous polyurethane resins by a) preparing a premix of polyol component including a least one diol having a molar mass of 500 to 5,000 Dalton, at least one polyhydroxyalkane at least one anionically modifiable dihydroxyalkane-carboxylic acid and 0 to 9 parts by weight of a solvent component in desired ratios; b) reacting a polyisocyanate component the premix from stage a) to give a polyurethane preadduct, c) reacting the polyurethane preadduct from stage b) with either the premix from stage a) or with an anionically modifiable dihydroxyalkanecarboxylic acid to give a polyurethane prepolymer; d) mixing the polyurethane prepolymer from stage c) with a prepared mixture of water, a neutralizing component and an antifoam component; and thereafter or simultaneously reacting the aqueous polyurethane prepolymer from stage d) with a chain-extending component which is diluted with water.
摘要翻译：一种制备自乳化的水性聚氨酯树脂的方法，该方法是：a）制备包含摩尔质量为500-5,000道尔顿的至少一种二醇的多元醇组分的预混物，至少一种聚羟基烷烃至少一种阴离子可修饰的二羟基烷烃羧酸和0 至9重量份的所需比例的溶剂组分; b）将多异氰酸酯组分与步骤a）的预混物反应得到聚氨酯预加成物，c）使来自阶段b）的聚氨酯预加合物与来自阶段a）的预混物或与阴离子可修饰的二羟基烷烃羧酸反应得到聚氨酯预聚物; d）将来自阶段c）的聚氨酯预聚物与制备的水，中和组分和消泡剂组分的混合物混合; 然后或同时使来自阶段d）的水性聚氨酯预聚物与用水稀释的链延伸组分反应。

12. 发明申请

US20090054588A1 Fluoride-modified additive for cementitious products, process for its preparation and use thereof 审中-公开
标题翻译：用于水泥质产品的氟化物改性添加剂，其制备方法和用途
公开(公告)号：US20090054588A1
公开(公告)日：2009-02-26
申请号：US12279605
申请日：2007-03-09
申请人： Alois Maier , Norbert Steidl , Johann Huber , Christian Huber , Marita Staudhammer
发明人： Alois Maier , Norbert Steidl , Johann Huber , Christian Huber , Marita Staudhammer
IPC分类号： C04B28/02
CPC分类号： C08G18/2885 , C04B24/282 , C04B24/288 , C04B24/32 , C04B28/04 , C04B2111/203 , C04B2111/2038 , C04B2111/25 , C04B2111/26 , C04B2111/27 , C08G18/10 , C08G18/283 , C08G18/36 , C08G18/792 , C08G18/8051 , Y02W30/92 , C04B14/06 , C04B18/08 , C04B20/0076 , C04B24/267 , C08G18/302
摘要： A fluoromodified admixture containing isocyanate and urethane and/or urea groups is described. Surprisingly, it has been found that the fluoromodified admixture according to the invention is outstandingly suitable even at a very low dosage for the permanent hydrophobic and/or oleophobic and/or dirt-repellent in-bulk finishing of products based on inorganic or hydraulic or mineral binders, without the fundamental property profile (e.g. compressive and flexural tensile strengths) of these products being substantially influenced. Moreover, it was not to be foreseen that in the case of the products treated with the fluoromodified admixtures according to the invention (e.g. hardened building material compositions) a markedly lower water absorption (avoidance of frost damage and corrosion) and a suppression of bleeding on the surfaces (avoidance of visual impairment) are to be observed. Furthermore, it could not be expected that in spite of the high fluorine modification an adequate self-dispersibility is afforded.
摘要翻译：描述了含有异氰酸酯和氨基甲酸酯和/或脲基团的氟改性混合物。令人惊奇的是，已经发现，基于无机或水力或矿物质的产品，即使在非常低的剂量下，基于无机或水力或矿物的产品的永久性疏水和/或疏油和/或污垢排斥的整体加工，本发明的氟改性混合物是显着的没有基本影响的这些产品的基本性质（例如压缩和弯曲拉伸强度）的粘合剂。此外，不要指出，在使用根据本发明的含氟改性混合物处理的产品（例如硬化的建筑材料组合物）的情况下，显着降低吸水率（避免霜冻损伤和腐蚀）和抑制出血要观察表面（避免视力损伤）。此外，不能指望尽管氟改性高，但仍具有足够的自分散性。

13. 发明授权

US06462127B1 Self-crosslinking polyurethane polymer hybrid dispersion 失效
标题翻译：自交联聚氨酯聚合物混合分散体
公开(公告)号：US06462127B1
公开(公告)日：2002-10-08
申请号：US09743116
申请日：2001-01-05
申请人： Stefan Ingrisch , Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Alfred Kern , Josef Weichmann
发明人： Stefan Ingrisch , Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Alfred Kern , Josef Weichmann
IPC分类号： C08J300
CPC分类号： C08G18/12 , C08F283/006 , C08G18/0823 , C08G18/6659 , C09D175/06 , C08G18/3228 , C08L2666/04
摘要： A self-crosslinking polyurethane polymer hybrid dispersion based on oxidatively drying polyols having a high degree of film hardness is described, which is characterized in that it contains the reaction components claimed. The advantages of the polyurethane polymer hybrid dispersion according to the invention, such as a high degree of hardness in combination with high flexibility of the tear-free films, good resistance to chemicals, high stability of the dispersions in a wide pH range, good stability in the freezing and thawing cycle and the use of economical raw materials, are achieved in a simplified synthesis pathway wityout subsequent chemical crosslinking, and simultaneously with a low content of organic solvent (≦4% by weight) and good film formation at temperatures of ≧+10° C.
摘要翻译：描述了一种基于氧化干燥具有高硬度膜的多元醇的自交联聚氨酯聚合物混合分散体，其特征在于其含有所要求的反应组分。根据本发明的聚氨酯聚合物混合分散体的优点，如硬度高，结合无撕裂膜的高柔性，耐化学性好，分散体在宽pH范围内的稳定性高，稳定性好在冷冻和解冻循环中使用经济的原料，在简化的合成途径中实现随后的化学交联，同时具有低含量的有机溶剂（<= 4重量％）和在 > = + 10°C

14. 发明申请

US20100285311A1 Dual component (aqueous) hybrid reactive resin system, method for production and use thereof 审中-公开
标题翻译：双组分（水性）混合反应性树脂体系，其生产和使用方法
公开(公告)号：US20100285311A1
公开(公告)日：2010-11-11
申请号：US12279081
申请日：2007-04-03
申请人： Norbert Steidl , Alois Maier , Michael Schroers , Roswitha Waldherr
发明人： Norbert Steidl , Alois Maier , Michael Schroers , Roswitha Waldherr
IPC分类号： B32B27/38 , C08L75/04 , C04B28/00 , C08K3/22 , C08K3/30 , C08K5/12 , C08K5/11 , C08K5/101 , C08K5/357 , B32B27/06 , B32B13/12
CPC分类号： C08G18/2845 , C08G18/4244 , C09D163/00 , Y10T428/269 , Y10T428/273 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , C08L2666/14
摘要： A dual component (aqueous) hybrid reactive system obtained by a) the production of an epoxy-functional (aqueous) binding agent component (I) with an epoxide equivalent of 100 to 12,500 g/eq, and average molecular mass of 200 to 25,000 Daltons and a viscosity of 1,000 to 15,000 mPas 920° C., Brookfield) and b) the production of a (latent) amino-functional hardener component (II).
摘要翻译：通过以下方法获得的双组分（水性）混合反应体系：a）制备环氧官能（水性）结合剂组分（I），其环氧当量为100至12,500g / eq，平均分子量为200至25,000道尔顿粘度为1000至15,000mPas 920℃，Brookfield）和b）（潜伏）氨基官能的硬化剂组分（II）的生产。

15. 发明授权

US07501472B2 Aqueous fluoromodified polyurethane system for anti-graffiti and anti-soiling coatings 失效
标题翻译：水性氟改性聚氨酯体系，用于防涂鸦和防污涂料
公开(公告)号：US07501472B2
公开(公告)日：2009-03-10
申请号：US10485617
申请日：2003-02-26
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Wolfgang Hiller , Rupert Stadler
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Wolfgang Hiller , Rupert Stadler
IPC分类号： C08J3/03 , C08G18/10 , C08G18/12 , C08G18/32 , C09D175/04
CPC分类号： C09D175/04 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/2885 , C08G18/3275 , C08G18/3812 , C08G18/44 , C08G18/6659 , C08G18/3271
摘要： An aqueous fluoromodified polyurethane system for one- or two-component anti-graffiti and anti-soiling coatings is prepared by (a) preparing a binder component based on an aqueous solution or dispersion of optionally hydroxy- and/or amino-functional oligourethanes and/or polyurethanes having fluorinated side chains, and, optionally, (b) subsequently reacting the binder component with a crosslinker.
摘要翻译：通过（a）基于任选的羟基和/或氨基官能的低聚氨酯和/或氨基官能的低聚氨酯的水溶液或分散体制备粘合剂组分来制备用于单组分或双组分防涂层和防污涂料的含水氟改性聚氨酯体系和/ 或具有氟化侧链的聚氨酯，和任选地（b）随后使粘合剂组分与交联剂反应。

16. 发明授权

US07414092B2 Electrosterically stabilized aqueous polyurethane resins, method for the production thereof, and use thereof 失效
标题翻译：电化学稳定的水性聚氨酯树脂，其制备方法及其用途
公开(公告)号：US07414092B2
公开(公告)日：2008-08-19
申请号：US10551526
申请日：2004-04-01
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Christian Huber , Sascha Raspl
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Christian Huber , Sascha Raspl
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/283 , C08G18/3275 , C08G18/4854 , C08G18/6692 , C09D175/04 , C08G18/50
摘要： Stabilized polyurethane resins and methods for their preparation are disclosed.
摘要翻译：公开了稳定的聚氨酯树脂及其制备方法。

17. 发明申请

US20050027092A1 Aqueous, highly cross-linked two-component polyurethane coating system, method for the production and use thereof 有权
标题翻译：水性高交联双组分聚氨酯涂料体系，其制备和使用方法
公开(公告)号：US20050027092A1
公开(公告)日：2005-02-03
申请号：US10830743
申请日：2004-04-23
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
IPC分类号： C08G18/08 , C08G18/12 , C08G18/42 , C08G18/44 , C08G18/66 , C09D175/04 , C08G18/00
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/4277 , C08G18/44 , C08G18/6659 , C08G18/792 , C08G18/3206 , C08G18/3275 , C08G18/348
摘要： An aqueous highly cross-linked two-component polyurethane coating system is described with reduced hydrophilicity and improved resistance to chemicals which can be obtained by a) producing a binder component based on an aqueous solution or dispersion of low-molecular hydroxyfunctional and/or aminofunctional oligourethanes or polyurethanes and b) by subsequently reacting the binder component a) with a cross-linking component (H) in a ratio of 3:1 to 5:1, wherein water-dispersible polyisocyanates are used as the cross-linking component (H).
摘要翻译：描述了一种水性高度交联的双组分聚氨酯涂料体系，其具有降低的亲水性和改善的抗化学药品性能，其可以通过以下方式获得：a）基于低分子量羟基官能团和/或氨基官能低聚氨酯的水溶液或分散体生产粘合剂组分或聚氨酯，和b）通过随后使粘合剂组分a）与3:1至5:1的比例的交联组分（H）反应，其中使用水分散性多异氰酸酯作为交联组分（H）。

18. 发明授权

US06825268B2 Polyurethane (polymer hybrid) dispersion with reduced hydrophilicity, method for producing the same and the use thereof 失效
标题翻译：具有降低的亲水性的聚氨酯（聚合物混合物）分散体，其制备方法及其用途
公开(公告)号：US06825268B2
公开(公告)日：2004-11-30
申请号：US10220089
申请日：2002-11-26
申请人： Alois Maier , Norbert Steidl , Alfred Kern , Franz Wolfertstetter , Gerhard Reusmann , Frank Reichel
发明人： Alois Maier , Norbert Steidl , Alfred Kern , Franz Wolfertstetter , Gerhard Reusmann , Frank Reichel
IPC分类号： C08G1848
CPC分类号： C09D153/00 , C08G18/0823 , C08G18/12 , C08G18/4854 , C08G18/4879 , C08G18/6659 , C08L53/00 , C08L2666/02 , C09D175/04 , C09J153/00 , C08G18/3228 , C08L2666/14 , C08L2666/24
摘要： Polyurethane or polyurethane polymer hybrid dispersions, with reduced hydrophilicity and methods for preparing and using them are disclosed.
摘要翻译：公开了具有降低的亲水性的聚氨酯或聚氨酯聚合物混合分散体及其制备和使用方法。

19. 发明申请

US20090240004A1 FUNCTIONALIZED POLYURETHANE RESIN, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
标题翻译：功能性聚氨酯树脂，其生产方法及其用途
公开(公告)号：US20090240004A1
公开(公告)日：2009-09-24
申请号：US12441589
申请日：2007-09-04
申请人： Alois Maier , Norbert Steidl , Christian Huber , Helmut Mack , Johann Huber , Thomas Schuhbeck , Franz Wolfertetter
发明人： Alois Maier , Norbert Steidl , Christian Huber , Helmut Mack , Johann Huber , Thomas Schuhbeck , Franz Wolfertetter
IPC分类号： C08G71/04
CPC分类号： C08G18/3812 , C08G18/0823 , C08G18/10 , C08G18/2885 , C08G18/792 , C09D175/04 , D21H27/26 , C08G18/3275 , C08G18/2865
摘要： Disclosed is a functionalized polyurethane resin containing a binder component, a hardener component and, optionally, a formulation component. The binder component consists essentially of urethane dispersions with defined structural components which, in turn, consist of special reaction products. Such polyurethane resins are used for the production of fluorine-modified polyurethane coatings and generally in construction or industrial applications for the permanent oil-, water- and dirt-resistant coating of mineral and non-mineral surfaces on the basis of, for example, hydraulically setting components.
摘要翻译：公开了含有粘合剂组分，硬化剂组分和任选的制剂组分的官能化聚氨酯树脂。粘合剂组分基本上由具有限定结构组分的氨基甲酸酯分散体组成，其又由特殊的反应产物组成。这种聚氨酯树脂用于生产氟改性聚氨酯涂料，一般用于建筑或工业应用中，用于矿物和非矿物表面的永久性耐油，防水和防污涂层，例如基于液压设置组件。

20. 发明授权

US07825210B2 Aqueous, highly cross-linked two-component polyurethane coating system, method for the production and use thereof 有权
标题翻译：水性高交联双组分聚氨酯涂料体系，其制备和使用方法
公开(公告)号：US07825210B2
公开(公告)日：2010-11-02
申请号：US10830743
申请日：2004-04-23
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
IPC分类号： C08G18/30 , C08G18/40 , C08G18/08
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/4277 , C08G18/44 , C08G18/6659 , C08G18/792 , C08G18/3206 , C08G18/3275 , C08G18/348
摘要： An aqueous highly cross-linked two-component polyurethane coating system is described with reduced hydrophilicity and improved resistance to chemicals which can be obtained by a) producing a binder component based on an aqueous solution or dispersion of low-molecular hydroxyfunctional and/or aminofunctional oligourethanes or polyurethanes and b) by subsequently reacting the binder component a) with a cross-linking component (H) in a ratio of 3:1 to 5:1, wherein water-dispersible polyisocyanates are used as the cross-linking component (H).
摘要翻译：描述了一种水性高度交联的双组分聚氨酯涂料体系，其具有降低的亲水性和改善的抗化学药品性能，其可以通过以下方式获得：a）基于低分子羟基官能和/或氨基官能的低聚氨酯的水溶液或分散体生产粘合剂组分或聚氨酯，和b）通过随后使粘合剂组分a）与3:1至5:1的比例的交联组分（H）反应，其中使用水分散性多异氰酸酯作为交联组分（H）。

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