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11. 发明授权

US4612133A Stable mixtures of chlorofluorocarbons and solvents and their use as heat transfer fluids 失效
标题翻译：氯氟烃和溶剂的稳定混合物及其作为传热流体的用途
公开(公告)号：US4612133A
公开(公告)日：1986-09-16
申请号：US752167
申请日：1985-07-03
申请人： Rene Bertocchio , Bernard Genest , Henri Mathais
发明人： Rene Bertocchio , Bernard Genest , Henri Mathais
IPC分类号： C09K5/04
CPC分类号： C09K5/047
摘要： Compositions for use as fluids in absorption heat pumps, which compositions comprise a chlorofluoro-hydrocarbon heat exchange fluid, an amide or glycol-ether solvent vehicle, and at least one metal salt of an alkylarylsulfonate which stabilizes the fluid against decomposition, together with use of the compositions in absorption heat pumps.
摘要翻译：用作吸收式热泵中的流体的组合物，该组合物包含氯氟烃热交换流体，酰胺或二醇醚溶剂载体，以及烷基芳基磺酸盐的至少一种金属盐，其使流体不会分解，并使用吸收式热泵组成。

12. 发明授权

US3941705A Fire extinguishing compositions containing fluorinated surfactants 失效
标题翻译：含氟表面活性剂的灭火组合物
公开(公告)号：US3941705A
公开(公告)日：1976-03-02
申请号：US559565
申请日：1975-03-18
申请人： Louis Foulletier , Rene Bertocchio
发明人： Louis Foulletier , Rene Bertocchio
IPC分类号： A62D1/02 , A62D1/00
CPC分类号： A62D1/0085 , Y10S516/06
摘要： A surface-active fluorinated composition characterized by the association therein of from 35% to about 60% of at least one surface-active ampholyte compound of the formula ##EQU1## wherein n is an integer between 1 and 20, a is a number between 2 and 10, R.sub.1 is an atom of hydrogen or an alkyl radical containing from 1 to 6 atoms of carbon, R.sub.2 and R.sub.3 are alkyl radicals containing from 1 to 3 atoms of carbon, at least one of which is the methyl radical and p and q are integers between 0 and 10; from about 20% to about 40% of at least one surface-active fluorinated non-ionic compound of the formulaC.sub.n F.sub.2n.sub.+1 -- (CH.sub.2).sub.a -- CO--O--(CH.sub.2 --CH.sub.2 --O).sub.m R.sub.4wherein n and a have the same meaning as above, m is an integer between 1 and 20 and R.sub.4 is an alkyl radical containing from 1 to 6 atoms of carbon; and from about 8% to about 40% of at least one amine salt compound of the formula ##EQU2## wherein X is the group CO or SO.sub.2 R.sub.1, R.sub.5 and R.sub.6 may be hydrogen atoms, alkyl radicals containing from 1 to 6 atoms of carbon, or the group ##EQU3## in which R.sub.2, R.sub.3, p and q have the values given above.
摘要翻译：一种表面活性氟化组合物，其特征在于其中含有35％至约60％的至少一种式R 2 C n F 2n + 1（CH 2）a-CON-（CH 2）p N +的表面活性两性电解质化合物 ---（CH2）qCOO - | R1R3其中n为1至20之间的整数，a为2至10之间的数，R1为氢原子或含有1至6个碳原子的烷基， R2和R3是含有1至3个碳原子的烷基，其中至少一个是甲基，p和q是0和10之间的整数; 约20％至约40％的至少一种式CnF2n + 1-（CH2）a-CO-O-（CH2-CH2-O）mR4的表面活性氟化非离子化合物，其中n和a具有 m为1〜20的整数，R 4为含有1〜6个碳原子的烷基; 和约8％至约40％的至少一种式R 1 C n F 2n + 1 - （CH 2）a -XO - HN - R 6 R 6的胺盐化合物，其中X为基团CO或SO 2 + L，R 1，R 5和R 6可以是氢原子，含有1至6个碳原子的烷基或基团R 2 - （CH 2）p N + - （CH 2）q -COOH - ，其中 R2，R3，p和q具有上面给出的值。

13. 发明授权

US6039845A Process for the purification of pentafluoroethane by extractive distillation 失效
标题翻译：通过萃取蒸馏纯化五氟乙烷的方法
公开(公告)号：US6039845A
公开(公告)日：2000-03-21
申请号：US2344
申请日：1998-01-02
申请人： Rene Bertocchio , Eric Lacroix , Sylvain Perdrieux
发明人： Rene Bertocchio , Eric Lacroix , Sylvain Perdrieux
IPC分类号： C07C17/386 , B01D3/34
CPC分类号： C07C17/386 , Y10S203/11
摘要： A process for the purification of pentafluoroethane (F125) containing chloropentafluoroethane (F115). The F125-F115 mixture to be purified is subjected to an extractive distillation, the extractant being a C.sub.5 -C.sub.8 perfluoroalkyl halide.
摘要翻译：一种用于纯化含有五氟乙烷（F115）的五氟乙烷（F125）的方法。将待纯化的F125-F115混合物进行萃取蒸馏，萃取剂为C5-C8全氟烷基卤化物。

14. 发明授权

US5917098A Preparation of 1,1,1,3,3-pentachlorobutane and 1,1,1,3,3-pentafluorobutane 失效
标题翻译： 1,1,1,3,3-五氯丁烷和1,1,1,3,3-五氟丁烷的制备
公开(公告)号：US5917098A
公开(公告)日：1999-06-29
申请号：US790757
申请日：1997-01-27
申请人： Rene Bertocchio , Andre Lantz , Laurent Wendlinger
发明人： Rene Bertocchio , Andre Lantz , Laurent Wendlinger
IPC分类号： B01J27/122 , B01J31/02 , C07B61/00 , C07C17/20 , C07C17/278 , C07C19/01 , C07C19/08 , C07C17/02
CPC分类号： C07C19/08 , C07C17/206 , C07C17/278
摘要： 1,1,1,3,3-Pentachlorobutane, whose fluorination leads to 1,1,1,3,3-pentafluorobutane, is prepared with high yield and selectivity by addition of carbon tetrachloride to 2-chloropropene in the presence of a copper salt and an amine.
摘要翻译：通过在铜的存在下向四氯化碳中加入四氯化碳，以高产率和选择性制备氟化得到1,1,1,3,3-五氟丁烷的1,1,1,3,3-五氯代丁烷盐和胺。

15. 发明授权

US5892137A Purification of pentafluroethane 失效
标题翻译：五氟乙烷的纯化
公开(公告)号：US5892137A
公开(公告)日：1999-04-06
申请号：US943182
申请日：1997-10-03
申请人： Rene Bertocchio , Andre Lantz
发明人： Rene Bertocchio , Andre Lantz
IPC分类号： C07C17/389 , C07C19/08 , C07C17/38
CPC分类号： C07C17/389
摘要： To remove the traces of chlorotrifluoroethylene (F1113) which are present in a pentafluoroethane (F125), the F125 is passed through a bed of active carbon.
摘要翻译：为了除去五氟乙烷（F125）中存在的三氟氯乙烯（F1113）痕迹，F125通过活性炭床。

16. 发明授权

US5650545A Synthesis of perfluoroalkyl iodides 失效
标题翻译：全氟烷基碘化物的合成
公开(公告)号：US5650545A
公开(公告)日：1997-07-22
申请号：US452759
申请日：1995-05-30
申请人： Rene Bertocchio , Patrick Lambert , Georges Lacote
发明人： Rene Bertocchio , Patrick Lambert , Georges Lacote
IPC分类号： C07C17/26 , C07C17/278 , C07C19/08 , C07C21/18
CPC分类号： C07C17/278 , Y02P20/582
摘要： The invention relates to a continuous process for the preparation of perfluoroalkyl iodides by thermal telomerization, in the gas phase, of tetrafluoroethylene with pentafluoroethyl iodide or heptafluoroisopropyl iodide in a tubular reactor.To improve the selectivity for a telomer of the desired extent, the telomers of lesser extent are recycled to at least one point in the reactor, which is situated between one-twentieth and three-quarters the length of the tube.
摘要翻译：本发明涉及通过在管式反应器中四氟乙烯与五氟乙基碘或七氟异丙基碘在气相中的热调聚来制备全氟烷基碘化物的连续方法。为了提高所需程度的调节物的选择性，较小程度的调节剂被再循环到反应器中的至少一个点，其位于管的长度的二十分之一到四分之三之间。

17. 发明授权

US5608129A Process for the purification of difluoromethane 失效
标题翻译：二氟甲烷纯化方法
公开(公告)号：US5608129A
公开(公告)日：1997-03-04
申请号：US534263
申请日：1995-09-26
申请人： Rene Bertocchio
发明人： Rene Bertocchio
IPC分类号： C07C19/08 , C07C17/389 , C07C17/38 , B01J20/34 , B01J38/64
CPC分类号： C07C17/389
摘要： To remove the traces of chlorofluoromethane present in a difluoromethane, the difluoromethane to be purified is passed over a 13X molecular sieve at a temperature of at least 60.degree. C.The sieve can be regenerated by washing with the aid of a solution of sodium or potassium carbonate and heating to high temperature under inert atmosphere or in vacuum.
摘要翻译：为了除去存在于二氟甲烷中的痕量的氯氟甲烷，待提纯的二氟甲烷在至少60℃的温度下通过13X分子筛。可以通过用钠或钾溶液洗涤来再生筛在惰性气氛或真空中加热至高温。

18. 发明授权

US5268516A Synthesis of perfluoroalkyl iodides 失效
标题翻译：全氟烷基碘化物的合成
公开(公告)号：US5268516A
公开(公告)日：1993-12-07
申请号：US3767
申请日：1993-01-13
申请人： Rene Bertocchio , Georges Lacote , Christophe Verge
发明人： Rene Bertocchio , Georges Lacote , Christophe Verge
IPC分类号： C07C17/26 , C07C17/278 , C07C19/08 , C07C17/04 , C07C21/185
CPC分类号： C07C17/278
摘要： The invention relates to a continuous process for the preparation of perfluoroalkyl iodides containing from 4 to 12 carbon atoms by thermal telomerization of tetrafluoroethylene by pentafluoroethyl iodide or heptafluoroisopropyl iodide in a tubular reactor.According to the invention, 30 to 75% of the tetrafluoroethylene is supplied at the head of the reactor; the remainder is introduced at a point in the reactor located between the 2/5 and 3/4 of the length of the tube.The proportion of undesirable heavy telomers is reduced in this way.
摘要翻译：本发明涉及通过四氟乙烯通过五氟乙基碘或七氟异丙基碘在管式反应器中的热调聚来制备含有4至12个碳原子的全氟烷基碘的连续方法。根据本发明，在反应器的头部供应30至75％的四氟乙烯; 剩余部分在反应器中位于管长度的2/5和3/4之间的点处引入。以这种方式减少不需要的重型调聚物的比例。

19. 发明授权

US4990277A Compositions based on chlorofluorinated ether and solvent and their application in absorption apparatus 失效
公开(公告)号：US4990277A
公开(公告)日：1991-02-05
申请号：US264072
申请日：1988-10-28
申请人： Laurence Rolland , Rene Bertocchio , Jacques Cheron
发明人： Laurence Rolland , Rene Bertocchio , Jacques Cheron
IPC分类号： C09K5/04
CPC分类号： C09K5/047
摘要： The invention relates to compositions which contain a chlorofluorinated ether and at least one solvent, and their use in thermal absorption apparatus for the generation of heat or cold.In the compositions according to the invention, the chlorofluorinated ether is 1-difluoromethoxy-1,1,2-trifluoro-2-chloroethane (enflurane: CF.sub.2 H-O-CF.sub.2 CHFCl) and the solvent is selected among aromatic esters and .omega.,.omega.'-dialkylated polyoxyethylene glycols.The present invention can be particularly applied in the heating and refrigeration areas using absorption systems such as, for example, heat pumps.

20. 发明授权

US4069158A Fire extinguishing compositions 失效
标题翻译：灭火组合物
公开(公告)号：US4069158A
公开(公告)日：1978-01-17
申请号：US678929
申请日：1976-04-21
申请人： Rene Bertocchio , Louis Foulletier
发明人： Rene Bertocchio , Louis Foulletier
IPC分类号： A62D1/00 , A62D1/02 , A62C1/00 , B01F17/30
CPC分类号： A62D1/0085 , A62D1/0042 , A62D1/0064 , Y10S516/06
摘要： Aqueous fire-extinguishing compositions comprising a mixture of (1) a nonionic surface-active agent, (2) a amphoteric surface active agent and (3) a fluorinated cationic surface active agent containing as a part of the molecule an aromatic radical.
摘要翻译：水性灭火组合物，其包含（1）非离子表面活性剂，（2）两性表面活性剂和（3）作为分子的一部分含有芳香族基团的氟化阳离子表面活性剂的混合物。

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