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    • 10. 发明授权
    • Polyfluoro compounds and method for preparing them
    • 多氟化合物及其制备方法
    • US4855025A
    • 1989-08-08
    • US111188
    • 1987-10-22
    • Martine GautierIsabelle RicoArmand LattesRene Bertocchio
    • Martine GautierIsabelle RicoArmand LattesRene Bertocchio
    • C07C53/21C07C233/12
    • C07C53/21
    • This invention relates to compounds which simultaneously contain a perfluorinated chain and a hydrogenated chain and which correspond to the general formula: ##STR1## in which R.sub.F is a perfluoroalkyl radical, m an integer from 0 to 2, R.sub.H an alkyl radical, X an OH or NR.sub.1 R.sub.2 group, and R.sub.1 and R.sub.2 are hydrogen atoms or methyl radicals. The amides (X=NR.sub.1 R.sub.2) are prepared by photoamidation of the polyfluoroolefins R.sub.F --(CH.sub.2).sub.p --CH.dbd.CH--C.sub.n H.sub.2n+1 where p is equal to 0 or 1 and n is an integer from 1 to 17, and the acids (X=OH) are prepared by hydrolysis of the amides thus obtained.The acids and their salts may be employed as surface-active agents or, as also the amides, as intermediates for the synthesis of such agents.
    • 本发明涉及同时含有全氟化链和氢化链的化合物,其对应于以下通式:其中RF是全氟烷基,m为0-2的整数,RH为烷基,X为OH 或NR1R2基团,R1和R2是氢原子或甲基。 酰胺(X = NR1R2)通过聚氟烯烃RF-(CH2)p-CH = CH-CnH2n + 1的光聚酰胺化制备,其中p等于0或1,n是1至17的整数,并且酸( X = OH)通过水解由此获得的酰胺制备。 酸和它们的盐可以用作表面活性剂,也可以作为酰胺用作合成这种试剂的中间体。