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11. 发明申请

US20100015188A1 CORE-SHELL-TYPE CERIUM OXIDE MICROPARTICLE, DISPERSION SOLUTION COMPRISING THE MICROPARTICLE, AND PROCESS FOR PRODUCTION OF THE MICROPARTICLE OR DISPERSION SOLUTION 有权
标题翻译：核心型氧化铈微球，包含微生物的分散溶液，以及微生物或分散液的生产方法
公开(公告)号：US20100015188A1
公开(公告)日：2010-01-21
申请号：US12444799
申请日：2007-10-09
申请人： Noriya Izu , Ichiro Matsubara , Woosuck Shin , Toshio Itoh
发明人： Noriya Izu , Ichiro Matsubara , Woosuck Shin , Toshio Itoh
IPC分类号： A61K8/19 , A61K8/02 , C08K3/22 , A61Q17/04 , B32B5/16
CPC分类号： A61Q17/04 , A61K8/0275 , A61K8/11 , A61K8/19 , A61K8/731 , A61K8/8176 , A61K2800/413 , A61K2800/437 , A61K2800/624 , B01J13/14 , B82Y30/00 , C01F17/0043 , C01P2002/82 , C01P2002/84 , C01P2002/88 , C01P2004/02 , C01P2004/03 , C01P2004/04 , C01P2004/32 , C01P2004/52 , C01P2004/64 , C01P2004/84 , Y10T428/2998
摘要： An object of the present invention is to provide a core-shell-type cerium oxide microparticle, a dispersion solution comprising the microparticle, and a process for production of the microparticle or dispersion solution, and to achieve the object, the present invention provides a core-shell-type cerium oxide microparticle which has an average particle diameter of 30 to 200 nm and a coefficient of variation therein no greater than 0.25, and in which the secondary particle forming the core portion is spherical in shape and a polymer is attached to its surface, a dispersion solution of this cerium oxide microparticle and a dry powder from the cerium oxide microparticle dispersion solution, and a process of producing a core-shell-type cerium oxide microparticle or a dispersion solution thereof, which comprises the steps of: mixing a cerium salt and a polymer in an organic solvent to obtain a mixture; and heating this mixture under reflux at a prescribed temperature to precipitate core-shell-type cerium oxide microparticles, wherein the cerium salt is cerium nitrate and the particle diameter of the microparticles is adjusted using the molecular weight of the polymer.
摘要翻译：本发明的目的是提供一种核 - 壳型氧化铈微粒，包含该微粒的分散溶液以及该微粒或分散液的制造方法，其目的在于提供一种核壳型氧化铈微粒，其平均粒径为30〜200nm，变异系数不大于0.25，其中形成芯部的二次粒子为球状，聚合物附着于其上表面，该氧化铈微粒的分散溶液和来自氧化铈微粒分散液的干粉，以及制备核 - 壳型氧化铈微粒或其分散液的方法，其包括以下步骤：将铈盐和聚合物在有机溶剂中得到混合物; 并在规定的温度下将该混合物加热回流以析出核 - 壳型氧化铈微粒，其中铈盐为硝酸铈，并使用聚合物的分子量调节微粒的粒径。

12. 发明申请

US20080118404A1 HIGH SENSITIVE GAS SENSOR AND ITS MANUFACTURING PROCESS 审中-公开
标题翻译：高灵敏度气体传感器及其制造工艺
公开(公告)号：US20080118404A1
公开(公告)日：2008-05-22
申请号：US11939959
申请日：2007-11-14
申请人： Toshio ITOH , Ichiro Matsubara , Woosuck Shin , Noriya Izu
发明人： Toshio ITOH , Ichiro Matsubara , Woosuck Shin , Noriya Izu
IPC分类号： G01N27/04 , B32B15/00 , H01B1/00
CPC分类号： G01N27/125 , G01N33/0047
摘要： The present invention provides a gas sensor element having the characteristic of detecting an aldehyde gas in concentrations of several tens of ppb, a process for manufacturing such a material, and a gas sensor element and the like comprising such a material, and the invention provides a gas sensor material comprising an organic-inorganic hybrid material in which a conductive organic polymer is intercalated between layers of an inorganic compound having a layer structure and from which a conductive organic polymer not intercalated between the layers of the inorganic compound is removed, and provides a process for manufacturing such a gas sensor material, as well as a chemical sensor member, and further the invention allows thus providing a chemical sensor material by which the gas sensor material can detect by itself an aldehyde gas in concentrations of several tens of ppb without using a sensitivity-enhancing element such as a gas-concentrating element.
摘要翻译：本发明提供了一种具有检测浓度为几十ppb的醛气体的特性的气体传感器元件，制造这种材料的方法，以及包含这种材料的气体传感器元件等，本发明提供了一种气体传感器材料，其包含有机 - 无机混合材料，其中导电有机聚合物插入具有层结构的无机化合物的层之间并且未插入在无机化合物的层之间的导电有机聚合物被除去，并且提供制造这种气体传感器材料的方法以及化学传感器构件，并且本发明进一步提供了一种化学传感器材料，通过该材料，气体传感器材料可以自身检测浓度为几十ppb的醛气体，而不使用诸如气体浓缩元件的敏感度增强元件。

13. 发明申请

US20070212263A1 Micro Thermoelectric Type Gas Sensor 审中-公开
标题翻译：微型热电式气体传感器
公开(公告)号：US20070212263A1
公开(公告)日：2007-09-13
申请号：US10593255
申请日：2005-03-16
申请人： Woosuck Shin , Noriya Izu , Ichiro Matsubara , Norimitsu Murayama , Kazuki Tajima , Fabin Qiu , Zhihui Zhao
发明人： Woosuck Shin , Noriya Izu , Ichiro Matsubara , Norimitsu Murayama , Kazuki Tajima , Fabin Qiu , Zhihui Zhao
IPC分类号： G01N27/16
CPC分类号： G01N27/16
摘要： The present invention provides a micro thermoelectric gas sensor having a thermoelectric conversion section, a microheater, a catalyst layer formed on the microheater and to be heated by the microheater, which acts as a catalyst for catalytic combustion of a combustible gas, and a sensor detection section with an electrode pattern therefore formed on a membrane of a predetermined thickness, and a method for forming a micropattern of a functional material of a catalyst or resistor in a predetermined position on a substrate in a state in which the microstructure of the functional material remains controlled.
摘要翻译：本发明提供一种具有热电转换部，微加热器，形成在微加热器上并被微加热器加热的催化剂层的微型热电气体传感器，其作为可燃气体的催化燃烧用催化剂，以及传感器检测由此形成在预定厚度的膜上的电极图案的方法，以及在功能材料的微观结构保留的状态下在基板上的预定位置形成催化剂或电阻器的功能材料的微图案的方法受控。

14. 发明授权

US07236083B2 Resistance type oxygen sensor and oxygen sensor device using it and air/fuel ratio control system 有权
标题翻译：电阻式氧气传感器和氧传感器装置使用它和空/燃比控制系统
公开(公告)号：US07236083B2
公开(公告)日：2007-06-26
申请号：US10517771
申请日：2003-06-25
申请人： Noriya Izu , Woosuck Shin , Norimitsu Murayama
发明人： Noriya Izu , Woosuck Shin , Norimitsu Murayama
IPC分类号： H01C7/00
CPC分类号： G01N27/12
摘要： The present invention provides a resistance-type oxygen sensor, and an oxygen sensor device and an air/fuel ratio control system using same. The present invention relates to a resistance-type oxygen sensor with suppressed temperature dependence, wherein: (1) a gas detection unit composed of an oxide semiconductor with a resistance value varying according to temperature and the oxygen partial pressure of atmospheric gas and a temperature compensation unit composed of a conductor with suppressed dependence of a resistance value on oxygen partial pressure are connected in series; (2) the temperature compensation unit is composed of an oxygen ion conductor; and (3) an electrode for electric contact with the temperature compensation unit is exposed to the atmospheric gas and is a porous body; an oxygen sensor device and an air/fuel ratio control system.
摘要翻译：本发明提供一种电阻型氧传感器，以及氧传感器装置和使用该氧传感器装置的空/燃比控制系统。本发明涉及一种具有抑制温度依赖性的电阻型氧传感器，其中：（1）气体检测单元，其由具有根据温度变化的电阻值和大气气体的氧分压的温度补偿由具有抑制的电阻值对氧分压的依赖性的导体构成的单元串联连接; （2）温度补偿单元由氧离子导体构成; 和（3）与温度补偿单元电接触的电极暴露于大气中，是多孔体; 氧传感器装置和空/燃比控制系统。

15. 发明申请

US20060081473A1 Resistive type oxygen sensor and air/fuel ratio control system using it 有权
公开(公告)号：US20060081473A1
公开(公告)日：2006-04-20
申请号：US11252721
申请日：2005-10-19
申请人： Noriya Izu , Norimitsu Murayama , Woosuck Shin , Ichiro Matsubara
发明人： Noriya Izu , Norimitsu Murayama , Woosuck Shin , Ichiro Matsubara
IPC分类号： G01N27/26
CPC分类号： G01N27/125
摘要： A resistance-type oxygen sensor which is provided to be used mainly for measuring the oxygen gas partial pressure of automobile exhaust gas, and which has a short output response time in response to changes in oxygen partial pressure, low resistivity of the oxide semiconductor, and low temperature dependence of the resistivity. In a resistance-type oxygen sensor, in which the oxygen gas detection part comprises an oxide semiconductor, the oxide semiconductor is an oxide comprising cerium ions and hafnium ions, the amount of substance of cerium ions as a percentage of the amount of substance of positive ions is 60 mol % or more, the amount of substance of hafnium ions as a percentage of the amount of substance of positive ions is 3 to 30 mol %, and the hafnium ions are an oxide in solid solution in the parent phase.

16. 发明授权

US09139745B2 Aggregate of spherical core-shell cerium oxide/polymer hybrid nanoparticles and method for producing the same 有权
标题翻译：球形核 - 壳氧化铈/聚合物杂化纳米颗粒的聚集体及其制备方法
公开(公告)号：US09139745B2
公开(公告)日：2015-09-22
申请号：US13389140
申请日：2010-07-23
申请人： Noriya Izu , Toshio Uchida , Ichiro Matsubara , Toshio Itoh , Woosuck Shin , Maiko Nishibori
发明人： Noriya Izu , Toshio Uchida , Ichiro Matsubara , Toshio Itoh , Woosuck Shin , Maiko Nishibori
IPC分类号： C08K3/22 , B82Y30/00 , C09D11/10 , C01F17/00 , C09D11/037
CPC分类号： C09D11/10 , B82Y30/00 , C01F17/0043 , C01P2004/03 , C01P2004/32 , C01P2004/64 , C01P2004/84 , C09D11/037
摘要： The present invention provides an aggregate of spherical core-shell cerium oxide/polymer hybrid nanoparticles, a process for producing the same, and a product such as an anti-reflection film having a high refractive index layer. The present invention relates to an aggregate of spherical core-shell cerium oxide/polymer hybrid nanoparticles in which the core and shell are cerium oxide and a polymer, respectively, and the aggregate is highly concentrated, with a volume fraction of the spherical core-shell cerium oxide/polymer hybrid nanoparticles being at least 32% or higher, the aggregate contains a fixing agent, the aggregate is configured such that the fixing agent fills in voids between the spherical core-shell cerium oxide/polymer hybrid nanoparticles, the aggregate has a uniform distribution of the core-shell cerium oxide/polymer hybrid nanoparticles, which are spherical secondary particles synthesized by the polyol method, and the aggregate has excellent mechanical strength, light transmittance, and UV light-blocking properties; and the present invention further relates a process for producing the same; and an antireflection film and ink having the same.
摘要翻译：本发明提供球形核 - 壳氧化铈/聚合物杂化纳米粒子的集合体，其制造方法以及具有高折射率层的抗反射膜等制品。本发明涉及一种球形核 - 壳氧化铈/聚合物杂化纳米颗粒的集合体，其中核和壳分别为氧化铈和聚合物，聚集体高度浓缩，体积分数为球形核 - 壳氧化铈/聚合物杂化纳米粒子为至少32％以上，聚集体含有固色剂，所述骨料被构造为使得固定剂填充在球形核 - 壳氧化铈/聚合物杂化纳米颗粒之间的空隙中，聚集体具有通过多元醇法合成的球形二次粒子的核 - 壳氧化铈/聚合物杂化纳米粒子的均匀分布，骨料具有优异的机械强度，透光率和UV遮光性; 本发明还涉及其制造方法; 以及具有该防反射膜和防反射膜的墨。

17. 发明申请

US20110003156A1 Core-Shell Type Cobalt Oxide Microparticle or Dispersion Containing the Microparticle, and Production Process and Use of the Microparticle or the Dispersion 审中-公开
标题翻译：核 - 壳型钴酸锂微粒或含有微粒的分散体，以及微粒或分散体的制备方法和用途
公开(公告)号：US20110003156A1
公开(公告)日：2011-01-06
申请号：US12865427
申请日：2009-02-06
申请人： Noriya Izu , Ichiro Matsubara , Toshio Itoh , Woosuck Shin , Maiko Nishibori
发明人： Noriya Izu , Ichiro Matsubara , Toshio Itoh , Woosuck Shin , Maiko Nishibori
IPC分类号： B32B5/16 , B01J13/02
CPC分类号： C01G51/04 , B82Y30/00 , C01P2002/72 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/04 , C01P2004/51 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C09C1/00 , Y10T428/2998
摘要： The objects of the present invention are to provide core-shell type cobalt oxide microparticles, a dispersion containing such microparticles, and a production process and uses of the microparticles and the dispersion, and the invention is directed at: core-shell type cobalt oxide microparticles having an average particle diameter of from 50 to 200 nm, wherein the core is a secondary particle of spherical shape to a surface of which an organic polymer is attached as the shell; a dispersion of such cobalt oxide microparticles; a dry powder obtained from such a cobalt oxide microparticle dispersion; a process for producing core-shell type cobalt oxide microparticles or a dispersion thereof, which process includes the steps of: mixing together a cobalt salt and an organic polymer in an organic solvent so as to obtain a mixture; and heating/refluxing the mixture at a predetermined temperature so as to cause core-shell type cobalt oxide microparticles to precipitate, wherein the cobalt salt is cobalt acetate; and uses of the cobalt oxide microparticles, the dispersion and the dry powder.
摘要翻译：本发明的目的是提供核 - 壳型氧化钴微粒，含有这种微粒的分散体以及微粒和分散体的制造方法和用途，本发明涉及：核 - 壳型氧化钴微粒平均粒径为50〜200nm，其中芯是作为外壳附着有有机聚合物的表面的球形二次粒子; 这种钴氧化物微粒的分散体; 由这种氧化钴微粒分散体得到的干燥粉末; 一种生产核 - 壳型钴氧化物微粒或其分散体的方法，该方法包括以下步骤：在有机溶剂中将钴盐和有机聚合物混合在一起得到混合物; 并在预定温度下加热/回流混合物，以使核 - 壳型氧化钴微粒沉淀，其中钴盐是乙酸钴; 以及氧化钴微粒，分散体和干粉的用途。

18. 发明申请

US20100330008A1 Core-Shell Type Zinc Oxide Microparticle or Dispersion Containing the Microparticle, and Production Process and Use of the Microparticle or the Dispersion 有权
标题翻译：含有微粒的核 - 壳型氧化锌微粒或分散体以及微粒或分散体的制备方法和用途
公开(公告)号：US20100330008A1
公开(公告)日：2010-12-30
申请号：US12865464
申请日：2009-02-06
申请人： Noriya Izu , Ichiro Matsubara , Toshio Itoh , Woosuck Shin , Maiko Nishibori
发明人： Noriya Izu , Ichiro Matsubara , Toshio Itoh , Woosuck Shin , Maiko Nishibori
IPC分类号： A61K8/27 , A61K8/02 , A61Q17/04 , B01J23/06 , B01J37/08 , B01J31/06 , F21V9/06 , G02B5/22
CPC分类号： A61K8/27 , A61K8/0275 , A61K8/731 , A61K8/8176 , A61K2800/412 , A61K2800/624 , A61Q17/04 , B82Y30/00 , C01G9/02 , C01P2002/72 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/04 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C09C1/043
摘要： The objects of the present invention are to provide core-shell type zinc oxide microparticles, a dispersion containing such microparticles, and a production process and uses of the microparticles and the dispersion, and the invention is directed at: core-shell type zinc oxide microparticles having an average particle diameter of from 50 to 1,000 nm, wherein a core is a secondary particle of spherical shape to the surface of which a polymer is attached as a shell; a dispersion of such zinc oxide microparticles; a dry powder obtained from such a zinc oxide microparticle dispersion; a process for producing core-shell type zinc oxide microparticles or a dispersion thereof, which process includes the steps of: mixing together a zinc salt and a polymer in an organic solvent so as to obtain a mixture; and heating/refluxing the mixture at a predetermined temperature so as to cause core-shell type zinc oxide microparticles to precipitate, wherein the zinc salt is zinc acetate; and uses such as cosmetics, resins and fibers which contain the core-shell type zinc oxide microparticles and have an ultraviolet light blocking action.
摘要翻译：本发明的目的是提供核 - 壳型氧化锌微粒，含有这种微粒的分散体以及微粒和分散体的制造方法和用途，本发明涉及：核 - 壳型氧化锌微粒平均粒径为50〜1000nm，其中核是作为壳体附着有聚合物的表面的球形二次粒子; 这种氧化锌微粒的分散体; 由这种氧化锌微粒分散体得到的干燥粉末; 制造核 - 壳型氧化锌微粒或其分散体的方法，该方法包括以下步骤：将锌盐和聚合物在有机溶剂中混合以获得混合物; 并在预定温度下加热/回流混合物以使核壳型氧化锌微粒沉淀，其中锌盐为乙酸锌; 并且使用含有核 - 壳型氧化锌微粒的化妆品，树脂和纤维，并且具有紫外线阻挡作用。

19. 发明申请

US20050236271A1 Resistance type oxygen sensor and oxygen sensor device using it and air/fuel ratio control system 有权
标题翻译：电阻式氧气传感器和氧传感器装置使用它和空/燃比控制系统
公开(公告)号：US20050236271A1
公开(公告)日：2005-10-27
申请号：US10517771
申请日：2003-06-25
申请人： Noriya Izu , Woosuck Shin , Norimitsu Murayama
发明人： Noriya Izu , Woosuck Shin , Norimitsu Murayama
IPC分类号： G01N27/12 , G01N27/26
CPC分类号： G01N27/12
摘要： The present invention provides a resistance-type oxygen sensor, and an oxygen sensor device and an air/fuel ratio control system using same. The present invention relates to a resistance-type oxygen sensor with suppressed temperature dependence, wherein: (1) a gas detection unit composed of an oxide semiconductor with a resistance value varying according to temperature and the oxygen partial pressure of atmospheric gas and a temperature compensation unit composed of a conductor with suppressed dependence of a resistance value on oxygen partial pressure are connected in series; (2) the temperature compensation unit is composed of an oxygen ion conductor; and (3) an electrode for electric contact with the temperature compensation unit is exposed to the atmospheric gas and is a porous body; an oxygen sensor device and an air/fuel ratio control system.
摘要翻译：本发明提供一种电阻型氧传感器，以及氧传感器装置和使用该氧传感器装置的空/燃比控制系统。本发明涉及一种具有抑制温度依赖性的电阻型氧传感器，其中：（1）气体检测单元，其由具有根据温度变化的电阻值和大气气体的氧分压的温度补偿由具有抑制的电阻值对氧分压的依赖性的导体构成的单元串联连接; （2）温度补偿单元由氧离子导体构成; 和（3）与温度补偿单元电接触的电极暴露于大气中，是多孔体; 氧传感器装置和空/燃比控制系统。

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