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161. 发明申请

US20060116275A1 Process for removing and regenerating a double metal cyanide (dmc) catalyst from a polymer polyol 审中-公开
标题翻译：从聚合物多元醇中除去和再生双金属氰化物（dmc）催化剂的方法
公开(公告)号：US20060116275A1
公开(公告)日：2006-06-01
申请号：US10541739
申请日：2003-10-17
申请人： Werner Hinz , Edward Dexheimer
发明人： Werner Hinz , Edward Dexheimer
IPC分类号： B01J38/62
CPC分类号： B01J27/28 , B01J27/26 , B01J38/62 , C08G65/2663 , C08G65/2696 , C08G65/30 , C08G65/32 , Y02P20/582 , Y02P20/584
摘要： A method of removing and reclaiming a double metal cyanide (DMC) catalyst from a polyol is disclosed. A polymeric acid that is soluble in the polyol is introduced into the polyol during or after the polymerization reaction. The polymeric acid reacts with the double metal cyanide catalyst thereby causing the double metal cyanide catalyst and the polymeric acid to form an agglomeration in the polyol. The agglomeration is easily separated from the polyol via filtration, for example. The recovered agglomerated DMC catalyst can then be reconstituted using an acid solution.
摘要翻译：公开了从多元醇中除去和回收双金属氰化物（DMC）催化剂的方法。在聚合反应期间或之后将可溶于多元醇的聚合酸引入多元醇中。聚合酸与双金属氰化物催化剂反应，从而导致双金属氰化物催化剂和聚合酸在多元醇中形成聚集体。例如，通过过滤容易地将聚集物与多元醇分离。然后可以使用酸溶液重构回收的附聚DMC催化剂。

162. 发明授权

US07012164B2 Method for continuously producing a polyether 失效
标题翻译：连续生产聚醚的方法
公开(公告)号：US07012164B2
公开(公告)日：2006-03-14
申请号：US10895063
申请日：2004-07-21
申请人： Kazuhiko Yamada , Nobuyuki Kasahara , Yoshinori Toyota , Chitoshi Suzuki , Shigeru Ikai , Hiroshi Hatano
发明人： Kazuhiko Yamada , Nobuyuki Kasahara , Yoshinori Toyota , Chitoshi Suzuki , Shigeru Ikai , Hiroshi Hatano
IPC分类号： C08G65/28
CPC分类号： C08G65/2696 , C08G65/2663
摘要： A method for precisely producing a polyether having a relatively high molecular weight by means of a double metal cyanide complex catalyst is provided. A method for continuously producing a polyether, which comprises ring opening addition polymerization of an alkylene oxide in the presence of a double metal cyanide complex catalyst, wherein substantially no vapor phase part is present in a reactor.
摘要翻译：提供了一种通过双金属氰化物配合物催化剂精确生产具有较高分子量的聚醚的方法。一种连续生产聚醚的方法，其包括在双金属氰化物配位催化剂存在下环氧烷的开环加成聚合反应，其中在反应器中基本上不存在气相部分。

163. 发明申请

US20050209438A1 Starter feed stream acidification in DMC-catalyzed process 审中-公开
标题翻译：起动器进料流酸化DMC催化过程
公开(公告)号：US20050209438A1
公开(公告)日：2005-09-22
申请号：US10804894
申请日：2004-03-19
申请人： Edward Browne
发明人： Edward Browne
IPC分类号： C08G65/10 , B01J27/26 , C08G65/26 , C08G59/68
CPC分类号： C08G65/2696 , B01J27/26 , C08G65/2663
摘要： The process of the present invention provides for the manufacture of lower molecular weight DMC-catalyzed polyols than is possible using non-acidified continuous addition of starter (CAOS) feeds, by adding excess acid to a starter feed stream over that required for mere neutralization of the basicity of the starter. The benefits of the invention also extend to starters which do not contain basicity. Polyether polyols made by the inventive process may be used to produce improved polyurethane products such as coatings, adhesives, sealants, elastomers, foams and the like.
摘要翻译：本发明的方法提供了比使用非酸化连续添加起动剂（CAOS）进料可能制备低分子量DMC-催化的多元醇，通过向起始物原料流中加入过量的酸，超过纯中和所需的起始者的基本性。本发明的优点还扩展到不包含碱性的起动器。通过本发明方法制备的聚醚多元醇可用于生产改进的聚氨酯产品，例如涂料，粘合剂，密封剂，弹性体，泡沫等。

164. 发明申请

US20050159627A1 Method for activating double metallocyanide-compounds 有权
标题翻译：活化双金属氰化物化合物的方法
公开(公告)号：US20050159627A1
公开(公告)日：2005-07-21
申请号：US10502803
申请日：2003-02-06
申请人： Michael Stosser , Edward Bohres , Georg Grosch , Wilfried Sager
发明人： Michael Stosser , Edward Bohres , Georg Grosch , Wilfried Sager
IPC分类号： C08G65/28 , B01J27/26 , C08G65/26 , C07C41/03
CPC分类号： C08G65/2696 , B01J27/26 , C08G65/2663
摘要： The present invention relates to a process for reacting epoxides with an initiator compound in the presence of a double metal cyanide compound as a catalyst, said process having a shortened induction period, and the double metal cyanide compound being activated by adding the epoxide to a mixture of double metal cyanide compound and initiator compound at an internal reactor pressure of less than 1 bar, and also to the polyethers themselves obtainable by such a process.
摘要翻译：本发明涉及一种在双金属氰化物化合物作为催化剂存在下使环氧化物与引发剂化合物反应的方法，所述方法具有缩短的诱导期，并且双金属氰化物通过向混合物中加入环氧化物而被活化的双金属氰化物化合物和引发剂化合物，其内反应器压力小于1巴，以及可通过这种方法获得的聚醚。

165. 发明申请

US20050107643A1 Preparation of polyether alcohols 审中-公开
标题翻译：聚醚醇的制备
公开(公告)号：US20050107643A1
公开(公告)日：2005-05-19
申请号：US10712707
申请日：2003-11-13
申请人： Thomas Ostrowski , Raimund Ruppel , Eva Baum , Kathrin Harre
发明人： Thomas Ostrowski , Raimund Ruppel , Eva Baum , Kathrin Harre
IPC分类号： C07C43/11 , C08G65/00 , C08G65/10 , C08G65/12 , C08G65/26
CPC分类号： C08G65/2663 , C08G18/4866 , C08G65/2696
摘要： The invention relates to a process for the continuous preparation of polyether alcohols by reaction of alkylene oxides with H-functional starter substances in the presence of DMC catalysts, which comprises, at the beginning of the process a) firstly placing initial charge material and DMC catalyst in a reactor, b) metering in alkylene oxide so that the metering rate which is maintained for continuous operation of the reactor is reached in a time of from 100 to 3 000 seconds, c) metering in starter substance during or after step b) so that the metering rate which is maintained for continuous operation of the reactor is reached in a time of from 5 to 500 seconds, d) after the fill level in the reactor which is desired for continuous operation of the reactor has been reached, taking product off continuously from the reactor while at the same time metering in starter substance and alkylene oxides in such an amount that the fill level in the reactor remains constant and metering in DMC catalyst so that the catalyst concentration necessary for continuous operation of the reactor is maintained in the reactor.
摘要翻译：本发明涉及一种通过在DMC催化剂存在下使烯化氧与H官能起始物质反应来连续制备聚醚醇的方法，该方法在方法开始时包括：a）首先将初始的电荷材料和DMC催化剂在反应器中，b）在环氧烷中计量，使得在100至3000秒的时间内达到维持反应器连续操作的计量速率，c）在步骤b）或之后计量起始物质在5至500秒的时间内达到维持反应器连续运行的计量速率，d）在达到反应器连续运行所需反应器的填充量后，将产品关闭连续地从反应器中同时在起始物质和环氧烷中计量，使得反应器中的填充水平保持恒定并且在DMC cata中计量使得在反应器中保持连续操作反应器所需的催化剂浓度。

166. 发明申请

US20040220353A1 Process for preparation of polyether polyols 审中-公开
标题翻译：聚醚多元醇的制备方法
公开(公告)号：US20040220353A1
公开(公告)日：2004-11-04
申请号：US10787812
申请日：2004-02-26
发明人： Johannes Gerhardus Joseph Beckers , Gerard Du Cauze De Nazelle , Gerardus Wilhelmus Henricus Ingenbleek , Parminder Singh Sangha
IPC分类号： C08G065/32 , C07D301/19
CPC分类号： C08G65/2609 , C08G65/2696 , C08G2650/68
摘要： The present invention relates to a process for the preparation of polyether polyols having an average molecular weight of at least 2000, in which the process involves (i) reacting an initiator with a crude alkylene oxide stream in the presence of a catalyst to obtain an intermediate product having an average molecular weight of from 200 to 1100; and (ii) reacting the intermediate product further with one or more alkylene oxides to yield polyether polyols.
摘要翻译：本发明涉及一种制备平均分子量至少为2000的聚醚多元醇的方法，其中该方法包括（i）在催化剂存在下使引发剂与粗环氧烷物流反应，得到中间体平均分子量为200〜1100的产品; 和（ii）使中间产物进一步与一种或多种环氧烷反应，得到聚醚多元醇。

167. 发明申请

US20040087718A1 Process for production of alkyllene oxide polymers 有权
标题翻译：烷基氧化烯聚合物的制备方法
公开(公告)号：US20040087718A1
公开(公告)日：2004-05-06
申请号：US10469736
申请日：2003-09-03
发明人： Shigeki Hamamoto , Nobutaka Fujimoto , Makoto Katou , Kazuyuki Miura
IPC分类号： C08K005/01
CPC分类号： C08G65/2696 , C08G65/2642 , C08G65/2648 , C08G65/2654 , C08G65/266
摘要： According to a process for production of alkylene oxide polymers offered by the present invention, an alkylene oxide is subjected to a polymerization reaction under presence of a catalyst in a solvent containing an aliphatic hydrocarbon having from five to seven carbon atoms and a branched structure. The aliphatic hydrocarbon is provided preferably by 2-methyl pentane, 3-methyl pentane, 2,3-dimethyl pentane, 2,4-dimethyl pentane, etc. The alkylene oxide is provided preferably by ethylene oxides and/or propylene oxides.
摘要翻译：根据本发明提供的烯化氧聚合物的制造方法，在含有5〜7个碳原子的脂族烃和支链结构的溶剂中，在催化剂存在下使烯化氧进行聚合反应。脂肪烃优选由2-甲基戊烷，3-甲基戊烷，2,3-二甲基戊烷，2,4-二甲基戊烷等提供。烯化氧优选由环氧乙烷和/或环氧丙烷提供。

168. 发明申请

US20040049007A1 Oxytetramethylene glycol copolymer and process for producing the same 有权
标题翻译：氧四亚甲基二醇共聚物及其制备方法
公开(公告)号：US20040049007A1
公开(公告)日：2004-03-11
申请号：US10250859
申请日：2003-07-09
发明人： Tamotsu Kodama , Haruyuki Minoura , Yoshiyuki Tsunematsu , Toshihiko Fukuzono , Satoshi Furubeppu
IPC分类号： C08G059/00
CPC分类号： C08G65/30 , C08G65/20 , C08G65/2609 , C08G65/2696
摘要： Disclosed is an oxytetramethylene glycol copolymer, which is obtained by copolymerizing tetrahydrofuran and neopentyl glycol and which has a specific number average molecular weight Mn, a specific molecular weight distribution Mn/Mw, a specific neopentyl glycol copolymerization whole ratio Nw and a specific neopentyl glycol copolymerization partial ratio Nh, and a method for producing the same. Also disclosed is a method for purifying an oxytetramethylene glycol copolymer, which comprises adding a fresh tetrahydrofuran to a reaction mixture comprising an oxytetramethylene glycol copolymer and an unreacted diol, wherein the amount of added tetrahydrofuran is not less than the weight of the unreacted diol contained in the reaction mixture, and distilling off the unreacted diol together with the added tetrahydrofuran.
摘要翻译：公开了通过四氢呋喃和新戊二醇的共聚获得的氧化四亚甲基二醇共聚物，其具有特定的数均分子量Mn，特定分子量分布Mn / Mw，特定的新戊二醇共聚合比Nw和特定的新戊二醇共聚部分比例Nh及其制造方法。还公开了一种用于纯化含氧四亚甲基二醇共聚物的方法，其包括向包含氧化四亚甲基二醇共聚物和未反应的二醇的反应混合物中加入新鲜的四氢呋喃，其中加入的四氢呋喃的量不小于反应混合物，并与加入的四氢呋喃一起蒸馏出未反应的二醇。

169. 发明申请

US20040014908A1 Activated starter mixtures and the processes related thereto 有权
标题翻译：活化起动混合物及其相关工艺
公开(公告)号：US20040014908A1
公开(公告)日：2004-01-22
申请号：US10199916
申请日：2002-07-19
发明人： John E. Hayes
IPC分类号： C08G059/14
CPC分类号： C08G65/2696 , C08G18/4866 , C08G65/2609 , C08G65/2663
摘要： The present invention is directed to an activated starter mixture which can be used to prepare polyoxyalkylene polyols. The present invention is also directed to a process for preparing an activated starter mixture, particularly, to a process for preparing an activated starter mixture which is composed of a low molecular weight starter compound. The present invention is also directed to a batch or semi-batch process for the polyaddition of an alkylene oxide on to an activated starter mixture, particularly, on to an activated starter mixture which is composed of a low molecular weight starter compound. The present invention provides an activated starter mixture, particularly, an activated starter mixture which is composed of a low molecular weight starter compound, which rapidly initiates polymerization. The present invention can eliminate the need to synthesize costly high molecular weight starter compounds by KOH catalysis in a separate, dedicated reactor.
摘要翻译：本发明涉及可用于制备聚氧化烯多元醇的活化起始混合物。本发明还涉及一种制备活化起始混合物的方法，特别是制备由低分子量起始化合物组成的活化起始混合物的方法。本发明还涉及用于将烯化氧加成到活化的起始混合物上的批次或半间歇方法，特别是涉及由低分子量起始化合物组成的活化起始混合物。本发明提供一种活化的起始混合物，特别是由低分子量起始化合物组成的活化起始物混合物，其快速引发聚合。本发明可以消除在单独的专用反应器中通过KOH催化合成昂贵的高分子量起始物化合物的需要。

170. 发明授权

US06664428B2 Method of producing polyetherpolyols 有权
标题翻译：生产聚醚多元醇的方法
公开(公告)号：US06664428B2
公开(公告)日：2003-12-16
申请号：US10204293
申请日：2002-08-20
申请人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Gerd Höppner , Peter de Vocht , Dirk Leys , Jürgen Winkler , Stephan Bauer
发明人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Gerd Höppner , Peter de Vocht , Dirk Leys , Jürgen Winkler , Stephan Bauer
IPC分类号： C07C4311
CPC分类号： C08G65/2696 , C08G65/2663
摘要： A process for the preparation of polyetherpolyols by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst is proposed, the reaction being carried out in a stirred kettle reactor and the reaction mixture being circulated via an external heat exchanger by means of a pump.
摘要翻译：提出了在多金属氰化物配合物催化剂存在下，通过二醇或多元醇与环氧乙烷，环氧丙烷，环氧丁烷或其混合物反应制备聚醚多元醇的方法，该反应在搅拌釜反应器中进行，反应混合物通过泵通过外部热交换器循环。

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