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    • 141. 发明授权
    • Dried nanocrystalline cellulose of controllable dispersibility and method therefor
    • 干燥的纳米晶纤维素的可控分散性及其方法
    • US08652636B2
    • 2014-02-18
    • US13008126
    • 2011-01-18
    • Stephanie BeckJean BouchardRichard Berry
    • Stephanie BeckJean BouchardRichard Berry
    • B32B5/16C08L1/02C09D101/02
    • C08B15/08C08J3/12C08J5/18C08J2301/02Y10T428/2982Y10T428/2991
    • Dried nanocrystalline cellulose (NCC), in particular films of NCC, of controlled water dispersibility and a method to control the dispersibility of dried NCC by controlling electrolyte solution ionic strength and ion valency is described. Neutral M-NCC suspensions containing monovalent counterions (e.g., M=Na+, K+, NH4+, Et4N+) produced by neutralization of acid-form NCC (H-NCC) with the appropriate hydroxide, are readily dispersible in water when fully dried; this is in contrast to H-NCC. The dispersion of dried M-NCC in aqueous media is effectively prevented by a combination of (1) increased electrolyte concentration and ionic strength, and (2) higher valency of the cation component of the dissolved salt. Additionally, pre-treatment of dried M-NCC films with an electrolyte solution having a polyvalent cation, for example a divalent or trivalent cation is sufficient to prevent the subsequent dispersion of the M-NCC film in pure water.
    • 描述了干燥的纳米晶纤维素(NCC),特别是NCC的膜的受控水分散性,以及通过控制电解质溶液的离子强度和离子价态来控制干燥的NCC的分散性的方法。 通过用合适的氢氧化物中和酸形式NCC(H-NCC)产生的含有一价抗衡离子(例如M = Na +,K +,NH 4 +,Et 4 N +)的中性M-NCC悬浮液在完全干燥时容易分散在水中; 这与H-NCC相反。 干燥的M-NCC在水性介质中的分散体通过(1)增加的电解质浓度和离子强度的组合和(2)溶解盐的阳离子组分的更高的价态被有效地预防。 另外,用具有多价阳离子(例如二价或三价阳离子)的电解质溶液预处理干燥的M-NCC膜足以防止M-NCC膜随后在纯水中分散。