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131. 发明申请

US20140018459A1 METHOD FOR PRODUCING SHORT-CHAIN POLYFUNCTIONAL POLYETHER POLYOLS UTILIZING SUPERACID AND DOUBLE-METAL CYANIDE CATALYSIS 审中-公开
标题翻译：生产使用超级和双金属氰化物催化剂的短链多官能聚醚多元醇的方法
公开(公告)号：US20140018459A1
公开(公告)日：2014-01-16
申请号：US14003058
申请日：2012-03-19
申请人： Pavel L. Shutov , Hanno R. Van der Wal , Jean-Paul Masy , David A. Babb
发明人： Pavel L. Shutov , Hanno R. Van der Wal , Jean-Paul Masy , David A. Babb
IPC分类号： C08G65/26 , C08G18/32
CPC分类号： C08G65/2609 , C08G18/3206 , C08G65/2678 , C08G65/2684 , C08G65/2696
摘要： A two stage alkoxlyation process for preparing a short-chain polyether polyol from a starter compound comprising from 3 to 9 hydroxyl groups and at least one alkylene oxide, wherein said starter compound has a hydroxy equivalent weight of from 22 to 90 Da. Said process comprises a first stage alkoxlyation using a superacid catalyst to prepare an oligomeric alkoxylated starter compound that is further alkoxylated to the short-chain polyether polyol of the invention in a second stage using a DMC catalyst. The process of the present invention may be performed continuously, in a batch, or semi-batch process.
摘要翻译：一种由起始化合物制备短链聚醚多元醇的二阶段烷氧化方法，所述起始化合物包含3至9个羟基和至少一种烯化氧，其中所述起始化合物的羟基当量为22至90Da。所述方法包括使用超强酸催化剂的第一阶段烷氧化，以制备在第二阶段中使用DMC催化剂进一步使本发明的短链聚醚多元醇烷氧基化的低聚烷氧基化引发剂化合物。本发明的方法可以连续地，分批或半间歇的方法进行。

132. 发明申请

US20130190462A1 PROCESS FOR PREPARING POLYETHER CARBONATE POLYOLS WITH DOUBLE METAL CYANIDE CATALYSTS AND IN THE PRESENCE OF METAL SALTS 有权
标题翻译：用双金属氰化物催化剂制备聚碳酸酯多元醇的方法和金属盐的存在
公开(公告)号：US20130190462A1
公开(公告)日：2013-07-25
申请号：US13579222
申请日：2011-02-17
申请人： Aurel Wolf , Stefan Grasser , Christoph Gürtler , Jörg Hofmann
发明人： Aurel Wolf , Stefan Grasser , Christoph Gürtler , Jörg Hofmann
IPC分类号： C08G64/34 , C08G64/20
CPC分类号： C08G64/34 , C08G18/32 , C08G18/44 , C08G64/205 , C08G65/2603 , C08G65/2663 , C08G65/2696
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerisation of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of metal salts.
摘要翻译：本发明涉及通过在双金属氰化物（DMC）催化剂的帮助下，在一种或多种H官能起始物质的存在下，二氧化碳（CO 2）与环氧烷的催化共聚制备聚醚碳酸酯多元醇的方法，在金属盐的存在下。

133. 发明授权

US08481788B2 Process for producing polyalkylene oxide 有权
标题翻译：生产聚环氧烷的方法
公开(公告)号：US08481788B2
公开(公告)日：2013-07-09
申请号：US12863919
申请日：2009-01-21
申请人： Hidetoshi Odaka , Takuya Maeda , Kiyotaka Bito , Michihide Homma
发明人： Hidetoshi Odaka , Takuya Maeda , Kiyotaka Bito , Michihide Homma
IPC分类号： C07C213/00
CPC分类号： C08G65/2663 , C08G65/2696
摘要： The present invention aims to provide a method for producing a polyalkylene oxide, which is capable of improving reduction in reactivity of a double metal cyanide complex catalyst in the case that a low molecular weight initiator is used, and producing the polyalkylene oxide with high productivity at low cost. The method for producing a polyalkylene oxide comprises carrying out a ring-opening addition reaction of an alkylene oxide with an initiator having at least one hydroxy group and having a molecular weight of not more than 300 per hydroxy group in the presence of a double metal cyanide complex catalyst in an organic solvent, wherein the organic solvent is used in an amount of 500 to 1,500 parts by weight relative to 100 parts by weight of the alkylene oxide used at the start of the reaction.
摘要翻译：本发明的目的在于提供一种聚环氧烷的制造方法，其能够在使用低分子量引发剂的情况下提高双金属氰化物配合物催化剂的反应性的降低，并且以高生产率制备聚环氧烷烃低成本。聚环氧烷的制造方法包括在双金属氰化物存在下，进行环氧烷与具有至少一个羟基的引发剂的开环加成反应，并且每个羟基的分子量不超过300个在有机溶剂中的复合催化剂，其中相对于100重量份在反应开始时使用的烯化氧，有机溶剂的用量为500至1500重量份。

134. 发明授权

US08399608B2 Process for the preparation of polyether alcohols from unsaturated starters having active hydrogen atoms 有权
标题翻译：从具有活性氢原子的不饱和起始物制备聚醚醇的方法
公开(公告)号：US08399608B2
公开(公告)日：2013-03-19
申请号：US12681789
申请日：2007-10-25
申请人： Georg Heinrich Grosch , Matthias Zipplies , Thomas Ostrowski , Ulrich Annen , Markus Klumpe
发明人： Georg Heinrich Grosch , Matthias Zipplies , Thomas Ostrowski , Ulrich Annen , Markus Klumpe
IPC分类号： C08G65/10 , C08G65/30 , C08G65/34 , C08F8/06 , C08F6/08
CPC分类号： C08G65/2609 , C08G65/2648 , C08G65/2696
摘要： A process for the preparation of polyether alcohols by reacting at least one alkylene oxide with at least one unsaturated starter having at least one active hydrogen atom per molecule under basic catalysis, that the alkoxylation is carried out in at least two stages, in stage (I) the alkoxylation of the starter or starters being carried out with not more than 10 mol of alkylene oxide per mole of starter with a catalyst concentration of not more than 0.0085 mol of basic catalyst per mole and in stage (II) and the optionally following stages, the alkoxylated starter or starters from stage (I) being reacted with further alkylene oxide at a catalyst concentration of at least 0.01 mol of basic catalyst per mole of starter.
摘要翻译：通过在碱性催化下使至少一种烯化氧与至少一种具有至少一个活性氢原子的不饱和起始物在每个分子中反应来制备聚醚醇的方法，该烷氧基化在至少两个阶段中在阶段（I ）起始物或起动器的烷氧基化作用，每摩尔起始物不超过10摩尔环氧烷烃，每摩尔催化剂浓度不大于0.0085摩尔碱性催化剂和（II）阶段和任选的后续阶段，来自阶段（I）的烷氧基化起始物或起始物与另外的烯化氧反应，每摩尔起始物的催化剂浓度为至少0.01摩尔碱性催化剂。

135. 发明申请

US20130046116A1 INTEGRATED COPOLYETHER GLYCOL MANUFACTURING PROCESS 审中-公开
标题翻译：一体化聚乙二醇制造工艺
公开(公告)号：US20130046116A1
公开(公告)日：2013-02-21
申请号：US13514801
申请日：2010-01-12
申请人： Robert B. Osborne , Qun Sun , Yanhui Sun , Gregg M. Sisler , Roy N. Eissmann , Robert D. Orlandi
发明人： Robert B. Osborne , Qun Sun , Yanhui Sun , Gregg M. Sisler , Roy N. Eissmann , Robert D. Orlandi
IPC分类号： C07C41/26 , C07C43/13
CPC分类号： C08G65/20 , C08G65/2678 , C08G65/2684 , C08G65/2696 , C08G65/30
摘要： The present invention relates to an improved, fully-integrated continuous process of enhanced process operability for manufacturing copolyether glycols having enhanced physical properties by polymerization of a reaction mixture comprising tetrahydrofuran and at least one alkylene oxide in the presence of an acid catalyst and at least one compound containing reactive hydrogen atoms. The copolyether glycols manufactured by the present process have enhanced physical properties of increased alkylene oxide incorporation, average molecular weight and polydispersity, as well as reduced crystallinity, color, oligomeric cyclic ether content, and linear oligomer having an average molecular weight of up to about 400 dalton content.
摘要翻译：本发明涉及一种改进的，完全一体化的连续方法，其增强了制备具有增强的物理性能的共聚醚二醇的工艺可操作性，所述共聚醚二醇在酸催化剂存在下通过聚合包含四氢呋喃和至少一种烯化氧的反应混合物和至少一种含有活性氢原子的化合物。通过本方法制备的共聚醚二醇具有增加的烯化氧掺入，平均分子量和多分散性以及降低的结晶度，颜色，低聚环醚含量和平均分子量高达约400的线性低聚物的物理性能达尔顿内容

136. 发明申请

US20130028803A1 METHOD OF MAKING ALKYLENE GLYCOLS 有权
标题翻译：制备亚苄基甘露糖的方法
公开(公告)号：US20130028803A1
公开(公告)日：2013-01-31
申请号：US13631832
申请日：2012-09-28
申请人： H R D Corporation
发明人： Abbas Hassan , Aziz Hassan , Rayford G. Anthony , Krishnan Viswanathan , Gregory G. Borsinger
IPC分类号： B01J8/10
CPC分类号： B01F7/00766 , B01F13/1013 , B01F13/1016 , B01J8/025 , B01J8/20 , B01J19/0066 , B01J19/1806 , B01J2219/00006 , B01J2219/00779 , C07C29/106 , C08G65/2696 , C07C31/202 , C07C31/205 , C07C31/207
摘要： Herein disclosed is a system for hydrating an alkylene oxide that includes a high shear device configured to form a dispersion of an alkylene oxide and water, the high shear device comprising a rotor, a stator, and a catalytic surface, wherein the dispersion comprises gas bubbles with an average gas bubble diameter of less than about 5 μm; a pump configured for delivering a liquid stream to the high shear device; and a reactor coupled to the high shear device, and configured to receive the dispersion from the high shear device, wherein the alkylene oxide is hydrated in the reactor.
摘要翻译：本文公开了一种用于水合环氧烷的系统，其包括构造成形成环氧烷和水的分散体的高剪切装置，所述高剪切装置包括转子，定子和催化表面，其中所述分散体包括气泡平均气泡直径小于约5μm; 构造成用于将液体流输送到高剪切装置的泵; 和耦合到高剪切装置的反应器，并被配置为从高剪切装置接收分散体，其中烯化氧在反应器中水合。

137. 发明授权

US08273925B2 Method and device for the production of alkylene oxide addition products 有权
标题翻译：用于生产环氧烷加成产物的方法和装置
公开(公告)号：US08273925B2
公开(公告)日：2012-09-25
申请号：US12524172
申请日：2007-12-08
申请人： Stefan Franzen , Thomas Koelker
发明人： Stefan Franzen , Thomas Koelker
IPC分类号： C07C29/00 , B01J19/00
CPC分类号： C08G65/2609 , C08G65/2615 , C08G65/2621 , C08G65/2696
摘要： A method for the production of alkylene oxide addition products comprising (i) charging a stirred reactor with a starting compound capable of adding on or inserting alkylene oxides, introducing at least one alkylene oxide plus a different diluent gas, wherein a portion of said alkylene oxide reacts in a liquid phase with said starting compound, and the remaining alkylene oxide together with said diluent gas forms a gas phase above the liquid phase, (ii) continuously drawing off said liquid phase from the bottom of the reactor via an outlet stub, and recycling to the top of the reactor via an external circulation system, which comprises at least one heat exchanger and at least one Venturi nozzle within said external circulation system, and (iii) metering said gas phase comprising alkylene oxide into said Venturi nozzle via a vacuum line.
摘要翻译：一种用于生产环氧烷加成产物的方法，包括（i）向搅拌反应器中加入能够加入或插入烯化氧的起始化合物，引入至少一种环氧烷加上不同的稀释气体，其中一部分所述环氧烷烃在液相中与所述起始化合物反应，剩余的环氧烷与所述稀释气体一起在液相上形成气相，（ii）经由出口残渣从反应器的底部连续地抽出液相，以及通过外部循环系统再循环到反应器的顶部，外部循环系统包括至少一个热交换器和在所述外部循环系统内的至少一个文丘里喷嘴，以及（iii）通过真空将所述包含环氧烷的气相计量到所述文丘里喷嘴中线。

138. 发明申请

US20120172537A1 PROCESS FOR PRODUCING POLYETHER 审中-公开
标题翻译：生产聚醚的方法
公开(公告)号：US20120172537A1
公开(公告)日：2012-07-05
申请号：US13418842
申请日：2012-03-13
申请人： Takeaki ARAI , Chitoshi Suzuki
发明人： Takeaki ARAI , Chitoshi Suzuki
IPC分类号： C08G65/12 , C08G18/48 , C08G65/26
CPC分类号： C08G65/2663 , C08G18/4866 , C08G18/4887 , C08G65/2696
摘要： To provide a process for producing a polyether, which comprises subjecting an alkylene oxide and the like to ring-opening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst (DMC catalyst), which can be carried out by use of a DMC catalyst at a low concentration, and accordingly the amount of the DMC catalyst remaining in a polyether to be obtained can be reduced.A process for producing a polyether, which comprises subjecting an alkylene oxide and an oxygen-containing heterocyclic compound other than an alkylene oxide, to ring-opening addition polymerization to an initiator having a hydroxy group in the presence of a DMC catalyst, wherein prior to the ring-opening addition polymerization, the DMC catalyst and the initiator are subjected to mixing treatment at a temperature of from 125° C. to 180° C. under an absolute pressure of at most 0.06 MPa for from 10 minutes to 24 hours.
摘要翻译：提供一种制备聚醚的方法，其包括在双金属氰化物配合物催化剂（DMC催化剂）的存在下，使烯化氧等进行开环加成聚合，引发剂可以通过使用低浓度的DMC催化剂，因此可以降低残留在所得聚醚中的DMC催化剂的量。一种制备聚醚的方法，其包括使环氧烷和除了烯化氧以外的含氧杂环化合物在DMC催化剂的存在下开环加成聚合成具有羟基的引发剂，其中在开环加成聚合，DMC催化剂和引发剂在125℃至180℃的温度下在绝对压力至多为0.06MPa下进行10分钟至24小时的混合处理。

139. 发明申请

US20120130134A1 PROCESS FOR THE PREPARATION OF POLYETHEROLS FROM ALKYLENE OXIDES 审中-公开
标题翻译：从亚烷基氧化物制备聚醚的方法
公开(公告)号：US20120130134A1
公开(公告)日：2012-05-24
申请号：US13387540
申请日：2010-07-27
申请人： Matthias Schopohl , Thomas Ostrowski , Dirk Meckelnburg , Renata Jovanovic , Achim Loeffler , Hans-Juergen Pallasch , Thorsten Friese , Eckard Schauss , Susanne Szeschkus , Vinit Chilekar , Hans Volkmar Schwarz
发明人： Matthias Schopohl , Thomas Ostrowski , Dirk Meckelnburg , Renata Jovanovic , Achim Loeffler , Hans-Juergen Pallasch , Thorsten Friese , Eckard Schauss , Susanne Szeschkus , Vinit Chilekar , Hans Volkmar Schwarz
IPC分类号： C07C29/04
CPC分类号： C08G65/2696 , C08G65/2663 , C08G65/30
摘要： A process for the preparation of polyetherols, comprising the following steps: a) reaction of at least one starter compound with at least one alkylene oxide and a catalyst to give a crude polyetherol and b) removal of low molecular weight byproducts from the crude polyetherol from step a), wherein the crude polyetherol is treated with a stripping gas in a column having internals.
摘要翻译：一种制备聚醚的方法，包括以下步骤：a）将至少一种起始化合物与至少一种烯化氧和催化剂反应，得到粗的聚乙烯醇，和b）从粗制的聚醚中除去低分子量副产物步骤a），其中在具有内部材料的塔中用脱气处理粗制聚醚。

140. 发明申请

US20110230581A1 PROCESS FOR THE PRODUCTION OF POLYETHER POLYOLS WITH A HIGH ETHYLENE OXIDE CONTENT 审中-公开
标题翻译：具有高乙烯氧化物含量的聚醚多元醇的生产方法
公开(公告)号：US20110230581A1
公开(公告)日：2011-09-22
申请号：US12725631
申请日：2010-03-17
申请人： Bert Klescewski , Jörg Hofmann , Klaus Lorenz , Jack R. Reese , Jose F. Pazos
发明人： Bert Klescewski , Jörg Hofmann , Klaus Lorenz , Jack R. Reese , Jose F. Pazos
IPC分类号： C07C43/11 , C08G18/32
CPC分类号： C08G65/2663 , C08G65/2696 , C08G2650/24
摘要： Polyether polyols with an OH number of from 15 to 120 mg of KOH/g are produced by (i) introducing a mixture of DMC catalyst and a poly(oxyalkylene)polyol or a mixture of DMC catalyst and a polyether polyol (“heel”) obtainable by the process according to the invention is initially into a reactor and (ii) continuously introducing one (or more) low molecular weight starter compound(s) with a (mixed) hydroxyl functionality of from 2.2 to 6.0 and a mixture composed of a) 73 to 80 parts by weight (per 100 parts by weight of a) plus b)) of ethylene oxide and b) 27 to 20 parts by weight (per 100 parts by weight of a) plus b)) of at least one substituted alkylene oxide corresponding to a specified formula into the mixture from step (i). These polyether polyols are particularly useful for the production of flexible polyurethane foams.
摘要翻译：通过（i）引入DMC催化剂和聚（氧化烯）多元醇或DMC催化剂和聚醚多元醇（“跟”）的混合物的混合物制备OH数为15至120mg KOH / g的聚醚多元醇，通过根据本发明的方法可获得的化合物最初进入反应器，和（ii）连续引入一种（或多种）低分子量起始化合物与（混合）羟基官能度为2.2至6.0的混合物和由）73至80重量份（每100重量份a）加b））环氧乙烷和b）27至20重量份（每100重量份a）加b））至少一个取代的对应于规定式的氧化烯进入步骤（i）的混合物中。这些聚醚多元醇特别可用于生产软质聚氨酯泡沫体。

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