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111. 发明授权

US4854966A Method of controlling undesirable vegetation utilizing certain 3-(substituted thio)-2-benzoyl-cyclohex-2-enones 失效
标题翻译：使用某些3-（取代的硫代）-2-苯甲酰基 - 环己-2-酮控制不希望的植物的方法
公开(公告)号：US4854966A
公开(公告)日：1989-08-08
申请号：US171077
申请日：1988-03-21
申请人： Christopher G. Knudsen
发明人： Christopher G. Knudsen
IPC分类号： A01N35/06 , A01N37/36 , A01N41/10 , C07C317/24 , C07C323/22 , C07C323/65
CPC分类号： C07C323/65 , A01N35/06 , A01N37/36 , A01N41/10 , C07C317/00 , C07C317/24 , C07C321/00 , C07C323/00 , C07C323/22 , C07C2101/16
摘要： A compound of the formula ##STR1## wherein R is halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 alkoxy, nitro; cyano; C.sub.1 -C.sub.2 haloalkyl, or R.sup.a SO.sub.n - wherein n is 0 or 2 and R.sup.a is C.sub.1 -C.sub.2 alkyl; R.sup.1 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.2 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.1 and R.sup.2 together are alkylene having 2 to 5 carbon atoms; R.sup.3 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.3 and R.sup.4 can be oxo; R.sup.5 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.5 and R.sup.6 together are alkylene having 2 to 5 carbon atoms; and R.sup.7 and R.sup.8 independently are (1) hydrogen; (2) halogen; (3) C.sub.1 -C.sub.4 alkyl; (4) C.sub. 1 -C.sub.4 alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C.sub.1 -C.sub.4 haloalkyl; (9) R.sup.b SO.sub.n -wherein n is the integer 0, 1 or 2; and R.sup.b is (a) C.sub.1 -C.sub.4 alkyl; (b) C.sub.1 -C.sub.4 alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) --NR.sup.c R.sup.d wherein R.sup.c and R.sup.d independently are hydrogen or C.sub.1 -C.sub.4 alkyl; (11) R.sup.e C(O)- wherein R.sup.e is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; (12) SO.sub.2 NR.sup.c R.sup.d wherein R.sup.c and R.sup.d are as defined; or (13) --N(R.sup.c)C(O)R.sup.d wherein R.sup.c and R.sup.d are as defined; m is the integer 0, 1 or 2; and R.sup.9 is C.sub.1 -C.sub.4 alkyl, phenyl, cyano, substituted phenyl, or --(CH.sub.2).sub.x --C(O)O--(C.sub.1 -C.sub.4 alkyl) wherein X is the integer 1, 2 or 3.
摘要翻译：其中R是卤素，C 1 -C 2烷基，C 1 -C 2烷氧基，硝基; 氰基; C 1 -C 2卤代烷基或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R1是氢或C1-C4烷基; R2是氢或C1-C4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R3是氢或C1-C4烷基; R4是氢或C1-C4烷基; 或R 3和R 4可以是氧代; R5是氢或C1-C4烷基; R6是氢或C1-C4烷基; 或R 5和R 6一起是具有2至5个碳原子的亚烷基; 和R7和R8独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C 1 -C 4烷氧基; （5）三氟甲氧基（6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）RbSOn-其中n是整数0,1或2; 并且R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NRcRd其中Rc和Rd独立地是氢或C1-C4烷基; （11）ReC（O） - 其中Re为C1-C4烷基或C1-C4烷氧基; （12）SO2NRcRd其中Rc和Rd如所定义; 或（13）-N（R c）C（O）R d，其中R c和R d如所定义; m是整数0,1或2; 并且R 9为C 1 -C 4烷基，苯基，氰基，取代的苯基或 - （CH 2）x -C（O）O-（C 1 -C 4烷基），其中X为整数1,2或3。

112. 发明授权

US4837352A 3-chloro-2-(2'-substituted benzoyl)-cyclohex-2-enone intermediate compounds 失效
标题翻译： 3-氯-2-（2'-取代苯甲酰基） - 环己-2-烯酮中间体化合物
公开(公告)号：US4837352A
公开(公告)日：1989-06-06
申请号：US171358
申请日：1988-03-21
申请人： Christopher G. Knudsen
发明人： Christopher G. Knudsen
IPC分类号： A01N35/06 , A01N37/36 , A01N41/10 , C07C317/24 , C07C323/22 , C07C323/65
CPC分类号： C07C323/65 , A01N35/06 , A01N37/36 , A01N41/10 , C07C317/00 , C07C317/24 , C07C321/00 , C07C323/00 , C07C323/22 , C07C2101/16
摘要： An intermediate compound having the structural formula ##STR1## wherein R is halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 alkoxy, nitro; cyano; C.sub.1 -C.sub.2 haloalkyl, or R.sup.a SO.sub.n - wherein n is 0 or 2 and R.sup.a is C.sub.1 -C.sub.2 alkyl; R.sup.1 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.2 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.1 and R.sup.2 together are alkylene having 2 to 5 carbon atoms; R.sup.3 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.3 and R.sup.4 together can be oxo; R.sup.5 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.5 and R.sup.6 together are alkylene having 2 to 5 carbon atoms; R.sup.7 and R.sup.8 independently are (1) hydrogen; (2) halogen; (3) C.sub.1 -C.sub.4 alkyl; (4) C.sub. 1 -C.sub.4 alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C.sub.1 -C.sub.4 haloalkyl; (9) R.sup.b SO.sub.n - wherein n is the integer 0, 1 or 2; and R.sup.b is (a) C.sub.1 -C.sub.4 alkyl; (b) C.sub.1 -C.sub.4 alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) --NR.sup.C R.sup.d wherein R.sup.c and R.sup.d independently are hydrogen or C.sub.1 -C.sub.4 alkyl; (11) R.sup.e C(O)- wherein R.sup.e is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; (12) SO.sub.2 NR.sup.c R.sup.d wherein R.sup.c and R.sup.d are as defined; or (13) --N(R.sup.c)C(O)R.sup.d wherein R.sup.c and R.sup.d are as defined.
摘要翻译：具有结构式为“IMAGE”的中间体化合物，其中R是卤素，C 1 -C 2烷基，C 1 -C 2烷氧基，硝基; 氰基; C 1 -C 2卤代烷基或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R1是氢或C1-C4烷基; R2是氢或C1-C4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R3是氢或C1-C4烷基; R4是氢或C1-C4烷基; 或者R 3和R 4一起可以是氧代; R5是氢或C1-C4烷基; R6是氢或C1-C4烷基; 或R 5和R 6一起是具有2至5个碳原子的亚烷基; R7和R8独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C 1 -C 4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）RbSO n-，其中n是整数0,1或2; 并且R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NRCRd其中Rc和Rd独立地是氢或C1-C4烷基; （11）ReC（O） - 其中Re为C1-C4烷基或C1-C4烷氧基; （12）SO2NRcRd其中Rc和Rd如所定义; 或（13）-N（R c）C（O）R d，其中R c和R d如所定义。

113. 发明授权

US4154693A 1-[3-(Methylthio)butyryl]-2,6,6-trimethyl-cyclohexene or 1,3-cyclohexadiene analog are used in detergent and soap compositions 失效
标题翻译： 1- {8 3-（甲硫基）丁酰基{9 -2,6,6-三甲基 - 环己烯或1,3-环己二烯类似物用于洗涤剂和皂组合物
公开(公告)号：US4154693A
公开(公告)日：1979-05-15
申请号：US917662
申请日：1978-06-21
申请人： Richard A. Wilson , Braja D. Mookherjee , Anne S. Hruza , Manfred H. Vock , Louis S. Frederick , Joaquin F. Vinals
发明人： Richard A. Wilson , Braja D. Mookherjee , Anne S. Hruza , Manfred H. Vock , Louis S. Frederick , Joaquin F. Vinals
IPC分类号： A23L27/20 , A24B3/12 , A24B15/34 , A61K8/35 , A61K47/20 , A61Q13/00 , C07C67/00 , C07C313/00 , C07C323/22 , C07C403/00 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C07C323/22 , A24B15/34 , C11B9/0034 , C07C2101/16 , Y10S514/974
摘要： The compounds 1-[3-(methylthio)butyryl]-2,6,6-trimethyl-cyclohexene and/or the corresponding 1,3-cyclohexadiene analog having the generic structure: ##STR1## wherein the dashed line could be a single or a double carbon-carbon bond and processes and compositions containing same are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma and perfume and perfumed article aroma augmenting and enhancing compositions and for use in foodstuffs, tobacco, perfume and perfumed article aroma imparting compositions; produced by a process illustrated by the reaction: ##STR2## The above-mentioned compounds produce: (A) In food flavorings, sweet, black tea-like cocoa-like, damascenone-like, chocolate-like, dried fruit-like, rose petal-like aroma characteristics and sweet, black-tea-like, cocoa-like, damascenone-like, chocolate-like, tobacco-like, dried fruit-like and rose petal-like flavor characteristics; p0 (b) In tobacco, a sweet honey-like, rich, slightly fruity, dried fruit-like, hay tobacco-like, woody, cedarwood, raspberry-like, blackcurrant-like aroma prior to smoking and sweet, fruity, hay tobacco and Virginia tobacco-like aroma on smoking; and(c) In perfumes, fruity, floral, natural rose oil-like and earthy aromas with potato top notes and minty, tomato vine, Brussel sprout-like and woody undertones.
摘要翻译：具有通用结构的化合物1- [3-（甲硫基）丁酰基] -2,6,6-三甲基 - 环己烯和/或相应的1,3-环己二烯类似物，其中虚线可以是单个或描述了用于食品，口香糖，牙膏和医药产品风味和香气，烟草风味和芳香和香料和香料制品香气增强和增强组合物并用于食品中的双碳 - 碳键和含有它们的方法和组合物，烟草，香水和香料制品香气赋予组合物; 由反应说明的方法制备：上述化合物产生：

114. 发明授权

US4152457A Tropone derivatives 失效
公开(公告)号：US4152457A
公开(公告)日：1979-05-01
申请号：US840938
申请日：1977-10-11
申请人： Jehan F. Bagli , Tibor Bogri
发明人： Jehan F. Bagli , Tibor Bogri
IPC分类号： A61K31/215 , A61K31/265 , C07C55/06 , C07C69/74 , C07C317/00 , C07C317/08 , C07C317/14 , C07C327/22 , C07C147/04 , C07C147/14
CPC分类号： C07C323/22 , C07C317/00 , C07C327/00 , C07C2101/18
摘要： Tropone derivatives substituted with an amino-, thio- or oxy-derivative of oxalic acid or acetic acid are disclosed. In addition, the tropone nucleus can be optionally further substituted. The foregoing compounds are useful for preventing or treating allergic conditions in a mammal. Methods for the preparation and use of the compounds are disclosed.

115. 发明授权

US4081480A 2-Mercaptocyclododecanone-1 失效
标题翻译： 2-巯基环十二酮-1
公开(公告)号：US4081480A
公开(公告)日：1978-03-28
申请号：US773964
申请日：1977-03-03
申请人： William J. Evers , Howard H. Heinsohn, Jr. , Manfred Hugo Vock
发明人： William J. Evers , Howard H. Heinsohn, Jr. , Manfred Hugo Vock
IPC分类号： A23L27/20 , A23L27/29 , C07C45/63 , C07C49/16 , C07C49/27
CPC分类号： C07C323/22 , A23L27/2022 , A23L27/203 , A23L27/29 , C07C2101/20
摘要： The fruity flavor of a foodstuff is augmented or enhanced by the use of one or more .alpha.-oxy(oxo)mercaptans having the formula: ##STR1## wherein X is one of: ##STR2## or ##STR3## and R.sub.1 and R.sub.2, taken separately, are the same and are either of methyl, ethyl, 1-propyl or 2-propyl, or R.sub.1 and R.sub.2 taken together, is nonylene having the structure: ##STR4## said .alpha.-oxy(oxo)mercaptan being selected from the group consisting of:3-mercapto-4-heptanol;4-mercapto-5-nonanol;4-mercapto-5-nonanone;3-mercapto-2,6-dimethyl-4-heptanone;2-mercaptocyclododecanone-1; and2-mercapto-3-pentanoneThese compounds augment or enhance the green, grapefruit, fruity, buchu leaf oil-like, floral, green vegetable and/or minty aromas and grapefruit-like, green, citrus, bitter, lemon, buchu leaf oil-like, blackcurrant-like, green vegetable-like, and/or cooling notes of food flavors.
摘要翻译：通过使用一种或多种具有下式的α-氧代（氧代）硫醇来增强或增强食品的水果味：其中X是以下之一：其中X是以下之一：R1和R2，分别是相同的，并且是甲基，乙基，1-丙基或2-丙基，或者R 1和R 2一起是具有以下结构的亚芳基：所述α-氧代（氧代）硫醇选自：包含由...组成：

116. 发明授权

US4034044A Menthone-8-thiol, carvomenthone-8-thiol and process for preparing same 失效
标题翻译：麦醇-8-硫醇，卡维生酮-8-硫醇及其制备方法
公开(公告)号：US4034044A
公开(公告)日：1977-07-05
申请号：US355470
申请日：1973-04-30
申请人： Erling Sundt , Gunther Ohloff
发明人： Erling Sundt , Gunther Ohloff
IPC分类号： A23L27/20 , C11B9/00 , C07C49/31 , C07C45/00
CPC分类号： C07C323/22 , A23L27/203 , C11B9/0034 , C07C2101/14
摘要： New ketone-thiols and their use as perfuming and odor-modifying agents in the manufacture of perfumes and perfumed products, and as flavoring and taste-modifying agents in the preparation of foodstuffs in general and imitation flavors for foodstuffs, beverages, animal feeds, pharmaceutical preparations and tobacco products.A method for the preparation of said ketone-thiols.
摘要翻译：新的酮硫醇及其在制造香料和香料产品中作为加香和气味改性剂的用途，以及作为食品制备中的调味剂和味道调节剂以及用于食品，饮料，动物饲料，药物制剂和烟草制品。

117. 发明授权

US3950429A 2-Methylthio-myrtanal 失效
标题翻译： 2-甲硫基 - 乙基甲脒
公开(公告)号：US3950429A
公开(公告)日：1976-04-13
申请号：US464417
申请日：1974-04-26
申请人： Dietmar Lamparsky , Peter Schudel
发明人： Dietmar Lamparsky , Peter Schudel
IPC分类号： A23L27/20 , C11B9/00 , C07C47/34
CPC分类号： C11B9/0034 , A23L27/2022 , A23L27/203 , C07C323/22 , C07C2102/42
摘要： There are provided novel mercapto- or alkylthio-substituted oxo-terpenoids having 10 carbon atoms in the terpenoid skeleton. These novel compounds may be acyclic monocyclic or bicyclic. The novel compounds are useful as odorants particularly, but also for producing aromas, e.g. of a vegetable note.
摘要翻译：在萜类骨架中提供了具有10个碳原子的新的巯基或烷硫基取代的氧代萜类化合物。这些新化合物可以是无环单环或双环的。这些新化合物特别用作气味剂，但也可用于产生香味，例如，的蔬菜笔记。

118. 发明授权

US3939184A Production of carbonyl compounds substituted in .alpha.-position 失效
标题翻译：生成在{60-位取代的羰基化合物
公开(公告)号：US3939184A
公开(公告)日：1976-02-17
申请号：US344632
申请日：1973-03-26
申请人： Horst Koenig , Horst Metzger , Werner Reif
发明人： Horst Koenig , Horst Metzger , Werner Reif
IPC分类号： C07C323/22 , C07C69/66 , C07C117/00 , C07C121/76 , C07C122/00
CPC分类号： C07C45/518 , C07C201/08 , C07C231/10 , C07C231/12 , C07C247/12 , C07C253/04 , C07C253/30 , C07C255/00 , C07C315/00 , C07C319/14 , C07C323/22
摘要： Production of carbonyl compounds substituted in the .alpha.-position and having the formula: ##EQU1## wherein R.sup.1 is alkyl, aralkyl, phenyl, toluyl, naphthyl, alkoxy or amino; R.sup.2 is hydrogen ##EQU2## A is hydrogen, alkyl, halo or ##EQU3## R.sup.6 is hydrogen or methyl, and R.sup.11 is alkyl; wherein said compounds are formed by reacting a sulfur ylide having the formula: ##EQU4## wherein Y is the radical ##EQU5## and R.sup.9 and R.sup.10 are alkyl or phenyl, with a solution containing both an electrophilic agent A' that is converted into the radical A and a nucleophilic agent B' that is converted into the radical B. The resulting carbonyl compounds are useful as starting materials for the production of paper, textile, and leather auxiliaries, plant protection agents, alkyd resins, polyesters and polyamides.
摘要翻译：制备在α-位取代的具有下式的羰基化合物：其中R1是烷基，芳烷基，苯基，甲苯基，萘基，烷氧基或氨基; R2是氢R6R6O R6R6O || PARALLEL || PARALLEL -CH-CH-CN，-C-R1或-CH-CH-C-OR11; A是氢，烷基，卤素或R6R6 | -CH-CH-CN R6是氢或甲基，R11是烷基; 其中所述化合物通过使具有下列结构式的硫叶立德反应形成：其中Y是基团CH 3 R 9 = S ANGLE或= S ANGLE PARALLEL OCH 3 R 10，R 9和R 10是烷基或苯基，与含有转化为自由基A的亲电子试剂A'和转化为自由基B的亲核试剂B'的溶液。得到的羰基化合物可用作生产纸，纺织品和皮革助剂的原料植物保护剂，醇酸树脂，聚酯和聚酰胺。

119. 发明授权

US3900520A Mercapto-butanone substituted cyclohexenes 失效
标题翻译： MERCAPTO-BUTANONE替代CYCLOHEXENES
公开(公告)号：US3900520A
公开(公告)日：1975-08-19
申请号：US40458273
申请日：1973-10-09
申请人： GIVAUDAN CORP
发明人： SCHENK HANSPETER , SIGG-GRUTTER TRUDI
IPC分类号： A23C9/158 , A01N35/02 , A23G3/34 , A23L27/20 , A23L27/29 , A61K8/35 , A61Q13/00 , C07C67/00 , C07C313/00 , C07C323/22 , C07C327/22 , C07C401/00 , C07C403/00 , C07C403/22 , C11B9/00 , C11D3/50 , C11D9/44 , C07C49/48
CPC分类号： C07C323/22 , A23L27/203 , A23L27/204 , C07C2601/16
摘要： Novel cycloaliphatic ketones, a process for making them and odorant and/or flavoring compositions containing the ketones are described.

120. 发明授权

US3873624A Process of preparing {60 -formyl sulfides and 2-hydrocarbyl-thioaldoximes therefrom 失效
标题翻译：从其制备{60-甲基硫化物和2-烃基 - 硫代肟的方法
公开(公告)号：US3873624A
公开(公告)日：1975-03-25
申请号：US32797973
申请日：1973-01-30
申请人： ALLIED CHEM
发明人： MATHEW CHEMPOLIL THOMAS , ULMER HARRY EDWARDS
IPC分类号： C07C323/22 , C07C45/63 , C07C47/14 , C07C67/00 , C07C313/00 , C07C319/14 , C07C319/20 , C07C323/47 , C07C325/00 , C07F9/40 , C07C47/00
CPC分类号： C07C319/14 , C07C45/63 , C07C47/14 , C07F9/4006 , C07C323/22 , C07C323/47 , C07C323/60
摘要： AND OXIMATING THE Alpha -FORMYL SULFIDE TO FORM A 2HYDROCARBYLTHIOALDOXIME OF THE FORMULA

WHEREIN X is defined as above, reacting in an aqueous medium the Alpha -haloaldehyde with a thiol salt of the formula R''''''SM, wherein R'''''' and M are defined as above, to form an Alpha formyl sulfide of the formula

WHEREIN R'' and R'''' are defined as above, to form an Alpha haloaldehyde of the formula

Also, 2-hydrocarbylthioaldoximes are prepared by oximating the above Alpha -formyl sulfides by reaction with a source of hydroxylamine. Additionally, 2-hydrocarbylthioaldoximes are prepared by a process which comprises halogenating an aldehyde having the formula

WHEREIN R'' and R'''' independently are hydrogen, hydrocarbon radicals of 1 to 18 carbon atoms selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl and aryl, or substituted hydrocarbon radicals of the above group, and X is a halogen selected from the group consisting of chlorine, bromine, and iodine, with a thiol salt of the formula R''''''SM, wherein R'''''' is a hydrocarbon radical of 1 to 18 carbon atoms selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl and aryl or a substituted hydrocarbon radical of the above group; and M is an alkali or alkaline earth metal, thereby forming an Alpha -formyl sulfide of the formula

An Alpha -formyl sulfide is prepared by a process which comprises reacting in an aqueous medium an Alpha -haloaldehyde of the formula
摘要翻译：通过一种方法制备α-甲酰基硫化物，该方法包括在水性介质中使式WHEREIN R'和R“的α-卤代醛独立地为氢，1至18个碳原子的烃基选自烷基，环烷基，烯基，环烯基和芳基或上述取代的烃基，X是选自氯，溴和碘的卤素，其具有式R“'SM的硫醇盐，其中 R“是选自上述基团的烷基，环烷基，烯基，环烯基和芳基或取代的烃基的1至18个碳原子的烃基; M是碱金属或碱土金属，从而形成下式的α-甲酰硫醚。另外，通过与羟胺源反应，使上述α-甲酰基硫化物肟化，制备2-烃基硫代肟。另外，2-烃基硫代肟通过一种方法制备，该方法包括卤化具有如上定义的式WHEREIN R'和R“的醛，以形成式WHEREIN X如上所定义的α-卤代醛，用式R“'SM的硫醇盐介导α-卤代醛，其中R”'和M如上所定义，以形成下式的α-甲酰硫醚，并且将α-甲酰硫醚氧化成形式A 公式的2-羟基乙酰氧基

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