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111. 发明授权

US07534402B2 Method for forming a chemical microreactor 失效
标题翻译：形成化学微反应器的方法
公开(公告)号：US07534402B2
公开(公告)日：2009-05-19
申请号：US11196634
申请日：2005-08-02
申请人： Jeffrey D. Morse , Alan Jankowski
发明人： Jeffrey D. Morse , Alan Jankowski
IPC分类号： B01J19/24 , B81B1/00
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00824 , B01J2219/00828 , B01J2219/00831 , B01J2219/00835 , B01J2219/00844 , B01J2219/00871 , B01J2219/00873
摘要： Disclosed is a chemical microreactor that provides a means to generate hydrogen fuel from liquid sources such as ammonia, methanol, and butane through steam reforming processes when mixed with an appropriate amount of water. The microreactor contains capillary microchannels with integrated resistive heaters to facilitate the occurrence of catalytic steam reforming reactions. Two distinct embodiment styles are discussed. One embodiment style employs a packed catalyst capillary microchannel and at least one porous membrane. Another embodiment style employs a porous membrane with a large surface area or a porous membrane support structure containing a plurality of porous membranes having a large surface area in the aggregate, i.e., greater than about 1 m2/cm3. Various methods to form packed catalyst capillary microchannels, porous membranes and porous membrane support structures are also disclosed.
摘要翻译：公开了一种化学微反应器，其提供了当与适量的水混合时通过蒸汽重整过程从液体源例如氨，甲醇和丁烷产生氢燃料的手段。微反应器包含具有集成电阻加热器的毛细管微通道，以促进催化蒸汽重整反应的发生。讨论了两种不同的实施方式。一种实施方案采用填充催化剂毛细管微通道和至少一种多孔膜。另一种实施方案采用具有大表面积的多孔膜或多孔膜支撑结构，其包含多个聚集体中具有大表面积的多孔膜，即大于约1m 2 / cm 3。还公开了形成填充催化剂毛细管微通道，多孔膜和多孔膜支撑结构的各种方法。

112. 发明申请

US20090084496A1 Method for fabricating a microfluidic component comprising at least one microchannel filled with nanostructures 有权
标题翻译：用于制造包含填充有纳米结构的至少一个微通道的微流体组分的方法
公开(公告)号：US20090084496A1
公开(公告)日：2009-04-02
申请号：US12230924
申请日：2008-09-08
申请人： Agnes Fonverne , Jean Dijon , Florence Ricoul , Emmanuelle Rouviere
发明人： Agnes Fonverne , Jean Dijon , Florence Ricoul , Emmanuelle Rouviere
IPC分类号： B32B38/00
CPC分类号： B81C1/00206 , B01J19/0093 , B01J2219/00783 , B01J2219/00824 , B01J2219/00831 , B01J2219/00835 , B01J2219/00846 , B01J2219/00862 , B01J2219/00869 , B01J2219/00873 , B01L3/502707 , B01L3/502753 , B01L2300/0816 , B01L2300/0887 , B01L2300/12 , B81B2201/058 , B81B2203/0338 , B81C2201/019 , B81C2203/038
摘要： A microfluidic component comprises at least one closed microchannel filled with nanostructures. The microchannel is produced by previously forming an opening delineating a bottom wall and two opposite side walls of the microchannel in a surface of a substrate. The nanostructures filling said microchannel are formed by in situ growth to constitute a layer of metallic catalyst deposited on said side walls and on said wall bottom. The microchannel is closed, before the nanostructures are formed, by sealing a protective cover onto said surface of the substrate. Sealing is obtained by formation of an eutectic compound between a material of the cover and the metal of the catalyst used for in situ growth of the nanostructures and deposited on the surface of the substrate designed to come into contact with the cover.
摘要翻译：微流体组分包括填充有纳米结构的至少一个闭合微通道。微通道预先形成在衬底的表面中描绘微通道的底壁和两个相对的侧壁的开口。填充所述微通道的纳米结构通过原位生长形成，以构成沉积在所述侧壁上和所述壁底上的金属催化剂层。在形成纳米结构之前，通过将保护盖密封在基材的所述表面上来封闭微通道。通过在盖的材料和用于纳米结构的原位生长的催化剂的金属之间形成共晶化合物并沉积在设计成与盖接触的基板的表面上来获得密封。

113. 发明申请

US20090064579A1 HEAT EXCHANGE REFORMER UNIT AND REFORMER SYSTEM 审中-公开
标题翻译：热交换器改造器和改造系统
公开(公告)号：US20090064579A1
公开(公告)日：2009-03-12
申请号：US12297653
申请日：2007-04-24
申请人： Tomohisa Wakasugi , Takashi Shimazu , Kenji Kimura
发明人： Tomohisa Wakasugi , Takashi Shimazu , Kenji Kimura
IPC分类号： C10J3/68
CPC分类号： C01B3/384 , B01J19/0093 , B01J19/249 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00873 , B01J2219/1928 , B01J2219/2453 , B01J2219/2458 , B01J2219/2465 , B01J2219/247 , B01J2219/2479 , B01J2219/2481 , B01J2219/2485 , B01J2219/2486 , B01J2219/2487 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/12 , C01B2203/141 , Y02P20/128
摘要： In a heat exchange reformer unit, a reforming passage supporting reform catalyst for inducing reforming reactions and a combustion passage supporting oxidizing catalyst for combustion are disposed adjacent to each other with a plate portion interposed therebetween. Heat-exchanging passages of the reforming passage that produce reformate gas that contains hydrogen from supplied reformation material, and heat-exchanging passages of the combustion passage that supply heat, which is generated by catalytically burning supplied fuel, to the reforming passage constitute a parallel-flow heat exchanger. Reformation material guide passages for introducing reformation material into the heat-exchanging passages in a predetermined direction, and mixed gas guide passages for introducing fuel into the heat-exchanging passages in a direction intersecting the gas flow direction in the reformation material guide passages, are provided upstream of the heat-exchanging passages in a gas flow direction.
摘要翻译：在热交换重整单元中，配置有用于引起重整反应的重整催化剂的重整通道和支持用于燃烧的氧化催化剂的燃烧通道彼此相邻地设置有插入其间的板部分。从供给的改质材料生成含有氢的重整气体的重整通道的热交换通道和通过催化燃烧供给燃料而产生的供给热量的燃烧通路的热交换通道构成并联 - 流量热交换器。提供了用于将改质材料沿预定方向引入热交换通道的改造材料引导通道，以及用于将燃料沿着与改变材料引导通道中的气体流动方向相交的方向将燃料引入热交换通道的混合气体引导通道在气体流动方向上在热交换通道的上游。

114. 发明申请

US20080274557A1 Permethylation Of Oligosaccharides 审中-公开
标题翻译：寡糖的乙基化
公开(公告)号：US20080274557A1
公开(公告)日：2008-11-06
申请号：US11817436
申请日：2006-03-03
申请人： Pilsoo Kang , Yehia S. Mechref , Milos V. Novotny
发明人： Pilsoo Kang , Yehia S. Mechref , Milos V. Novotny
IPC分类号： G01N33/00 , B01J19/00 , C07H1/00
CPC分类号： B01J19/0093 , B01J2219/00788 , B01J2219/00824 , B01J2219/00835 , B01J2219/00837 , B01J2219/00891 , B01J2219/00916 , B01J2219/00957 , C07K1/1077 , G01N30/02 , Y10T436/11 , Y10T436/143333 , Y10T436/25 , B01D15/325
摘要： A solid-phase permethylation procedure is described. For example, solid-phase permethylation can be utilized to prepare permethylated linear and branched, neutral and sialylated oligosaccharides, which can be analyzed by MALDI-MS.
摘要翻译：描述了固相去甲基化方法。例如，可以使用固相甲基化来制备可以通过MALDI-MS分析的二甲基化的直链和支链，中性和唾液酸化寡糖。

115. 发明申请

US20080184915A1 PROCESS FOR MAKING UNSATURATED HYDROCARBONS USING MICROCHANNEL PROCESS TECHNOLOGY 有权
标题翻译：使用微通道工艺技术制备不饱和烃的方法
公开(公告)号：US20080184915A1
公开(公告)日：2008-08-07
申请号：US11670608
申请日：2007-02-02
申请人： Anna Lee Tonkovich , Thomas Yuschak , Timothy J. LaPlante , Scott Rankin , Steven T. Perry , Sean Patrick Fitzgerald , Wayne W. Simmons , Terry Mazanec , Eric Daymo
发明人： Anna Lee Tonkovich , Thomas Yuschak , Timothy J. LaPlante , Scott Rankin , Steven T. Perry , Sean Patrick Fitzgerald , Wayne W. Simmons , Terry Mazanec , Eric Daymo
IPC分类号： C10G47/00
CPC分类号： C10G47/22 , B01J19/0093 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00833 , B01J2219/0086 , B01J2219/00873 , B01J2219/00889 , B01J2219/00891 , C07C5/327 , C07C5/48 , C10G9/18 , C10G45/00 , C07C11/04
摘要： The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200° C. to about 1200° C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.
摘要翻译：所公开的发明涉及将包含一种或多种烃的进料组合物转化成包含一种或多种不饱和烃的产物的方法，该方法包括：将进料组合物和蒸汽在微通道反应器中彼此接触，温度为范围为约200℃至约1200℃，以将进料组合物转化为产物，该方法的特征在于不存在用于将一种或多种烃转化为一种或多种不饱和烃的催化剂。氢和/或氧可以与进料组合物和蒸汽组合。

116. 发明申请

US20080058574A1 Microchannel Apparatus and Methods of Conducting Catalyzed Oxidative Dehydrogenation 有权
标题翻译：微通道装置和催化氧化脱氢方法
公开(公告)号：US20080058574A1
公开(公告)日：2008-03-06
申请号：US11469847
申请日：2006-09-01
申请人： Anna Lee Tonkovich , Bin Yang , Steven T. Perry , Terry Mazanec , Ravi Arora , Francis P. Daly , Richard Long , Thomas D. Yuschak , Paul W. Neagle , Amanda Glass
发明人： Anna Lee Tonkovich , Bin Yang , Steven T. Perry , Terry Mazanec , Ravi Arora , Francis P. Daly , Richard Long , Thomas D. Yuschak , Paul W. Neagle , Amanda Glass
IPC分类号： C07C5/333
CPC分类号： C07C5/48 , B01J19/0093 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/0086 , B01J2219/00869 , B01J2219/00873 , B01J2219/00891 , B01J2219/00984 , C01B3/386 , C01B3/50 , C01B2203/0261 , C01B2203/04 , C01B2203/048 , C01B2203/1035 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1247 , C07C2523/42 , C07C2523/44 , C07C2523/52 , C07C11/04
摘要： Methods of oxidative dehydrogenation are described. Surprisingly, Pd and Au alloys of Pt have been discovered to be superior for oxidative dehydrogenation in microchannels. Methods of forming these catalysts via an electroless plating methodology are also described. An apparatus design that minimizes heat transfer to the apparatus' exterior is also described.
摘要翻译：描述了氧化脱氢方法。令人惊奇的是，已经发现Pt的Pd和Au合金对于微通道中的氧化脱氢是优越的。还描述了通过化学镀方法形成这些催化剂的方法。还描述了最小化到设备外部的热传递的设备设计。

117. 发明申请

US20070254095A1 Catalyst filling method in micro-channels and reforming apparatus manufactured by the method 失效
标题翻译：微通道中的催化剂填充方法和通过该方法制造的重整装置
公开(公告)号：US20070254095A1
公开(公告)日：2007-11-01
申请号：US11783652
申请日：2007-04-11
申请人： Ji Ha , Young Oh , Jae Jang , Hong Lee , Jae Gil , Sung Kim
发明人： Ji Ha , Young Oh , Jae Jang , Hong Lee , Jae Gil , Sung Kim
IPC分类号： B05D7/22
CPC分类号： B01J19/0093 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00828 , B01J2219/00831 , B01J2219/00833 , B01J2219/00835 , B01J2219/0086 , C01B3/323 , C01B2203/0227 , C01B2203/1288 , H01M8/0631 , Y02P70/56
摘要： A catalyst filling method in a micro channel and a reformer manufactured by the method. The catalyst is filled in the micro channel using water, and unidirectional pressure is applied to the catalyst in the micro channel to fill the micro channel with high density. The catalyst in the micro channel is dried. The method according to the present invention allows uniformly filling the catalyst particles in the micro channel of the reformer with high density, increasing the reactive surface area of the catalyst particles with the fuel, thereby allowing highly efficient reforming effect.
摘要翻译：微通道中的催化剂填充方法和通过该方法制造的重整器。使用水将催化剂填充在微通道中，并且向微通道中的催化剂施加单向压力以以高密度填充微通道。将微通道中的催化剂干燥。根据本发明的方法允许以高密度均匀地填充重整器的微通道中的催化剂颗粒，增加催化剂颗粒与燃料的反应表面积，从而允许高效的重整效果。

118. 发明申请

US20070217970A1 Reaction apparatus 审中-公开
标题翻译：反应装置
公开(公告)号：US20070217970A1
公开(公告)日：2007-09-20
申请号：US11716875
申请日：2007-03-12
申请人： Kaoru Saito , Naotomo Miyamoto , Tadao Yamamoto
发明人： Kaoru Saito , Naotomo Miyamoto , Tadao Yamamoto
IPC分类号： B01J19/00
CPC分类号： C01B3/323 , B01J19/0093 , B01J19/249 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00833 , B01J2219/00835 , B01J2219/00867 , B01J2219/00959 , B01J2219/00961 , B01J2219/2453 , B01J2219/2458 , B01J2219/2466 , B01J2219/2467 , B01J2219/247 , B01J2219/2479 , B01J2219/2485 , B01J2219/2486 , B01J2219/2487 , B01J2219/2488 , B01J2219/249 , B01J2219/2496 , C01B3/583 , C01B2203/0233 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0822 , C01B2203/0827 , C01B2203/085 , C01B2203/0866 , C01B2203/1035 , C01B2203/1064 , C01B2203/1076 , C01B2203/1223 , C01B2203/1288 , Y02E60/324 , Y02P20/128
摘要： Disclosed is a reaction apparatus, comprising a reaction container to receive a supply of a reactant and to cause a reaction of the reactant supplied thereto, wherein the reaction container comprises a hollow box member having a first plate wherein a supplying passage of the reactant is formed, a second plate opposite to the first plate, and a third plate provided continuously with edges of the first and second plates, at least one partition plate which is disposed to partition a space inside the box member and to form a reaction passage through which the reactant flows, the partition plate or each of the partition plates including a diaphragm portion provided substantially in a perpendicular direction to the second plate and a joint portion provided at an end of the diaphragm portion substantially perpendicularly thereto, and the joint portion being joined to an inner surface of the second plate.
摘要翻译：公开了一种反应装置，包括反应容器，用于接收反应物的供应并引起反应物的反应，其中反应容器包括具有第一板的中空箱件，其中形成反应物的供应通道，与第一板相对的第二板，以及连续设置第一板和第二板的边缘的第三板，至少一个隔板，其设置成隔开箱构件内的空间并形成反作用通道，反应物流动，隔板或每个隔板包括基本上与第二板垂直的方向设置的隔膜部分和设置在隔膜部分的基本上垂直于其的端部的接合部分，并且接合部分接合到第二板的内表面。

119. 发明申请

US20070217963A1 Microfluidic chip capable of synthesizing radioactively labeled molecules on a scale suitable for human imaging with positron emission tomography 有权
标题翻译：能够以适合于使用正电子发射断层扫描的人成像的量表合成放射性标记分子的微流控芯片
公开(公告)号：US20070217963A1
公开(公告)日：2007-09-20
申请号：US11540344
申请日：2006-09-29
申请人： Arkadij Elizarov , Hartmuth Kolb
发明人： Arkadij Elizarov , Hartmuth Kolb
IPC分类号： B01J19/00
CPC分类号： B01F11/0042 , B01F11/0071 , B01F13/0059 , B01J19/0093 , B01J2219/00286 , B01J2219/00396 , B01J2219/00398 , B01J2219/00414 , B01J2219/00418 , B01J2219/00495 , B01J2219/00585 , B01J2219/00599 , B01J2219/00731 , B01J2219/00759 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00826 , B01J2219/00828 , B01J2219/00831 , B01J2219/00833 , B01J2219/00858 , B01J2219/0086 , B01J2219/00862 , B01J2219/00873 , B01J2219/00889 , B01J2219/00891 , B01J2219/00907 , B01J2219/00916 , B01J2219/00927 , B01J2219/00986
摘要： Described herein are automated, integrated microfluidic device comprising a chemical reaction chip comprising for performing chemical reaction, a microscale column integrated with the chip and configured for liquid flow from the column to at least one flow channel, and wherein the fluid flow into the column is controlled by on-chip valves; and comprising at least two on-chip valves for controlling fluid flow in the microfluidic device.
摘要翻译：本文描述的是包括用于进行化学反应的化学反应芯片的自动化集成微流体装置，与芯片集成的微量柱，并且构造成用于从柱流到至少一个流动通道的液体流，并且其中流入塔的流体流是由片上阀控制; 并且包括用于控制微流体装置中的流体流动的至少两个片上阀。

120. 发明申请

US20070071653A1 Reactor 失效
标题翻译：反应堆
公开(公告)号：US20070071653A1
公开(公告)日：2007-03-29
申请号：US11529685
申请日：2006-09-28
申请人： Naotomo Miyamoto , Kaoru Saito , Tadao Yamamoto
发明人： Naotomo Miyamoto , Kaoru Saito , Tadao Yamamoto
IPC分类号： B01J19/00 , B01J19/32
CPC分类号： B01J19/0093 , B01J19/249 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00833 , B01J2219/00835 , B01J2219/00867 , B01J2219/00959 , B01J2219/00961 , B01J2219/2453 , B01J2219/2458 , B01J2219/2466 , B01J2219/2467 , B01J2219/247 , B01J2219/2479 , B01J2219/2485 , B01J2219/2486 , B01J2219/2487 , B01J2219/2488 , B01J2219/249 , B01J2219/2496 , C01B3/323 , C01B2203/0233 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/085 , C01B2203/1035 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , Y02E60/324 , Y02P20/128
摘要： A reactor supplied with a reactant to cause reaction of the reactant includes a reaction device which has a hollow box type member having a top plate and a bottom plate opposed to each other and side plates connected to an edge of the top plate and an edge of the bottom plate. A partition member is housed in the box type member, the partition member coming into contact with at least internal faces of the side plates of the box type member and partitioning a space in the box type member into a plurality of reaction chambers to which the reactant is to be supplied. A penetrating region is provided in the partition member to connect the adjacent reaction chambers to each other, the penetrating region having the reactant passed therethrough.
摘要翻译：提供有反应物以引起反应物的反应物的反应器包括反应装置，该反应装置具有中空箱型构件，该中空箱型构件具有彼此相对的顶板和底板以及连接到顶板边缘的侧板和底板。分隔构件容纳在箱型构件中，分隔构件至少与箱型构件的侧板的内表面接触并将箱型构件中的空间分隔成多个反应室，反应物将供应。在分隔构件中设置穿透区域，以将相邻的反应室彼此连接，使具有反应物的穿透区域通过。

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