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    • 113. 发明授权
    • Paper products containing a biodegradable chemical softening composition
    • 纸制品含有可生物降解的化学软化组合物
    • US5312522A
    • 1994-05-17
    • US4334
    • 1993-01-14
    • Dean Van PhanPaul D. TrokhanToan Trinh
    • Dean Van PhanPaul D. TrokhanToan Trinh
    • D21H17/06D21H17/07D21H17/14D21H17/53D21H21/22
    • D21H17/07D21H17/06D21H17/14D21H17/53D21H21/22
    • Fibrous cellulose materials useful in the manufacture of soft, absorbent paper products such as paper towels, facial tissues, and toilet tissue are disclosed. The paper products contain a biodegradable chemical softening composition comprising a mixture of a biodegradable quaternized ester-amine compound and a polyhydroxy compound. Preferred biodegradable quaternized ester-amine compounds include diester dialkyldimethylammonium salts such as the diester ditallow dimethyl ammonium chloride, diester di(touch hydrogenated) tallow dimethyl ammonium chloride and diester di(hydrogenated) tallow dimethyl ammonium chloride. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, and polyethylene glycols and polypropylene glycols having a weight average molecular weight from about 200 to 4000.The biodegradable chemical softening compositions are prepared by first mixing the biodegradable quaternized ester-amine compound into the polyhydroxy compound at a specific temperature range wherein the polyhydroxy compound is miscible with the biodegradable quaternized ester-amine compound and then diluting the mixture with water at an specific temperature and pH range to form an aqueous vesicle dispersion suitable for treating the fibrous cellulose material.
    • 公开了用于制造柔软的,吸收性纸制品如纸巾,面巾纸和卫生纸的纤维素纤维素材料。 纸产品含有可生物降解的化学软化组合物,其包含可生物降解的季铵化酯 - 胺化合物和多羟基化合物的混合物。 优选的可生物降解的季铵化胺 - 胺化合物包括二酯二烷基二甲基铵盐如二酯二牛脂二甲基氯化铵,二酯(触摸氢化)牛脂二甲基氯化铵和二酯(氢化)牛脂二甲基氯化铵。 优选的多羟基化合物选自甘油,聚乙二醇和重均分子量为约200至4000的聚丙二醇。可生物降解的化学软化组合物是通过首先将生物降解的季铵化的胺 - 胺化合物混合到多羟基 化合物在特定温度范围内,其中多羟基化合物与可生物降解的季铵化胺 - 胺化合物混溶,然后在特定温度和pH范围内用水稀释混合物,形成适于处理纤维状纤维素材料的水性囊泡分散体。
    • 114. 发明授权
    • Solid, particulate fabric softener with protected, dryer-activated,
cyclodextrin/perfume complex
    • 固体,具有保护,干活性,环糊精/香料复合物的颗粒织物
    • US5232612A
    • 1993-08-03
    • US751402
    • 1991-08-28
    • Toan TrinhDennis R. Bacon
    • Toan TrinhDennis R. Bacon
    • D06M13/46C11D3/00C11D3/22C11D3/50C11D17/00D06M13/02D06M13/224D06M13/322D06M13/35D06M13/352D06M13/402D06M13/405D06M15/03D06M23/12
    • C11D17/0039C11D3/001C11D3/222C11D3/505
    • Fabric softening compositions, preferably in liquid form, for use in the rise cycle of home laundry operations are improved by: (a) using certain protected water sensitive materials, especially particulate complexes of cyclodextrins and perfumes, which are protected in fabric softening compositions and/or detergent compositions, by e.g., imbedding said particulate complex in relatively high melting protective material that is substantially water-insoluble and, preferably, non-water-swellable and is solid at normal storage conditions, but which melts at the temperatures encountered in automatic fabric dryers (laundry dryers); (b) using soil release polymers to help suspend water-insoluble particles in aqueous fabric softening compositions: and/or (c) preparing the said protected particulate water sensitive materials (complexes) by melting the said high melting materials, dispersing the said particulate complexes, or other water sensitive material, in the molten high melting protective material and dispersing the resulting molten mixture in aqueous media, especially surfactant solution or aqueous fabric softener composition, and cooling to form small, smooth, spherical particles of the particulate complexes, or other water sensitive material, substantially protected by the high melting material.
    • 织物软化组合物,优选为液体形式,用于家庭洗衣操作的上升循环,通过:(a)使用某些受保护的水敏感材料,特别是环糊精和香料的颗粒复合物,其在织物软化组合物和/ 或洗涤剂组合物,例如,将所述颗粒状复合物嵌入基本上不溶于水的较高熔点的保护材料中,优选非水溶胀性和在正常储存条件下为固体,但是在自动织物中遇到的温度下熔化 干衣机(洗衣机); (b)使用去污聚合物帮助将水不溶性颗粒悬浮在水性织物软化组合物中;和/或(c)通过熔化所述高熔点材料来制备所述受保护的颗粒状水敏感材料(复合物),将所述颗粒状复合物 或其它水敏材料,并将所得熔融混合物分散在水性介质,特别是表面活性剂溶液或水性织物柔软剂组合物中,并冷却以形成颗粒状复合物的小而平滑的球形颗粒,或其它 水敏感材料,基本上被高熔点材料保护。
    • 115. 发明授权
    • Liquid fabric softener with insoluble particles stably suspended by soil
release polymer
    • 具有不溶性颗粒的液体织物柔软剂由土壤释放聚合物稳定
    • US5207933A
    • 1993-05-04
    • US751427
    • 1991-08-28
    • Toan TrinhHelen B. Tordil
    • Toan TrinhHelen B. Tordil
    • D06M13/46C11D3/00C11D3/22C11D3/37C11D3/50D06M13/02D06M13/148D06M13/224D06M13/322D06M13/35D06M13/352D06M13/402D06M13/405D06M15/03D06M23/12
    • C11D3/0015C11D3/0036C11D3/222C11D3/3715C11D3/505
    • Fabric softening compositions, preferably in liquid form, for use in the rinse cycle of home laundry operations are improved by: (a) using certain protected water sensitive materials, especially particulate complexes of cyclodextrins and perfumes, which are protected in fabric softening compositions and/or detergent compositions, by e.g., imbedding said particulate complex in relatively high melting protective material that is substantially water-insoluble and, preferably, non-water-swellable and is solid at normal storage conditions, but which melts at the temperatures encountered in automatic fabric dryers (laundry dryers); (b) using soil release polymers to help suspend water-insoluble particles in aqueous fabric softening compositions; and/or (c) preparing the said protected particulate water sensitive materials (complexes) by melting the said high melting materials, dispersing the said particulate complexes, or other water sensitive material, in the molten high melting protective material and dispersing the resulting molten mixture in aqueous media, especially surfactant solution or aqueous fabric softener composition, and cooling to form small, smooth, spherical particles of the particulate complexes, or other water sensitive material, substantially protected by the high melting material.
    • 通过以下方式改善用于家庭洗衣操作的漂洗循环中的织物软化组合物,优选为液体形式:(a)使用某些受保护的水敏感材料,特别是环糊精和香料的颗粒复合物,其在织物柔软组合物和/ 或洗涤剂组合物,例如,将所述颗粒状复合物嵌入基本上不溶于水的较高熔点的保护材料中,优选非水溶胀性和在正常储存条件下为固体,但是在自动织物中遇到的温度下熔化 干衣机(洗衣机); (b)使用去污聚合物帮助将水不溶性颗粒悬浮在水性织物软化组合物中; 和/或(c)通过熔化所述高熔点材料,将所述颗粒复合物或其它水敏物质分散在熔融的高熔点保护材料中并分散所得的熔融混合物来制备所述受保护的颗粒状水敏感材料(络合物) 在水性介质中,特别是表面活性剂溶液或水性织物柔软剂组合物,并冷却以形成基本被高熔点材料保护的颗粒复合物或其它水敏材料的小而平滑的球形颗粒。