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101. 发明授权

US4910077A Polynorbornene laminates and method of making the same 失效
标题翻译：聚降冰片烯层压板及其制作方法
公开(公告)号：US4910077A
公开(公告)日：1990-03-20
申请号：US228034
申请日：1988-08-04
申请人： George M. Benedikt
发明人： George M. Benedikt
IPC分类号： B32B15/08 , B32B27/04 , C08F32/00 , C08F32/08 , C08F290/00 , C08F299/00 , C08G61/08 , C08J5/08 , C08J5/24 , C09J5/02 , H05K1/03 , H05K3/38
CPC分类号： C08J5/08 , B32B15/08 , C08G61/08 , C08J5/24 , H05K1/032 , H05K3/389 , C08J2365/00 , H05K1/0366 , H05K2201/0355 , Y10S428/901 , Y10T29/49126 , Y10T428/12549 , Y10T428/12569 , Y10T442/3415 , Y10T442/656
摘要： Printed wiring boards useful for high frequency applications are obtained by laminating a copper foil pretreated with a silane to a polynorbornene prepreg. The prepreg is made by impregnating a fiberglass cloth with a ring-opening polymerized polymer. The copper foil is pretreated with a silane which is capable of improving the bond strength between the copper foil and a norbornene copolymer.

102. 发明授权

US4900763A Ultraviolet radiation curable vehicles 失效
标题翻译：紫外线辐射固化车
公开(公告)号：US4900763A
公开(公告)日：1990-02-13
申请号：US160740
申请日：1988-02-26
申请人： Douglas J. Kraushaar
发明人： Douglas J. Kraushaar
IPC分类号： C08F299/00 , C04B41/50 , C04B41/52 , C04B41/86 , C04B41/89 , C08F2/50 , C08F290/00 , C08F299/02 , C08F299/06
CPC分类号： C04B41/009 , C04B41/5022 , C04B41/52 , C04B41/86 , C04B41/89 , C08F299/024 , C08F299/065
摘要： Vehicles for ultraviolet radiation-curable ceramic enamels comprising (a) acrylate- or methacrylate- modified oligomers; (b) monofunctional acrylate- or methacrylate-modified monomers; (c) pentafunctional acrylate or methacrylate-modified monomers; and (d) a photoinitiator system for said polymerizable components; and the enamels prepared therefrom comprising glass enamels and the vehicles as described.
摘要翻译：用于紫外线辐射固化的陶瓷搪瓷的载体，其包含（a）丙烯酸酯或甲基丙烯酸酯改性的低聚物; （b）单官能丙烯酸酯或甲基丙烯酸酯改性的单体; （c）五官能丙烯酸酯或甲基丙烯酸酯改性单体; 和（d）用于所述可聚合组分的光引发剂体系; 和由其制备的搪瓷包括玻璃搪瓷和所述的载体。

103. 发明授权

US4888403A Process for producing plastic-like woody moldings from dibasic acid anhydrides and unsaturated monoglycidyl ethers 失效
标题翻译：从二元酸酐和不饱和单缩水甘油醚生产塑料样木质成型品的方法
公开(公告)号：US4888403A
公开(公告)日：1989-12-19
申请号：US148574
申请日：1988-01-26
申请人： Minoru Ueda , Hideaki Matsuda , Hideki Mori
发明人： Minoru Ueda , Hideaki Matsuda , Hideki Mori
IPC分类号： C08J5/00 , B27K5/00 , C08F290/00 , C08F299/00 , C08F299/02 , C08H8/00 , C08L97/00 , C08L97/02
CPC分类号： C08H8/00 , C08F299/024 , C08L97/02
摘要： The process for producing a plastic-like cured woody molding, which comprises applying a pressure necessary for plasticizing at least a woody component at temperature of from 120.degree. C. to 180.degree. C. to a composition comprising (A) an oligoesterified woody material obtained by alternately adding a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond to the hydroxy groups of a woody material and (B) an oligomer obtained from a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond with the addition of (C) a radical polymerization initiator to simultaneously perform the plasticization and crosslinking by the polymerization of the unsaturated double bonds. The plastic-like cured woody moldings thus obtained have dense and glossy surfaces and are particularly excellent in dimensional stability, mechanical properties and heat distortion temperature.
摘要翻译：一种塑料状固化木质成型体的制造方法，其包括将至少一种木质成分在120℃至180℃的温度下塑化所需的压力，包括（A）获得的低聚酯化木质材料通过向木质材料的羟基交替添加具有不饱和双键的多元酸酐和单环氧化合物，和（B）由多元酸酐和具有不饱和双键的单环氧化合物得到的低聚物，加入（C）自由基聚合引发剂，通过不饱和双键的聚合同时进行增塑和交联。由此获得的塑料状固化木质模制品具有致密和光泽的表面，并且在尺寸稳定性，机械性能和热变形温度方面特别优异。

104. 发明授权

US4871816A Triblock polyarylene polyether with polysiloxane segment and impact-improved blends thereof 失效
标题翻译：具有聚硅氧烷链段的三嵌段聚亚芳基聚醚和其冲击改进的共混物
公开(公告)号：US4871816A
公开(公告)日：1989-10-03
申请号：US111317
申请日：1987-10-22
申请人： Virgil Percec , Paul P. Nicholas , Dana Garcia
发明人： Virgil Percec , Paul P. Nicholas , Dana Garcia
IPC分类号： C08F299/00 , C08G65/40 , C08G65/48 , C08G81/00 , C08L71/00
CPC分类号： C08G81/00 , C08F299/00 , C08G65/40 , C08G65/4012 , C08G65/48 , C08L71/00 , C08L2205/05
摘要： Polyarylene polyethers ("PAPE") with vinyl chain ends may be crosslinked to form networks with excellent physical and chemical properties except they tend to be brittle. In particular, a polysulfone ("PSU" made from bisphenol A and dichlorodiphenyl sulfone) with vinylbenzyl chain ends ("di-VB-PSU") is too brittle for many applications where impact resistance is essential. This brittleness is combatted by inserting a thermally stable rubbery poly(dimethylsiloxane) ("PDMS") segment having a number average molecular weight in the range from about 600 to about 5000 connected to di-VB-PSU segments by hydrosilylation in the presence of a Pt catalyst, to form a thermoplastic linear predominantly triblock oligomer with vinylbenzyl chain ends which are thermally crosslinkable. When crosslinked, the network formed has improved impact resistance and toughness, with only a little loss in the upper glass transition temperature if the relative lengths of the PDMS and PAPE are such as to provide the desired degree of phase microincompatibility sufficient to improve toughness. The triblock may be blended with a polymer with which the triblock may be crosslinked upon curing. If the VB-PSU-PDMS-PSU-VB triblock is blended with di-VB-PSU the polyblend may be crosslinked to provide improved toughness.
摘要翻译：具有乙烯基链末端的聚亚芳基聚醚（“PAPE”）可以交联以形成具有优异物理和化学性质的网络，除非它们易于脆化。具体地说，具有乙烯基苄基链端（“di-VB-PSU”）的聚砜（“双酚A和二氯二苯基砜制备的”PSU“）对于耐冲击性至关重要的许多应用来说太脆了。通过在存在下存在下通过氢化硅烷化插入数均分子量在约600至约5000的数均分子量的热稳定的橡胶状聚（二甲基硅氧烷）（“PDMS”）链段，来抵抗这种脆性。 Pt催化剂，以形成热塑性线性主要是三嵌段低聚物，其具有可热交联的乙烯基苄基链端。当交联时，所形成的网络具有改进的抗冲击性和韧性，如果PDMS和PAPE的相对长度能够提供足以提高韧性的所需程度的相微相容性，则在上玻璃化转变温度中仅有一点损失。三嵌段可以与固化时三嵌段可以交联的聚合物共混。如果将VB-PSU-PDMS-PSU-VB三嵌段与二-VP-PSU混合，则可将该共混物交联以提供改善的韧性。

105. 发明授权

US4864003A Block-graft polymer and process for producing it 失效
标题翻译：嵌段聚合物及其制备方法
公开(公告)号：US4864003A
公开(公告)日：1989-09-05
申请号：US229738
申请日：1988-08-01
申请人： Teruo Fujimoto , Mikio Shiono , Osamu Watanabe , Koichi Ito
发明人： Teruo Fujimoto , Mikio Shiono , Osamu Watanabe , Koichi Ito
IPC分类号： C08F293/00 , C08F8/44 , C08F275/00 , C08F285/00 , C08F287/00 , C08F290/00 , C08F297/00 , C08F297/02 , C08F299/00 , C08G65/02 , C08G65/08 , C08G77/42 , C08G77/442 , C08G81/02
CPC分类号： C08G81/024 , C08F275/00 , C08F287/00 , C08F297/02 , C08F8/44 , C08G81/021
摘要： Disclosed are a block-graft copolymer comprising a polymer block having a repetitive unit represented by General Formula: ##STR1## wherein A represents an organopolysiloxane chain, a polyalkylene oxide chain, a polyalkylene-imine chain, a polyacrylate chain or a polyacryloyl chain,and a process for producing the same. This block-graft copolymer can have various performances such as an oxygen enrichment performance, an ion concentration property, a capability of forming a complex with a metal salt and a biocompatibility, depending on the kind of graft polymer chains.
摘要翻译：公开了一种嵌段共聚物，其包含具有由通式表示的重复单元的聚合物嵌段：其中A表示有机聚硅氧烷链，聚环氧烷链，聚亚烷基亚胺链，聚丙烯酸酯链或聚丙烯酰基链，以及其制造方法。根据接枝聚合物链的种类，该嵌段共聚物可以具有各种性能，例如富氧性能，离子浓度性质，与金属盐形成络合物的能力和生物相容性。

106. 发明授权

US4847329A (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylate polymers and compositions made therefrom 失效
标题翻译：（N-取代氨基甲酰氧基）烷酰氧基烷基丙烯酸酯聚合物及由其制备的组合物
公开(公告)号：US4847329A
公开(公告)日：1989-07-11
申请号：US67828
申请日：1987-06-30
申请人： Joseph V. Koleske , Donald F. Smith, Jr. , Robert J. Weber, Jr.
发明人： Joseph V. Koleske , Donald F. Smith, Jr. , Robert J. Weber, Jr.
IPC分类号： C08F299/00 , C08F20/36 , C08F290/00
CPC分类号： C08F20/36 , Y10T428/31681 , Y10T428/31688 , Y10T428/31699
摘要： This invention is directed to polymers (including oligomers) that contain (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylates, to a process for their preparation by reacting the carbamoyloxy alkanoyloxyalkyl acrylates with other ethylenically unsaturated monomers, and to coating, ink, adhesive, and sealant compositions (including the cured coatings, inks, adhesives, and sealants) that are obtained by crosslinking the above compositions by various means. The cured compositions, which are, for example, high-quality industrial finishes, sealants or encapsulants, are made by incorporation of various conventional crosslinking agents and other normally-used formulating ingredients with the polymeric compositions of the invention.

107. 发明授权

US4789710A Process for preparation of a room-temperature curable resin 失效
标题翻译：室温固化树脂的制备方法
公开(公告)号：US4789710A
公开(公告)日：1988-12-06
申请号：US135408
申请日：1987-12-21
申请人： Hisao Furukawa , Jo Kawamura
发明人： Hisao Furukawa , Jo Kawamura
IPC分类号： C08F8/30 , C08F8/42 , C08F20/34 , C08F22/22 , C08F290/00 , C08F299/00 , C08G18/10 , C08G18/83 , C08G63/91 , C08G71/00 , C08G71/04 , C08G85/00 , C08G18/61
CPC分类号： C08G85/004 , C08G18/10 , C08G18/837 , Y10T428/2969
摘要： A process for the preparation of a room-temperature curable resin comprises reacting a compound (A) containing at least two acryloyl groups and/or methacryloyl groups in a molecule, and having from 100 to 100,000 of number-average molecular weight, with an aminosilane compound (B) represented by formula, ##STR1## (wherein X is a hydrolyzable group selected from the group consisting of halogen, alkoxy, acryloxy, ketoxymate, amino, acid amide, aminoxy, mercapto, alkenyloxy groups; R.sub.1 is C.sub.1 -C.sub.10 alkyl group, aryl group, or aralkyl group; n is an integer of from 1 to 3, and m is an integer of from 1 to 10),at the ratio of at least 0.2 equivalents of primary amino groups contained in the compound (B) to equivalent of acryloyl groups and/or methacryloyl groups contained in the compound (A), under substantially water-free condition, subsequently reacting the reaction product of aminosilane-modified resin and, furtherwith a monofunctional isocyanate compound (C) represented by formula,R.sub.3 --NCO(wherein R.sub.3 is a C.sub.1 -C.sub.25 alkyl group, aryl group, aralkyl group, (C.sub.2 H.sub.5 O).sub.3 Si--CH.sub.2).sub.3 or (CH.sub.3 O).sub.3 Si--CH.sub.2).sub.3)at the ratio of from 0.9 to 1.5 equivalents to equivalent of active hydrogen of amino groups contained in the aminosilane-modified resin, and under substantially water-free condition to obtain a room-temperature curable resin having 2 mg KOH or lower of an amine value.

108. 发明授权

US4763312A Bonding structure for timepieces 失效
标题翻译：钟表的结合结构
公开(公告)号：US4763312A
公开(公告)日：1988-08-09
申请号：US132247
申请日：1987-12-14
申请人： Ikuo Tokunaga , Shigemi Sasaki
发明人： Ikuo Tokunaga , Shigemi Sasaki
IPC分类号： G04B39/02 , C03C27/04 , C08F2/50 , C08F290/00 , C08F299/00 , C08F299/06 , G04B37/22 , G04B37/00
CPC分类号： G04B37/22 , C08F299/065
摘要： A bonding structure of a timepiece case such as the glass, bezel, case band, pipe, core and case back. Seams bonded with the bonding agent are both durable and waterproof. The bonding agent includes relative to:(A) 100 parts by weight urethane (met) acrylate having more than one acryloyl group and/or methacryloyl group per molecule;(B) 30 to 200 parts by weight (meta) acrylate having more than one hydroxyl group per molecule;(C) 30 to 200 parts by weight isobornyl (meta) acrylate;(D) 30 to 200 parts by weight pre-tacky resin of the petroleum series and coal series and/or the rosin ester series which are soluble in (meta) acrylate monomer;(E) 5 to 50 parts by weight acrylic acid and/or methacrylic acid; and(F) 0.5 to 15 parts by weight photopolymerization initiator of benzoin or benzyldimethylketal or the like.
摘要翻译：钟表盒的接合结构，例如玻璃，表圈，表带，管，芯和表壳背。与粘合剂粘合的接缝既耐用又防水。粘合剂包括：（A）每分子具有多于一个丙烯酰基和/或甲基丙烯酰基的100重量份氨基甲酸酯（met）丙烯酸酯; （B）每分子具有多于一个羟基的30〜200重量份（甲基）丙烯酸酯; （C）30〜200重量份（甲基）丙烯酸异冰片酯; （D）30〜200重量份石油系预粘性树脂和可溶于（甲基）丙烯酸酯单体的煤系和/或松香酯系列; （E）5〜50重量份丙烯酸和/或甲基丙烯酸; 和（F）0.5〜15重量份的苯偶姻或苄基二甲基缩酮的光聚合引发剂等。

109. 发明授权

US4758640A Vinylsilyl group-containing monodisperse polymeric compound and a method for the preparation thereof 失效
标题翻译：含有乙烯基甲硅烷基的单分散高分子化合物及其制备方法
公开(公告)号：US4758640A
公开(公告)日：1988-07-19
申请号：US861739
申请日：1986-05-07
申请人： Teruo Fujimoto , Minoru Takamizawa , Akira Yamamoto , Toshinobu Ishihara
发明人： Teruo Fujimoto , Minoru Takamizawa , Akira Yamamoto , Toshinobu Ishihara
IPC分类号： C08F30/00 , C08F2/04 , C08F2/06 , C08F4/46 , C08F4/50 , C08F30/08 , C08F290/00 , C08F299/00 , C08F299/08 , G03C5/08 , G03F7/004 , G03F7/038 , G03F7/075 , C08F230/08
CPC分类号： G03F7/0758 , C08F30/08
摘要： The invention provides a novel polymeric compound having crosslinkability by irradiation with actinic rays, e.g. ultraviolet light, and useful as a polymeric base ingredient of a negative type photoresist composition with high sensitivity and resistance against dry etching. The polymer is obtained by the anionic living polymerization of a vinylsilyl group-containing styrene derivative of the formulaCH.sub.2 .dbd.CH--C.sub.6 H.sub.4 --CH.sub.2).sub.n SiR.sub.2 --CH.dbd.CH.sub.2,in which R is a monovalent hydrocarbon group, e.g. methyl and phenyl, and n is an integer of 0 to 3, in a specific solvent in the presence of a specific polymerization initiator so that the polymerization takes place only at the styrenic vinyl groups leaving the silicon-bonded vinyl groups unpolymerized. Quite unexpectedly, the polymer has a very uniform monodisperse distribution of the molecular weight.
摘要翻译：本发明提供了通过用光化射线照射具有交联性的新型聚合物，例如紫外光，并且可用作具有高灵敏度和抗干蚀刻性的负型光致抗蚀剂组合物的聚合基底成分。该聚合物通过式CH 2 = CH-C 6 H 4 -CH 2）n SiR 2 -CH = CH 2的含乙烯基甲硅烷基的苯乙烯衍生物的阴离子活性聚合获得，其中R是一价烃基，例如，甲基和苯基，n为0〜3的整数，在特定的溶剂中，在特定的聚合引发剂的存在下，仅在苯乙烯基的乙烯基上进行聚合，离开与硅键合的乙烯基未聚合。非常出人意料地，聚合物具有非常均匀的单分散分子量分布。

110. 发明授权

US4746714A Stabilized acrylic resin 失效
标题翻译：稳定的丙烯酸树脂
公开(公告)号：US4746714A
公开(公告)日：1988-05-24
申请号：US875059
申请日：1986-06-17
申请人： Harry J. Spinelli , Christopher Scopazzi , Joseph A. Antonelli
发明人： Harry J. Spinelli , Christopher Scopazzi , Joseph A. Antonelli
IPC分类号： C08F4/58 , C08F4/00 , C08F265/00 , C08F265/06 , C08F290/00 , C08F290/04 , C08F299/00 , C09D133/00 , C09D151/00 , C09D151/06 , C08L51/00 , C08L33/08 , C08L33/10
CPC分类号： C08F290/046 , Y10S524/923
摘要： Stabilized acrylic resin having a core of acrylic polymer and a substantially linear stabilizer having one polymerizable functional group at one end of the stabilizer molecule, the resins being useful as rheology control agents for coating compositions.
摘要翻译：具有丙烯酸聚合物核心的稳定化丙烯酸树脂和在稳定剂分子的一端具有一个可聚合官能团的基本上线性的稳定剂，该树脂可用作涂料组合物的流变控制剂。

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