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101. 发明授权

US5091350A Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom 失效
标题翻译：用氢氧化镁催化剂进行氢化处理和其分离
公开(公告)号：US5091350A
公开(公告)日：1992-02-25
申请号：US605939
申请日：1990-10-29
申请人： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
发明人： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
IPC分类号： B01J23/96 , B01J31/40 , C01G55/00 , C07C45/50 , C07C45/80 , C07C45/85 , C22B3/38 , C22B7/00 , B01J38/68 , C22B11/04
CPC分类号： C22B11/048 , B01J31/2404 , B01J31/4046 , C01G55/001 , C07C45/50 , C07C45/80 , C07C45/85 , C22B3/0051 , C22B7/009 , B01J2231/321 , B01J23/464 , B01J2531/822 , Y02P10/214 , Y02P10/234 , Y02P20/584
摘要： A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.
摘要翻译：一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。还阐述了在络合剂和增溶剂存在下制备醛的方法。增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。

102. 发明授权

US5085835A Process for recovering rhodium 失效
标题翻译：回收方法
公开(公告)号：US5085835A
公开(公告)日：1992-02-04
申请号：US750709
申请日：1991-08-20
申请人： Jurgen Weber , Ludger Bexten , Dieter Kupies , Peter Lappe , Helmut Springer
发明人： Jurgen Weber , Ludger Bexten , Dieter Kupies , Peter Lappe , Helmut Springer
IPC分类号： B01J31/40 , C01G55/00 , C22B3/32
CPC分类号： B01J31/4046 , B01J31/24 , B01J31/2404 , C01G55/001 , C22B3/0024 , B01J2231/321 , B01J2531/822 , B01J2531/96 , B01J31/04 , Y02P10/234 , Y02P20/584 , Y10S423/14
摘要： A process for recovering rhodium from an aqueous solution containing its complex compounds and optionally complex ligands in the presence of a water-soluble salt of a carboxylic acid by treatment of the aqueous solution at 20.degree. to 120.degree. C. with hydrogen peroxide (or a substance forming hydrogen peroxide) and with oxygen (or an oxygen-containing gas). The rhodium is then removed as a water-insoluble compound.
摘要翻译：在含有羧酸水溶性盐的水溶液的存在下，通过在20〜120℃下用过氧化氢（或形成过氧化氢的物质）和氧（或含氧气体）。然后将铑作为水不溶性化合物除去。

103. 发明授权

US4935550A Catalytic metal recovery from non-polar organic solutions 失效
标题翻译：从非极性有机溶液中回收催化金属
公开(公告)号：US4935550A
公开(公告)日：1990-06-19
申请号：US231508
申请日：1988-08-12
申请人： David J. Miller , David R. Bryant
发明人： David J. Miller , David R. Bryant
IPC分类号： B01D11/04 , B01J31/40 , B01J38/00 , C01G55/00 , C07B61/00 , C07C45/50 , C07C47/02
CPC分类号： B01J31/24 , B01J31/2404 , B01J31/2409 , B01J31/2414 , B01J31/4046 , C07C45/50 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/96 , B01J31/0201 , Y02P20/584
摘要： A method for recovering a transition metal, e.g., rhodium, from a non-polar organic solution containing non-polar organic solvent-soluble and polar solvent-insoluble coordination complex of the transition metal and a non-polar organic solvent-soluble and polar solvent-insoluble ligand, e.g., an organophosphorus ligand, by contacting the non-polar organic solution with a polar solution of an ionic organophosphine ligand, the transition metal then can be transferred back into a non-polar solution for reuse. In one embodiment rhodium is rendered amenable for back-extraction by treating the polar solution with a suitable conditioning reagent.

104. 发明授权

US4871432A Recovery process 失效
公开(公告)号：US4871432A
公开(公告)日：1989-10-03
申请号：US52052
申请日：1987-05-21
申请人： Richard B. A. Pardy
发明人： Richard B. A. Pardy
IPC分类号： B01J38/00 , B01D61/42 , B01D61/44 , B01J31/40 , C07C45/50
CPC分类号： B01J31/20 , B01D61/44 , B01J31/0234 , B01J31/0239 , B01J31/26 , B01J31/4038 , B01J31/4046 , B01J31/4061 , B01J31/4069 , C22B11/048 , B01J2231/34 , B01J2531/82 , B01J2531/822 , Y02P10/214
摘要： A process for recovering a Group VIII noble metal catalyst, e.g. rhodium, from a liquid medium comprising Group VIII metal and a tar formed as a by-product in a carbonylation process is provided. The process comprises feeding the liquid medium to a first compartment of an electrodialysis cell and feeding a solvent to a second compartment adjacent the first. A voltage is applied to the electrodialysis cell to effect migration of the Group VIII metal from the first compartment to the second. The solvent used is preferably aqueous acetic acid.

105. 发明授权

US4861918A Reactivation of hydroformylation catalysts 失效
标题翻译：加氢甲酰化催化剂的再活化
公开(公告)号：US4861918A
公开(公告)日：1989-08-29
申请号：US231510
申请日：1988-08-12
申请人： David J. Miller , David R. Bryant , Ernst Billig , Bernard L. Shaw
发明人： David J. Miller , David R. Bryant , Ernst Billig , Bernard L. Shaw
IPC分类号： B01J31/40 , C07B61/00 , C07C29/16 , C07C31/02 , C07C45/50 , C07C47/02
CPC分类号： B01J31/4046 , B01J31/24 , B01J31/2404 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/0201 , B01J31/0215 , B01J31/0231 , B01J31/0255 , B01J31/04 , Y02P20/582 , Y02P20/584
摘要： A process for improving the catalytic activity of a partially deactivated solubilized rhodium - tertiary organophosphine complex hydroformylation catalyst.

106. 发明授权

US4746640A Process for purifying and recovering catalyst solution contaminated during the carbonylation of methyl acetate and/or dimethylether 失效
标题翻译：纯化和回收在乙酸甲酯和/或二甲醚羰基化过程中污染的催化剂溶液的方法
公开(公告)号：US4746640A
公开(公告)日：1988-05-24
申请号：US25962
申请日：1987-03-16
申请人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork
发明人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork
IPC分类号： B01J38/00 , B01J31/40 , C07B61/00 , C07C51/00 , C07C51/12 , C07C53/12 , C07C67/00 , C07C67/37 , C07C69/14 , B01J38/68 , C07C51/56 , C07C67/36
CPC分类号： B01J31/0268 , B01J31/0239 , B01J31/20 , B01J31/4046 , C07C51/42 , C07C51/48 , C07C51/573 , C07C67/48 , B01J2231/34 , B01J2531/822 , Y02P20/584
摘要： Catalyst solution contaminated during the carbonylation of methyl acetate and/or dimethylether. To this end, the contaminated catalyst solution is subjected in a first processing stage to extraction with a dialkylether and alkanol, each of which has from 1-4 carbon atoms per alkyl group, and thereby freed from its organic contaminants, from acetic acid, acetic anhydride and ethylidene diacetate, and the ether phase is separated from the purified promoter-containing catalyst solution; next, the ether phase is treated in a second processing stage with iodine and/or methyl iodide; the precipitated promoter containing catalyst complex is separated and dissolved in the purified catalyst solution coming from the first processing stage; the ether phase is separated into its constituents by distilling it; recovered dialkylether and alkanol are used again in the extraction stage; fresh catalyst solution is prepared from the recovered mixture of acetic acid, acetic anhydride and ethylidene diacetate and from the united purified catalyst solution while residual dialkylether and alkanol are distilled off, and the organic contaminants retained in the residue of the ether phase distillation are expelled.
摘要翻译：催化剂溶液在乙酸甲酯和/或二甲醚的羰基化过程中被污染。为此，将污染的催化剂溶液在第一个处理阶段进行，用二烷基醚和链烷醇进行萃取，每个烷基烷基和烷醇每个烷基具有1-4个碳原子，从而从乙酸，乙酸中除去其有机污染物酸酐和亚乙基二乙酸酯，并从纯化的含有助催化剂的催化剂溶液中分离出醚相; 接下来，乙醚相在碘和/或碘甲烷的第二个处理阶段进行处理; 将含有沉淀促进剂的催化剂配合物分离并溶解在来自第一处理阶段的纯化催化剂溶液中; 通过蒸馏将乙醚相分离成其成分; 在提取阶段再次使用回收的二烷基醚和链烷醇; 从回收的乙酸，乙酸酐和亚乙基二乙酸酯的混合物中制备新鲜的催化剂溶液，并从合并的纯化的催化剂溶液中蒸出残余的二烷基醚和链烷醇，并且保留在醚相蒸馏残余物中的有机污染物被排出。

107. 发明授权

US4613701A Recovery of rhodium from hydroformylation reaction product 失效
标题翻译：从加氢甲酰化反应产物中回收铑
公开(公告)号：US4613701A
公开(公告)日：1986-09-23
申请号：US777648
申请日：1985-09-19
申请人： James R. Strong
发明人： James R. Strong
IPC分类号： B01J31/40 , C07C45/50 , C07C45/78 , C07C45/81 , C07C45/82
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/2404 , B01J31/4092 , C07C45/50 , C07C45/783 , C07C45/81 , C07C45/82 , B01J2231/321 , B01J2531/822 , Y02P20/584
摘要： In a hydroformylation process wherein an alpha-alkene of 2 to about 10 carbon atoms is reacted with carbon monoxide and hydrogen in the presence of a rhodium triorganophosphine complex to produce an aldehyde having one carbon atom more than the alkene, the aldehyde product being continuously separated from the liquid reaction medium by gas stripping or distillation, rhodium moiety is recovered from the condensed reactor overhead vapors by redistillation under defined conditions.
摘要翻译：在加氢甲酰化方法中，其中在铑三有机膦配合物的存在下，使2-约10个碳原子的α-烯烃与一氧化碳和氢气反应以产生一个碳原子比该烯烃多的醛，醛产物被连续分离通过汽提或蒸馏从液体反应介质中通过在限定的条件下重新蒸馏从冷凝的反应器塔顶蒸气中回收铑部分。

108. 发明授权

US4557760A Process for recovering noble metals belonging to group VIII of the Periodic System of the elements from a contaminated catalyst solution originating from the carbonylation of methyl acetate and/or dimethylether 失效
标题翻译：从源于乙酸甲酯和/或二甲醚的羰基化的污染的催化剂溶液中回收属于元素周期系第VIII族的贵金属的方法
公开(公告)号：US4557760A
公开(公告)日：1985-12-10
申请号：US614480
申请日：1984-05-29
申请人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork , Peter Prinz
发明人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork , Peter Prinz
IPC分类号： C07C27/00 , B01J31/40 , C01G55/00 , C07C21/00 , C07C51/12 , C07C51/42 , C07C51/54 , C07C67/00 , C22B3/16 , C22B3/26 , C22B5/20 , C22B11/00
CPC分类号： B01J31/4046 , B01J31/0239 , B01J31/0268 , B01J31/04 , B01J31/20 , B01J31/26 , B01J31/4038 , C22B11/04 , C22B3/0018 , C22B5/20 , B01J2231/34 , B01J2531/82 , B01J2531/822 , B01J31/0201 , Y02P10/234
摘要： In this process for recovering noble metals of group VIII from a contaminated catalyst solution originating from the carbonylation of methyl acetate and/or dimethylether (the catalyst solution containing carbonyl complexes of these noble metals, organic or inorganic promoters, undistillable organic contaminants as well as volatiles) the volatiles are distillatively removed from the catalyst solution and the remaining distillation residue is water-treated, whereby the noble metal/carbonyl-complex is precipitated together with the organic contaminants and is separated from the aqueous phase, while the promotor is dissolved and recovered in conventional manner. The noble metals are then set free in elemental form by subjecting the noble metal/carbonyl-complex separated and contaminated with organic polymers at temperatures of 150.degree. to 300.degree. C. to treatment with an ethyleneglycoldialkylether solvent of the formula R(--OCH.sub.2 --CH.sub.2).sub.n --OR, in which n stands for a number of from 1 to 4 and R stands for identical or different alkyl groups having from 1 to 6 carbon atoms. The noble metal can then be recovered by filtration, and the solvent can be freed of organic contaminants by distillation.
摘要翻译：在用于从源自乙酸甲酯和/或二甲醚的羰基化的污染的催化剂溶液（含有这些贵金属的羰基络合物的催化剂溶液，有机或无机促进剂，不可挥发的有机污染物以及挥发物）中回收第VIII族的贵金属的方法中）将挥发物从催化剂溶液中蒸馏除去，剩余的蒸馏残余物进行水处理，由此贵金属/羰基络合物与有机污染物一起沉淀并与水相分离，同时促进剂被溶解和回收以常规方式。然后通过使贵金属/羰基络合物在150℃至300℃的温度下用有机聚合物分离和污染来将贵金属自由化，以用式R（-OCH 2 -CH 2）的乙二醇缩酮基醚溶剂）n-OR，其中n表示1至4的数，R表示具有1至6个碳原子的相同或不同的烷基。然后可以通过过滤回收贵金属，并且溶剂可以通过蒸馏而除去有机污染物。

109. 发明授权

US4537997A Process for treating hydroformylation catalyst 失效
标题翻译：处理加氢甲酰化催化剂的方法
公开(公告)号：US4537997A
公开(公告)日：1985-08-27
申请号：US557763
申请日：1983-12-02
申请人： Hidetaka Kojima , Takeshi Horikawa , Masahiro Kagotani
发明人： Hidetaka Kojima , Takeshi Horikawa , Masahiro Kagotani
IPC分类号： C07C45/50 , B01J31/40 , B01J38/48 , C07B61/00 , C07C45/00 , C07C45/49 , C07C45/80 , C07C47/02 , C07C67/00
CPC分类号： B01J31/24 , B01J31/2404 , B01J31/4046 , C07C45/49 , C07C45/80 , B01J2231/321 , B01J2531/822 , Y02P20/584
摘要： In a process for producing an aldehyde by hydroformylating allyl alcohol with carbon monoxide and hydrogen gas in the presence of a catalyst comprising a rhodium compound and a tertiary phosphine in an organic solvent and separating the resulting aldehyde with water extraction from the reaction mixture, the catalyst is maintained and recovered in the activity by treating the catalyst-containing solution in the organic solvent with a gaseous mixture of carbon monoxide and hydrogen gas after the water extraction step.
摘要翻译：在通过在一种有机溶剂中包含铑化合物和叔膦的催化剂存在下，用一氧化碳和氢气将烯丙醇加氢甲酰化制备醛的方法中，用反应混合物中的水提取将得到的醛分离出来，通过在水提取步骤之后用一氧化碳和氢气的气体混合物处理有机溶剂中的含催化剂的溶液来维持和回收活性。

110. 发明授权

US4528403A Hydroformylation process for preparation of aldehydes and alcohols 失效
标题翻译：用于制备醛和醇的加氢甲酰化方法
公开(公告)号：US4528403A
公开(公告)日：1985-07-09
申请号：US535783
申请日：1983-09-26
申请人： Kazuo Tano , Keiichi Sato , Toru Okoshi
发明人： Kazuo Tano , Keiichi Sato , Toru Okoshi
IPC分类号： C07C29/16 , C07C45/50
CPC分类号： B01J31/1875 , B01J31/2404 , B01J31/4046 , B01J31/4053 , C07C29/16 , C07C45/50 , B01J2231/321 , B01J2531/822 , Y02P20/584
摘要： A hydroformylation process which comprises hydroformylating an olefinic compound by reacting it with water gas in a catalyst solution containing rhodium and an oxide of an organic trivalent phosphorus compound; adding an organic trivalent phosphorus compound to the reaction mixture, followed by distillation to separate a distillate containing the hydroformylation product from a high-boiling residue containing rhodium; oxidizing the high-boiling residue at the same time as or subsequent to the distillation, to convert the organic trivalent phosphorus compound to its oxide; and recycling the oxidized residue to the hydroformylation reaction zone.
摘要翻译：加氢甲酰化方法，其包括通过使烯烃化合物与含有铑和有机三价磷化合物的氧化物的催化剂溶液中的水气反应来加氢甲酰化; 向反应混合物中加入有机三价磷化合物，然后蒸馏以从含有铑的高沸点残渣中分离含有加氢甲酰化产物的馏出物; 在蒸馏同时或之后同时氧化高沸点残余物，将有机三价磷化合物转化成其氧化物; 并将氧化的残余物再循环到加氢甲酰化反应区。

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