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1. 发明授权

US4990639A Novel recovery process 失效
标题翻译：新的恢复过程
公开(公告)号：US4990639A
公开(公告)日：1991-02-05
申请号：US438572
申请日：1989-11-16
申请人： Ludger Bexten , Dieter Kupies
发明人： Ludger Bexten , Dieter Kupies
IPC分类号： B01J38/64 , B01J31/40 , B01J38/00 , C01G55/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C51/41 , C07C67/00 , C07F15/00 , C22B3/32 , C22B11/00
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/24 , B01J31/2404 , B01J31/2447 , C01G55/00 , C01G55/001 , C07C45/50 , C22B3/0024 , B01J2231/321 , B01J2531/822 , B01J2531/96 , B01J31/04 , Y02P10/234 , Y02P20/584
摘要： A process for the recovery of rhodium from aqueous solutions of rhodium complex carbon atoms comprising adding a molar excess of a water-soluble salt of an organic carboxylic acid of 7 to 22 carbon atoms to an aqueous solution of a rhodium complex compound, treating the solution with an oxidant at 50.degree. to 200.degree. C. and recovering the rhodium as a water-insoluble compound.
摘要翻译：一种用于从铑络合物碳原子的水溶液中回收铑的方法，包括将摩尔过量的7-22个碳原子的有机羧酸的水溶性盐加入到铑络合物的水溶液中，与氧化剂在50至200℃下回收铑作为水不溶性化合物。

2. 发明授权

US4883853A Copolymers of ethylene and 2,4,4-trimethylpentene-1 失效
标题翻译：乙烯和2,4,4-三甲基戊烯-1的共聚物
公开(公告)号：US4883853A
公开(公告)日：1989-11-28
申请号：US55722
申请日：1987-05-29
申请人： John Hobes , Wolfgang Payer , Ludger Bexten
发明人： John Hobes , Wolfgang Payer , Ludger Bexten
IPC分类号： C08F4/04 , C08F4/34 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/913
摘要： Novel copolymers of ethylene containing per 100 parts by weight ethylene 0.2 to 5.0 parts by weight of 2,4,4-trimethylpentene-(1) and optionally 2.0 to 20 parts by weight of vinyl ester or vinyl ether or ester of acrylic acid or methacrylic acid with alcohols of 1 to 8 carbon atoms having a melt index MFI (190/2.16) of 0.4 to 20 g/10 min. a density of 0.915 to 0.960 g/ml and an impact tensile strength of 850 to 2,600 mJ/mm.sup.2 and a process for their preparation useful for making transparent films.
摘要翻译：新的乙烯共聚物，每100重量份乙烯0.2至5.0重量份的2,4,4-三甲基戊烯 - （1）和任选的2.0至20重量份的乙烯基酯或乙烯基醚或丙烯酸或甲基丙烯酸酯酸与具有熔体指数MFI（190 / 2.16）的1至8个碳原子的醇为0.4至20g / 10min。密度为0.915〜0.960g / ml，冲击拉伸强度为850〜2600mJ / mm 2，其制备方法可用于制造透明膜。

3. 发明授权

US4723047A Process for the preparation of nonadecanediols 失效
标题翻译：制备十九烷二醇的方法
公开(公告)号：US4723047A
公开(公告)日：1988-02-02
申请号：US910650
申请日：1986-09-23
申请人： Helmut Bahrmann , Boy Cornils , Werner Konkol , Jurgen Weber , Ludger Bexten , Hanswilhelm Bach
发明人： Helmut Bahrmann , Boy Cornils , Werner Konkol , Jurgen Weber , Ludger Bexten , Hanswilhelm Bach
IPC分类号： C07C29/16 , B01J31/00 , B01J31/24 , C07B61/00 , C07C27/00 , C07C29/158 , C07C31/20 , C07C45/49 , C07C67/00 , C07C29/14
CPC分类号： C07C45/49 , C07C29/158 , C07C31/20
摘要： The present invention relates to a process for the preparation of nonadecanediols by the hydroformylation of oleyl alcohol. Rhodium and salts of sulfonated or carboxylated triarylphosphines, which are soluble in organic media and insoluble in water, are used as hydroformylation catalysts. The hydroformylation product is then treated with a diluted solution of a base dissolved in water, the aqueous phase separated and the hydroformylation product treated with hydrogen at elevated temperature in the presence of a hydrogenation catalyst.
摘要翻译：本发明涉及通过油醇加氢甲酰化来制备非十二烷二醇的方法。可溶于有机介质并且不溶于水的磺化或羧化的三芳基膦的铑和盐被用作加氢甲酰化催化剂。然后用溶解在水中的碱的稀释溶液处理加氢甲酰化产物，分离出水相，加氢甲酰化产物在氢化催化剂存在下在高温下用氢气处理。

4. 发明授权

US5294415A Process for the separation and recovery of rhodium from the products of the oxo synthesis 失效
标题翻译：从羰基合成产物中分离和回收铑的方法
公开(公告)号：US5294415A
公开(公告)日：1994-03-15
申请号：US903010
申请日：1992-06-23
申请人： Peter Lappe , Ludger Bexten , Dieter Kupies
发明人： Peter Lappe , Ludger Bexten , Dieter Kupies
IPC分类号： C01G55/00 , C07C45/50 , C22B3/38 , B01J38/48 , B01J38/64 , C22B11/00
CPC分类号： C07C45/50 , C01G55/001 , C22B3/0051 , Y02P10/234
摘要： To separate and recover rhodium, the distillation residues of oxo synthesis products are initially treated with an oxidant. Then the reaction mixture is reacted, in the presence of carbon monoxide (or a compound which splits off carbon monoxide), with an aqueous solution of a reagent forming a water-soluble complex compound with rhodium. The reaction mixture breaks into an organic phase and an aqueous phase, the complex goes to the aqueous phase as it is substantially insoluble in the organic phase.
摘要翻译：为了分离和回收铑，首先用氧化剂处理氧合成产物的蒸馏残余物。然后在一氧化碳（或分解一氧化碳的化合物）存在下，使反应混合物与形成水溶性络合物与铑的试剂的水溶液反应。反应混合物分解成有机相和水相，当它基本上不溶于有机相时，络合物进入水相。

5. 发明授权

US5085835A Process for recovering rhodium 失效
标题翻译：回收方法
公开(公告)号：US5085835A
公开(公告)日：1992-02-04
申请号：US750709
申请日：1991-08-20
申请人： Jurgen Weber , Ludger Bexten , Dieter Kupies , Peter Lappe , Helmut Springer
发明人： Jurgen Weber , Ludger Bexten , Dieter Kupies , Peter Lappe , Helmut Springer
IPC分类号： B01J31/40 , C01G55/00 , C22B3/32
CPC分类号： B01J31/4046 , B01J31/24 , B01J31/2404 , C01G55/001 , C22B3/0024 , B01J2231/321 , B01J2531/822 , B01J2531/96 , B01J31/04 , Y02P10/234 , Y02P20/584 , Y10S423/14
摘要： A process for recovering rhodium from an aqueous solution containing its complex compounds and optionally complex ligands in the presence of a water-soluble salt of a carboxylic acid by treatment of the aqueous solution at 20.degree. to 120.degree. C. with hydrogen peroxide (or a substance forming hydrogen peroxide) and with oxygen (or an oxygen-containing gas). The rhodium is then removed as a water-insoluble compound.
摘要翻译：在含有羧酸水溶性盐的水溶液的存在下，通过在20〜120℃下用过氧化氢（或形成过氧化氢的物质）和氧（或含氧气体）。然后将铑作为水不溶性化合物除去。

6. 发明授权

US4740626A Process for the preparation of aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US4740626A
公开(公告)日：1988-04-26
申请号：US907033
申请日：1986-09-12
申请人： Helmut Bahrmann , Werner Konkol , Jugen Weber , Hanswilhelm Bach , Ludger Bexten
发明人： Helmut Bahrmann , Werner Konkol , Jugen Weber , Hanswilhelm Bach , Ludger Bexten
IPC分类号： C07C47/02 , B01J31/00 , B01J31/24 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： C07C45/50
摘要： The present invention relates to a process for the preparation of aldehydes by the reaction of olefinic compounds with hydrogen and carbon monoxide in the presence of a catalyst system containing rhodium and aromatic phosphines. The aromatic phosphines are soluble in organic media and represent salts of sulfonated or carboxylated triarylphosphines which are insoluble in water. After hydroformylation, the reaction product is treated with a diluted aqueous solution of a base and the aqueous phase containing rhodium and aromatic phosphines is separated. Thus, thermal loading of the catalyst, for example by the redistillation of the reaction product, is avoided.
摘要翻译：本发明涉及通过烯烃化合物与氢和一氧化碳在含铑和芳香膦的催化剂体系存在下反应制备醛的方法。芳族膦可溶于有机介质，代表不溶于水的磺化或羧化三芳基膦的盐。加氢甲酰化后，反应产物用碱的稀释水溶液处理，分离含有铑和芳香族膦的水相。因此，避免了催化剂的热负荷，例如通过反应产物的再蒸馏。

7. 发明授权

US4623490A Process for the purification of sulfonated aryl phosphines 失效
标题翻译：磺化芳基膦的纯化方法
公开(公告)号：US4623490A
公开(公告)日：1986-11-18
申请号：US770303
申请日：1985-08-27
申请人： Ludger Bexten , Boy Cornils , Dieter Kupies
发明人： Ludger Bexten , Boy Cornils , Dieter Kupies
IPC分类号： B01J38/00 , C07F9/50 , C07F15/00 , C07C143/24
CPC分类号： C07F9/5095 , C07F9/5054
摘要： A process for the purification of salts of at least one member of the group consisting of diphenylphosphine-phenyl-m-sulfonic acid, phenylphosphine-di-(m-phenylsulfonic acid) and triphenylphosphine-tri-(m-sulfonic acid) from aqueous solutions thereof comprising adding at least a molar equivalent amount of at least one member of the group consisting of di-(n-pentyl)-amine, di-(n-hexyl)-amine and water-soluble salts of said amines to an aqueous solution containing at least one member of the group consisting diphenylphosphine-phenyl-m-sulfonic acid, phenylphosphine-di-(m-phenylsulfonic acid), triphenylphosphine-tri(m-sulfonic acid) and salts thereof to adjust the pH value to .ltoreq.7, recovering the precipitate, washing the precipitate and dissolving the same in an aqueous basic solution.
摘要翻译：从水溶液中纯化二苯基膦 - 苯基间磺酸，苯基膦 - 二 - （间苯磺酸）和三苯基膦 - 三 - （间 - 磺酸）中的至少一种成员的盐的方法其包括将至少一种摩尔当量的所述胺的二（正戊基） - 胺，二 - （正己基） - 胺和水溶性盐组成的组中的至少一种添加到水溶液中含有二苯基膦 - 苯基 - 间磺酸，苯基膦 - 二 - （间苯磺酸），三苯基膦 - 三（m-磺酸）及其盐中的至少一个成员以将pH值调节至< 7，回收沉淀物，洗涤沉淀物并将其溶于碱性水溶液中。

8. 发明授权

US4504588A Process for the recovery of water-soluble hydroformylation catalysts containing rhodium 失效
标题翻译：用于回收含有铑的水溶性加氢甲酰化催化剂的方法
公开(公告)号：US4504588A
公开(公告)日：1985-03-12
申请号：US534088
申请日：1983-09-20
申请人： Roderich Gartner , Boy Cornils , Ludger Bexten , Dieter Kupies
发明人： Roderich Gartner , Boy Cornils , Ludger Bexten , Dieter Kupies
IPC分类号： B01J23/96 , B01J23/90 , B01J31/40 , B01J38/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： B01J31/2404 , B01J31/26 , B01J31/4046 , B01J2231/321 , B01J2531/822 , B01J2531/96 , B01J31/0235
摘要： To recover a hydroformylation catalyst system containing rhodium and phosphine, the aqueous solution containing the catalyst system is mixed with acid and then extracted with an amine which is dissolved in an organic solvent. The organic phase is separated and treated with the aqueous solution of an inorganic base, thereby recovering the catalyst in essentially pure form as an aqueous solution.
摘要翻译：为了回收含有铑和膦的加氢甲酰化催化剂体系，将含有催化剂体系的水溶液与酸混合，然后用溶解在有机溶剂中的胺萃取。将有机相分离并用无机碱的水溶液处理，从而以基本上纯的形式作为水溶液回收催化剂。

9. 发明授权

US4222966A Process for the manufacture of aldehydes 失效
标题翻译：醛的制造方法
公开(公告)号：US4222966A
公开(公告)日：1980-09-16
申请号：US934668
申请日：1978-08-17
申请人： Ludger Bexten , Boy Cornils , Hans-Dieter Hahn , Hans Tummes
发明人： Ludger Bexten , Boy Cornils , Hans-Dieter Hahn , Hans Tummes
IPC分类号： B01J31/00 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , C07C45/10
CPC分类号： C07C45/50
摘要： An improvement in the process for the continuous manufacture of an aldehyde by reaction of an olefin with carbon monoxide and hydrogen in the presence of a rhodium catalyst at an elevated temperature and pressure followed by distillative separation of the non-converted feedstocks and low boiling components of the reaction mixture, the improvement residing in employing a carbon monoxide/hydrogen mixture containing 2-20 ppm sulfur and recycling residual rhodium compounds, both dissolved and suspended in the distillation residue, to the reaction zone.
摘要翻译：在铑催化剂存在下，在升高的温度和压力下，通过烯烃与一氧化碳和氢气的反应连续制造醛的方法的改进，随后将未转化的原料和低沸点组分蒸馏分离该反应混合物的优点在于使用含有2-20ppm硫的一氧化碳/氢气混合物和再循环的剩余的铑化合物，两者都溶解并悬浮在蒸馏残余物中。

10. 发明授权

US4041081A Method for the preparation of pure n-aldehydes 失效
标题翻译：纯正醛的制备方法
公开(公告)号：US4041081A
公开(公告)日：1977-08-09
申请号：US637739
申请日：1975-12-04
申请人： Ludger Bexten , Heinz Noeske , Hans Tummes , Boy Cornils
发明人： Ludger Bexten , Heinz Noeske , Hans Tummes , Boy Cornils
IPC分类号： C07C45/00 , C07C45/50 , C07C45/85 , C07C47/02 , C07C47/228 , C07C67/00
CPC分类号： C07C45/85 , C07C45/50
摘要： A process for the isolation of n-aldehyde from a mixture of n-aldehyde and i-aldehyde in a solvent by the addition of no more than a stoichiometric amount of an alkali metal hydrogen sulfite in aqueous solution to the mixture. The resulting precipitate is separated, washed, and later decomposed to yield substantially pure n-aldehyde.
摘要翻译：通过在混合物中加入不多于化学计量的碱金属亚硫酸氢盐，从溶剂中的正醛与异醛的混合物中分离出正醛的方法。将所得沉淀物分离，洗涤，然后分解，得到基本上纯的正醛。

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