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    • 102. 发明授权
    • Abrasive lubricant layer for photographic element
    • 照相材料磨料润滑剂层
    • US6048677A
    • 2000-04-11
    • US221465
    • 1998-12-28
    • Janglin ChenYongcai WangVito A. DePalmaRobert O. James
    • Janglin ChenYongcai WangVito A. DePalmaRobert O. James
    • G03C1/76G03C1/795
    • G03C1/7614Y10S430/151Y10S430/162
    • The present invention is a photographic element which includes a support having a first side and a second side, at least one light sensitive emulsion layer superposed on the first side of the support, a transparent magnetic layer superposed on the second side of the support. The transparent magnetic layer includes magnetic particles and a film forming binder. An outermost abrasive lubricant layer overlies the transparent magnetic layer. The outermost abrasive lubricant layer is formed from a non-aqueous coating composition of a composite wax particle, an abrasive particle and an organic solvent. The composite wax particle is composed of a wax phase having a wax having a melting point of greater than 30.degree. C. the wax being greater than 80% by weight of the wax phase and a non-crosslinked polymer phase free of chemically bonded acid groups.
    • 本发明是一种照相元件,其包括具有第一侧和第二侧的支撑体,叠置在支撑体的第一侧上的至少一个感光乳剂层,叠置在支撑体的第二侧上的透明磁性层。 透明磁性层包括磁性颗粒和成膜粘合剂。 最外面的磨料润滑剂层覆盖着透明磁性层。 最外面的研磨剂润滑剂层由复合蜡颗粒,磨料颗粒和有机溶剂的非水性涂料组合物形成。 复合蜡颗粒由具有大于30℃熔点的蜡的蜡相组成,蜡大于蜡相的80重量%以及不含化学键合的酸基的非交联聚合物相 。
    • 104. 发明授权
    • Photographic element having surface protective layer
    • 具有表面保护层的摄影元件
    • US5866312A
    • 1999-02-02
    • US878791
    • 1997-06-19
    • Yongcai WangDennis E. SmithAlfred B. Fant
    • Yongcai WangDennis E. SmithAlfred B. Fant
    • G03C1/005G03C1/04G03C1/76G03C1/95G03C1/89
    • G03C1/95G03C1/7614G03C1/005G03C1/04Y10S430/162
    • The present invention is a photographic element which includes a support, at least one silver halide emulsion layer, and a light-insensitive protective overcoat. The light insensitive protective overcoat includes a hydrophilic binder and polymer particles having a glass transition temperature of at least 70.degree. C. The polymer particles prepared by the process of mechanically forming oil-in-water droplets having a size less than 400 nm of an ethylenically unsaturated monomer having hydrophobic groups, the hydrophobic groups having a logP.sub.(calc) greater than a logP.sub.(calc) of the ethylenically unsaturated monomer by at least 1 unit in an aqueous medium. A hydrophilic colloid is added to the aqueous medium in an amount sufficient to render the polymer partice compatible with the hydrophilic binder. The droplets are polymerized to a size of less than 400 nm. The present invention is also a photographic element which includes a support, at least one silver halide emulsion layer, and a light-insensitive protective overcoat. The light insensitive protective overcoat includes a hydrophilic binder and polymer particles having a glass transition temperature of at least 70.degree. C. The polymer particles prepared by the process of mechanically forming oil-in-water droplets having a size less than 400 nm of an ethylenically unsaturated monomer having a logP.sub.(calc) greater than 4, preferably greater than 6 in an aqueous medium. A hydrophilic colloid is added to the aqueous medium in an amount sufficient to render the polymer partice compatible with the hydrophilic binder. The droplets are polymerized to a size of less than 400 nm.
    • 本发明是一种照相材料,它包括一种载体,至少一种卤化银乳剂层和一种不透光的保护性外涂层。 光不敏感的保护性外涂层包括亲水性粘合剂和玻璃化转变温度至少为70℃的聚合物颗粒。通过机械地形成尺寸小于400nm的水包油液滴制备的聚合物颗粒为烯属 具有疏水基团的不饱和单体,所述疏水基团在水性介质中具有大于所述烯键式不饱和单体的logP(calc))至少1单位的logP(calc)。 将亲水胶体以足以使聚合物部分与亲水性粘合剂相容的量加入到水性介质中。 液滴聚合成小于400nm的尺寸。 本发明还是一种照相元件,它包括一种载体,至少一种卤化银乳剂层和一种不透光的保护性外涂层。 光不敏感的保护性外涂层包括亲水性粘合剂和玻璃化转变温度至少为70℃的聚合物颗粒。通过机械地形成尺寸小于400nm的水包油液滴制备的聚合物颗粒为烯属 在水性介质中logP(calc)大于4,优选大于6的不饱和单体。 将亲水胶体以足以使聚合物部分与亲水性粘合剂相容的量加入到水性介质中。 液滴聚合成小于400nm的尺寸。