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    • 110. 发明申请
    • Method of preventing surface roughening during hydrogen pre-bake of SiGe substrates using chlorine containing gases
    • 在使用含氯气体的SiGe衬底的氢预烘烤期间防止表面粗糙化的方法
    • US20050148162A1
    • 2005-07-07
    • US10751207
    • 2004-01-02
    • Huajie ChenDan MocutaRichard MurphyStephen BedellDevendra Sadana
    • Huajie ChenDan MocutaRichard MurphyStephen BedellDevendra Sadana
    • C30B25/02C30B29/52H01L21/20H01L21/205H01L21/306H01L21/36H01L21/44
    • H01L21/02046C30B25/02C30B29/52H01L21/02052H01L21/02381H01L21/0243H01L21/02532H01L21/02658H01L21/02661
    • The invention forms an epitaxial silicon-containing layer on a silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface and avoids creating a rough surface upon which the epitaxial silicon-containing layer is grown. In order to avoid creating the rough surface, the invention first performs a hydrofluoric acid etching process on the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. This etching process removes most of oxide from the surface, and leaves only a sub-monolayer of oxygen (typically 1×1013-1×1015/cm2 of oxygen) at the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. The invention then performs a hydrogen pre-bake process in a chlorine containing environment which heats the silicon germanium, strained silicon, or thin silicon-on-insulator surface sufficiently to remove the remaining oxygen from the surface. By introducing a small amount of chlorine containing gases, the heating processes avoid changing the roughness of the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. Then the process of epitaxially growing the epitaxial silicon-containing layer on the silicon germanium, patterned strained silicon, or patterned silicon-on-insulator surface is performed.
    • 本发明在硅​​锗,图案化的应变硅或图案化的绝缘体上硅表面上形成外延含硅层,并避免产生外延含硅层生长的粗糙表面。 为了避免产生粗糙表面,本发明首先对硅锗,图案化应变硅或图案化的绝缘体上硅表面进行氢氟酸蚀刻工艺。 该蚀刻工艺从表面除去大部分氧化物,并且仅留下氧气的亚单层(通常为1×10 13/1×10 15 / cm 2以上) 的氧),图案化的应变硅或图案化的绝缘体上硅表面。 然后,本发明在含氯环境中进行氢预烘烤过程,其中充分加热硅锗,应变硅或薄的绝缘体上硅表面以从表面除去剩余的氧。 通过引入少量的含氯气体,加热过程避免改变硅锗,图案化的应变硅或图案化的绝缘体上硅表面的粗糙度。 然后进行外延生长硅锗,图案化应变硅或图案化硅绝缘体表面上的外延硅含量层的工艺。