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    • 100. 发明授权
    • Sulfonation process
    • 磺化过程
    • US5117041A
    • 1992-05-26
    • US612353
    • 1990-11-13
    • Edward F. McBride
    • Edward F. McBride
    • C08G63/688C08G63/91
    • C08G63/6888C08G63/918
    • Allyl end-capped propylene terephthalate polyester oligomers are sulfonated in an aqueous system in the presence of a free radical initiator by a process in which only a part (about 15% to 40%) of the source of bisulfite is added at the start of the sulfonation step with the remainder being added later in that step, in such increments as will permit maintaining a clear single phase, to give sulfinate-containing sulfonated products, following which the sulfinate content is oxidized to give sulfonated end-capped propylene terephthalate polyester oligomers.
    • 烯丙基封端的对苯二甲酸丙二醇酯聚酯低聚物在自由基引发剂存在下,在含水体系中被磺化,其中只有一部分(约15%至40%)的亚硫酸氢盐源在 磺化步骤,其余部分在该步骤中稍后加入,允许保持澄清的单相,得到含亚磺酸盐的磺化产物,随后亚硫酸盐含量被氧化,得到磺化封端的对苯二甲酸丙二醇酯聚酯低聚物。