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    • 94. 发明授权
    • Methods of making platinum and platinum alloy catalysts with nanonetwork structures
    • 制备具有纳米网络结构的铂和铂合金催化剂的方法
    • US07700520B2
    • 2010-04-20
    • US10907950
    • 2005-04-22
    • Chun Ching ChienKing Tsai JengShean Du ChiouSu Hsine Lin
    • Chun Ching ChienKing Tsai JengShean Du ChiouSu Hsine Lin
    • B01J37/34B01J31/00B01J21/00
    • B01J37/0018B01J23/42B01J37/16B01J37/18H01M4/8621H01M4/8814H01M4/8842H01M4/885H01M8/1011H01M2008/1095Y02E60/523Y10S977/883
    • This invention relates to the preparations of noble metal catalysts, i.e., platinum and platinum alloys, on suitable supports with nanonetwork structures and high catalytic efficiencies. A compact structure of a monolayer or a few layers is formed by self-assembly of organic polymer, e.g., polystyrene (PS), nanospheres or inorganic, i.e., silicon dioxide (SiO2), nanospheres on a support surface. In the void spaces of such a compact arrangement, catalyst is formed by filling with catalyst metal ion-containing aqueous solution and reduced by chemical reduction, or formed by vacuum sputtering. When using organic polymer nanospheres as the starting or structure-directing material, the polymer particles are removed by burning at a high temperature and the catalyst having a nanonetwork structure is obtained. In the case of using silicon dioxide nanospheres as the starting material, silicon dioxide particles are dissolved with hydrofluoric acid solution and evaporated away leading to formation of a similar nanonetwork structure made of catalyst. The catalysts prepared by these methods possess characteristics of robust in structure, uniform in hole size and high in catalytic surface area. Their main applications include uses as catalysts in direct methanol and proton exchange membrane fuel cells, as well as in chemical reactors, fuel reformers, catalytic converters, etc.
    • 本发明涉及贵金属催化剂即铂和铂合金在具有纳米网络结构和高催化效率的合适载体上的制备。 通过在载体表面上自组装有机聚合物,例如聚苯乙烯(PS),纳米球或无机即二氧化硅(SiO 2)纳米球,形成单层或几层的致密结构。 在这种紧凑结构的空隙空间中,通过填充含催化剂金属离子的水溶液并通过化学还原减少或通过真空溅射形成催化剂。 当使用有机聚合物纳米球作为起始或结构导向材料时,通过在高温下燃烧除去聚合物颗粒,并获得具有纳米网络结构的催化剂。 在使用二氧化硅纳米球作为起始材料的情况下,二氧化硅颗粒用氢氟酸溶液溶解并蒸发掉,导致形成由催化剂制成的类似的纳米网络结构。 通过这些方法制备的催化剂具有结构坚固,孔尺寸均匀,催化表面积高的特点。 其主要应用包括用作直接甲醇和质子交换膜燃料电池中的催化剂,以及化学反应器,燃料重整器,催化转化器等。
    • 98. 发明申请
    • Nanomachined mechanical components using nanoplates, methods of fabricating the same and methods of manufacturing nanomachines
    • 使用纳米板的纳米机械部件,其制造方法和制造纳米机械的方法
    • US20080006888A1
    • 2008-01-10
    • US11263476
    • 2005-10-31
    • Yong YunChil AhDong HaHyung ParkWan YunKwang-Cheol LeeGwang Park
    • Yong YunChil AhDong HaHyung ParkWan YunKwang-Cheol LeeGwang Park
    • H01L21/00
    • B81C99/0095B81B2201/035B81C2201/0143Y10S977/883Y10S977/888
    • Disclosed herein is a method of fabricating nano-components using nanoplates, including the steps of: printing a grid on a substrate using photolithography and Electron Beam Lithography; spraying an aqueous solution dispersed with nanoplates onto the grid portion to position the nanoplates on the substrate; depositing a protective film of a predetermined thickness on the substrate and the nanoplates positioned on the substrate; ion-etching the nanoplates deposited with the protective film by using a Focused Ion Beam (FIB) or Electron Beam Lithography; and eliminating the protective film remaining on the substrate using a protective film remover after the ion-etching of the nanoplates, and a method of manufacturing nanomachines or nanostructures by transporting such nano-components using a nano probe and assembling with other nano-components. The present invention makes it possible to fabricate the high-quality nano-components in a more simple and easier manner at a lower cost, as compared to other conventional methods. Further, the present invention provides a method of implementing nanomachines through combination of such nano-components and biomolecules, etc.
    • 本文公开了使用纳米板制造纳米组分的方法,包括以下步骤:使用光刻和电子束光刻在衬底上印刷栅格; 将分散有纳米板的水溶液喷射到栅格部分上以将纳米板定位在基底上; 在衬底和位于衬底上的纳米板上沉积预定厚度的保护膜; 通过使用聚焦离子束(FIB)或电子束光刻法离子蚀刻沉积有保护膜的纳米板; 并且在纳米板的离子蚀刻之后使用保护膜去除剂去除残留在基板上的保护膜,以及通过使用纳米探针传输这种纳米成分并与其他纳米成分组装来制造纳米机械或纳米结构的方法。 与其它常规方法相比,本发明可以以更简单和更容易的方式以更低的成本制造高质量的纳米组分。 此外,本发明提供了通过这些纳米组分和生物分子等的组合来实现纳米机器的方法。