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    • 96. 发明授权
    • Staged catalytic ammonia decomposition in integrated gasification
combined cycle systems
    • 综合气化联合循环系统分阶段催化氨分解
    • US5912198A
    • 1999-06-15
    • US691084
    • 1996-08-01
    • Alan S. FeitelbergRaul Eduardo AyalaStephen Lan-Sun HungDavid Joseph Najewicz
    • Alan S. FeitelbergRaul Eduardo AyalaStephen Lan-Sun HungDavid Joseph Najewicz
    • B01D53/58B01D53/86C01B3/58C10J3/00C10J1/20
    • C01B3/583B01D53/58B01D53/8634C10J3/00C10K1/004C10K1/101C10K1/16C10K3/02C10K3/04C01B2203/044C01B2203/047C10J2300/165C10J2300/1662C10J2300/1687C10J2300/1861Y02E20/16Y02E20/18
    • The ammonia content of fuel gas in an IGCC power generation system is reduced through ammonia decomposition, thereby reducing the NO.sub.x emissions from the plant. The power generation system includes a gasifier, a gas turbine and at least one catalytic reactor arranged between the gasifier and the gas turbine. The catalytic reactor may be either a three stage or two stage device. The three stage reactor includes a first catalyst which promotes water-gas-shift, a second catalyst which promotes CO methanation, and a third catalyst which promotes ammonia decomposition. The two stage reactor includes a first catalyst which promotes water-gas-shift and CO methanation and a second catalyst which promotes ammonia decomposition. The plural catalytic stages may be disposed in a single vessel or successively disposed in individual vessels, and the catalysts may be in a pelletized form or coated on honeycomb structures. Alternatively, fluidized bed reactors may be used. The reactions are carried out either adiabatically or non-adiabatically. Heat from the water-gas-shift and CO methanation reactions may be used to generate steam, which can be injected downstream or sent to a steam turbine. Preferably, a second catalytic reactor is provided in parallel with the first reactor so that the two reactors can alternately receive fuel gas from the gasifier.
    • IGCC发电系统中燃气的氨含量通过氨分解而降低,从而减少了工厂的NOx排放。 发电系统包括气化器,燃气轮机和布置在气化器和燃气轮机之间的至少一个催化反应器。 催化反应器可以是三级或二级装置。 三级反应器包括促进水煤气转移的第一催化剂,促进CO甲烷化的第二催化剂和促进氨分解的第三催化剂。 两级反应器包括促进水煤气变换和CO甲烷化的第一催化剂和促进氨分解的第二催化剂。 多个催化级可以设置在单个容器中或相继设置在各个容器中,并且催化剂可以是颗粒形式或涂覆在蜂窝结构上。 或者,可以使用流化床反应器。 反应是绝热的或非绝热的。 来自水煤气变换和CO甲烷化反应的热量可用于产生蒸汽,其可以向下游喷射或送到蒸汽轮机。 优选地,与第一反应器平行地设置第二催化反应器,使得两个反应器可以交替地从气化器接收燃料气体。
    • 98. 发明授权
    • Production of pipeline gas from coal
    • 从煤炭生产管道煤气
    • US4410336A
    • 1983-10-18
    • US351838
    • 1982-02-24
    • Henry J. Blaskowski
    • Henry J. Blaskowski
    • C10J3/54C10J3/00
    • C10J3/00C10J2300/093C10J2300/0959C10J2300/1662C10J2300/1671C10J2300/1675
    • A process for producing pressurized pipeline gas wherein coal is gasified in oxygen at a relatively low pressure, typically less than 5 atmospheres, to produce a raw gas containing carbon monoxide, hydrogen, carbon dioxide, gaseous sulfur compounds and particulates. A major portion of the raw gas is cooled, cleaned and methanated to produce a pipeline quality product gas consisting essentially of methane. The remaining portion of the raw gas is cleaned, compressed and combusted to produce a high temperature, high pressure flue gas which is used to power a gas turbine and generate steam to power a steam turbine. The gas turbine and steam turbine each drive compressors for compressing the low pressure product gas to pipeline pressure.
    • 一种用于生产加压管道气体的方法,其中煤气通常在低于5个大气压的较低压力下在氧气中气化,以产生含有一氧化碳,氢气,二氧化碳,气态硫化合物和颗粒物的原料气体。 原料气体的主要部分被冷却,清洁和甲烷化,以产生基本上由甲烷组成的管道质量产品气体。 原始气体的剩余部分被清洁,压缩和燃烧,以产生高温高压烟道气,其用于为燃气轮机供电并产生蒸汽以为汽轮机供电。 燃气轮机和蒸汽轮机每个驱动用于将低压产物气体压缩到管道压力的压缩机。
    • 100. 发明授权
    • Process for production of synthesis gas
    • 合成气生产工艺
    • US4017271A
    • 1977-04-12
    • US588563
    • 1975-06-19
    • Kenneth M. BarclayJames R. BirkWilliam E. Parkins
    • Kenneth M. BarclayJames R. BirkWilliam E. Parkins
    • C01B3/36C10J3/57C10K1/00C10J3/00
    • C10G19/00C10J3/57C10J3/78C10J3/84C01B2203/0283C01B2203/0415C01B2203/0475C01B2203/84C10J2300/093C10J2300/0943C10J2300/0946C10J2300/0956C10J2300/0959C10J2300/0969C10J2300/0976C10J2300/0986C10J2300/1662C10J2300/1671C10J2300/1815C10J2300/1846
    • A process for the production of a synthesis gas, capable of being upgraded to a high BTU pipeline gas, by the partial oxidation and substantially complete gasification of a carbonaceous material under CO-promoting conditions wherein the carbonaceous material, oxygen, and recycled carbon dioxide from the process are introduced into a molten salt containing an alkali metal carbonate and a minor portion of an alkali metal sulfide, the system being operated at a selected temperature and pressure between 1400.degree. and 2000.degree. F and between 1 and 100 atmospheres. The molar ratio of carbon dioxide to oxygen employed is controlled at from about 0.6:1 to about 1.2:1 to control the CO production and also to maintain the molten salt at a desired operating temperature. Sulfur and ash introduced with the fuel are retained in the molten salt. The gaseous effluent, containing a molar ratio of carbon monoxide to carbon dioxide substantially greater than one, is reacted in a water gas shift reaction, followed by removal of the carbon dioxide present in the gaseous effluent from the shift reaction to produce the synthesis gas, capable of being reacted further under appropriate conditions to produce pipeline gas, methanol, ammonia, or gasoline. At least a portion of the removed carbon dioxide is recycled for admixture with the oxygen to form the feed gas to the molten salt containing the carbonaceous material.
    • 通过在CO促进条件下部分氧化和基本上完全气化碳质材料,生产合成气的方法,其能够升级为高BTU管道气体,其中碳质材料,氧气和循环二氧化碳从 将该方法引入含有碱金属碳酸盐和少量碱金属硫化物的熔盐中,该体系在1400〜2000°F的选择的温度和压力下操作,并且在1〜100个大气压下进行。 将二氧化碳与所使用的氧气的摩尔比控制在约0.6:1至约1.2:1,以控制CO产生并且还将熔融盐保持在期望的操作温度。 与燃料一起引入的硫和灰被保留在熔盐中。 含有一氧化碳与二氧化碳的摩尔比基本上大于1的气态流出物在水煤气变换反应中反应,然后除去存在于来自换档反应的气态流出物中的二氧化碳以产生合成气, 能够在合适的条件下进一步反应生成管道气体,甲醇,氨或汽油。 将去除的二氧化碳的至少一部分再循环用于与氧混合以在含有碳质材料的熔融盐中形成进料气体。