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91. 发明申请

US20120004465A1 Process For The Preparation Of An Isomorphously Substituted Silicate 审中-公开
标题翻译：制备同晶取代硅酸盐的方法
公开(公告)号：US20120004465A1
公开(公告)日：2012-01-05
申请号：US13254015
申请日：2010-03-03
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Hermann Gies , Dirk de Vos , Xinhe Bao , Weiping Zhang , Takashi Tatsumi
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Hermann Gies , Dirk de Vos , Xinhe Bao , Weiping Zhang , Takashi Tatsumi
IPC分类号： C07C209/00 , C01B33/26 , C01B35/10 , C01B33/20
CPC分类号： C01B33/20 , B01J21/16 , B01J29/061 , B01J29/70 , B01J35/002 , C01B33/38 , C01B37/00 , C01B39/02 , C01B39/04 , C07C1/20 , C07C209/16 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C211/04
摘要： A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.
摘要翻译：一种制备同晶取代的层状硅酸盐的方法，包括（1）提供含有二氧化硅或其前体的混合物，至少一种允许层状硅酸盐结晶的结构导向剂（SDA）和水; （2）在水热条件下加热根据（1）获得的混合物; （3）至少一种源至少一种适用于同晶取代的元素; （4）在水热条件下加热根据（3）获得的混合物。

92. 发明授权

US08030508B2 Porous zeolite of organosilicon, a method for preparing the same and the use of the same 有权
标题翻译：有机硅的多孔沸石，其制备方法及其用途
公开(公告)号：US08030508B2
公开(公告)日：2011-10-04
申请号：US12377159
申请日：2007-07-17
申请人： Huanxin Gao , Bin Zhou , Yilun Wei , Hua Fang , Ruifang Gu , Shufang Ji
发明人： Huanxin Gao , Bin Zhou , Yilun Wei , Hua Fang , Ruifang Gu , Shufang Ji
IPC分类号： C07F7/02 , B01J29/04 , C01B39/00
CPC分类号： B01J20/18 , B01J29/70 , C01B39/04 , C01B39/48 , C07C2/66 , C07C15/107
摘要： The present invention relates to an organosilicon porous zeolite, preparation of the same, and use of the same. The organosilicon porous zeolite of the invention has the following composition on molar basis: (1/n)Al2O3:SiO(2-m/2):mR:xM, wherein n=5 to 1000, m=0.001 to 1, x=0.005 to 2, R is at least one selected from the group consisting of alkyl, alkenyl and phenyl and connected to a silicon atom in the framework of the zeolite, and M is an organic amine templating agent, wherein a solid Si29NMR spectrum of the zeolite has at least one Si29 nuclear magnetic resonance peak in the range of from −80 to +50 ppm, and wherein a X-ray diffraction pattern of the zeolite exhibits diffraction peaks corresponding to d-spacing of 12.4±0.2, 11.0±0.3, 9.3±0.3, 6.8±0.2, 6.1±0.2, 5.5±0.2, 4.4±0.2, 4.0±0.2 and 3.4±0.1 Å. The porous zeolite can be used as an adsorbent or as a component of a catalyst for the conversion of an organic compound.
摘要翻译：本发明涉及一种有机硅多孔沸石，其制备方法及其用途。本发明的有机硅多孔沸石的摩尔比为：（1 / n）Al2O3：SiO（2-m / 2）：mR：xM，其中n = 5〜1000，m = 0.001〜1，x = 0.005至2，R是选自烷基，烯基和苯基中的至少一种，并且与沸石骨架中的硅原子连接，M是有机胺模板剂，其中沸石的固体Si 29 NMR光谱具有至少一个在-80至+50ppm范围内的Si29核磁共振峰，并且其中该沸石的X射线衍射图显示了对应于d间距为12.4±0.2,11.0±0.3,9.3 ±0.3，6.8±0.2，6.1±0.2,5.5±0.2,4.4±0.2,4.0±0.2和3.4±0.1。多孔沸石可以用作吸附剂或用作转化有机化合物的催化剂的组分。

93. 发明申请

US20110237423A1 ZEOLITE STRUCTURE AND MANUFACTURING METHOD THEREOF 有权
标题翻译：沸石结构及其制造方法
公开(公告)号：US20110237423A1
公开(公告)日：2011-09-29
申请号：US13050381
申请日：2011-03-17
申请人： Yoshio KIKUCHI , Haruo Otsuka
发明人： Yoshio KIKUCHI , Haruo Otsuka
IPC分类号： B01J29/06 , B01J35/10 , B01J29/40 , B01J29/08 , B01J29/65 , B01J29/072 , B01J29/076 , B01J29/068 , B01J29/48 , B01J29/44 , B01J29/46 , B01J29/12 , B01J29/14 , B01J29/16 , B01J29/67 , B01J29/68 , B01J35/04 , B01J37/04 , B01J37/08 , B01J20/30 , B01J20/28 , B01J20/18
CPC分类号： C01B39/04 , B01D53/9413 , B01D71/028 , B01D2253/108 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/502 , B01D2255/912 , B01D2255/92 , B01J29/06 , B01J35/04
摘要： The zeolite structure is a porous zeolite structure constituted of a formed article obtained by extruding a zeolite raw material containing zeolite particles and an inorganic binding material including at least basic aluminum chloride, a ratio P1 (P1=V2/V1×100) of a volume V2 of the inorganic binding material in the zeolite structure with respect to a volume V1 of the zeolite structure is from 10 to 50 vol %, and a relation of equation (1) is satisfied: P2/P1≦1.0 (1), in which P1 is the ratio of the volume V2 of the inorganic binding material in the zeolite structure with respect to the volume V1 of the zeolite structure and P2 (P2=Vb/Va×100) is a ratio of volumes Vb of pores having pore diameters of 0.003 to 0.03 μm with respect to the whole pore volume Va of the zeolite structure.
摘要翻译：沸石结构是由通过挤出含有沸石粒子的沸石原料和至少含有碱性氯化铝的无机结合材料而得到的成形体，多孔沸石结构体，比例P1（P1 = V2 / V1×100）沸石结构中的无机结合材料的V2相对于沸石结构的体积V1为10〜50体积％，满足式（1）的关系：P2 / P1＆nlE; 1.0（1）其中 P1是沸石结构中的无机结合材料的体积V2相对于沸石结构的体积V1的比例，P2（P2 = Vb / Va×100）是孔径的孔的体积Vb的比例相对于沸石结构的整个孔体积Va为0.003〜0.03μm。

94. 发明申请

US20110190561A1 Process for Making Crystalline Metallosilicates 审中-公开
标题翻译：制备结晶金属硅酸盐的方法
公开(公告)号：US20110190561A1
公开(公告)日：2011-08-04
申请号：US12994561
申请日：2009-02-24
申请人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesternko , Jean-Pierre Dath , Sander Van Donk
发明人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesternko , Jean-Pierre Dath , Sander Van Donk
IPC分类号： C07C1/20 , C01B39/00 , C01B39/02
CPC分类号： B01J29/40 , B01J2229/62 , C01B37/005 , C01B39/02 , C01B39/04 , C01B39/38 , C01B39/40 , C07C2/864 , C07C2529/70 , C10G29/205 , Y02P20/52 , C07C15/08
摘要： The present invention relates to a process for making a crystalline metallosilicate composition comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that: the ratio Si/metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising: a) providing an aqueous medium comprising OH— anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallyze the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is
摘要翻译：本发明涉及一种制备结晶金属硅酸盐组合物的方法，其包含具有内部部分（芯部）和外部部分（外层或外壳）的微晶，使得：外部部分的Si /金属比例高于所述内部部分，所述微晶在结晶截面上具有金属和硅的连续分布，所述方法包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机源的水性介质的硅和任选的模板剂，c）任选地提供包含任选的二氧化硅有机源的非水性液体培养基，d）在有效地使所需的金属硅酸盐水解的条件下，将培养基a），b）和任选的c））回收所需的金属硅酸盐，其中在混合物a）+ b）+ c）中，在结晶之前，Si org / Si无机物的比例<0.3，有利地<0.2，优选为0，摩尔浓度 tio OH- / SiO 2为至少0.3，有利地为0.3至0.62，优选为0.31至0.61，更优选为0.32至0.61，非常优选为0.33至0.6，混合物a）+ b）+ c），在结晶之前，高于13，优选高于13.1，更优选高于13.2，还更优选高于13.3，最优选高于13.4。

95. 发明申请

US20110144328A1 METHOD FOR PREPARING TITANIUM-SILICALITE MOLECULAR SIEVE AND METHOD FOR PREPARING CYCLOHEXANONE OXIME USING TITANIUM-SILICALITE MOLECULAR SIEVE 有权
标题翻译：用于制备钛 - 硅酸盐分子筛的方法及使用钛 - 硅酸盐分子筛制备环己酮氧化物的方法
公开(公告)号：US20110144328A1
公开(公告)日：2011-06-16
申请号：US12748932
申请日：2010-03-29
申请人： Pin-To Yao , Cheng-Fa Hsieh , Shih-Yao Chao , Yang-Min Liang
发明人： Pin-To Yao , Cheng-Fa Hsieh , Shih-Yao Chao , Yang-Min Liang
IPC分类号： C07D223/10 , B01J29/89
CPC分类号： C01B39/023 , B01J29/405 , C01B37/005 , C01B39/04
摘要： The present invention provides a method for preparing large particles of titanium-silicalite molecular sieves. The method of the present invention includes the steps of preparing a dispersion solution of a primary crystalline molecular sieve; forming an aggregated particle solution by adding a flocculating agent and a coagulating agent into the dispersion solution; mixing the aggregated particle solution with a synthesis gel to form a mixture; and heat-treating the mixture. The average diameter of the titanium-silicalite molecular sieves in the present invention is more than 5 μm. In the preparation of cyclohexanone oxime using the molecular sieve of the present invention as the catalyst, the selectivity and conversion rate of cyclohexanone oxime are high, the usage of hydrogen peroxide is enhanced, and the catalyst is easy to be recovered.
摘要翻译：本发明提供一种制备钛 - 硅沸石分子筛大颗粒的方法。本发明的方法包括制备一级结晶分子筛的分散液的步骤; 通过向分散液中添加絮凝剂和凝结剂形成凝集颗粒溶液; 将聚集的颗粒溶液与合成凝胶混合以形成混合物; 并对该混合物进行热处理。本发明中钛 - 硅沸石分子筛的平均直径大于5μm。在使用本发明的分子筛作为催化剂的环己酮肟的制备中，环己酮肟的选择性和转化率高，过氧化氢的用途增加，催化剂容易回收。

96. 发明申请

US20110105300A1 MESOSTRUCTURED ALUMINOSILICATE MATERIAL MADE OF SPHERICAL PARTICLES OF SPECIFIC SIZE 有权
标题翻译：特殊尺寸的球形颗粒的结构化铝氧化物材料
公开(公告)号：US20110105300A1
公开(公告)日：2011-05-05
申请号：US12935335
申请日：2009-02-26
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , Michel Martin
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , Michel Martin
IPC分类号： B01J29/06 , B01J20/28 , B01J37/04 , B01J20/30
CPC分类号： C01B39/04 , B01J20/18 , B01J20/28004 , B01J20/28019 , B01J20/28057 , B01J20/28083 , B01J21/12 , B01J29/041 , B01J35/1057 , B01J35/1061 , B01J35/109 , Y10T428/2991 , Y10T428/2993
摘要： A mesostructured aluminosilicate material is described, which consists of at least two elementary spherical particles, each one of said spherical particles consisting of a matrix based on silicon oxide and aluminium oxide, said matrix having a pore diameter ranging between 1.5 and 30 nm, a Si/Al molar ratio at least equal to 1 and amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a diameter D such that 10
摘要翻译：描述了介质结构的硅铝酸盐材料，其由至少两个基本球形颗粒组成，每个所述球形颗粒由基于氧化硅和氧化铝的基体组成，所述基体的孔径范围为1.5至30nm，Si / Al摩尔比至少等于1，厚度范围在1至30nm之间的非晶壁，所述基本球形颗粒的直径D使得10

97. 发明授权

US07858062B2 Synthesis and use of nanocrystalline zeolites 失效
标题翻译：纳米晶体沸石的合成与应用
公开(公告)号：US07858062B2
公开(公告)日：2010-12-28
申请号：US12510776
申请日：2009-07-28
申请人： Sarah Larsen , Vicki Grassian , Weiguo Song , Gonghu Li
发明人： Sarah Larsen , Vicki Grassian , Weiguo Song , Gonghu Li
IPC分类号： B01D53/56 , B01D53/86 , B01D47/00 , B01D53/94 , B01J8/00 , B01J8/02 , C01B21/00 , B01J29/08
CPC分类号： C01B39/02 , B01D2255/50 , B01D2257/402 , B01D2257/404 , B01J29/035 , B01J29/084 , B01J35/0013 , B82Y30/00 , C01B21/02 , C01B21/22 , C01B37/02 , C01B39/04 , C01B39/205 , C01B39/24 , C01P2002/72 , C01P2002/82 , C01P2002/86 , Y02C20/10
摘要： Embodiments of the present invention relate to a method for synthesizing nanocrystalline zeolites, the method comprising contacting starting products that comprise a solvent, a silicon source, a cation base, an organic template, and an aluminum source, or any combination thereof sufficient to produce a zeolite gel by hydrolysis, heating the zeolite gel sufficient to produce a first batch of zeolite crystals and a first clear solution, separating the first batch of zeolite crystals from the first clear solution, heating the first clear solution sufficient to produce a second batch of zeolite crystals and second clear solution and separating the second batch of zeolite crystals from the second clear solution. In addition, embodiments relate to a method of using nanocrystalline zeolites, the method comprising contacting a nanocrystalline zeolite with a reductant sufficient to produce a nanocrystalline zeolite with adsorbed reductant and exposing the nanocrystalline zeolite with adsorbed reductant to reactant gases sufficient to obtain reaction products and the nanocrystalline zeolite.
摘要翻译：本发明的实施方案涉及一种用于合成纳米晶体沸石的方法，所述方法包括将包含溶剂，硅源，阳离子碱，有机模板和铝源的起始产物或其足以产生沸石凝胶，加热沸石凝胶足以产生第一批沸石晶体和第一澄清溶液，将第一批沸石晶体与第一澄清溶液分离，加热足以产生第二批沸石的第一澄清溶液晶体和第二透明溶液，并将第二批沸石晶体与第二澄清溶液分离。此外，实施方案涉及使用纳米晶体沸石的方法，所述方法包括使纳米晶体沸石与还原剂接触，所述还原剂足以产生具有吸附还原剂的纳米晶体沸石，并将具有吸附还原剂的纳米晶体沸石暴露于足以获得反应产物的反应气体纳米晶体沸石。

98. 发明授权

US07816573B2 Molecular sieve composition 有权
标题翻译：分子筛组成
公开(公告)号：US07816573B2
公开(公告)日：2010-10-19
申请号：US11698533
申请日：2007-01-26
申请人： Wenyih Frank Lai , Robert Ellis Kay , Christine N. Elia , Frederick Y. Lo , David O. Marler
发明人： Wenyih Frank Lai , Robert Ellis Kay , Christine N. Elia , Frederick Y. Lo , David O. Marler
IPC分类号： C07C2/66 , B01J29/04 , B01J29/80 , C01B39/00 , C01B39/02
CPC分类号： B01J29/7038 , B01J29/04 , B01J29/06 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/002 , B01J37/0009 , B01J37/06 , B01J2229/12 , B01J2229/18 , B01J2229/42 , B01J2229/64 , C01B39/04 , C01B39/48 , C07C2/66 , C07C15/085 , C07C2529/08 , C07C2529/18 , C07C2529/40 , Y02P20/52
摘要： The invention relates to a process for converting hydrocarbons with a catalyst comprising a crystalline molecular sieve composition which is obtainable by crystallizing a pre-formed extrudate mixture in a reactor and, during crystallization, removing excess alkali metal hydroxide from the pre-formed extrudate. The pre-formed extrudate mixture comprises at least one source of ions of tetravalent element Y, at least one source of alkali metal hydroxide, water, optionally at least one seed crystal, and optionally at least one source of ions of trivalent element X. The reaction mixture has the following mole composition: Y:X2=10 to infinity; OH−:Y=0.001 to 2; and M+:Y=0.001 to 2; wherein M is an alkali metal. The amount of water in the mixture is at least sufficient to permit extrusion of said reaction mixture.
摘要翻译：本发明涉及一种用催化剂转化烃的方法，该催化剂包括结晶分子筛组合物，其可通过在反应器中结晶预形成的挤出物混合物并在结晶过程中从预形成的挤出物中除去过量的碱金属氢氧化物而获得。预形成的挤出物混合物包含至少一种四价元素Y的离子源，至少一种碱金属氢氧化物源，水，任选的至少一种晶种和任选的至少一种三价元素X的离子源。反应混合物具有以下摩尔组成：Y：X2 = 10至无穷大; OH-：Y = 0.001〜2; 和M +：Y = 0.001〜2; 其中M是碱金属。混合物中的水的量至少足以允许挤出所述反应混合物。

99. 发明申请

US20100098623A1 ZEOLITE MATERIALS AND SYNTHESIS METHOD THEREOF 审中-公开
标题翻译：沸石材料及其合成方法
公开(公告)号：US20100098623A1
公开(公告)日：2010-04-22
申请号：US12526414
申请日：2008-02-07
申请人： Bogdan Gagea , Pierre Jacobs , Johan Martens , Hans Vandepitte
发明人： Bogdan Gagea , Pierre Jacobs , Johan Martens , Hans Vandepitte
IPC分类号： C01B39/04 , C01B39/40
CPC分类号： C01B39/04 , C01B37/00 , C01B37/02 , C01B39/36
摘要： The present invention provides zeolites and zeolite-like material having an enhanced microporosity. It was found that such zeolites can be obtained using a zeolite synthesis method comprising the preparation of a gel or solution for the synthesis of a zeolite, said gel or solution comprising appropriate amounts of (i) a conventional monomeric or polymeric silica source and (ii) a molecular template as a microstructuring agent, characterized in that said gel or solution further comprises an organosilane compound having limited self-assembling capacity.
摘要翻译：本发明提供具有增强的微孔性的沸石和类沸石材料。已经发现，这种沸石可以使用包括制备用于合成沸石的凝胶或溶液的沸石合成方法获得，所述凝胶或溶液包含适量的（i）常规单体或聚合二氧化硅源和（ii））作为微结构化剂的分子模板，其特征在于所述凝胶或溶液还包含有限自组装能力的有机硅烷化合物。

100. 发明申请

US20090247776A1 POROUS ZEOLITE OF ORGANOSILICON, A METHOD FOR PREPARING THE SAME AND THE USE OF THE SAME 有权
标题翻译：有机硅的多孔沸石，其制备方法及其使用方法
公开(公告)号：US20090247776A1
公开(公告)日：2009-10-01
申请号：US12377159
申请日：2007-07-17
申请人： Huanxin Gao , Bin Zhou , Yilun Wei , Hua Fang , Ruifang Gu , Shufang Ji
发明人： Huanxin Gao , Bin Zhou , Yilun Wei , Hua Fang , Ruifang Gu , Shufang Ji
IPC分类号： C07F7/02 , C07C2/66
CPC分类号： B01J20/18 , B01J29/70 , C01B39/04 , C01B39/48 , C07C2/66 , C07C15/107
摘要： The present invention relates to an organosilicon porous zeolite, preparation of the same, and use of the same. The organosilicon porous zeolite of the invention has the following composition on molar basis: (1/n)Al2O3:SiO(2-m/2):mR:xM, wherein n=5 to 1000, m=0.001 to 1, x=0.005 to 2, R is at least one selected from the group consisting of alkyl, alkenyl and phenyl and connected to a silicon atom in the framework of the zeolite, and M is an organic amine templating agent, wherein a solid Si29NMR spectrum of the zeolite has at least one Si29 nuclear magnetic resonance peak in the range of from −80 to +50 ppm, and wherein a X-ray diffraction pattern of the zeolite exhibits diffraction peaks corresponding to d-spacing of 12.4±0.2, 11.0±0.3, 9.3±0.3, 6.8±0.2, 6.1±0.2, 5.5±0.2, 4.4±0.2, 4.0±0.2 and 3.4±0.1 Å. The porous zeolite can be used as an adsorbent or as a component of a catalyst for the conversion of an organic compound.
摘要翻译：本发明涉及一种有机硅多孔沸石，其制备方法及其用途。本发明的有机硅多孔沸石的摩尔比为：（1 / n）Al2O3：SiO（2-m / 2）：mR：xM，其中n = 5〜1000，m = 0.001〜1，x = 0.005至2，R是选自烷基，烯基和苯基中的至少一种，并且与沸石骨架中的硅原子连接，M是有机胺模板剂，其中沸石的固体Si 29 NMR光谱具有至少一个在-80至+50ppm范围内的Si29核磁共振峰，并且其中该沸石的X射线衍射图显示了对应于d间距为12.4±0.2,11.0±0.3,9.3 ±0.3，6.8±0.2，6.1±0.2,5.5±0.2,4.4±0.2,4.0±0.2和3.4±0.1。多孔沸石可以用作吸附剂或用作转化有机化合物的催化剂的组分。

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