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91. 发明授权

US08809464B2 Polymers functionalized with halosilanes containing an amino group 有权
标题翻译：用含有氨基的卤代硅烷官能化的聚合物
公开(公告)号：US08809464B2
公开(公告)日：2014-08-19
申请号：US13588033
申请日：2012-08-17
申请人： Terrence E. Hogan , Steven Luo , Yoichi Ozawa , Junko Matsushita , Ryuji Nakagawa , Eiju Suzuki , Ken Tanaka
发明人： Terrence E. Hogan , Steven Luo , Yoichi Ozawa , Junko Matsushita , Ryuji Nakagawa , Eiju Suzuki , Ken Tanaka
IPC分类号： C08F236/06 , C08F8/32
CPC分类号： C08C19/44 , C08F8/42 , C08L15/00 , C08L19/006 , C08F297/04
摘要： A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer, and reacting the reactive polymer with a halosilane compound containing an amino group.
摘要翻译：一种制备官能化聚合物的方法，该方法包括如下步骤：制备反应性聚合物，并使反应性聚合物与含有氨基的卤代硅烷化合物反应。

92. 发明申请

US20140031471A1 Stabilization Of Polymers That Contain A Hydrolyzable Functionality 有权
标题翻译：包含可水解功能的聚合物的稳定性
公开(公告)号：US20140031471A1
公开(公告)日：2014-01-30
申请号：US13976352
申请日：2012-01-03
申请人： Christine M. Rademacher , Terrence E. Hogan , Christopher G. Robertson , Jessica C. Kurasch
发明人： Christine M. Rademacher , Terrence E. Hogan , Christopher G. Robertson , Jessica C. Kurasch
IPC分类号： C08K5/54 , C08K5/541 , C08K3/34
CPC分类号： C08K5/5406 , C08C19/25 , C08C19/44 , C08K3/34 , C08K3/36 , C08K5/541 , C08L7/00 , C08L9/06
摘要： A process for treating a polymer having a hydrolyzable functionality, the method comprising: (i.) providing a polymer having hydrolyzable functionality; and (ii.) introducing a stabilizing agent to the polymer, where the stabilizing agent is defined by the formula (I) where ÷ is a hydrolyzable group that forms an acidic species upon hydrolysis, where R2, R3, and R4 are each independently a halogen atom, a hydrocarbyl group, a hydrocarboxylate group, or a hydrocarbyloxy group.
摘要翻译：一种用于处理具有可水解官能团的聚合物的方法，所述方法包括：（i）提供具有可水解官能团的聚合物; 和（ii）将稳定剂引入聚合物中，其中稳定剂由式（I）定义，其中÷是在水解时形成酸性物质的可水解基团，其中R 2，R 3和R 4各自独立地为卤素原子，烃基，氢化羧酸酯基或烃氧基。

93. 发明申请

US20130281645A1 Aminosilane Initiators And Functionalized Polymers Prepared Therefrom 有权
标题翻译：氨基硅烷引发剂和官能化聚合物
公开(公告)号：US20130281645A1
公开(公告)日：2013-10-24
申请号：US13977296
申请日：2011-06-22
申请人： David F. Lawson , Terrence E. Hogan , Christine Rademacher , David M. Roggeman , Fuminori Ota
发明人： David F. Lawson , Terrence E. Hogan , Christine Rademacher , David M. Roggeman , Fuminori Ota
IPC分类号： C08F36/06
CPC分类号： C08C19/25 , B60C1/00 , C08C19/22 , C08C19/44 , C08F4/48 , C08F8/42 , C08F36/04 , C08F36/06 , C08F236/10 , C08L15/00 , C08L19/006 , Y02T10/862
摘要： Metallated aminosilane compounds for use as functional initiators in anionic polymerizations and processes for producing an aminosilane-functionalized polymer using the metallated aminosilane compounds to initiate anionic polymerization of at least one type of anionically polymerizable monomer. Preferred use of the metallated aminosilane compounds results in rubber compositions for use in tires comprising an aminosilane functionalized polymer. A telechelic polymer may result from use of the metallated aminosilane compound as a functional terminator.
摘要翻译：用于阴离子聚合中的官能引发剂的金属化氨基硅烷化合物和使用金属化氨基硅烷化合物制备氨基硅烷官能化聚合物以引发至少一种类型的阴离子聚合单体的阴离子聚合的方法。优选使用金属化的氨基硅烷化合物产生用于包含氨基硅烷官能化聚合物的轮胎的橡胶组合物。使用金属化氨基硅烷化合物作为功能性终止剂可产生遥爪聚合物。

94. 发明授权

US08501895B2 Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes 有权
标题翻译：制备烷氧基改性倍半硅氧烷和氨基烷氧基改性倍半硅氧烷的方法
公开(公告)号：US08501895B2
公开(公告)日：2013-08-06
申请号：US12347047
申请日：2008-12-31
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C08G77/26
CPC分类号： C08G77/28 , C08G77/26 , Y02P20/584
摘要： A method is presented for making an amino alkoxy-modified silsesquioxane (amino AMS) comprising one or more compounds selected from the group consisting of an amino-AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, and mixtures of these. The use of solid strong cationic catalysts in this reaction system is advantageous because the catalyst remains as a solid throughout the reaction, allowing simplified separation of the solid catalyst from the soluble amino AMS or amino co-AMS products, resulting in total or near total recovery of the amino AMS or amino co-AMS products, as well as virtual total recovery of the catalyst for recycling. The use of the solid strong cationic catalysts is advantageous because it results in amino AMS products that are free of, or substantially free of, residual acid catalyst.
摘要翻译：提出了一种制备氨基烷氧基改性倍半硅氧烷（氨基AMS）的方法，其包含一种或多种选自氨基AMS，氨基/硫醇共-AMS，氨基/封端的硫醇共-AMS的化合物和这些的混合物。在该反应体系中使用固体强阳离子催化剂是有利的，因为催化剂在整个反应中保持固体，使固体催化剂与可溶性氨基AMS或氨基共聚AMS产物的分离更简单，导致总的或接近总的回收的氨基AMS或氨基共AMS产物，以及用于再循环的催化剂的虚拟总回收率。使用固体强阳离子催化剂是有利的，因为其导致氨基AMS产物不含或基本上不含残留的酸催化剂。

95. 发明授权

US08399570B2 Functionalized polymers and improved tires therefrom 有权
标题翻译：官能化聚合物和改良的轮胎
公开(公告)号：US08399570B2
公开(公告)日：2013-03-19
申请号：US12555843
申请日：2009-09-09
申请人： Christine Rademacher , Steven Luo , Terrence E. Hogan
发明人： Christine Rademacher , Steven Luo , Terrence E. Hogan
IPC分类号： C08C19/00 , C08C19/22
CPC分类号： C08C19/44 , B60C1/0016 , C08K3/013 , C08L15/00
摘要： A tire component comprising a vulcanized residue of a functionalized polymer defined by the formula I where π is a rubbery polymer chain, B is a boron atom, R1 is a bond or a divalent organic group, and each υ is independently selected from thioalkoxy groups (—SR), amino groups (—NR2), or phosphino groups (—PR2), where each R is independently selected from monovalent organic groups or two R groups form a divalent organic group, which forms a cyclic structure.
摘要翻译：一种轮胎组件，其包含由式I定义的官能化聚合物的硫化残余物，其中pgr; 是橡胶状聚合物链，B是硼原子，R1是键或二价有机基团，每个υ独立地选自硫代烷氧基（-SR），氨基（-NR2）或膦基（-PR2）其中每个R独立地选自一价有机基团或两个R基团形成二价有机基团，其形成环状结构。

96. 发明授权

US08399562B2 Amine-containing alkoxysilyl-functionalized polymers 有权
标题翻译：含胺的烷氧基甲硅烷基官能化聚合物
公开(公告)号：US08399562B2
公开(公告)日：2013-03-19
申请号：US13406714
申请日：2012-02-28
申请人： Terrence E. Hogan , William L. Hergenrother , Maria Tallman
发明人： Terrence E. Hogan , William L. Hergenrother , Maria Tallman
IPC分类号： C08G77/26
CPC分类号： C08C19/22 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/25 , C08C19/44 , C08F8/32 , C08F8/42 , C08L15/00
摘要： An amine-containing alkoxysilyl-functionalized polymer, a method of preparing a reactive polymer functionalized with an alkoxysilane functionalizing agent and further reacted with an amino alcohol, the resulting polymer, and vulcanizates thereof.
摘要翻译：含胺的烷氧基甲硅烷基官能化聚合物，制备用烷氧基硅烷官能化剂官能化的反应性聚合物的方法，并进一步与氨基醇反应，得到的聚合物和硫化产物。

97. 发明授权

US08399550B2 Tread compositions with improved dynamic storage modulus 有权
标题翻译：具有改进的动态储能模量的胎面组合物
公开(公告)号：US08399550B2
公开(公告)日：2013-03-19
申请号：US13283812
申请日：2011-10-28
申请人： Terrence E. Hogan , Christopher G. Robertson , Alberto Scurati
发明人： Terrence E. Hogan , Christopher G. Robertson , Alberto Scurati
IPC分类号： C07C323/12 , C08G73/10 , C08K5/06 , B60C1/00 , B60C3/04
CPC分类号： C08K3/04 , B60C1/0016 , B60C1/0025 , B60C2011/0025 , C08C19/44 , C08L15/00 , C08L21/00 , G06F2221/2101 , G06F2221/2105 , C08L19/006 , C08L2666/08
摘要： A process for forming a tire component, the process comprising the steps of introducing a vulcanizable polymer, a curative, a first carbon black characterized by an iodine adsorption number, per ASTM D1510, that is greater than 60 g/kg, and a second carbon black characterized by an iodine adsorption number, per ASTM D1510, that is less than 60 g/kg to form a vulcanizable composition, fabricating a tire component from the vulcanizable composition, and curing the tire component.
摘要翻译：一种用于形成轮胎部件的方法，所述方法包括以下步骤：将根据ASTM D1510特征的以碘吸附数为特征的第一炭黑，固化剂，大于60g / kg的可硫化聚合物和第二碳黑色，其特征在于根据ASTM D1510的碘吸附数，小于60g / kg以形成可硫化组合物，从可硫化组合物制造轮胎组分，并固化轮胎组分。

98. 发明申请

US20120077922A1 Amino Alkoxy-Modified Silsesquioxane Adhesives For Improved Metal Adhesion And Metal Adhesion Retention To Cured Rubber 有权
标题翻译：用于改善金属粘附性和固化橡胶金属粘附保持性的氨基烷氧基改性倍半硅氧烷粘合剂
公开(公告)号：US20120077922A1
公开(公告)日：2012-03-29
申请号：US13174129
申请日：2011-06-30
申请人： William L. Hergenrother , Walter Tomaszewski , Ashley Hilton , Michael Hayes , James H. Pawlow , Terrence E. Hogan , Zhong-Ren Chen
发明人： William L. Hergenrother , Walter Tomaszewski , Ashley Hilton , Michael Hayes , James H. Pawlow , Terrence E. Hogan , Zhong-Ren Chen
IPC分类号： C08K3/08
CPC分类号： C08K3/08 , C08G77/26 , C08K5/544 , C09J183/08 , C08L21/00
摘要： Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water. Vulcanized rubber compositions that contain an amino AMS and/or amino/mercaptan co-AMS compound also have improved adhesion to embedded uncoated steel after humidity aging compared with vulcanized rubber compositions not containing the amino alkoxy-modified silsesquioxane.
摘要翻译：还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷（氨基AMS）和/或氨基共-MSMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂，用于将线粘附到橡胶原料上。氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用，并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂，例如但不限于钴，树脂和高硫含量。特别地，使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能，以获得足够的粘合，其耐受在时间上的劣化，特别是电阻热老化和/或热氧化老化，特别是在水存在下的腐蚀。与不含氨基烷氧基改性的倍半硅氧烷的硫化橡胶组合物相比，含有氨基AMS和/或氨基/硫醇共-AMS化合物的硫化橡胶组合物在湿度老化后也具有改善的对包埋未涂层钢的粘附性。

99. 发明授权

US08106117B2 Method to improve cold flow resistance of polymers 有权
标题翻译：改善聚合物耐冷流动性的方法
公开(公告)号：US08106117B2
公开(公告)日：2012-01-31
申请号：US12535911
申请日：2009-08-05
申请人： Kevin M. McCauley , Terrence E. Hogan , Zbyslaw R. Owczarczyk , Amy M. Randall
发明人： Kevin M. McCauley , Terrence E. Hogan , Zbyslaw R. Owczarczyk , Amy M. Randall
IPC分类号： C08K5/00
CPC分类号： C08K5/55 , C08K5/56 , C08L21/00
摘要： A method for reducing the cold flow of a polymeric composition of matter by introducing polymer with the combination or reaction product of (i) an acetal or ketal of an alditol and (ii) (a) a hydrocarbylated boric acid, (b) an organoaluminum compound, or (c) both a hydrocarbylated boric acid and an organoaluminum compound.
摘要翻译：通过将聚合物与（i）醛糖醇的缩醛或缩酮和（ii）（a）烃基硼酸的组合或反应产物引入聚合物来降低聚合物组合物的冷流动方法，（b）有机铝化合物，或（c）烃基硼酸和有机铝化合物。

100. 发明授权

US08058357B2 Vulcanizable compositions and tire treads prepared therewith 有权
标题翻译：可硫化组合物和用其制备的轮胎胎面
公开(公告)号：US08058357B2
公开(公告)日：2011-11-15
申请号：US12347762
申请日：2008-12-31
申请人： Amy Randall , Terrence E. Hogan , William L. Hergenrother
发明人： Amy Randall , Terrence E. Hogan , William L. Hergenrother
IPC分类号： C08C19/20 , C08F8/34
CPC分类号： B60C1/0016 , C08C19/44 , C08K5/40 , C08L15/00 , C08L21/00
摘要： A method for preparing a tire tread, the method comprising vulcanizing a vulcanizable composition comprising a rubber component including a functionalized polymer and a cure system, where the cure system includes sulfur and a disulfide compound represented by the formula I R1—S—S—R3—S—S—R2 where R3 represents a divalent organic group and R1 and R2 each independently include a monovalent organic group including a nitrogen atom.
摘要翻译：一种制备轮胎胎面的方法，所述方法包括硫化包含含官能化聚合物和固化体系的橡胶组分的可硫化组合物，其中所述固化体系包括硫和由式I R1-S-S-R3表示的二硫化物 -S-S-R 2，其中R 3表示二价有机基团，并且R 1和R 2各自独立地包括包含氮原子的一价有机基团。

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