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91. 发明授权

US08399723B2 Processes for production and purification of hydrofluoroolefins 失效
标题翻译：生产和净化氢氟烯烃的方法
公开(公告)号：US08399723B2
公开(公告)日：2013-03-19
申请号：US13013065
申请日：2011-01-25
申请人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/38
CPC分类号： C07C17/383 , C01B7/196 , C07C17/25 , C07C17/38 , C07C17/386 , C07C21/18 , Y02P20/582
摘要： Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.
摘要翻译：本文公开了通过脱氟化氢生产氢氟烯烃的方法。本文还公开了从氢氟烃和氟化氢分离氢氟烯烃的方法。

92. 发明申请

US20120042668A1 COMPOSITIONS COMPRISING FLUOROOLEFINS AND USES THEREOF 有权
标题翻译：包含氟化物的组合物及其用途
公开(公告)号：US20120042668A1
公开(公告)日：2012-02-23
申请号：US13286765
申请日：2011-11-01
申请人： Mario Joseph Nappa , Barbara Haviland Minor , Allen Capron Sievert
发明人： Mario Joseph Nappa , Barbara Haviland Minor , Allen Capron Sievert
IPC分类号： F25B1/00 , C09K5/04
CPC分类号： C09K5/045 , C07C21/18 , C09K5/04 , C09K2205/126 , C09K2205/22 , C09K2205/40 , F25B1/00 , F25B30/02 , F25B31/002 , F25B39/00 , F25B39/02 , F25B45/00 , F25B2400/12 , F25B2400/121
摘要： The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.
摘要翻译：本发明涉及氟烯烃组合物。本发明的氟代烯烃组合物可用作制冷剂或传热流体以及用于生产冷却或加热的方法。另外，本发明的氟代烯烃组合物可用于替代目前使用的具有较高全球变暖潜能的制冷剂或传热流体组合物。

93. 发明授权

US08053613B2 Processes for producing 1,2,3,3,3-pentafluoropropene and precursors thereof 有权
标题翻译：制备1,2,3,3,3-五氟丙烯及其前体的方法
公开(公告)号：US08053613B2
公开(公告)日：2011-11-08
申请号：US12377761
申请日：2007-09-05
申请人： Allen Capron Sievert
发明人： Allen Capron Sievert
IPC分类号： C07C19/08
CPC分类号： C07C17/25 , C07C17/206 , C07C17/278 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for making CH2ClCF2CClF2. The process involves reacting CH2ClF with CClF═CF2 in an addition reaction zone in the presence of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3−x, provided that the average values of x and y are not both 0. Also disclosed is a process for making CH2FCF2CF3 that involves reacting the CH2ClCF2CClF2 with HF in a fluorination reaction zone in the presence of a fluorination catalyst. Also disclosed is a process for making CHF═CFCF3 that involves dehydrofluorinating the CH2FCF2CF3.
摘要翻译：公开了制备CH 2 ClCF 2 CClF 2的方法。该方法包括在加成反应区中，在具有主体配方为AlCl x BryF 3-xy的卤化铝组合物的存在下，使CH 2 ClF与CClF = CF 2反应，其中x的平均值为0-3，y的平均值为0-3 -x，条件是x和y的平均值不为0。还公开了一种制备CH2CFF2CF3的方法，其包括在氟化催化剂存在下在氟化反应区中使CH 2 ClCF 2 CClF 2与HF反应。还公开了制备CHF = CFCF 3的方法，其涉及使CH 2 CFF 2 CF 3脱氟化氢。

94. 发明申请

US20110118514A1 Process for the Preparation of 1,1,1,3,3,3-Hexafluoro-Propane and at Least One Of 1,1,1,2,3,3-Hexafluoropropane, Hexafluoropropane and 1,1,1,2,3,3,3-Heptafluoropropane 失效
标题翻译： 1,1,1,3,3,3-六氟丙烷的制备方法和1,1,1,2,3,3-六氟丙烷，六氟丙烷和1,1,1,2,3 ，3,3-七氟丙烷
公开(公告)号：US20110118514A1
公开(公告)日：2011-05-19
申请号：US11988258
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/23 , C07C17/20
CPC分类号： B01J37/26 , B01J23/868 , C07C17/21 , C07C17/23 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane, hexafluoropropene and/or 1,1,1,2,3,3,3-heptafluoropropane. The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product comprising CF3CCI2CF3 and CF3CCIFCCIF2; (b) reacting CF3CCI2CF3 and CF3CCIFCCIF2 produced in (a) with hydrogen, optionally in the presence of HF, to produce a product comprising CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3. In (a), the CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了用于制造1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烯和/或1,1,1,2,3， 3,3-七氟丙烷。该方法包括（a）使HF，Cl 2和至少一种式CX3CCI = CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应，以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2的产物; （b）任选地在HF存在下使（a）中产生的CF 3 CCl 2 CF 3和CF 3 CClF CIFF 2与氢反应，以产生包含CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种的产物; 和（c）从（b）中产生的产物，CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种中回收。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2在氯氟化催化剂存在下制备，包括（i）α-氧化铬晶格中至少0.05原子％的铬原子被二价铜取代的结晶α-氧化铬，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

95. 发明授权

US07872161B2 Process for producing 2,3,3,3-tetrafluoropropene 有权
标题翻译：制备2,3,3,3-四氟丙烯的方法
公开(公告)号：US07872161B2
公开(公告)日：2011-01-18
申请号：US12444526
申请日：2007-11-15
申请人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/10 , C07C17/00 , C07C17/26
CPC分类号： C07C21/18 , C07C17/23 , C07C17/25 , C07C17/278 , C07C19/10
摘要： A process is disclosed for making CF3CF═CH2 The process involves (i) contacting CHCl2CF2CF3 in a reaction zone in the presence of a catalytically effective amount of a dehydrofluorination catalyst to produce CCl2═CFCF3; (ii) contacting CCl2═CFCF3 with H2 formed in (i) in a reaction zone in the presence of a catalyst comprising a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina fluorided alumina, aluminum fluoride and mixtures thereof, to produce a product mixture comprising CF3CF═CH2, wherein the mole ratio of H2 to CCl2═CFCF3 fed to the reaction zone is between about 1:1 and about 4:1 and (iii) recovering CF3CF═CH2 from the product mixture formed in (ii).
摘要翻译：公开了制备CF 3CF≡CH2的方法。该方法包括（i）在催化有效量的脱氟化氢催化剂存在下，在反应区中使CHCl 2 CF 2 CF 3接触以产生CCl 2 = CFCF 3; （ⅱ）在催化剂存在下，在反应区中将CCl 2 = CFCF 3与（ⅰ）中形成的H 2接触，所述催化剂包含催化有效量的负载在选自氧化铝氟化铝，氟化铝及其混合物的载体上的钯，以产生包含CF 3 CF = CH 2的产物混合物，其中进料到反应区的H 2与CCl 2 = CFCF 3的摩尔比为约1:1至约4:1，和（iii）从形成的产物混合物中回收CF 3 CF = CH 2 在（ii）中。

96. 发明申请

US20100320412A1 PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3-TETRAFLUOROPROPENE 失效
标题翻译：制备2,3,3,3-四氢呋喃和/或1,2,3,3-四氯丙烯的方法
公开(公告)号：US20100320412A1
公开(公告)日：2010-12-23
申请号：US12446063
申请日：2007-10-31
申请人： Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C09K5/04 , C07C17/25 , C07C17/38
CPC分类号： C07C21/18 , C07C17/23 , C07C17/25 , C07C19/08
摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF2CF═CHF. This process involves (a) reacting CHCl2CF2CF3, and optionally CHClFCF2CClF2, with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 and, when CHClFCF2CClF2 is present, CH2FCF2CHF2; (b) dehydrofluorinating CH3CF2CF3, and optionally any CH2FCF2CHF2, from (a) to form a product mixture including CF3CF═CH2 and, if CH2FCF2CHF2 is present, CHF2CF═CHF; and optionally (c) recovering CF3CF═CH2, or a mixture thereof with CHF2CF═CHF from the product mixture formed in (b) and/or (d) separating at least a portion of any CHF2CF═CHF in the product mixture formed in (b) from the CF3CF═CH2 in the product mixture formed in (b).
摘要翻译：公开了制备CF 3CF≡CH2或其与CHF 2 CF = CHF的混合物的方法。该方法包括（a）在催化有效量的氢化催化剂存在下使CHCl 2 CF 2 CF 3和任选的CHClFCF 2 CClF 2与H 2反应以形成CH 3 CF 2 CF 3，并且当CHClFCF 2 CClF 2存在时，CH 2 FCF 2 CHF 2; （b）从（a）得到（CF 3 CF 2 CH 2）和（如果存在CH 2 CF 2 CHF 2）的产物混合物的CH 3 CF 2 CF 3和任选的任何任何CH 2 CF 2 CHF 2脱氟氟化CHF 2 CF = CHF; 和（c）从（b）和/或（d）中形成的产物混合物中回收CF 3 CF = CH 2或其与CHF 2 CF = CHF的混合物，从而分离出在（b）中形成的产物混合物中的至少一部分CHF 2 CF = CHF， b）从（b）中形成的产品混合物中的CF 3CF≡CH2。

97. 发明申请

US20100294979A1 PROCESS FOR PRODUCING 1,2,3,3,3-PENTAFLUOROPROPENE AND RELATED AZEOTROPIC COMPOSITIONS 有权
标题翻译：生产1,2,3,3,3-二氟丙烯的方法及相关的AZEOTROPIC组合物
公开(公告)号：US20100294979A1
公开(公告)日：2010-11-25
申请号：US12377776
申请日：2007-09-05
申请人： Allen Capron Sievert
发明人： Allen Capron Sievert
IPC分类号： C09K5/00 , C07C17/25
CPC分类号： C07C17/23 , C07C17/25 , C07C21/18 , C09K5/045 , C09K2205/126 , C07C19/08
摘要： A process for making CHF═CFCF3 is disclosed. The process involves (a) reacting CCl2FCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH2FCF2CF3; and (b) dehydrofluorinating CH2FCF2CF3from (a) to form CHF═CFCF3.Also disclosed are compositions including CCl3CF2CF3 and HF, wherein the HF is present in an effective amount to form an azeotropic combination with the CCl3CF2CF3; and compositions including CCl2FCF2CF3 and HF, wherein the HF is present in an effective amount to form an azeotropic combination with the CCl2FCF2CF3.
摘要翻译：公开了制造CHF = CFCF3的方法。该方法包括（a）在催化有效量的氢化催化剂存在下使CCl 2 FCF 2 CF 3与H 2反应以形成CH 2 FCF 2 CF 3; 和（b）从（a）中将CH 2 CF 2 CF 3脱氟化氢以形成CHF = CFCF 3。还公开了包含CCl 3 CF 2 CF 3和HF的组合物，其中HF以有效量存在以与CCl 3 CF 2 CF 3形成共沸组合; 和包括CCl 2 FCF 2 CF 3和HF的组合物，其中HF以有效量存在以与CCl 2 FCF 2 CF 3形成共沸组合。

98. 发明申请

US20100197981A1 PROCESSES FOR PRODUCING 1,2,3,3,3-PENTAFLUOROPROPENE AND PRECURSORS THEREOF 有权
标题翻译：生产1,2,3,3,3-戊二烯及其前体的方法
公开(公告)号：US20100197981A1
公开(公告)日：2010-08-05
申请号：US12377761
申请日：2007-09-05
申请人： Allen Capron Sievert
发明人： Allen Capron Sievert
IPC分类号： C07C21/18 , C07C19/08 , C07C17/269
CPC分类号： C07C17/25 , C07C17/206 , C07C17/278 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for making CH2ClCF2CClF2. The process involves reacting CH2ClF with CClF═CF2 in an addition reaction zone in the presence of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3−x, provided that the average values of x and y are not both 0. Also disclosed is a process for making CH2FCF2CF3 that involves reacting the CH2ClCF2CClF2 with HF in a fluorination reaction zone in the presence of a fluorination catalyst. Also disclosed is a process for making CHF═CFCF3 that involves dehydrofluorinating the CH2FCF2CF3.
摘要翻译：公开了制备CH 2 ClCF 2 CClF 2的方法。该方法包括在加成反应区中，在具有主体配方为AlCl x BryF 3-xy的卤化铝组合物的存在下，使CH 2 ClF与CClF = CF 2反应，其中x的平均值为0-3，y的平均值为0-3 -x，条件是x和y的平均值不为0。还公开了一种制备CH2CFF2CF3的方法，其包括在氟化催化剂存在下在氟化反应区中使CH 2 ClCF 2 CClF 2与HF反应。还公开了制备CHF = CFCF 3的方法，其涉及使CH 2 CFF 2 CF 3脱氟化氢。

99. 发明申请

US20100168482A1 PROCESSES FOR THE PRODUCTION OF FLUOROPROPANES AND HALOPROPENES 有权
标题翻译：生产氟磷酸盐和恶唑烷的方法
公开(公告)号：US20100168482A1
公开(公告)日：2010-07-01
申请号：US12444462
申请日：2007-10-31
申请人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/25 , C07C17/07
CPC分类号： C07C17/21 , C07C17/10 , C07C17/206 , C07C17/25 , C07C19/08 , C07C21/18
摘要： A process is disclosed for making CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2. The process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CH2CH2X, halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3, CF3CF═CH2, and CF3CCl═CH2; and recovering the CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2 from the product mixture. Also disclosed is a process for making CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl. This process involves reacting at least one starting material selected from the group consisting of halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CH2CHF2, CF3CH═CHF and CF3CH═CHCl; and recovering the CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl from the product mixture. The molar ratio of HF to the total amount of starting materials fed to the reaction zone for both of these processes is at least stoichiometric, and the molar ratio of Cl2 to total amount of starting material fed to the reaction zone for both of these processes is 2:1 or less.
摘要翻译：公开了一种制备CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2的方法。该方法包括使选自式CX3CH2CH2X的卤代丙烷，式CX3CH = CH2的卤代丙烯和式CX2 = CHCH2X的卤代丙烯，其中每个X独立地为F或Cl的至少一种原料与HF和Cl 2反应在反应区中产生包含HF，HCl，CF 3 CF 2 CH 3，CF 3 CF = CH 2和CF 3 CCl = CH 2的产物混合物; 并从产物混合物中回收CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2。还公开了制备CF 3 CH 2 CHF 2，CF 3 CH = CHF和/或CF 3 CH = CHCl的方法。该方法包括使选自式CX3CH = CH2的卤代丙烯和式CX2 = CHCH2X的卤代丙烯，其中每个X独立地为F或Cl的至少一种起始材料与HF和Cl 2在反应区中反应以产生包含HF，HCl，CF 3 CH 2 CHF 2，CF 3 CH = CHF和CF 3 CH = CHCl的产物混合物; 并从产物混合物中回收CF 3 CH 2 CHF 2，CF 3 CH = CHF和/或CF 3 CH = CHCl。对于这两种方法，HF与进料到反应区的起始原料的总量的摩尔比至少为化学计量，并且对于这两种方法，进料到反应区的Cl 2与原料的总量的摩尔比为 2：1或更少。

100. 发明授权

US07728183B2 Selectively reacting olefins having a terminal CF2 group in a mixture 有权
标题翻译：选择性地使具有末端CF 2基团的烯烃在混合物中反应
公开(公告)号：US07728183B2
公开(公告)日：2010-06-01
申请号：US12278789
申请日：2007-04-03
申请人： Mario Joseph Nappa , Allen Capron Sievert , Victor Filippovich Cherstkov , Nina Ivanova Delyagina
发明人： Mario Joseph Nappa , Allen Capron Sievert , Victor Filippovich Cherstkov , Nina Ivanova Delyagina
IPC分类号： C07C17/38
CPC分类号： C07C17/395 , C07C303/24 , C07C305/06
摘要： A process is disclosed for reducing the mole ratio of (1) compounds of the formula Y1Y2C═CF2 wherein Y1 and Y2 are each independently H, F, Cl, Br, C1-C6 alkyl or C1-C6 haloalkyl containing no more than 3 chlorine substituents, 2 bromine substituents and 1 iodo substituent to (2) saturated compounds of the formula CdHeFfClgBrhIk wherein d is an integer from 1 to 10, and e+f+g+h+k is equal to 2d+2, provided that g is 0, 1, 2 or 3, h is 0, 1 or 2 and k is 0 or 1 and/or unsaturated compounds of the formula Y3Y4C═CY5Y6, wherein Y3, Y5 and Y6 are each independently H, F, Cl, Br, C1-C6 alkyl or C1-C6 haloalkyl containing no more than 3 chlorine substituents, 2 bromine substituents and 1 iodo substituent, provided that Y5 and Y6 are not both F, and Y4 is C1-C6 alkyl or C1-C6 haloalkyl containing no more than 3 chlorine substituents, 2 bromine substituents and 1 iodo substituent, in a mixture. The process involves contacting the mixture with at least one selective removal agent selected from the group consisting of SO3 and RSO3H, wherein R is selected from the group consisting of F, Cl, OH, C1-C8 alkyl, C1-C8 fluoroalkyl, and C1-C8 fluoroalkoxyalkyl containing no more than two ether oxygens to selectively react the formula Y1Y2C═CF2 compounds.
摘要翻译：公开了一种降低（1）式Y1Y2C≡CF2化合物的摩尔比的方法，其中Y1和Y2各自独立地为H，F，Cl，Br，C1-C6烷基或含有不超过3个氯的C 1 -C 6卤代烷基取代基，2个溴取代基和1个碘取代基与（2）式CdHeFfClgBrhIk的饱和化合物反应，其中d为1至10的整数，e + f + g + h + k等于2d + 2，条件是g为 0,1,2或3，h为0,1或2，k为0或1，和/或式Y3Y4C≡CY5Y6的不饱和化合物，其中Y3，Y5和Y6各自独立地为H，F，Cl，Br，含有不超过3个氯取代基的C1-C6烷基或C1-C6卤代烷基，2个溴取代基和1个碘取代基，条件是Y5和Y6不同时为F，Y4为C1-C6烷基或不含任何更多的C 1 -C 6卤代烷基 3个氯取代基，2个溴取代基和1个碘取代基。该方法包括使混合物与至少一种选自SO 3和RSO 3 H的选择性去除剂接触，其中R选自F，Cl，OH，C 1 -C 8烷基，C 1 -C 8氟烷基和C 1 含有不多于两个醚氧的-C8氟烷氧基烷基，以选择性地使式Y1Y2C≡CF2化合物反应。

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