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91. 发明申请

US20050215800A1 Method for producing gamma-butyrolactone 审中-公开
标题翻译： γ-丁内酯的制造方法
公开(公告)号：US20050215800A1
公开(公告)日：2005-09-29
申请号：US10513040
申请日：2003-04-25
申请人： Rolf Pinkos , Rolf-Hatmuth Fischer , Markus Rosch , Nils Bottke , Stephan Schlitter , Michael Hesse , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Rolf Pinkos , Rolf-Hatmuth Fischer , Markus Rosch , Nils Bottke , Stephan Schlitter , Michael Hesse , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： C07D307/33 , B01J21/08 , B01J23/72 , C07B61/00 , C07D307/20 , C07D307/26
CPC分类号： C07D307/20 , B01J21/08 , B01J23/72
摘要： The present invention relates to a process for preparing unsubstituted or C1-C4-alkyl-substituted gamma-butyrolactone by catalytic hydrogenation of maleic acid and/or its derivatives in the presence of chromium-free catalyst comprising from 10 to 80% by weight of copper oxide and from 10 to 90% by weight of at least one catalyst support selected from the group consisting of silicon dioxide, titanium dioxide, hafnium dioxide, magnesium silicate, activated carbon, silicon carbide, zirconium dioxide and alpha-aluminum oxide.
摘要翻译：本发明涉及通过马来酸和/或其衍生物的催化氢化制备未取代的或C 1 -C 4 - 烷基取代的γ-丁内酯的方法存在包含10至80重量％的氧化铜和10至90重量％的至少一种催化剂载体的无铬催化剂，所述催化剂载体选自二氧化硅，二氧化钛，二氧化铪，硅酸镁，活化的碳，碳化硅，二氧化锆和α-氧化铝。

92. 发明授权

US06583281B2 Stabilized N-alkenyllactam 失效
公开(公告)号：US06583281B2
公开(公告)日：2003-06-24
申请号：US09851346
申请日：2001-05-09
申请人： Arnd Böttcher , Rolf Pinkos , Rudolf Erich Lorenz , Hansjörg Nickel , Jihong He
发明人： Arnd Böttcher , Rolf Pinkos , Rudolf Erich Lorenz , Hansjörg Nickel , Jihong He
IPC分类号： C07D22310
CPC分类号： C07D279/20 , C07D201/18
摘要： The invention provides an N-alkenyllactam having at least a 6-membered lactam ring, stabilized by phenothiazine and/or derivatives thereof, and a process for the stabilization of N-alkenyllactams.

93. 发明授权

US06521763B1 Method for producing gamma-butyrolactone 有权
标题翻译： γ-丁内酯的制造方法
公开(公告)号：US06521763B1
公开(公告)日：2003-02-18
申请号：US10069771
申请日：2002-02-28
申请人： Rolf Fischer , Rolf Pinkos
发明人： Rolf Fischer , Rolf Pinkos
IPC分类号： C07D30733
CPC分类号： C07D307/33
摘要： In a process for preparing GBL by reaction of 1,4 butanediol over a copper catalyst, use is made of a 1,4 butanediol-containing reaction mixture which comprises further alcohols other than 1,4-butanediol and water.
摘要翻译：在通过1,4-丁二醇与铜催化剂反应制备GBL的方法中，使用含有1,4-丁二醇的反应混合物，其还包含除1,4-丁二醇和水以外的其它醇。

94. 发明授权

US06433229B1 Method of producing cyclic, &agr;, &bgr;-unsaturated ketones 失效
标题翻译：制备环状α，β-不饱和酮的方法
公开(公告)号：US06433229B1
公开(公告)日：2002-08-13
申请号：US09914796
申请日：2001-09-05
申请人： Rolf Fischer , Rolf Pinkos
发明人： Rolf Fischer , Rolf Pinkos
IPC分类号： C07C4500
CPC分类号： C07C45/65 , B01J23/00 , B01J23/06 , B01J23/40 , B01J23/72 , B01J23/888 , B01J35/10 , Y02P20/582 , C07C49/597 , C07C49/603
摘要： Preparation of cyclic, &agr;,&bgr;-unsaturated ketones of formula II by dehydrogenation of cyclic ketones which conform to formula I in which n denotes an integer from 1 to 10, and which may be substituted, at elevated temperature in the presence of catalysts in the vapor phase, wherein the reaction is carried out in the absence of oxygen or in the presence of less than 0.5 mol of oxygen per mol of compound I at temperatures ranging from 250° to 600° C. and using catalysts having a surface area (BET) of more than 0.5 m2/g.
摘要翻译：通过使符合式Iin的环酮脱氢制备式II的环状α，β-不饱和酮，其中n表示1至10的整数，并且可以在升高的温度下在蒸气中的催化剂存在下被取代相，其中反应在250℃至600℃的温度范围内，在不存在氧气的情况下或在每摩尔化合物I小于0.5摩尔的氧气存在下进行，并使用具有表面积（BET）超过0.5 m2 / g。

95. 发明授权

US06433192B1 Method for producing mixtures of 1,4-butanediol, tetrahydrofuran and &ggr;-butyrolactone 失效
标题翻译：生产1,4-丁二醇，四氢呋喃和γ-丁内酯的混合物的方法
公开(公告)号：US06433192B1
公开(公告)日：2002-08-13
申请号：US09673847
申请日：2001-06-04
申请人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
发明人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
IPC分类号： C07D30702
CPC分类号： C07D315/00 , C07C29/149 , C07D307/08 , C07C31/207
摘要： In a process for preparing 1,4-butanediol, tetrahydrofuran and &ggr;-butyrolactone by oxidation of butane to give a product stream comprising maleic anhydride, absorption of maleic anhydride from the product stream using a high-boiling alcohol to give a liquid absorption product comprising monoesters and diesters of maleic acid and also high-boiling alcohol, after-esterification of the liquid absorption product and subsequent hydrogenation of the after-esterified product in the liquid phase, the high-boiling alcohol is a polyhydric alcohol having a boiling point at atmospheric pressure of above 233° C. and the after-esterified product has an acid number of less than 30 mg KOH/g and a water content of less than 1% by weight.
摘要翻译：在通过丁烷氧化制备1,4-丁二醇，四氢呋喃和γ-丁内酯以产生包含马来酸酐的产物流的方法中，使用高沸点醇从产物流中吸收马来酸酐，得到液体吸收产物，其包含马来酸的单酯和二酯以及高沸点醇，液体吸收产物的酯化和后期酯化产物在液相中的氢化后，高沸点醇是沸点在大气压下的多元醇高于233℃的压力，后酯化产物的酸值小于30mg KOH / g，水含量小于1重量％。

96. 发明授权

US06350924B1 Method for producing 1,4-butanediol 有权
标题翻译：生产1,4-丁二醇的方法
公开(公告)号：US06350924B1
公开(公告)日：2002-02-26
申请号：US09673134
申请日：2000-10-11
申请人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
发明人： Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
IPC分类号： C07C2700
CPC分类号： C07D315/00 , C07C29/177 , C07D307/08 , C07C31/207
摘要： A process for preparing 1,4-butanediol and, if desired, &ggr;-butyrolactone and THF by oxidizing butane or benzene to form a product stream including maleic anhydride, absorbing maleic anhydride from the product stream with a high-boiling inert solvent in an absorption stage to give a liquid absorption product, esterifying the liquid absorption product with a C1-C5 esterifying alcohol in an esterification stage to form an esterification product comprising the corresponding diester and high-boiling inert solvent, then hydrogenating the esterification product to give a hydrogenation product which comprises the products of value, 1,4-butanediol and, if desired, &ggr;-butyrolactone and tetrahydrofuran and the esterifying alcohol and which is separated by distillation into the products of value and the esterifying alcohol, and recycling the esterifying alcohol to the esterification zone, which comprises separating the esterification product into the diester and the inert solvent by distillation under reduced pressure prior to the hydrogenation, recycling the inert solvent to the absorption stage, and hydrogenating the diester in the liquid phase over a fixed-bed catalyst.
摘要翻译：通过氧化丁烷或苯来制备1,4-丁二醇和（如果需要的话）γ-丁内酯和THF以形成包含马来酸酐的产物流的方法，在吸收中用高沸点惰性溶剂从产物流中吸收马来酸酐阶段以得到液体吸收产物，在酯化阶段用C1-C5酯化醇酯化液体吸收产物以形成包含相应的二酯和高沸点惰性溶剂的酯化产物，然后氢化酯化产物得到氢化产物其包括价值的产物，1,4-丁二醇，如果需要的话，γ-丁内酯和四氢呋喃和酯化醇，并通过蒸馏分离成产物和酯化醇，并将酯化醇再循环到酯化反应其包括通过蒸馏分离酯化产物成二酯和惰性溶剂在氢化之前在减压下进行反应，将惰性溶剂循环到吸收阶段，并在固定床催化剂中使液相中的二酯氢化。

97. 发明授权

US09186599B2 Process for isolating tetrahydrofuran 有权
标题翻译：四氢呋喃分离方法
公开(公告)号：US09186599B2
公开(公告)日：2015-11-17
申请号：US13235427
申请日：2011-09-18
申请人： Maria Guixa Guardia , Rolf Pinkos , Nadja Pollmer , Wolf-Steffen Weissker , Hugues Vandenmersch
发明人： Maria Guixa Guardia , Rolf Pinkos , Nadja Pollmer , Wolf-Steffen Weissker , Hugues Vandenmersch
IPC分类号： C07D307/00 , B01D3/14 , B01D3/36 , C07D307/36
CPC分类号： B01D3/143 , B01D3/36 , C07D307/36
摘要： A process which isolates tetrahydrofuran from a stream of tetrahydrofuran, alkanol and high boilers, by: (a) separating off a first stream of tetrahydrofuran and alkanol as azeotrope in a first distillation stage; (b) feeding part of the first stream into a reactor for esterifying maleic anhydride, giving a second stream of tetrahydrofuran and monoalkyl maleate; (c) separating the second stream into a third stream of monoalkyl maleate and a fourth stream of tetrahydrofuran in a second distillation stage; (d) feeding the fourth stream of tetrahydrofuran from the second distillation stage and the part of the first stream from (a) which is not fed to the reactor into a third distillation stage to obtain a product stream of tetrahydrofuran and a sixth stream of tetrahydrofuran and alkanol; (e) recirculating the sixth stream from the third distillation stage into the first distillation stage or the reactor in (b).
摘要翻译：通过以下步骤分离四氢呋喃与四氢呋喃，烷醇和高沸点物流的方法：（a）在第一蒸馏阶段中分离第一流的四氢呋喃和链烷醇作为共沸物; （b）将第一流的一部分进料到用于酯化马来酸酐的反应器中，得到第二股四氢呋喃和马来酸单烷基酯; （c）在第二蒸馏阶段将第二物流分离成马来酸单烷基酯和第四四氢呋喃流; （d）将来自第二蒸馏阶段的第四个四氢呋喃流和来自（a）的未进料到反应器中的第一个物流部分进入第三个蒸馏阶段以获得四氢呋喃的产物流和第六个四氢呋喃流和链烷醇; （e）将第六流从第三蒸馏段再循环到第一蒸馏阶段或（b）中的反应器中。

98. 发明授权

US08759594B2 Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters 有权
标题翻译：低聚和聚酯氢化生产1,6-己二醇的方法
公开(公告)号：US08759594B2
公开(公告)日：2014-06-24
申请号：US13258207
申请日：2010-03-29
申请人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
发明人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
IPC分类号： C07C27/00
CPC分类号： C07C45/33 , C07C29/149 , C07C29/50 , C07C51/313 , C07C67/08 , C07C2601/14 , C07C31/20 , C07C35/08 , C07C49/403 , C07C55/14 , C07C69/44
摘要： The present invention relates to a process for hydrogenating oligo- and/or polyesters obtainable by esterifying a DCS with a diol or diol mixture, said hydrogenation being performed in the presence of a catalyst whose catalyst precursor comprises copper oxide, aluminum oxide and at least one oxide of lanthanum, of iron, of tungsten, of molybdenum, of titanium or of zirconium, and to a process for preparing 1,6-hexanediol by catalytically hydrogenating ester mixtures which comprise, as main components, oligo- and polyesters of adipic acid and 6-hydroxycaproic acid, and are obtained by esterifying DCS with diols, especially 1,6-hexanediol or diol mixtures.
摘要翻译：本发明涉及一种氢化通过用二醇或二醇混合物酯化DCS得到的低聚物和/或聚酯的方法，所述氢化在其催化剂前体包含氧化铜，氧化铝和至少一种镧，铁，钨，钼，钛或锆的氧化物，以及通过催化氢化酯混合物制备1,6-己二醇的方法，所述酯混合物作为主要组分包含己二酸的低聚和聚酯和 6-羟基己酸，并且通过用二醇，特别是1,6-己二醇或二醇混合物酯化DCS获得。

99. 发明授权

US08471042B2 Method for producing 1,6-hexanediol and caprolactone 有权
标题翻译： 1,6-己二醇和己内酯的制备方法
公开(公告)号：US08471042B2
公开(公告)日：2013-06-25
申请号：US13258166
申请日：2010-03-31
申请人： Rolf Pinkos , Daniel Breuninger , Gerd-Dieter Tebben
发明人： Rolf Pinkos , Daniel Breuninger , Gerd-Dieter Tebben
IPC分类号： C07D313/00 , C07C27/04
CPC分类号： C07C29/145 , C07C29/149 , C07C29/80 , C07C51/313 , C07C67/08 , C07D307/33 , C07D313/04 , C07C35/14 , C07C31/125 , C07C59/185 , C07C59/01 , C07C55/14 , C07C69/02
摘要： The invention relates to a process for preparing 1,6-hexanediol and caprolactone, preferably with at least 99.5% purity, which are especially virtually free of 1,4-cyclohexanediols, from a carboxylic acid mixture which is obtained as a by-product of the catalytic oxidation of cyclohexane to cyclohexanone/cyclohexanol with oxygen or oxygen-comprising gases and by water extraction of the reaction mixture, by hydrogenating the carboxylic acid mixture, esterifying and hydrogenating a substream to hexanediol and cyclizing 6-hydroxycaproic ester, the 1,4-cyclohexanediols being removed either in the course of fractionation of the esterification mixture or last from the caprolactone.
摘要翻译：本发明涉及一种制备1,6-己二醇和己内酯的方法，该方法优选具有至少99.5％的纯度，特别是基本上不含1,4-环己烷二醇的羧酸混合物，其作为副产物通过氢化羧酸混合物，将子流酯化和氢化成己二醇并使6-羟基己酸酯环化，使1,4-环己酮与环氧丙烷/环氧丙烷的催化氧化反应，在酯化混合物分馏或最后由己内酯过程中除去环己烷二醇。

100. 发明授权

US08168807B2 Process for one-stage preparation of 2-methyltetrahydrofuran from furfural over two catalysts in a structured bed 有权
标题翻译：在结构化床中通过两种催化剂从糠醛一步制备2-甲基四氢呋喃的方法
公开(公告)号：US08168807B2
公开(公告)日：2012-05-01
申请号：US12442877
申请日：2008-06-24
申请人： Tobias Wabnitz , Daniel Breuninger , Jens Heimann , Rene Backes , Rolf Pinkos
发明人： Tobias Wabnitz , Daniel Breuninger , Jens Heimann , Rene Backes , Rolf Pinkos
IPC分类号： C07D307/89
CPC分类号： C07D307/06
摘要： The present invention provides a process for preparing 2-methyltetrahydrofuran by one-stage hydrogenation of furfural with a hydrogen-comprising gas in the presence of a structured bed of at least one copper catalyst and at least one catalyst which comprises at least one noble metal from groups 8, 9 and/or 10 of the periodic table of the elements applied on a support material.
摘要翻译：本发明提供了一种通过在含有至少一种铜催化剂的结构化床和至少一种包含至少一种贵金属的催化剂的存在下，用含氢气体糠醛进行一步氢化制备2-甲基四氢呋喃的方法，施加在支撑材料上的元素周期表的组8,9和/或10。

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