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91. 发明授权

US07008914B2 Alkylbenzene detergents with high 2-isomer content 有权
公开(公告)号：US07008914B2
公开(公告)日：2006-03-07
申请号：US10263547
申请日：2002-10-03
申请人： George A. Smith , Prakasa R. Anantaneni , Samir S. Ashrawi , Raeda M. Smadi , John F. Knifton , Melvin Stockton
发明人： George A. Smith , Prakasa R. Anantaneni , Samir S. Ashrawi , Raeda M. Smadi , John F. Knifton , Melvin Stockton
IPC分类号： C11D17/00
CPC分类号： C11D17/0073 , C11D1/22
摘要： This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.

92. 发明授权

US06315964B1 Process and system for alkylation of aromatic compounds 失效
标题翻译：芳香族化合物的烷基化方法和系统
公开(公告)号：US06315964B1
公开(公告)日：2001-11-13
申请号：US08879745
申请日：1997-06-20
申请人： John F. Knifton , Prakasa Rao Anantaneni , Melvin Stockton
发明人： John F. Knifton , Prakasa Rao Anantaneni , Melvin Stockton
IPC分类号： B01J802
CPC分类号： B01J37/26 , B01D3/322 , B01J29/18 , B01J2229/16 , C07C2/66 , C07C2521/16 , C07C2529/18 , C07C2529/70 , Y02P20/127 , C07C15/107
摘要： This invention is directed to a reactive distillation process and system for the alkylation of liquid aromatic compounds with a liquid olefin or olefin/paraffin mixture. The aromatic compound may have from about 6 to about 30 carbons and the olefin may have from about 8 to 30 carbons. The system has a reactor configuration utilizing an alkylation catalyst, a reboiler with product takeoff, and a feed inlet above the catalyst bed. The system may also include a means for in-situ mixing of the aromatic compound and olefin or olefin/paraffin mixture, an overhead condenser and/or a water takeoff.
摘要翻译：本发明涉及用液体烯烃或烯烃/石蜡混合物烷基化液体芳族化合物的反应蒸馏方法和系统。芳族化合物可以具有约6至约30个碳，并且烯烃可以具有约8至30个碳。该系统具有利用烷基化催化剂的反应器构型，具有产物起飞的再沸器和在催化剂床上方的进料入口。该系统还可以包括用于原位混合芳族化合物和烯烃或烯烃/石蜡混合物，塔顶冷凝器和/或水分起飞的装置。

93. 发明授权

US5777187A Two-step process for alkylation of benzene to form linear alkylbenzenes 失效
标题翻译：用于烷基化苯形成直链烷基苯的两步法
公开(公告)号：US5777187A
公开(公告)日：1998-07-07
申请号：US662786
申请日：1996-06-12
申请人： John F. Knifton , Prakasa Rao Anantaneni
发明人： John F. Knifton , Prakasa Rao Anantaneni
IPC分类号： B01J21/16 , B01D3/32 , B01J29/18 , B01J37/00 , B01J37/26 , C01B39/02 , C07B61/00 , C07C2/66 , C07C2/68 , C07C2/72 , C07C15/02 , C07C15/107 , C07C2/64
CPC分类号： B01J29/18 , B01D3/322 , B01J37/26 , C01B39/026 , C07C2/66 , B01J2229/16 , C07C2521/16 , C07C2529/16 , C07C2529/18 , Y02P20/127 , Y02P20/52
摘要： This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of linear alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. Yield and bromine index of the LAB may be improved by further alkylation using a fluorine containing clay catalyst such as montmorillonite clay.
摘要翻译：本发明涉及一种含氟丝光沸石催化剂及其通过苯与烯烃烷基化制备直链烷基苯（LAB）的用途。烯烃可以具有约10至14个碳。通常通过用氟化氢水溶液处理来制备含氟丝光沸石。苯烷基化可以使用反应蒸馏进行。通过使用含氟粘土催化剂如蒙脱石粘土进一步烷基化可以提高LAB的产率和溴指数。

94. 发明授权

US5550300A Gradient catalyst system for the integrated production of isopropyl alcohol and diisopropyl ethers 失效
标题翻译：梯度催化剂体系，用于综合生产异丙醇和二异丙醚
公开(公告)号：US5550300A
公开(公告)日：1996-08-27
申请号：US338725
申请日：1994-12-30
申请人： Robert J. Taylor, Jr. , Pei-Shing E. Dai , John F. Knifton
发明人： Robert J. Taylor, Jr. , Pei-Shing E. Dai , John F. Knifton
IPC分类号： C07B61/00 , C07C29/149 , C07C41/01 , C07C41/09 , C07C43/04 , C07C43/06
CPC分类号： C07C41/01 , C07C29/149 , C07C41/09 , Y02P20/125
摘要： Disclosed is an integrated process for the generation of a mixture of ethers, such as diisopropyl ether, methyl tertiary butyl ether, and/or isopropyl tertiary butyl ether, from a crude by-product acetone stream composed of acetone, tertiary butyl alcohol and methanol by passing such a stream, in the presence of hydrogen, over a catalyst system characterized by having both a hydrogenation activity gradient along the reactor in one direction and an etherification activity gradient in the opposite direction.
摘要翻译：公开了从由丙酮，叔丁醇和甲醇组成的粗副产物丙酮流中由醚，如二异丙基醚，甲基叔丁基醚和/或异丙基叔丁基醚的混合物的混合物的综合方法，在氢的存在下使这种流在催化剂体系上，其特征在于沿一个方向具有反应器的氢化活性梯度和相反方向的醚化活性梯度。

95. 发明授权

US5488178A Ditertiary butyl peroxide preparation from tertiary butyl hydroperoxide 失效
标题翻译：二叔丁基过氧化物由叔丁基过氧化氢制备
公开(公告)号：US5488178A
公开(公告)日：1996-01-30
申请号：US401107
申请日：1995-03-08
申请人： John F. Knifton , Edward T. Marquis , Pei-Shing E. Dai
发明人： John F. Knifton , Edward T. Marquis , Pei-Shing E. Dai
IPC分类号： C07C409/16
CPC分类号： C07C409/16 , C07C407/00
摘要： Disclosed is a method of selective preparation of ditertiary butyl peroxide from tertiary butyl hydroperoxide and t-butanol which comprises reacting said tertiary butyl hydroperoxide and t-butanol over a solid acid catalyst selected from:a) an acidic montmorillonite clay;b) an acidic zeolite selected from the group consisting of dealuminized Y-zeolite and pentasil zeolite;c) an acidic organic resin; andd) heteropoly acids supported on an oxide selected from Group III or Group IV.
摘要翻译：公开了从叔丁基过氧化氢和叔丁醇中选择性制备二叔丁基过氧化物的方法，其包括使所述叔丁基过氧化氢和叔丁醇在选自以下的固体酸催化剂中反应：a）酸性蒙脱土粘土; b）选自脱铝Y沸石和pentasil沸石的酸性沸石; c）酸性有机树脂; 和d）负载在选自III或IV族的氧化物上的杂多酸。

96. 发明授权

US5457243A Neutralization of crude MTBE effluent streams using solid bases 失效
标题翻译：使用固体碱中和粗制MTBE流出物流
公开(公告)号：US5457243A
公开(公告)日：1995-10-10
申请号：US172345
申请日：1993-12-23
申请人： John F. Knifton , Mark A. Mueller , Michael W. Peters
发明人： John F. Knifton , Mark A. Mueller , Michael W. Peters
IPC分类号： C07C41/36 , C07C29/88 , C07C31/12 , C07C41/44 , C07C43/04 , C07C41/00
CPC分类号： C07C41/44 , C07C29/88 , C07C31/12
摘要： Disclosed is a method for removing organic acids and derivatives thereof from a crude methyl tertiary butyl ether (MTBE) stream of the type found in the feed to, or effluent from, a reactor for a one-step process for producing MTBE which comprises:contacting said crude MTBE stream in a treating zone over one or more beds of a solid base for a period of time sufficient to neutralize said organic acids and derivatives thereof; andwithdrawing a substantially organic acid-free crude MTBE product from said treating zone.
摘要翻译：公开了一种从用于生产MTBE的一步方法的反应器的反应器或从流出物中的流出物类型的粗甲基叔丁基醚（MTBE）流中除去有机酸及其衍生物的方法，其包括：接触所述粗制MTBE流在处理区中超过一个或多个固体碱床，时间足以中和所述有机酸及其衍生物; 以及从所述处理区取出基本上无机酸的粗MTBE产物。

97. 发明授权

US5313006A Cogeneration of isobutylene plus MTBE from crude t-butanol/methanol feedstocks 失效
标题翻译：来自粗品叔丁醇/甲醇原料的异丁烯加MTBE的热电联产
公开(公告)号：US5313006A
公开(公告)日：1994-05-17
申请号：US994015
申请日：1992-12-21
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07B61/00 , C07C1/24 , C07C41/09 , C07C43/04
CPC分类号： C07C41/09 , C07C1/24 , C07C2529/08
摘要： Disclosed is an improvement in a method for cogeneration of isobutylene and MTBE by etherification of tBA/MeOH over an ion-exchange resin which allows for more complete conversion of the remaining tBA fraction and comprises a second step consisting essentially of recovering the MTBE from the primary fractionator as an overhead fraction and etherifying the bottoms from the primary fractionator over an inorganic acid catalyst comprising a crystalline aluminosilicate faujasite-type Y-zeolite modified with a compound selected from a fluoride-containing compound including hydrofluoric acid, ammonium fluoride, fluorosulfonic acids and their cogeners and triflic anhydride at a temperature of greater than 120.degree. C.
摘要翻译：公开了通过tBA / MeOH通过离子交换树脂的醚化来进行异丁烯和MTBE的热电联产方法的改进，其允许剩余的tBA馏分更完全的转化，并且包括基本上由主要从回收的MTBE 分馏器作为塔顶馏分，并将来自主分馏器的塔底馏分在无机酸催化剂上进行醚化，所述无机酸催化剂包含用选自包含氢氟酸，氟化铵，氟代磺酸的含氟化合物及其它化合物的化合物改性的结晶硅铝酸盐八面沸石型Y-沸石共聚物和三氟甲磺酸酐在大于120℃的温度下

98. 发明授权

US5304681A Tert-butylamine synthesis over montmorillonite clays 失效
标题翻译：蒙脱石粘土上的叔丁胺合成
公开(公告)号：US5304681A
公开(公告)日：1994-04-19
申请号：US894841
申请日：1991-11-22
申请人： John F. Knifton , Neal J. Grice
发明人： John F. Knifton , Neal J. Grice
IPC分类号： B01J27/16 , B01J27/18 , B01J29/06 , C07B61/00 , C07C209/60 , C07C211/06
CPC分类号： C07C209/60
摘要： Disclosed is a method for preparation of alkylamines which comprises reacting ammonia and a monounsaturated olefin in the presence of a catalyst selected from the group consisting of:a. Acid modified montmorillonite clays;b. Heterogeneous catalysts comprising a fluorine-containing compound on an inert support; andc. Heteropoly acids on an inert support.
摘要翻译：公开了一种制备烷基胺的方法，其包括在选自以下的催化剂存在下使氨和单不饱和烯烃反应：a。酸改性蒙脱石粘土; b。在惰性载体上含有含氟化合物的非均相催化剂; 和c。惰性支持物上的杂多酸。

99. 发明授权

US5242621A Combinations of alkanoic hydrocarbyl dicarboxylic and carbocyclic alkanoic acids or salts useful as heat transfer fluid corrosion inhibitors 失效
标题翻译：链烷烃二羧酸和碳环链烷酸或可用作传热流体腐蚀抑制剂的盐的组合
公开(公告)号：US5242621A
公开(公告)日：1993-09-07
申请号：US892875
申请日：1992-06-03
申请人： David L. Miller , Brian L. Benac , John F. Knifton
发明人： David L. Miller , Brian L. Benac , John F. Knifton
IPC分类号： C09K5/08 , C09K5/20 , C09K15/06 , C23F11/12
CPC分类号： C23F11/126 , C09K5/20 , C23F11/10
摘要： Corrosion inhibitors containing alkanoic, hydrocarbyl dicarboxylic and carbocyclic-substituted, alkanoic acids or salts give high performance, heat transfer fluids and antifreezes, with improved properties including storage stability.

100. 发明授权

US5214217A Method for one-step synthesis of methyl t-butyl ether 失效
标题翻译：一步合成甲基叔丁基醚的方法
公开(公告)号：US5214217A
公开(公告)日：1993-05-25
申请号：US917218
申请日：1992-07-22
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C41/09
CPC分类号： C07C41/09
摘要： A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in the presence of a catalyst to provide methyl-tert-butyl ether and the improvement of accomplishing the reaction in one-step which comprises:a. using a catalyst selected from the group consisting of acidic aluminas, and crystalline aluminosilicate faujasite-type zeolites, particularly dealuminized Y-type zeolites;b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl-tert-butyl product.
摘要翻译：公开了一种方法，其中在催化剂存在下，使叔丁醇与甲醇在反应区中反应，得到甲基叔丁基醚，并改进一步完成反应，该方法包括：a。使用选自酸性氧化铝和结晶硅铝酸盐八面沸石型沸石，特别是脱铝Y型沸石的催化剂; b。在约20℃至约250℃的温度和大约大气压的压力下，使所述叔丁醇和甲醇以摩尔量的约0.1至10摩尔甲醇/摩尔叔丁醇与所述催化剂连续接触至约1000psig，得到甲基 - 叔丁基产物。

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