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91. 发明授权

US6030421A Ultra thin solid state lithium batteries and process of preparing same 失效
标题翻译：超薄固态锂电池及其制备方法
公开(公告)号：US6030421A
公开(公告)日：2000-02-29
申请号：US64821
申请日：1998-04-23
申请人： Michel Gauthier , Ginette Lessard , Guy Vassort , Patrick Bouchard , Alain Vallee , Michel Perrier
发明人： Michel Gauthier , Ginette Lessard , Guy Vassort , Patrick Bouchard , Alain Vallee , Michel Perrier
IPC分类号： H01M4/64 , H01M4/04 , H01M6/18 , H01M6/40 , H01M10/04 , H01M10/40 , H01M6/16 , H01M6/00
CPC分类号： H01M10/052 , H01M10/0436 , H01M10/0565 , H01M4/04 , H01M6/188 , H01M6/40 , Y10T29/49108 , Y10T29/49112
摘要： There is provided a mother-battery containing at least the following films: an anode of metallic lithium or sodium, a polymer electrolyte which is conductive towards the alkaline ions of the anode and also acts as a separator between the electrodes, and a composite cathode consisting of a compound which is reducible to lithium or sodium, an additive of electronic conduction and a polymer electrolyte binder. The mother battery also includes an electronically conductive thin coating on the external face of the anode and, possibly of the cathode, in which the conductive material is chemically inert towards the electrode material and which also serves to establish permanent electrical contacts on the external faces. The laminated mother-battery of larger surface area and at least partially charged is thereafter subjected to a sharp mechanical cutting out to give thin polymer electrolyte batteries with lithium or sodium anode. The thus cut out batteries preserve substantially their voltage after mechanical cutting out which is recovered by a mechanism of self-healing.
摘要翻译：提供了至少包含以下膜的母体电池：金属锂或钠的阳极，朝向阳极的碱性离子导电并且还用作电极之间的隔板的聚合物电解质，以及包含的可还原成锂或钠的化合物，电子传导添加剂和聚合物电解质粘合剂。母电池还包括在阳极的外表面上以及可能的阴极的电子导电薄涂层，其中导电材料对于电极材料具有化学惰性，并且还用于在外表面上建立永久性电接触。然后将具有较大表面积并且至少部分带电的叠层母电池进行锋利的机械切割以得到具有锂或钠阳极的薄聚合物电解质电池。这样切出的电池在机械切割之后基本保持其电压，其通过自愈机制回收。

92. 发明授权

US06019801A Additives for lubricating agents used in the lamination of lithium sheets into thin films 失效
标题翻译：用于将锂片层压成薄膜的润滑剂用添加剂
公开(公告)号：US06019801A
公开(公告)日：2000-02-01
申请号：US979230
申请日：1997-11-26
申请人： Michel Gauthier , Patrick Bouchard , Paul-Emile Guerin , Michel Armand
发明人： Michel Gauthier , Patrick Bouchard , Paul-Emile Guerin , Michel Armand
IPC分类号： B21B1/40 , B21B3/00 , B21B45/02 , C10M145/38 , H01M4/04 , H01M4/134 , H01M4/1395 , H01M10/052 , H01M10/0565 , H01M10/36 , H01M10/40 , H01M0/029
CPC分类号： H01M4/0404 , B21B3/00 , B21B45/0242 , C10M145/38 , H01M10/052 , H01M10/0565 , H01M4/04 , H01M4/0402 , H01M4/0411 , H01M4/0416 , H01M4/0435 , H01M4/134 , H01M4/1395 , B21B1/40 , B21B45/0251 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2203/045 , C10M2203/06 , C10M2203/065 , C10M2209/084 , C10M2209/104 , C10M2209/105 , C10M2209/108 , C10M2209/109 , C10M2215/04 , C10M2215/042 , C10M2215/26 , C10M2217/046 , C10M2217/06 , C10N2220/02 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , Y10T29/49108 , Y10T29/49112
摘要： These additives are represented by the following general formula:L--Y--Sin which L designates a hydrocarbon radical which serves as lubricating segment; S designates an oligomer segment which serves as solvating segment of metallic salts and Y designates a chemical bond which joins the hydrocarbon radical and the oligomer segment. With these additives there is no more need to subsequently wash the surface of laminated lithium.
摘要翻译：这些添加剂由以下通式表示：L-Y-Sin，其中L表示作为润滑链段的烃基; S表示用作溶剂化金属盐部分的低聚物部分，Y表示连接烃基和低聚物部分的化学键。使用这些添加剂不再需要随后洗涤层压锂的表面。

93. 发明授权

US5916475A Ionic conducting material having good anticorrosive properties 失效
标题翻译：离子导电材料具有良好的防腐蚀性能
公开(公告)号：US5916475A
公开(公告)日：1999-06-29
申请号：US537944
申请日：1995-11-21
申请人： Christophe Michot , Michel Armand , Jean-Yves Sanchez , Yves Choquette , Michel Gauthier
发明人： Christophe Michot , Michel Armand , Jean-Yves Sanchez , Yves Choquette , Michel Gauthier
IPC分类号： C01B21/093 , C07C307/00 , C07C311/48 , C07C317/04 , C07C317/24 , C07F9/36 , C07F9/53 , H01B1/12 , H01B1/20 , H01G9/02 , H01G9/025 , H01G11/02 , H01G11/20 , H01G11/54 , H01G11/56 , H01G11/60 , H01G11/62 , H01M4/66 , H01M6/16 , H01M6/18 , H01M10/05 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/36 , C08L7/02
CPC分类号： H01G9/038 , C01B21/0935 , C07C307/00 , H01B1/122 , H01G11/20 , H01G11/56 , H01M10/052 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M6/181 , H01M10/0525 , Y02E60/13
摘要： An ionically conductive material which contains at least one ionic compound in solution in an aprotic solvent, wherein the ionic compound is selected from the group consisting of compounds of the formulae (1/mM).sup.61 ((ZY)2N).sup..crclbar., (1/mM).sup..sym. ((ZY).sub.3 C).sup..crclbar., or (1/mM).sup..sym. ((ZY).sub.2 CQ).sup..crclbar., wherein M, Z, Y and Q are as defined herein.
摘要翻译： PCT No.PCT / FR95 / 00343 Sec。 371日期：1995年11月21日 102（e）1995年11月21日日期PCT 1995年3月21日PCT PCT。公开号WO95 / 26056 日期1995年9月28日在非质子溶剂中含有溶液中的至少一种离子化合物的离子导电材料，其中离子化合物选自式（1 / mM）61（（ZY）2 N）化合物，（ - ），（1）/（+）（（ZY）3C）（ - ）或（1 / mM）（+）（（ZY）2CQ）（ - ），其中M，Z，Y和Q为如本文所定义。

94. 发明授权

US5415954A Electrical contact outlet for anodes 失效
标题翻译：阳极电接点
公开(公告)号：US5415954A
公开(公告)日：1995-05-16
申请号：US52833
申请日：1993-04-27
申请人： Michel Gauthier , Andre Belanger , James K. Jacobs , Guy St-Amant , Serge Ricard
发明人： Michel Gauthier , Andre Belanger , James K. Jacobs , Guy St-Amant , Serge Ricard
IPC分类号： H01M2/22 , H01M2/26 , H01M4/40 , H01M4/66 , H01M6/46
CPC分类号： H01M2/263 , H01M2/22 , H01M4/661 , H01M6/46
摘要： Electrical contact outlet for an anode sheet of a lithium generator with polymer electrolyte, consisting of one or more multilayer electrochemical cells. The cell comprises at least one lithium base sheet having a thickness between about 1 and 50 microns to constitute the anode and its collector and additionally includes a cathode and its collector as well as the polymer electrolyte. A lateral end of the anode sheet extends beyond corresponding ends of the cathode and the collector to constitute a projecting zone. A metallic layer consisting of at least one rigid metal which is compatible with lithium is in electrical contact with the lateral end of the anode sheet but without electronic contact with the other components of the cell. The metallic layer constitutes the external terminal of the generator when the latter is in non-finished condition. According to a variant, a conductive and cohesive intermediate metallic zone, which consists of lithium or lithium rich ductile alloys is in intimate contact with the lateral end of the anode sheet and the metallic layer mentioned above is therefore in electrical contact with the lateral end of the anode sheet by means of the intermediate zone of lithium. Generators provided with such contact outlet as well as a process for the preparation of these contact outlets are described.
摘要翻译：具有聚合物电解质的锂发生器的阳极片的电接触出口，由一个或多个多层电化学电池组成。电池包括至少一个厚度在约1微米至50微米之间的锂基片，以构成阳极及其集电体，另外还包括阴极及其集电体以及聚合物电解质。阳极片的横向端部延伸超过阴极和集电器的相应端部以构成突出区域。由与锂相容的至少一种刚性金属组成的金属层与阳极片的侧端电接触，但与电池的其它部件没有电接触。当后者处于未完成状态时，金属层构成发电机的外部端子。根据一个变型，由富含锂或锂的延性合金构成的导电和内聚中间金属区域与阳极片的侧端紧密接触，因此上述金属层与外部端部电接触通过锂的中间区形成阳极片。描述了提供有这种接触插座的发电机以及用于制备这些接触插座的工艺。

95. 发明授权

US4517265A Composite and flexible anodes for lithium cells in non-aqueous medium 失效
标题翻译：用于非水介质中锂电池的复合和柔性阳极
公开(公告)号：US4517265A
公开(公告)日：1985-05-14
申请号：US430696
申请日：1982-09-30
申请人： Andre Belanger , Denis Fauteux , Michel Gauthier
发明人： Andre Belanger , Denis Fauteux , Michel Gauthier
IPC分类号： H01M4/40 , H01M4/06 , H01M4/134 , H01M4/38 , H01M4/58 , H01M4/587 , H01M4/62 , H01M6/16 , H01M6/18 , H01M10/052 , H01M10/0565 , H01M10/36 , H01M4/60
CPC分类号： H01M4/587 , H01M10/052 , H01M4/134 , H01M4/40 , H01M4/625 , H01M6/181 , H01M10/0565
摘要： Anode composition based on a mixture of plastic or elastomeric macromolecular material with ionic conduction, an alloy of lithium and particles of a carbon compound of the formula: Li.sub.x C where 0.ltoreq.x
摘要翻译：基于具有离子传导性的塑料或弹性体高分子材料的混合物的阳极组合物，锂的合金和下式的化合物的碳化合物：LixC，其中0

96. 发明授权

US4436709A Laser production of carbon-13 based on CF.sub.2 HCl 失效
标题翻译：基于CF2HCl的碳-13激光生产
公开(公告)号：US4436709A
公开(公告)日：1984-03-13
申请号：US350741
申请日：1982-02-22
申请人： Michel Gauthier , Peter A. Hackett , Clive Willis
发明人： Michel Gauthier , Peter A. Hackett , Clive Willis
IPC分类号： B01D59/34 , B01D59/00
CPC分类号： B01D59/34
摘要： A method of producing carbon-13 using CF.sub.2 HCl as the feedstock (substrate) material in which the CF.sub.2 HCl is enriched up to a first level of C-13 by I.R. laser photodissociation and then to 90-99% C-13 by a second exchange process. In the preferred arrangement the second stage is a chemical exchange process.
摘要翻译：使用CF2HCl作为原料（基质）材料生产碳-13的方法，其中CF2HCl由I.R.富集至第一级C-13。激光光解，然后通过第二次交换进行到90-99％C-13。在优选的布置中，第二阶段是化学交换过程。

97. 发明授权

US4388155A Solid sensor for anhydrides 失效
标题翻译：固体传感器用于酸酐
公开(公告)号：US4388155A
公开(公告)日：1983-06-14
申请号：US174186
申请日：1980-07-31
申请人： Andre M. Chamberland , Michel Gauthier
发明人： Andre M. Chamberland , Michel Gauthier
IPC分类号： G01N27/407 , G01N27/416 , G01N27/46
CPC分类号： G01N27/4074
摘要： The invention concerns a detector for anhydrides, present in the air or stack gases, which comprises a solid state electrolyte element containing oxy-anions of the particular anhydride to be detected. This solid state element is provided with metal areas to which potentiometric measuring means are connected. The detecting element is, preferably, sintered and may consist of one or several juxtaposed solid state compounds, according as the reference source is a gas or a solid state electrode, respectively. The electrolyte element is heated to a temperature not exceeding its fusion point. In addition, particular arrangements are provided to compensate for the oxygen content variations in air due to varying measurement conditions.
摘要翻译：本发明涉及存在于空气或烟道气体中的酸酐检测器，其包含含有要检测的特定酸酐的氧阴离子的固态电解质元件。该固体元件设置有连接有电位计测量装置的金属区域。检测元件优选地被烧结并且可以由一个或多个并置的固态化合物组成，根据参考源分别是气体或固态电极。将电解质元件加热到不超过其熔点的温度。此外，提供了特定的布置以补偿由于变化的测量条件而导致的空气中的氧含量变化。

98. 发明授权

US4282078A Solid state sensor for anhydrides 失效
标题翻译：用于酸酐的固态传感器
公开(公告)号：US4282078A
公开(公告)日：1981-08-04
申请号：US718511
申请日：1976-08-30
申请人： Andre M. Chamberland , Michel Gauthier
发明人： Andre M. Chamberland , Michel Gauthier
IPC分类号： G01N27/407 , G01N27/413 , G01N27/416 , G01N27/417 , G01N27/58
CPC分类号： G01N27/417 , G01N27/4074
摘要： The invention concerns a detector for anhydrides, present in the air or stack gases, which comprises a solid state electrolyte element containing oxy-anions of the particular anhydride to be detected. This solid state element is provided with metal areas to which potentiometric measuring means are connected. The detecting element is, preferably, sintered and may consist of one or several juxtaposed solid state compounds, according as the reference source is a gas or a solid state electrode, respectively. The electrolyte element is heated to a temperature not exceeding its fusion point. In addition, particular arrangements are provided to compensate for the oxygen content variations in air due to varying measurement conditions.
摘要翻译：本发明涉及存在于空气或烟道气体中的酸酐检测器，其包含含有要检测的特定酸酐的氧阴离子的固态电解质元件。该固体元件设置有连接有电位计测量装置的金属区域。检测元件优选地被烧结并且可以由一个或多个并置的固态化合物组成，根据参考源分别是气体或固态电极。将电解质元件加热到不超过其熔点的温度。此外，提供了特定的布置以补偿由于变化的测量条件而导致的空气中的氧含量变化。

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