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    • 91. 发明授权
    • Chemical vapor deposition plasma process using an ion shower grid
    • 使用离子淋浴网格的化学气相沉积等离子体工艺
    • US07244474B2
    • 2007-07-17
    • US10873485
    • 2004-06-22
    • Hiroji HanawaTsutomu TanakaKenneth S. CollinsAmir Al-BayatiKartik RamaswamyAndrew Nguyen
    • Hiroji HanawaTsutomu TanakaKenneth S. CollinsAmir Al-BayatiKartik RamaswamyAndrew Nguyen
    • H05H1/03H05H1/46C23C16/30C23C16/34C23C16/40
    • C23C16/452C23C16/402C23C16/517
    • A chemical vapor deposition process is carried out in a reactor chamber with an ion shower grid that divides the chamber into an upper ion generation region and a lower process region, the ion shower grid having plural orifices oriented in a non-parallel direction relative to a surface plane of the ion shower grid. A workpiece is placed in the process region facing the ion shower grid, the workpiece having a workpiece surface generally facing the surface plane of the ion shower grid. A gas mixture is furnished comprising deposition precursor species into the ion generation region and the process region is evacuated at an evacuation rate sufficient to create a pressure drop across the ion shower grid from the ion generation region to the process region whereby the pressure in the ion generation region is at least several times the pressure in the process region. A layer of material of a desired thickness is deposited on the workpiece by: (a) applying plasma source power to generate a plasma of the deposition precursor species in the ion generation region, and (b) applying a grid potential to the ion shower grid to create a flux of ions from the plasma through the grid and into the process region.
    • 在具有离子喷淋网格的反应室中进行化学气相沉积工艺,该离子喷淋网格将室分成上部离子产生区域和下部工艺区域,离子喷淋格栅具有相对于一个非平行方向取向的多个孔口 离子淋浴网格的表面。 工件放置在面向离子喷淋格栅的工艺区域中,工件具有大致面向离子喷淋栅格的表面的工件表面。 配备气体混合物,其包括沉积前体物质进入离子产生区域,并且处理区域以足以在从离子产生区域到过程区域的离子喷淋网格上产生压降的抽空速率抽真空,由此离子中的压力 发生区域至少是过程区域压力的几倍。 通过以下步骤沉积所需厚度的一层材料:(a)施加等离子体源功率以在离子产生区域中产生沉积前体物质的等离子体,和(b)将栅格电位施加到离子喷淋栅格 以从等离子体中产生离子通过网格并进入过程区域。
    • 94. 发明授权
    • Removal of surface dopants from a substrate
    • 从基底去除表面掺杂物
    • US07989329B2
    • 2011-08-02
    • US11963034
    • 2007-12-21
    • Kartik RamaswamyKenneth S. CollinsBiagio GalloHiroji HanawaMajeed A. FoadMartin A. HilkeneKartik SanthanamMatthew D. Scotney-Castle
    • Kartik RamaswamyKenneth S. CollinsBiagio GalloHiroji HanawaMajeed A. FoadMartin A. HilkeneKartik SanthanamMatthew D. Scotney-Castle
    • H01L21/38
    • H01L21/2254H01L21/2253
    • A method and apparatus for removing excess dopant from a doped substrate is provided. In one embodiment, a substrate is doped by surfaced deposition of dopant followed by formation of a capping layer and thermal diffusion drive-in. A reactive etchant mixture is provided to the process chamber, with optional plasma, to etch away the capping layer and form volatile compounds by reacting with excess dopant. In another embodiment, a substrate is doped by energetic implantation of dopant. A reactive gas mixture is provided to the process chamber, with optional plasma, to remove excess dopant adsorbed on the surface and high-concentration dopant near the surface by reacting with the dopant to form volatile compounds. The reactive gas mixture may be provided during thermal treatment, or it may be provided before or after at temperatures different from the thermal treatment temperature. The volatile compounds are removed. Substrates so treated do not form toxic compounds when stored or transported outside process equipment.
    • 提供了用于从掺杂衬底去除多余掺杂剂的方法和装置。 在一个实施例中,通过表面沉积掺杂剂掺杂衬底,然后形成覆盖层和热扩散驱入。 将反应性蚀刻剂混合物与任选的等离子体提供给处理室,以通过与多余的掺杂剂反应来蚀刻掉覆盖层并形成挥发性化合物。 在另一个实施例中,通过掺杂剂的高能注入来掺杂衬底。 通过与掺杂剂反应形成挥发性化合物,将具有任选等离子体的反应气体混合物提供给处理室,以除去吸附在表面上的多余掺杂物和表面附近的高浓度掺杂剂。 反应性气体混合物可以在热处理期间提供,或者可以在与热处理温度不同的温度之前或之后提供。 除去挥发性化合物。 如此处理的基材在储存或运输到工艺设备外时不会形成有毒化合物。