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1. 发明申请

US20030153693A1 Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions 失效
公开(公告)号：US20030153693A1
公开(公告)日：2003-08-14
申请号：US10359960
申请日：2003-02-07
发明人： Roderic Paul Quirk , Young Joon Lee , James Anthony Schwindeman , Robert James Letchford
IPC分类号： C08F008/34
CPC分类号： C08C19/44 , C08F8/42 , C08F12/00
摘要： Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed.

2. 发明申请

US20030004262A1 Tire with tread of rubber composition containing carbon black with silicon domains on its surface 审中-公开
标题翻译：具有橡胶组合物的胎面，其表面上含有具有硅结构域的碳黑
公开(公告)号：US20030004262A1
公开(公告)日：2003-01-02
申请号：US10116897
申请日：2002-04-05
发明人： Charles Edward Drvol , Sherman L. Taylor , Tom Dominique Linster , Michael Brendan Rodgers , Fahri Ozel
IPC分类号： C08F008/34
CPC分类号： C08K5/548 , B60C1/0016 , C08K9/02 , C08L7/00 , C08L9/00 , C08L21/00
摘要： A tire is provided having a circumferential tread of a cis 1,4-polyisoprene rubber based rubber composition reinforced with a carbon black/silica composite, wherein said carbon black/silica composite is a treated carbon black having silicon-containing domains, namely domains of silica, primarily on the surface of the carbon black, where said silica domains contain hydroxyl groups on their surface, wherein said silica domains cover at least 50 percent of the carbon black surface, and where said rubber composition contains a coupling agent as bis (3-triethoxysilylpropyl) polysulfide having an average of from 2 to 2.6 connecting sulfur atoms in its polysulfidic bridge, exclusive of a bis (3-trialkoxysilylalkyl) polysulfide having an average of greater than 2.6 sulfur atoms in its polysulfidic bridge; wherein said rubber composition contains from zero to a maximum of about 15 phr of unmodified carbon black and wherein said rubber composition contains from zero to a maximum of about 10 phr of precipitated silica and exclusive of any other carbon black and exclusive of any other silica.
摘要翻译：提供一种轮胎，其具有用炭黑/二氧化硅复合材料增强的顺式1,4-聚异戊二烯橡胶基橡胶组合物的周向胎面，其中所述炭黑/二氧化硅复合物是具有含硅畴的处理炭黑，即具有含硅畴二氧化硅，主要在炭黑的表面上，其中所述二氧化硅域在其表面上含有羟基，其中所述二氧化硅域覆盖至少50％的炭黑表面，并且其中所述橡胶组合物含有偶联剂作为双（3 - 三乙氧基甲硅烷基丙基）多硫化物，其多硫链中的硫原子平均连接2至2.6个，不包括其多硫桥中平均大于2.6个硫原子的双（3-三烷氧基甲硅烷基烷基）多硫化物; 其中所述橡胶组合物含有0至最大约15phr未改性炭黑，并且其中所述橡胶组合物含有0至最大约10phr的沉淀二氧化硅，不包括任何其它炭黑并且不包括任何其它二氧化硅。

3. 发明申请

US20020120070A1 Anti reflective coating polymers and the preparation method thereof 失效
公开(公告)号：US20020120070A1
公开(公告)日：2002-08-29
申请号：US10015333
申请日：2001-12-11
申请人： Hyundai Electronics Industries Co., Ltd.
发明人： Sung-Eun Hong , Min-Ho Jung , Hyeong-Soo Kim , Ki-Ho Baik
IPC分类号： C08F008/34
CPC分类号： C08F212/14 , C08F8/34 , G03F7/023 , G03F7/091 , C08F12/14 , C08F220/20
摘要： The present invention relates to organic anti-reflective coating polymers and preparation methods therefor. Anti-reflective coatings are used in a semiconductor device during photolithography processes to prevent the reflection of light from lower layers of the device, or resulting from changes in the thickness of the photoresist layer, and to eliminate the standing wave effect when ArF light is used. The present invention also relates to anti-reflective compositions and coatings containing these organic anti-reflective coating polymers, alone or in combination with certain light-absorbing compounds, and preparation methods therefor. When the polymers of the present invention are used in an anti-reflective coating in a photolithography process for forming submicro-patterns, the resultant elimination of changes in CD due to diffractive and reflective lights originating from lower layers increases the product yield in the formation of submicro-patterns during the manufacture of 64 M, 256 M, 1 G, 4 G and 16 G DRAM semiconductor devices.

4. 发明申请

US20030208006A1 Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making 有权
标题翻译：芳香酰亚胺和芳香族甲基亚磺酰基化合物及其制备方法
公开(公告)号：US20030208006A1
公开(公告)日：2003-11-06
申请号：US10436325
申请日：2003-05-12
申请人： 3M Innovative Properties Company
发明人： Steven Joseph Hamrock
IPC分类号： C08F008/34 , C07C317/12 , C07C317/34
CPC分类号： C07C303/36 , C07C311/48
摘要： A method is provided for making aromatic-imide and aromatic-methylidynetrissulfonyl species by reaction of aromatic species with a reactant according to formula (I): (XnullSO2-)m-QHnull(nullSO2nullR1)nnullnull(I) wherein Q is C or N; wherein each X is independently selected from the group consisting of halogens, typically F or Cl; wherein each R1 is independently selected from the group consisting of aliphatic and aromatic groups, which may or may not be saturated, unsaturated, straight-chain, branched, cyclic, heteroatomic, polymeric, halogenated, fluorinated or substituted; wherein m is greater than 0; wherein mnullnnull2 when Q is N; and wherein mnullnnull3 when Q is C. Ar may be derived from an aromatic polymeric compound. In addition, compounds are provided according to the formula: (ArnullSO2-)m-QHnull(nullSO2nullR1)n wherein R1 comprises a highly acidic group selected from sulfonic acid, carboxylic acid and phosphonic acid, and Ar is derived from an aromatic compound.
摘要翻译：通过芳香族物质与式（I）的反应物的反应制备芳香族 - 酰亚胺和芳香族 - 亚甲基三磺酰基物质的方法：（X-SO 2 - ）m-QH - （ - SO 2 -R 1）n（I）其中 Q是C或N; 其中每个X独立地选自卤素，通常为F或Cl; 其中每个R 1独立地选自脂族和芳族基团，其可以是饱和的，不饱和的，直链的，支链的，环状的，杂原子的，聚合的，卤代的，氟化的或取代的; 其中m大于0; 其中当Q为N时m + n = 2; 且当Q为C时m + n = 3。Ar可以衍生自芳族聚合物。另外，根据下式可以提供化合物：（Ar-SO 2 - ）m -QH - （ - SO 2 -R 1）n其中R 1包括选自磺酸，羧酸和膦酸的高度酸性基团，Ar衍生来自芳香族化合物。

5. 发明申请

US20020045699A1 Solution rubbers having nonpolar side groups 审中-公开
标题翻译：溶液橡胶具有非极性侧基
公开(公告)号：US20020045699A1
公开(公告)日：2002-04-18
申请号：US09736505
申请日：2000-12-13
发明人： Thomas Scholl , Jurgen Trimbach
IPC分类号： C08F008/34
CPC分类号： C08C19/20 , C08L19/006
摘要： The present invention relates to rubbers based on diolefins that are characterized in that they have a content of 0.1 to 40 wt. %, relative to the total quantity of rubber, of non-polar lateral, saturated, linear, branched or cyclic hydrocarbons bound via sulfur atoms containing 1 to 22 carbon atoms or aromatic hydrocarbon radicals containing 6 to 22 carbon atoms, wherein the rubbers are produced by polymerization in solution.
摘要翻译：本发明涉及基于二烯烃的橡胶，其特征在于它们的含量为0.1-40wt。相对于橡胶总量的通过含有1至22个碳原子的硫原子或含有6至22个碳原子的芳族烃基结合的非极性侧向，饱和，直链，支链或环状烃的％，其中所述橡胶被制备通过在溶液中聚合。

6. 发明申请

US20020022701A1 Sulfenyl halide polymerization terminators 有权
标题翻译：磺酰卤聚合终止子
公开(公告)号：US20020022701A1
公开(公告)日：2002-02-21
申请号：US09878077
申请日：2001-06-08
发明人： David F. Lawson , Mark L. Stayer JR. , Thomas A. Antkowiak
IPC分类号： C08F008/34
CPC分类号： C08C19/44
摘要： A method of preparing a functionalized polymer comprising the steps of initiating the formation and propagation of an anionically-polymerized living polymer, and terminating the propagation of the living polymer by reacting the polymer with a terminating agent selected from the group of agents defined by the formulas (III), (IV), and (V) 1 where C is a carbon atom, S is a sulfur atom, X is a halogen atom, R2 and R4 are independently selected from hydrogen and carbon-based moieties, and where the phenyl groups are selected from unsubstituted and substituted phenyl groups.
摘要翻译：一种制备官能化聚合物的方法，包括以下步骤：引发阴离子聚合的活性聚合物的形成和扩散，并通过使聚合物与选自由式（III），（IV）和（V）其中C是碳原子，S是硫原子，X是卤素原子，R2和R4独立地选自氢和碳基部分，并且其中苯基选自未取代的和取代的苯基。

7. 发明申请

US20020007016A1 Methods for making multivalent arrays 有权
标题翻译：制作多价数组的方法
公开(公告)号：US20020007016A1
公开(公告)日：2002-01-17
申请号：US09888098
申请日：2001-06-22
发明人： Laura L. Kiessling , Laura E. Strong
IPC分类号： C08F008/30 , C08F004/26 , C08F008/34 , C08F008/40 , C08F004/06 , C08F132/00 , C08F034/04 , C08F234/02 , C08F008/28
CPC分类号： B01J31/2404 , B01J19/0046 , B01J31/2265 , B01J2219/00497 , B01J2219/005 , B01J2219/00585 , B01J2219/00596 , B01J2219/00603 , B01J2219/00605 , B01J2219/0061 , B01J2219/00637 , B01J2219/00722 , B01J2219/00738 , B01J2231/14 , B01J2531/821 , C07B2200/11 , C07F15/002 , C07F15/0046 , C08F10/00 , C40B40/14 , C08F2/38 , C08F4/80
摘要： A method of preparing a multivalent array that includes: polymerizing at least one monomer comprising at least one polymerizable group and at least one latent reactive group in the presence of a metal carbene catalyst to form a polymer template comprising at least one latent reactive group; and combining the polymer template with at least one functionalizing reagent comprising at least one reactive group under conditions effective to react the latent reactive group of the polymer template with the reactive group of the functionalizing reagent to form a multivalent array.
摘要翻译：一种制备多价阵列的方法，其包括：在金属卡宾催化剂的存在下聚合至少一种包含至少一个可聚合基团和至少一个潜在反应性基团的单体以形成包含至少一个潜在反应性基团的聚合物模板; 以及在有效使聚合物模板的潜在反应性基团与官能化试剂的反应性基团反应形成多价阵列的条件下，将聚合物模板与至少一种包含至少一个反应性基团的官能化试剂组合。

8. 发明申请

US20040116617A1 Polymer-supported arylbis(perfluoroalkylsulfonyl)-methane 失效
标题翻译：聚合物负载的芳基双（全氟烷基磺酰基） - 甲烷
公开(公告)号：US20040116617A1
公开(公告)日：2004-06-17
申请号：US10471447
申请日：2003-09-10
发明人： Kazuaki Ishihara , Hisashi Yamamoto
IPC分类号： C08F008/34 , C08C019/20
CPC分类号： B01J31/0224 , B01J31/06 , B01J31/10 , B01J2231/342 , B01J2231/346 , B01J2231/348 , B01J2231/40 , B01J2231/44 , C07B2200/11 , C07C17/14 , C07C17/263 , C07C29/38 , C07C41/56 , C07C45/511 , C07C45/64 , C07C45/673 , C07C67/08 , C07C2601/14 , C07C25/18 , C07C49/83 , C07C69/78 , C07C43/303 , C07C33/30
摘要： The present invention provides a solid acid catalyst that is excellent from the point of toxicity, environment and others, wherein reaction can be progressed effectively with Bronsted acid or Lewis acid catalyst. For example, the benzoylation reaction of alcohol can also be progressed easily, and further, the catalyst can be recovered and recycled easily. The para position of arylbis(perfluoroalkylsulfonyl)methane represented by the general formula null1null (wherein R1 shows a substituted or unsubstituted aryl group, Rf1 and Rf2 are independent to each other and show a perfluoroalkyl group), a pentafluorophenylbis(perfluoroalkylsulfonyl)methane, for example, is supported on a polystyrene resin, and a polystyrene-supported arylbis(perfluoroalkylsulfonyl)methane represented by the general formula null3null (wherein R3 shows a substituted or unsubstituted arylene group, Rf1 and Rf2 are the same as described above) is obtained. 1 2
摘要翻译：本发明提供从毒性，环境等方面优异的固体酸催化剂，其中可以使用布朗斯台德酸或路易斯酸催化剂有效地进行反应。例如，醇的苯甲酰化反应也可以容易地进行，此外，可以容易地回收和回收催化剂。由通式[1]表示的芳基双（全氟烷基磺酰基）甲烷的对位（其中R 1表示取代或未取代的芳基，Rf 1和Rf 2彼此独立，表示全氟烷基），五氟苯基双（全氟烷基磺酰基）甲烷例如负载在聚苯乙烯树脂上，由通式[3]表示的聚苯乙烯担载的芳基双（全氟烷基磺酰基）甲烷（其中R 3表示取代或未取代的亚芳基，Rf 1和Rf 2与上述相同）。

9. 发明申请

US20030138846A1 Solid phase supports 审中-公开
公开(公告)号：US20030138846A1
公开(公告)日：2003-07-24
申请号：US10245420
申请日：2002-09-17
发明人： David Gani , Friedrich Erich Karl Kroll , Michael John Plater , John Richard Morphy , David Rees
IPC分类号： G01N033/53 , C08F008/34 , C07D213/18 , C08C019/22 , G01N033/543
CPC分类号： G01N33/545 , C07K1/042 , C08F8/30 , C08F8/34
摘要： Embodiments of the present invention generally relate to carrying out organic chemistry on solid supports comprising derivatised functionalities, methods for synthesizing said supports, methods for synthesizing compounds comprising amine groups or N-containing heterocycles using said solid supports, intermediate compounds linked to said supports and uses thereof.

10. 发明申请

US20020188082A1 Novel vulcanizing agent for diene-based rubber and rubber composition using the same 审中-公开
标题翻译：用于二烯系橡胶的新型硫化剂和使用其的橡胶组合物
公开(公告)号：US20020188082A1
公开(公告)日：2002-12-12
申请号：US09797679
申请日：2001-03-05
申请人： THE YOKOHAMA RUBBER CO, LTD.
发明人： Yuko Nakata , Kazunori Ishikawa
IPC分类号： C07C321/00 , C08F008/34 , C08F136/20
CPC分类号： C08G75/14 , C08K5/372 , C08L21/00
摘要： A novel vulcanizing agent giving a vulcanized rubber superior in heat aging resistance and reversion resistance, comprising an organic sulfur vulcanizing agent obtained by reaction of sulfur and norbornene or its derivative or dicyclopentadiene in the presence of catalyzing amounts of a vulcanization accelerator and an accelerator activator.
摘要翻译：提供耐热老化性和耐逆转性优异的硫化橡胶的新型硫化剂，其含有硫和降冰片烯或其衍生物或二环戊二烯在催化量的硫化促进剂和促进剂活化剂的存在下反应得到的有机硫磺硫化剂。

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