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    • 2. 发明授权
    • Process for the preparation of solutions of anionic organic compounds
    • 制备阴离子有机化合物溶液的方法
    • US06719906B1
    • 2004-04-13
    • US10111948
    • 2002-04-26
    • Jacek MaliszAdolf KäserRainer KaufelHolger LautenbachElke PolleyMartina Hoffmann
    • Jacek MaliszAdolf KäserRainer KaufelHolger LautenbachElke PolleyMartina Hoffmann
    • B01D6116
    • C09B67/0096C09B67/0073
    • A process for the preparation of concentrated solutions or suspensions of anionic organic compounds is described, which process comprises a) acidifying an aqueous solution or dispersion of an anionic organic compound that comprises salts and/or impurities to a pH of 4.5 or less, if the pH is above that value, so that the anionic organic compound becomes insoluble in water and precipitates out in the form of the free acid, b) bringing the suspension obtained from the previous step to a salt content below 2% by weight, based on the total weight of retentate, by means of ultra-filtration with a ceramic membrane or an acid-resistant organic membrane having a pore size of from 1 to 20 nm, and c) optionally washing out of the salts with water at a pH of less than 4.5, d) optionally carrying out acid-free washing with water thereafter, and then e) concentrating so that the content of anionic organic compound is from 5 to 50 % by weight, and f) optionally bringing the anionic organic compound into solution by adding a suitable base.
    • 描述了用于制备阴离子有机化合物的浓缩溶液或悬浮液的方法,该方法包括a)如果pH为4.5或更低,则将包含盐和/或杂质的阴离子有机化合物的水溶液或分散体酸化至pH 4.5或更低 使得阴离子有机化合物变得不溶于水并以游离酸的形式沉淀出来,b)使得从前一步获得的悬浮液的盐含量低于2重量%,基于总量 通过用陶瓷膜或孔径为1至20nm的耐酸有机膜进行超滤,并且c)任选地在pH小于4.5的情况下用水洗涤所述盐, d)任选地用水进行无酸洗涤,然后进行浓缩,使得阴离子有机化合物的含量为5至50重量%,和f)任选将阴离子有机化合物引入s 通过添加合适的碱来说明。
    • 3. 发明授权
    • Method and device for demulsifying an oil-containing aqueous emulsion
    • 含油水乳液的破乳方法和装置
    • US06413430B1
    • 2002-07-02
    • US09555437
    • 2000-05-30
    • Thomas Berger
    • Thomas Berger
    • B01D6116
    • C10M175/04B01D17/0214B01D17/042B01D17/044B01D17/047B01D17/085
    • A process for separation of an oil-containing aqueous emulsion includes mixing the oil-containing aqueous emulsion with carbon-dioxide and subjecting the emulsion and carbon dioxide for a specified time within an autoclave to an elevated pressure and an elevated temperature. A rising stream of bubbles is formed within the autoclave by suddenly relieving the pressure within the autoclave with the rising stream of bubbles serving to separate the oil-containing aqueous emulsion into an oil-rich phase and an oil-depleted emulsion. The oil depleted emulsion is transferred to a segrating tank. At least a fraction of the oil-depleted emulsion within the segregated tank is subjected to ultrafiltration to separate the fraction into a permeate and a retentate.
    • 含油水乳液的分离方法包括将含油水乳液与二氧化碳混合,并在高压釜内将乳液和二氧化碳在规定时间内进行升高的压力和升高的温度。 通过突然释放高压釜内的压力,在高压釜内形成气泡的上升气流,起泡气流用于将含油水乳液分离成富油相和无油乳状液。 将耗油的乳液转移到一个分流槽中。 将分离罐内的至少一部分油耗的乳液进行超滤,将馏分分离成渗透物和渗余物。