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1. 发明授权

US11806703B2 Emission control during catalyst regeneration 有权
公开(公告)号：US11806703B2
公开(公告)日：2023-11-07
申请号：US17361357
申请日：2021-06-29
申请人： Monsanto Technology LLC
发明人： Kam-To Wan
IPC分类号： B01J38/02 , C07C17/358 , B01J21/06 , B01J23/22 , B01J29/076 , B01J29/90 , B01J38/06 , B01J38/50 , C07C37/00 , C07C37/60 , F01N9/00 , B01J38/16 , B01J38/12 , B01J38/14 , B01D53/86
CPC分类号： B01J38/02 , B01D53/8662 , B01J21/063 , B01J23/22 , B01J29/076 , B01J29/90 , B01J38/06 , B01J38/12 , B01J38/14 , B01J38/16 , B01J38/50 , C07C17/358 , C07C37/00 , C07C37/60 , F01N9/00 , B01D2255/2073 , B01D2255/20723 , B01D2255/20784 , B01D2255/50 , B01D2258/02 , Y02T10/40 , C07C37/60 , C07C39/30 , C07C37/60 , C07C39/27 , C07C17/358 , C07C25/08 , C07C37/00 , C07C39/30 , C07C37/00 , C07C39/27
摘要： Catalyst regeneration processes that include measures for controlling emissions generated during the regeneration are described. The present invention further relates to catalytic processes for producing various chlorinated aromatic compounds that include provisions for controlling emissions during catalyst regeneration.

2. 发明申请

US20170113991A1 PROCESS FOR PRODUCING HYDROQUINONE AND DERIVATES 有权
公开(公告)号：US20170113991A1
公开(公告)日：2017-04-27
申请号：US14922358
申请日：2015-10-26
申请人： Chang Chun Plastics Co. Ltd.
发明人： Chien Fu Huang , Yi Hung Chou
IPC分类号： C07C46/06 , C07C37/60 , C07C45/28
CPC分类号： C07C46/06 , C07C37/07 , C07C37/60 , C07C45/28 , C07C46/04 , Y02P20/584 , C07C50/04 , C07C39/04 , C07C50/02 , C07C50/24 , C07C39/08 , C07C39/245
摘要： The present disclosure relates to an improved, environmentally friendly, process for producing compounds such as hydroquinone (benzene-1,4-diol) and its derivatives. The process can be carried out at ambient temperature and pressure using a recyclable copper catalyst and recyclable intermediate materials. The process generally entails reacting an aromatic compound such as benzene with hydrogen peroxide in the present of a pure elemental copper catalyst or a copper (I) salt catalyst to form oxidation product such as benzoquinone, and reducing the compound to hydroquinone or a hydroquinone derivative.

3. 发明申请

US20160176795A1 PROCESS FOR PRODUCING AROMATIC DIHYDROXY COMPOUND 有权
标题翻译：生产芳族二羟基化合物的方法
公开(公告)号：US20160176795A1
公开(公告)日：2016-06-23
申请号：US14764344
申请日：2014-09-11
申请人： MITSUI CHEMICALS, INC.
发明人： Yuya GOTO , Takashi NABETA
IPC分类号： C07C37/60
CPC分类号： C07C37/60 , B01J29/89 , Y02P20/52 , C07C39/08
摘要： [Problem] To provide a process for producing an aromatic dihydroxy compound, in which a hydroquinone compound is highly selectively produced while suppressing formation of by-products derived from a solvent and maintaining a high yield based on hydrogen peroxide when a phenol compound is allowed to react with hydrogen peroxide. [Solution]A process for producing an aromatic dihydroxy compound, including allowing a phenol compound to react with hydrogen peroxide in the presence of a titanosilicate, a C4-C5 alcohol containing a tertiary or quaternary carbon, and water and/or methanol, the amount of the water and/or methanol being 5 to 90 mass % based on the total mass of the reaction liquid.
摘要翻译：本发明提供一种芳香族二羟基化合物的制造方法，其中氢醌化合物被高选择性地制备，同时抑制来自溶剂的副产物的形成，并且当使苯酚化合物被允许时，保持基于过氧化氢的高收率与过氧化氢反应。 [方案]一种芳族二羟基化合物的制备方法，其包括使苯酚化合物在钛硅酸盐，含有叔或季碳的C 4 -C 5醇和水和/或甲醇的存在下与过氧化氢反应，所述量的水和/或甲醇为5〜90质量％，基于反应液的总质量。

4. 发明申请

US20140296544A1 CYCLIC PEROXIDE OXIDATION OF AROMATIC COMPOUNDS PRODUCTION AND USE THEREOF 审中-公开
标题翻译：芳香化合物生产的循环过氧化氢及其用途
公开(公告)号：US20140296544A1
公开(公告)日：2014-10-02
申请号：US13967040
申请日：2013-08-14
申请人： Board of Regents, The University of Texas System
发明人： Dionicio Siegel , Andrew M. Camelio , Anders Eliasen , Trevor C. Johnson , Abram Axelrod , Changxia Yuan
IPC分类号： C07C29/09 , C07C67/00 , C07C253/30 , C07D311/64 , C07C45/27
CPC分类号： C07D311/64 , C07B41/02 , C07C37/0555 , C07C37/60 , C07C41/26 , C07C45/64 , C07C51/367 , C07C67/00 , C07C67/29 , C07C67/31 , C07C209/68 , C07C247/04 , C07C253/30 , C07C269/06 , C07C2602/08 , C07C2602/10 , C07C2603/26 , C07C2603/97 , C07D209/48 , C07D303/40 , C07D311/72 , C07D317/36 , C07C255/13 , C07C255/36 , C07C271/10 , C07C217/20 , C07C43/23 , C07C43/253 , C07C43/295 , C07C47/575 , C07C47/27 , C07C69/28 , C07C69/92 , C07C69/734 , C07C69/732 , C07C59/52 , C07C69/80 , C07C69/76 , C07C39/07 , C07C39/06 , C07C39/17 , C07C39/15 , C07C39/14 , C07C39/27 , C07C39/28 , C07C39/367 , C07C39/11 , C07C49/83 , C07C49/755 , C07C59/64 , C07C69/63
摘要： The present invention provides a method for converting an aromatic hydrocarbon to a phenol by providing an aromatic hydrocarbon comprising one or more aromatic C—H bonds and one or more activated C—H bonds in a solvent; adding a phthaloyl peroxide to the solvent; converting the phthaloyl peroxide to a di-radical; contacting the di-radical with the one or more aromatic C—H bonds; oxidizing selectively one of the one or more aromatic C—H bonds in preference to the one or more activated C—H bonds; adding a hydroxyl group to the one of the one or more aromatic C—H bonds to form one or more phenols; and purifying the one or more phenols.
摘要翻译：本发明提供一种通过在溶剂中提供包含一个或多个芳族C-H键和一个或多个活化C-H键的芳族烃来将芳族烃转化为苯酚的方法; 向溶剂中加入邻苯二甲酰过氧化物; 将过氧化二苯甲酰转化为二基; 使二基与一个或多个芳族C-H键接触; 优选选择性地一种或多种芳族C-H键中的一种，优选一种或多种活化的C-H键; 向所述一个或多个芳族C-H键中的一个添加羟基以形成一种或多种酚; 并纯化一种或多种酚类。

5. 发明申请

US20140274668A1 ENHANCED PROCATALYST COMPOSITION AND PROCESS 有权
标题翻译：增强方法的组合物和方法
公开(公告)号：US20140274668A1
公开(公告)日：2014-09-18
申请号：US14293468
申请日：2014-06-02
申请人： W. R. Grace & Co.-Conn.
发明人： Kelly Gonzalez , Clark C. Williams , Linfeng Chen
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C07C37/02 , C07C37/14 , C07C37/16 , C07C37/50 , C07C37/56 , C07C37/60 , C07C67/14 , C08F110/06 , C08F210/06 , C07C69/78 , C08F4/651 , C08F210/16 , C08F2500/12 , C07C39/08 , C08F4/6494 , C08F4/6465 , C08F2500/18 , C08F4/6545
摘要： Disclosed herein are processes for preparing procatalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity and also increase the bulk density of the formant polymer.
摘要翻译：本文公开了制备原催化剂组合物和聚合物的方法，即由其制备的基于丙烯的聚合物。本发明的前催化剂组合物改善催化剂选择性并且还增加共振峰聚合物的体积密度。

6. 发明授权

US08778826B2 Enhanced procatalyst composition and process 有权
标题翻译：增强主催化剂组成和工艺
公开(公告)号：US08778826B2
公开(公告)日：2014-07-15
申请号：US12651032
申请日：2009-12-31
申请人： Kelly Gonzalez , Clark C. Williams , Linfeng Chen
发明人： Kelly Gonzalez , Clark C. Williams , Linfeng Chen
IPC分类号： C08F110/06 , C08F4/16
CPC分类号： C08F10/06 , C07C37/02 , C07C37/14 , C07C37/16 , C07C37/50 , C07C37/56 , C07C37/60 , C07C67/14 , C08F110/06 , C08F210/06 , C07C69/78 , C08F4/651 , C08F210/16 , C08F2500/12 , C07C39/08 , C08F4/6494 , C08F4/6465 , C08F2500/18 , C08F4/6545
摘要： Disclosed herein are processes for preparing procatalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity and also increase the bulk density of the formant polymer.
摘要翻译：本文公开了制备原催化剂组合物和聚合物的方法，即由其制备的基于丙烯的聚合物。本发明的前催化剂组合物改善催化剂选择性并且还增加共振峰聚合物的体积密度。

7. 发明申请

US20140073818A1 Method for hydroxylating phenols and phenol ethers 有权
标题翻译：苯酚和苯酚醚的羟基化方法
公开(公告)号：US20140073818A1
公开(公告)日：2014-03-13
申请号：US14118082
申请日：2012-05-15
申请人： Laurent Garel , Stephanie Normand , Pascal Pitiot , Jean-Christophe Bigouraux
发明人： Laurent Garel , Stephanie Normand , Pascal Pitiot , Jean-Christophe Bigouraux
IPC分类号： C07C41/26 , C07C37/60
CPC分类号： C07C41/26 , C07C37/60 , Y02P20/582 , C07C39/08
摘要： A method for hydroxylating phenols and phenol ethers using hydrogen peroxide and specifically, a method for hydroxylating phenol using hydrogen peroxide. The method for hydroxylating a phenolic substrate selected from a phenol or a phenol ether by reacting such phenolic substrate with hydrogen peroxide in the presence of an acid catalyst comprises the following steps, implemented consecutively or simultaneously: a first step consisting of mixing a phenolic substrate with a hydrogen peroxide solution under conditions in which the temperature is sufficient for the initial phenolic substrate to remain liquid and for minimizing the conversion rate of the hydrogen peroxide; a second step consisting of carrying out the phenolic substrate hydroxylation reaction under adiabatic conditions, the acid catalyst being added at the mixing stage and/or at the beginning of the hydroxylation reaction; and a third step, if necessary, consisting of recovering the hydroxylated product.
摘要翻译：使用过氧化氢使酚和酚醚羟基化的方法，具体地说，使用过氧化氢使苯酚羟基化的方法。在酸催化剂存在下使这种酚类底物与过氧化氢反应，通过使酚类底物与过氧化氢反应来羟基化选自酚或酚醚的方法包括以下步骤：连续或同时实施：第一步，将酚类底物与过氧化氢溶液，其中温度足以使初始酚类底物保持液体并使过氧化氢的转化率最小化; 第二步是在绝热条件下进行酚类底物羟基化反应，在混合阶段和/或在羟化反应开始时加入酸催化剂; 如果需要，第三步是回收羟基化产物。

8. 发明授权

US06936740B1 Dense phase oxidation of benzene 失效
标题翻译：苯的强相氧化
公开(公告)号：US06936740B1
公开(公告)日：2005-08-30
申请号：US10921686
申请日：2004-08-19
申请人： Robert N. Cochran , Jay F. Miller , Eric John Beckman , Sarah Emma Jones
发明人： Robert N. Cochran , Jay F. Miller , Eric John Beckman , Sarah Emma Jones
IPC分类号： C07C37/58 , C07C37/60 , C07C39/04
CPC分类号： C07C37/58 , C07C37/60 , C07C39/04
摘要： Phenol is formed by reaction of oxidant and benzene over a solid catalyst such as Pd on TS-1, the reaction being carried out in carbon dioxide solvent at conditions effective to provide a dense phase reaction mixture.
摘要翻译：苯酚通过氧化剂和苯在固体催化剂如Pd在TS-1上的反应形成，反应在有效提供致密相反应混合物的条件下在二氧化碳溶剂中进行。

9. 发明授权

US06692632B1 Method of producing hydroxyl radicals for chemical reactions 有权
标题翻译：生成化学反应的羟基自由基的方法
公开(公告)号：US06692632B1
公开(公告)日：2004-02-17
申请号：US10069939
申请日：2002-06-25
申请人： David Bremner , Arthur Ernest Burgess
发明人： David Bremner , Arthur Ernest Burgess
IPC分类号： C25B300
CPC分类号： C02F1/4672 , C02F1/36 , C02F1/461 , C02F2001/46133 , C02F2101/308 , C02F2101/363 , C02F2101/38 , C02F2103/14 , C02F2305/026 , C07C37/60 , C07C39/04
摘要： A method of reacting chemicals comprising the exposure of the reactants to ultrasound and electrochemical energies in the presence of a metal or metal salt and hydrogen peroxide. HO* radicals are efficiently formed and react with a carbon-based reactant to form a carbon radical which then reacts with other reactants or may dimerize. The invention regenerates the metal ions and may be performed using no special facilities. Increased product yield was achieved for a number of hydroxylation reactions.
摘要翻译：包括在金属或金属盐和过氧化氢的存在下将反应物暴露于超声和电化学能的化学反应的方法。 HO *自由基被有效地形成并与碳基反应物反应形成碳自由基，然后与其它反应物反应或可以二聚化。本发明再生金属离子，并且可以不使用专门的设备进行。实现了许多羟化反应的产物产率提高。

10. 发明授权

US06414197B1 Preparation of phenol and its derivatives 失效
标题翻译：苯酚及其衍生物的制备
公开(公告)号：US06414197B1
公开(公告)日：2002-07-02
申请号：US09078253
申请日：1998-05-13
申请人： Leonid Modestovich Kustov , Viktor Ignatyevich Bogdan , Vladimir Borisovich Kazansky
发明人： Leonid Modestovich Kustov , Viktor Ignatyevich Bogdan , Vladimir Borisovich Kazansky
IPC分类号： C07C3902
CPC分类号： C07C37/60 , B01J29/40 , B01J2229/26 , B01J2229/36 , B01J2229/42 , Y02P20/52 , C07C39/04 , C07C39/27 , C07C39/07 , C07C39/06
摘要： A method and a catalyst are described for selective oxidation of aromatic compounds (e.g., benzene and its derivatives) into hydroxylated aromatic compounds (e.g., corresponding phenols). For example, benzene can be converted into phenol with a yield of at least 30-40%, and a selectivity on the basis of benzene of at least 95-97%. The selectivity for this reaction based on N2O is at least 90-95%. Therefore, no substantial N2O decomposition or consumption for complete benzene oxidation to CO+CO2 or other side products occurs. Similar results are obtained with benzene derivatives (e.g., fluorobenzene, difluorobenzene, phenol), although the selectivity is somewhat lower in the case of derivatives (e.g., about 80-85% in the case of fluorosubstituted benzenes). A preferred catalyst for this process is a composition containing a high-silica pentasil-type zeolite (e.g, an HZSM-5 type zeolite) which contains no purposefully introduced additives such as transition or noble metals. The catalytic effect is achieved by performing a specific zeolite modification with strong Lewis acid-base centers of a specific nature. This modification can be achieved by a pretreatment comprising two steps: a first conventional calcination step at 300-600° C., and a second high-temperature calcination step at 600-950° C.
摘要翻译：描述了将芳族化合物（例如苯及其衍生物）选择性氧化成羟基化芳族化合物（例如相应的酚）的方法和催化剂。例如，苯可以转化成苯酚，产率至少为30-40％，苯的选择性至少为95-97％。基于N2O的该反应的选择性为至少90-95％。因此，不会发生完全苯氧化成CO + CO2或其他副产物的大量N2O分解或消耗。尽管在衍生物的情况下选择性略低（例如在氟取代的苯的情况下为约80-85％），但苯衍生物（例如，氟苯，二氟苯，苯酚）也可得到类似的结果。用于该方法的优选催化剂是含有不需要有目的地引入的添加剂如过渡金属或贵金属的高二氧化硅pentasil型沸石（例如，HZSM-5型沸石）的组合物。通过用特定性质的强路易斯酸碱中心进行具体的沸石改性来实现催化效果。该改性可以通过包括两个步骤的预处理来实现：在300-600℃下进行第一常规煅烧步骤，在600-950℃进行第二高温煅烧步骤。

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