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1. 发明授权

US5733999A Silicone compounds containing a phenylenediamine functional group and their application in the protection of rubber materials against ozone 失效
标题翻译：含有苯二胺官能团的硅氧烷化合物及其在保护橡胶材料中抵抗臭氧的应用
公开(公告)号：US5733999A
公开(公告)日：1998-03-31
申请号：US644028
申请日：1996-05-09
申请人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
发明人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
IPC分类号： C08G77/26 , C08G77/28 , C08G77/388 , C08G77/42 , C08G77/44 , C08L21/00 , C07F7/08
CPC分类号： C08G77/388 , C08L21/00 , C08L7/00 , C08L9/00
摘要： The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si--(hydrocarbon linking unit)--N and/or Si--(hydrocarbon linking unit)--C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.
摘要翻译：本发明涉及基本上由直链，环状或支化的聚有机硅氧烷组成的化合物，其每分子具有至少3个甲硅烷氧基单元，包括至少一个下式的式（I）的硅氧烷基官能单元：（R1）aXSi（O）+ E， a / 2 + EE，其中R1表示C1-C4烷基或苯基，X含有N，N'-二 - 和/或三取代苯二胺官能团，通过Si - （烃连接单元）-N 和/或Si-（烃连接单元）-C键，a是选自0,1和2的数字。本发明还涉及这种化合物作为橡胶的抗臭氧剂，特别是用于轮胎的橡胶组合物的用途。

2. 发明授权

US5929166A Silicone compounds containing a phenylenediamine functional group and their application in the protection of rubber materials against ozone 失效
标题翻译：含有苯二胺官能团的硅氧烷化合物及其在保护橡胶材料中抵抗臭氧的应用
公开(公告)号：US5929166A
公开(公告)日：1999-07-27
申请号：US979498
申请日：1997-11-26
申请人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
发明人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
IPC分类号： C08G77/26 , C08G77/28 , C08G77/388 , C08G77/42 , C08G77/44 , C08L21/00 , C08F8/30
CPC分类号： C08G77/388 , C08L21/00 , C08L7/00 , C08L9/00
摘要： The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si-(hydrocarbon linking unit)-N and/or Si-(hydrocarbon linking unit)-C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.
摘要翻译：本发明涉及基本上由直链，环状或支化的聚有机硅氧烷组成的化合物，其每分子具有至少3个甲硅烷氧基单元，包括至少一个下式的甲硅烷氧基官能单元：其中R 1表示C 1至C 4烷基或苯基，X 含有通过Si-（烃连接单元）-N和/或Si-（烃连接单元）-C键与硅结合的N，N'-二 - 和/或三取代的苯二胺官能团，a是本发明还涉及这种化合物作为橡胶的抗臭氧剂，特别是用于轮胎的橡胶组合物的用途。

3. 发明授权

US06372843B1 Method for preparing polyorganosiloxanes (POS) with thiol functions, POS obtainable by this method and their use particularly in rubber materials 失效
标题翻译：制备具有硫醇官能团的聚有机硅氧烷（POS）的方法，该方法可通过该方法得到并且特别用于橡胶材料中
公开(公告)号：US06372843B1
公开(公告)日：2002-04-16
申请号：US09462565
申请日：2000-04-19
申请人： Pierre Barruel , Yves Bomal , Nathalie Guennouni , Gerard Mignani , Christian Priou
发明人： Pierre Barruel , Yves Bomal , Nathalie Guennouni , Gerard Mignani , Christian Priou
IPC分类号： C08L8308
CPC分类号： C08K3/36 , C08G77/392 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L83/08 , C08L2205/03 , C08L2666/14
摘要： The present invention relates to a process for preparing multifunctionalized polyorganosiloxanes (POSs) comprising alkoxyl functional siloxyl units and siloxyl units each having an SH functional group, which consists in introducing the SH functional group by the reaction of H2S on a precursor POS of formula: A—(RXSiO)a—(RYSiO)b—B where R is especially a C1-C6 alkyl radical, X is a C1-C15 alkoxyl radical, Y is a C2-C30 hydrocarbon group which includes an ethylenically unsaturated group from which the SH functionality derives, a is a number ranging from 1 to 150, b is a number ranging from 1 to 150, the number a+b ranging from 2 to 300 and A and B are terminal groups which are selected respectively, from, in particular, on the one hand (R)3SiO— radicals taken alone or as mixtures with (R)2XSiO— and/or R(X)2SiO— and/or (X)3SiO— radicals and on the other hand —Si(R)3 radicals taken alone or as mixtures with —SiX(R)2 and/or —Si(X)2R and/or —Si(X)3 radicals.
摘要翻译：本发明涉及一种制备多官能化聚有机基硅氧烷（POSs）的方法，该多官能化聚有机硅氧烷（POSs）包含烷氧基官能硅氧烷单元和含有SH官能团的甲硅烷氧基单元，其包括通过H 2 S在式A的前体POS上反应引入SH官能团 - （RXSiO）a-（RYSiO）bB其中R特别是C 1 -C 6烷基，X是C 1 -C 15烷氧基，Y是C 2 -C 30烃基，其包括具有SH官能度的烯属不饱和基团 a为1〜150的数，b为1〜150的数，a + b的数量为2〜300，A，B为分别选择的端子组，特别是单独（R）3SiO-基单独或与（R）2 XSiO-和/或R（X）2SiO-和/或（X）3SiO-基团的混合物，另一方面-Si（R）3基团取代单独或作为与-SiX（R）2和/或-Si（X）2R和/或-Si（X）3基团的混合物）。

4. 发明授权

US5834613A Perhalogenated polyorganosiloxanes and the processes for their preparation 失效
标题翻译：全卤代聚有机硅氧烷及其制备方法
公开(公告)号：US5834613A
公开(公告)日：1998-11-10
申请号：US686400
申请日：1996-07-25
申请人： Philippe Jost , Philippe Karrer , Gerard Mignani , Philippe Olier
发明人： Philippe Jost , Philippe Karrer , Gerard Mignani , Philippe Olier
IPC分类号： C08L83/04 , C08G77/24 , C08G77/38 , C08G77/382 , C08G77/385 , C08G77/42 , C08L83/08 , C10M107/50 , C11D3/37 , C07F7/08 , C07F7/10
CPC分类号： C08G77/385 , C08G77/382
摘要： Chemically stable, perfluorinated, linear or cyclic polyorganosiloxanes (POS), and a process for the preparation thereof. Antifoams, agents for lowering surface tension, dirt repellents, antiadhesives, lubricants, oleophobic and/or hydrophobic agents, coatings and other compositions containing the perfluorinated POS are disclosed.
摘要翻译：化学稳定的全氟化，线性或环状聚有机硅氧烷（POS）及其制备方法。公开了消泡剂，降低表面张力的试剂，防污剂，抗粘合剂，润滑剂，疏油和/或疏水剂，包含全氟化POS的涂料和其它组合物。

5. 发明授权

US06555678B1 Method for preparing a regenerated cellulose fibre or yarn 失效
标题翻译：制备再生纤维素纤维或纱线的方法
公开(公告)号：US06555678B1
公开(公告)日：2003-04-29
申请号：US09530188
申请日：2000-09-25
申请人： Christian Allandrieu , Lucile Gambut , Philippe Karrer , Ties Karstens , Gerard Mignani , Armin Stein
发明人： Christian Allandrieu , Lucile Gambut , Philippe Karrer , Ties Karstens , Gerard Mignani , Armin Stein
IPC分类号： C08B1600
CPC分类号： D01F2/24 , D01F2/00
摘要： A method has been developed for making regenerated cellulose yarn. The method includes the steps of spinning a solution derived from cellulose or a cellulose derivative in a molten state through at least one extrusion die, then regenerating the cellulose by treating the resulting yarn, wherein a silylated cellulose derivative is prepared by reaction with a silylating agent; the silylated cellulose is extracted from the synthesis reaction medium; then spun through at least an extrusion die; and the resultant yarn treated with a desilylation agent to regenerate the cellulose and a siloxane. The resulting cellulose yarns or fibers may be used for making woven or knitted textile surfaces or non-woven surfaces. Said yarns or fibers are also useful as reinforcing fibers in elastomeric materials and more particularly, in tires.
摘要翻译：已经开发了用于制备再生纤维素纱线的方法。该方法包括以下步骤：通过至少一个挤出模头将来自纤维素或纤维素衍生物的溶液通过至少一个挤出模头纺丝，然后通过处理所得纱线再生纤维素，其中通过与甲硅烷基化试剂反应制备甲硅烷基化纤维素衍生物 ; 从合成反应介质中提取甲硅烷基化纤维素; 然后通过至少一个挤出模头旋转; 用脱甲基剂处理得到的纱线再生纤维素和硅氧烷。所得到的纤维素纱线或纤维可用于制造机织或针织织物表面或无纺织物表面。所述纱线或纤维也可用作弹性体材料中的增强纤维，更具体地，在轮胎中。

6. 发明授权

US5792825A Silicone compounds containing sterically hindered cyclic amine functional groups which are useful for the light and thermal stabilization of polymers 失效
标题翻译：含有空间位阻环状胺官能团的硅氧烷化合物，可用于聚合物的光稳定和热稳定性
公开(公告)号：US5792825A
公开(公告)日：1998-08-11
申请号：US661692
申请日：1996-06-11
申请人： Philippe Karrer , Gerard Mignani , Bernard Pontini , Storet Isabelle
发明人： Philippe Karrer , Gerard Mignani , Bernard Pontini , Storet Isabelle
IPC分类号： C07D491/113 , C07F7/08 , C08F283/12 , C08G77/388 , C08G77/42 , C08L101/00 , C08G77/04
CPC分类号： C08G77/388 , C07F7/0879 , C08L101/00
摘要： The present invention relates to linear, cyclic or branched polyorganosiloxanes having, per molecule, at least three siloxy units, including at least one functional unit of formula: ##EQU1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical and X contains a secondary or tertiary cyclic amine functional group bonded to the silicon via an Si--A--C bond where A is a residue comprising a cyclic acetal group. X more specifically represents a monovalent group of formula: ##STR1## The present invention also relates to the use of such polyorganosiloxanes in polymers for improving in particular their photostabilization.
摘要翻译：本发明涉及每分子具有至少三个甲硅烷氧基单元的直链，环状或支化的聚有机基硅氧烷，其包括至少一个下式的官能单元：其中R 1表示C 1至C 4烷基或苯基，X包含仲或通过Si-AC键与硅键合的叔环胺官能团，其中A是包含环状缩醛基团的残基。 X更具体地表示下式的单价基团：（II）本发明还涉及这种聚有机硅氧烷在聚合物中的用途，特别是其改善光稳定性。

7. 发明申请

US20130306917A1 QUINONE COMPOUNDS FOR USE IN PHOTOVOLTAIC APPLICATION 审中-公开
标题翻译：用于光伏应用的QUINONE化合物
公开(公告)号：US20130306917A1
公开(公告)日：2013-11-21
申请号：US13880283
申请日：2011-10-21
申请人： Floryan Decampo , Gerard Mignani , Bertrand Pavageau
发明人： Floryan Decampo , Gerard Mignani , Bertrand Pavageau
IPC分类号： H01L51/00
CPC分类号： H01L51/0032 , C07C255/37 , C07D333/24 , C08G61/124 , C08G61/126 , C08G73/00 , C08G2261/3223 , C08G2261/3241 , C08G2261/3422 , C09D5/24 , C09D7/63 , C09D179/00 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/0083 , H01L51/4253 , Y02E10/549 , Y02P70/521
摘要： The invention relates to a photovoltaic coating containing a mixture of organic N-type (acceptor) and P-type (donor) semiconductor compounds, which makes it possible, when selecting the donor/acceptor pair, to modulate the semiconductor properties of the photovoltaic coating so as to enable the use thereof within a photovoltaic device, wherein one of the organic semiconductors includes a quinone core.
摘要翻译：本发明涉及含有有机N型（受体）和P型（供体）半导体化合物的混合物的光伏涂层，这使得当选择供体/受体对时可以调节光伏涂层的半导体性质以使其能够在光电器件中使用，其中有机半导体之一包括醌核。

8. 发明申请

US20080255292A1 Process for preparing functionalized polyorganosiloxane resins by redistribution in the presence of triflic acid and/or of at least one derivative thereof and of a nonbasic inert filler 审中-公开
标题翻译：在三氟酸和/或其至少一种衍生物和非碱性惰性填料的存在下再分配制备官能化聚有机硅氧烷树脂的方法
公开(公告)号：US20080255292A1
公开(公告)日：2008-10-16
申请号：US12142318
申请日：2008-06-19
申请人： Fernande Boisson , Lucile Gambut , Gerard Mignani
发明人： Fernande Boisson , Lucile Gambut , Gerard Mignani
IPC分类号： C08L83/06 , C08K3/34
CPC分类号： C08G77/10 , C08G77/08
摘要： The invention provides a method for preparing functionalized polyorganosiloxane resins (POS) comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), wherein in said units R is C1-C10 alkyl or C8-C12 aryl and Y is a functional group (such as Si—H), by redistributing POS resins, using POSf bearing functional groups M′ and/or D′ and/or in the presence of an acid catalyst such as triflic acid or one of its derivatives and a non-basic inert filler: carbon black, diatomaceous earth, zeolite or acid or neutral oxide (Al2O3, Na2O, TiO2, MgO, silica). The invention also provides said catalyst system.
摘要翻译：本发明提供了一种制备官能化聚有机硅氧烷树脂（POS）的方法，所述聚有机硅氧烷树脂（POS）包含单元M：（R 3 SiO 2 1/2），Q：（SiO 4/2 ）和M'：（Y a a R 3-a SiO 1/2）和任选的D：（R SUB 和/或D'：（RYSiO 2/2/2）和T：（RS 3 O 3/2/2） SUB）和/或T'：（YSiO 3/2/2），其中在所述单元中R是C 1 -C 10烷基或 C 8 -C 12芳基，Y是官能团（如Si-H），通过重新分配POS树脂，使用具有POS的官能团M'和/或D 和/或在酸催化剂如三氟甲烷或其衍生物之一和非碱性惰性填料：碳黑，硅藻土，沸石或酸或中性氧化物（Al 2 O 3）存在下， O 3，Na 2 O，TiO 2，MgO，二氧化硅）。本发明还提供了所述催化剂体系。

9. 发明申请

US20050080215A1 Method for preparing polyorganosiloxanes (pos) by polycondensation/redistribution of oligosiloxanes in the presence of a strong base and strong bases used 审中-公开
标题翻译：在强碱和强碱的存在下，通过缩聚/再分布低聚硅氧烷制备聚有机硅氧烷（pos）的方法
公开(公告)号：US20050080215A1
公开(公告)日：2005-04-14
申请号：US10497756
申请日：2002-12-13
申请人： Antoire Baceiredo , Guy Bertrand , Alla Lemeune , Gerard Mignani
发明人： Antoire Baceiredo , Guy Bertrand , Alla Lemeune , Gerard Mignani
IPC分类号： C07F9/535 , C07F9/54 , C08G77/08 , C08G77/06
CPC分类号： C07F9/5463 , C07F9/5352 , C07F9/54 , C08G77/08
摘要： The invention concerns the synthesis of silicone by anionic polymerisation of cyclic organosiloxane oligomers in the presence of a slightly nucleophilic strong base. The invention aims at providing novel strong base catalysts, more efficient in terms of solubility in the silicones, with hydrolysis stability strength and polymerising capacity. To achieve this, the invention provides for the use of ylides derived from aminophosphonium such as for example that of formula: [Me3N)3P—CHMe2]+, MeO or derived from phosphoranylidenes such as that of formula: [Me3P—HC=Pme3]+, t-BuO. The invention also concerns strong base catalysts as novel products.
摘要翻译：本发明涉及通过在轻微亲核的强碱存在下通过环状有机硅氧烷低聚物的阴离子聚合来合成硅氧烷。本发明旨在提供新的强碱催化剂，在硅氧烷中的溶解度方面更有效，具有水解稳定性强度和聚合能力。为了实现这一点，本发明提供了使用衍生自氨基鏻的内鎓盐，例如式：[Me 3 N）3 P-CHMe 2] +，MeO或衍生自如下式的亚正膦的衍生物：[Me 3 P-HC = Pme 3] +，t-BuO。本发明还涉及作为新产品的强碱催化剂。

10. 发明授权

US5189134A Nonlinearly optically active polymers 失效
标题翻译：非线性光学活性聚合物
公开(公告)号：US5189134A
公开(公告)日：1993-02-23
申请号：US408382
申请日：1989-09-18
申请人： Gerard Mignani , Pascal Barthelemy , Remi Meyrueix
发明人： Gerard Mignani , Pascal Barthelemy , Remi Meyrueix
IPC分类号： G02F1/35 , C08G18/00 , C08G18/30 , C08G18/32 , C08G18/67 , C08G83/00 , C08L101/00 , C09K19/38 , G02F1/355 , G02F1/361
CPC分类号： G02F1/3617 , C08G18/676 , C08G18/678 , C09K19/3885
摘要： Novel nonlinearly optically active polymers, well suited for electrooptical applications, are prepared by copolymerizing a first difunctional monomer with a second difunctional comonomer, with at least one of such difunctional monomers including a polar charge transfer moiety containing at least one electron acceptor group and at least one electron donor group (D), and further wherein the polymerizable functional groups are borne by the one or more electron donor groups (D).
摘要翻译：通过将第一双官能单体与第二双官能共聚单体共聚合而制备的新型非线性光学活性聚合物与至少一种这样的双官能单体包括含有至少一个电子受体基团的极性电荷转移部分和至少一个电子给体基团（D），其中可聚合官能团由一个或多个电子给体基团（D）承载。

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