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1. 发明申请

US20100147191A1 FLUORINE-CONTAINING ACRYLATE 有权
标题翻译：含氟丙烯酸酯
公开(公告)号：US20100147191A1
公开(公告)日：2010-06-17
申请号：US12619135
申请日：2009-11-16
申请人： Yasunori SAKANO , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori SAKANO , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C09D4/00 , C07F7/10
CPC分类号： C08G77/045 , C07F7/21 , C08F220/22 , C08F220/24 , C08F230/08 , C08G18/61 , C08G18/8116 , C08G77/38 , C08G77/388 , C09D175/16
摘要： The present invention is a fluorine-containing acrylate or alpha-substituted, fluorine-containing acrylate, represented by the following formula (1): wherein a is an integer of from 1 to 4 and b is an integer of from 1 to 4, provided that a total of a and b is 3, 4, or 5;R1 is a group represented by the following formula (2): —(C4H8O)d(C3H6O)e(C2H4O)f(CH2O)g— (2) wherein d, e, f, and g are, independently of each other, an integer of from 0 to 4, provided that a molecular weight of R1 is in a range of 30 to 300, andthese repeating units may be sequenced at random;R2 is an acryl group- or alpha-substituted acryl group-containing group having 4 to 20 carbon atoms and represented by the following formula (3): wherein R3 is, independently of each other, a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group,R4 is a divalent or trivalent linking moiety having 1 to 18 carbon atoms, optionally having an ether bond and/or an ester bond, andn is 1 or 2;Rf is a perfluoropolyether residue represented by the following formula (4): wherein j, k, l, and m are, independently of each other, an integer of from 0 to 50, provided that a molecular weight of Rf is in a range of 200 to 6000,X is a fluorine atom or a trifluoromethyl group, andthese repeating units may be sequenced at random;Z is a divalent organic group; andc is 0 or 1.
摘要翻译：本发明是由下式（1）表示的含氟丙烯酸酯或α-取代的含氟丙烯酸酯，其中a为1〜4的整数，b为1〜4的整数，总共a和b为3,4或5; R1是由下式（2）表示的基团： - （C4H8O）d（C3H6O）e（C2H4O）f（CH2O）g-（2）其中d，e，f和g彼此独立地是如果R1的分子量在30〜300的范围内，则0〜4的整数，这些重复单元可以随机排列; R2是具有4〜20个碳原子的丙烯酰基或α-取代的含丙烯酰基的基团，由下式（3）表示：其中R 3彼此独立地为氢原子，氟原子，甲基基团或三氟甲基，R 4是具有1至18个碳原子的二价或三价连接部分，任选具有醚键和/或酯键，n为1或2; Rf是由下式（4）表示的全氟聚醚残基：其中j，k，l和m彼此独立地为0至50的整数，条件是Rf的分子量在 200〜6000，X为氟原子或三氟甲基，这些重复单元可以随机排列; Z是二价有机基团; c为0或1。

2. 发明申请

US20120077041A1 FLUOROOXYALKYLENE GROUP-CONTAINING POLYMER COMPOSITION, A SURFACE TREATMENT AGENT COMPRISING THE SAME AND AN ARTICLE TREATED WITH THE AGENT 有权
标题翻译：包含含氟聚合物的含聚合物组合物，包含该聚合物组合物的表面处理剂和与该试剂一起处理的物品
公开(公告)号：US20120077041A1
公开(公告)日：2012-03-29
申请号：US13226987
申请日：2011-09-07
申请人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
发明人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C08L71/00 , C08L67/00 , B32B27/32 , C09D171/00
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

3. 发明申请

US20100317875A1 PERFLUOROPOLYETHER GROUP-CONTAINING ACRYLATE COMPOUND 有权
标题翻译：全氟聚醚基团含丙烯酸酯化合物
公开(公告)号：US20100317875A1
公开(公告)日：2010-12-16
申请号：US12797103
申请日：2010-06-09
申请人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07D307/04 , C07F7/10
CPC分类号： C08G77/50 , C07F7/21 , C08F230/08 , C08G77/388 , C08G77/46 , C09D183/12 , C09D183/14
摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1 (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.
摘要翻译：本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

4. 发明授权

US08900711B2 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译：含有含氟氧化烯基的聚合物组合物，包含该组合物的表面处理剂和用该试剂处理的制品
公开(公告)号：US08900711B2
公开(公告)日：2014-12-02
申请号：US13226987
申请日：2011-09-07
申请人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
发明人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C08L71/00 , C08G65/336 , C08G65/00 , C08G77/24 , C08G77/46 , C09D171/02
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

5. 发明授权

US08283480B2 Perfluoropolyether group-containing acrylate compound 有权
标题翻译：含全氟聚醚基团的丙烯酸酯化合物
公开(公告)号：US08283480B2
公开(公告)日：2012-10-09
申请号：US12797103
申请日：2010-06-09
申请人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07F7/21 , C07F7/08 , C07F7/10
CPC分类号： C08G77/50 , C07F7/21 , C08F230/08 , C08G77/388 , C08G77/46 , C09D183/12 , C09D183/14
摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1 (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.
摘要翻译：本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

6. 发明授权

US07781604B2 Fluorine-containing acrylate 有权
标题翻译：含氟丙烯酸酯
公开(公告)号：US07781604B2
公开(公告)日：2010-08-24
申请号：US12619135
申请日：2009-11-16
申请人： Yasunori Sakano , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07C7/10
CPC分类号： C08G77/045 , C07F7/21 , C08F220/22 , C08F220/24 , C08F230/08 , C08G18/61 , C08G18/8116 , C08G77/38 , C08G77/388 , C09D175/16
摘要： The present invention is a fluorine-containing acrylate or alpha-substituted, fluorine-containing acrylate, represented by the following formula (1): wherein a is an integer of from 1 to 4 and b is an integer of from 1 to 4, provided that a total of a and b is 3, 4, or 5; R1 is a group represented by the following formula (2): —(C4H8O)d(C3H6O)e(C2H4O)f(CH2O)g— (2) wherein d, e, f, and g are, independently of each other, an integer of from 0 to 4, provided that a molecular weight of R1 is in a range of 30 to 300, and these repeating units may be sequenced at random; R2 is an acryl group- or alpha-substituted acryl group-containing group having 4 to 20 carbon atoms and represented by the following formula (3): wherein R3 is, independently of each other, a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group, R4 is a divalent or trivalent linking moiety having 1 to 18 carbon atoms, optionally having an ether bond and/or an ester bond, and n is 1 or 2; Rf is a perfluoropolyether residue represented by the following formula (4): wherein j, k, l, and m are, independently of each other, an integer of from 0 to 50, provided that a molecular weight of Rf is in a range of 200 to 6000, X is a fluorine atom or a trifluoromethyl group, and these repeating units may be sequenced at random; Z is a divalent organic group; and c is 0 or 1.
摘要翻译：本发明是由下式（1）表示的含氟丙烯酸酯或α-取代的含氟丙烯酸酯，其中a为1〜4的整数，b为1〜4的整数，总共a和b为3,4或5; R1是由下式（2）表示的基团： - （C4H8O）d（C3H6O）e（C2H4O）f（CH2O）g-（2）其中d，e，f和g彼此独立地是如果R1的分子量在30〜300的范围内，则0〜4的整数，这些重复单元可以随机排列; R2是具有4〜20个碳原子的丙烯酰基或α-取代的含丙烯酰基的基团，由下式（3）表示：其中R 3彼此独立地为氢原子，氟原子，甲基基团或三氟甲基，R 4是具有1至18个碳原子的二价或三价连接部分，任选具有醚键和/或酯键，n为1或2; Rf是由下式（4）表示的全氟聚醚残基：其中j，k，l和m彼此独立地为0至50的整数，条件是Rf的分子量在 200〜6000，X为氟原子或三氟甲基，这些重复单元可以随机排列; Z是二价有机基团; c为0或1。

7. 发明授权

US06552152B2 Curable fluoropolyether rubber compositions 有权
公开(公告)号：US06552152B2
公开(公告)日：2003-04-22
申请号：US09893603
申请日：2001-06-29
申请人： Yasunori Sakano , Shinichi Sato , Koichi Yamaguchi , Noriyuki Koike , Masatoshi Arai , Hirofumi Kishita
发明人： Yasunori Sakano , Shinichi Sato , Koichi Yamaguchi , Noriyuki Koike , Masatoshi Arai , Hirofumi Kishita
IPC分类号： C08G7712
CPC分类号： C08G65/336 , C08G65/007
摘要： A curable fluoropolyether rubber composition comprising (A) a straight-chain fluoropolyether compound having at least two alkenyl groups and a perfluoropolyether structure backbone, (B) an organosilicon compound having at least two silicon atom-bonded hydrogen atoms, which all form H—SiCH2— structures, and (C) a hydrosilylation catalyst cures into parts which have good heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency and weather resistance as well as improved acid and alkali resistance and are useful as sealants.

8. 发明授权

US08420763B2 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译：含有含氟氧化烯基的聚合物组合物，包含该组合物的表面处理剂和用该试剂处理的制品
公开(公告)号：US08420763B2
公开(公告)日：2013-04-16
申请号：US12911890
申请日：2010-10-26
申请人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
发明人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C08G77/24
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.
摘要翻译：本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性，良好的耐污染性，并提供包含该表面处理剂的表面处理剂。本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

9. 发明授权

US08362186B2 Coating composition and a coating therefrom having waterdrop sliding property 有权
标题翻译：涂料组合物及其具有水滑滑性的涂层
公开(公告)号：US08362186B2
公开(公告)日：2013-01-29
申请号：US12167873
申请日：2008-07-03
申请人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
发明人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/24
CPC分类号： C08L83/12 , C09D183/12 , Y10T428/31663
摘要： A coating composition comprising a fluorine-containing silicon compound represented by the following formula (1) wherein Z is a linear or branched divalent polyorganosiloxane residue having 1 to 40 siloxane units, R is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, Q is a C2-12 divalent connecting group, a is an integer of 2 or 3, b is an integer of from 1 to 10, y is an integer of 1 to 5, and Rf is a group represented by the following formula (2) -Rf1-(Q-W-Q-Rf1)q- (2) wherein Rf1 is a perfluoropolyether residue, W is an organopolysiloxane residue having 1 to 40 siloxane units and Q is as defined above and may be the same with or different from each other, and q is an integer of from 0 to 3, and at least one solvent selected from the group consisting of alcohols, esters, ethers, ketones, and perfluoroethers. The coating prepared from the composition is oil-repellent, water-repellent and has water sliding property.
摘要翻译：一种涂料组合物，其包含由下式（1）表示的含氟硅化合物，其中Z为具有1至40个硅氧烷单元的直链或支链二价聚有机硅氧烷残基，R为具有1至4个碳原子的烷基或苯基 X为水解性基团，Q为C2-12二价连接基团，a为2或3的整数，b为1〜10的整数，y为1〜5的整数，Rf为基团由下式（2）-Rf1-（QWQ-Rf1）q-（2）表示，其中Rf1是全氟聚醚残基，W是具有1至40个硅氧烷单元的有机聚硅氧烷残基，Q如上定义并且可以相同 q为0〜3的整数，以及选自醇，酯，醚，酮，全氟醚中的至少一种溶剂。由该组合物制备的涂料具有防油，防水，具有水滑动性。

10. 发明申请

US20110098402A1 FLUOROOXYALKYLENE GROUP-CONTAINING POLYMER COMPOSITION, A SURFACE TREATMENT AGENT COMPRISING THE SAME AND AN ARTICLE TREATED WITH THE AGENT 有权
标题翻译：包含含氟聚合物的含聚合物组合物，包含该聚合物组合物的表面处理剂和与该试剂一起处理的物品
公开(公告)号：US20110098402A1
公开(公告)日：2011-04-28
申请号：US12911890
申请日：2010-10-26
申请人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
发明人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C09D127/12
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.
摘要翻译：本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性，良好的耐污染性，并提供包含该表面处理剂的表面处理剂。本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

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