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    • 1. 发明授权
    • Coating compositions
    • 涂料组合物
    • US09080059B2
    • 2015-07-14
    • US13817015
    • 2011-09-13
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner, Jr.
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner, Jr.
    • B32B15/092B32B27/38C09D163/00C08G59/24B05D3/02C09D5/00C08G59/06
    • C09D5/00C08G59/066C08L2205/05C09D163/00C08L33/02C08L67/00
    • A coating composition comprising an advanced epoxy resin polymeric composition having the following chemical structure:(formula) I where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); R′1-R′4 are independently hydrogen, an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent, for example, a nitro, an isocyanate, or an alkyloxy group; additionally, any two of R′1-R′4 may form fused ring independently; and X is cycloalkylene group, including substituted cycloalkylene group, where the substituent groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halide, a cyano, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
    • 一种涂料组合物,其包含具有以下化学结构的高级环氧树脂聚合物组合物:(式)I,其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基(饱和二价脂族烃基); R'1-R'4独立地为氢,烷基,环烷基,芳基或芳烷基或其它取代基,例如硝基,异氰酸酯基或烷氧基; 此外,R'1-R'4中的任何两个可以独立地形成稠环; 并且X是亚环烷基,包括取代的亚环烷基,其中取代基包括烷基,环烷基,芳基或芳烷基或其它取代基,例如卤素,氰基,硝基,封端异氰酸酯或 烷氧基 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。
    • 3. 发明申请
    • COATING COMPOSITIONS
    • 涂料组合物
    • US20130178584A1
    • 2013-07-11
    • US13816772
    • 2011-09-20
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner, JR.
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner, JR.
    • C09D167/02
    • C09D167/025C08G59/066C08G59/4223C08L2205/05C09D163/00C09D167/02C08L33/02C08L67/00
    • A coating composition comprising an advanced poly epoxy ester resin polymeric composition having the following chemical structure: where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); Ar is a divalent aromatic fused-ring moiety, which is most preferably a divalent naphthalene group, substituted divalent naphthalene group, where the substitute groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent; and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
    • 一种涂料组合物,其包含具有以下化学结构的先进的聚环氧酯树脂聚合物组合物:其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基(饱和二价脂族烃基); Ar是二价芳香稠环部分,其中最优选二价萘基,取代二价萘基,其中取代基包括烷基,环烷基,芳基或芳烷基或其它取代基; X是亚环烷基,包括取代的亚环烷基,其中取代基包括烷基,环烷基,芳基或芳烷基或其它取代基,例如卤素,硝基,封端异氰酸酯或烷氧基; 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。
    • 5. 发明申请
    • COATING COMPOSITIONS
    • 涂料组合物
    • US20130143982A1
    • 2013-06-06
    • US13817015
    • 2011-09-13
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner
    • C09D5/00
    • C09D5/00C08G59/066C08L2205/05C09D163/00C08L33/02C08L67/00
    • A coating composition comprising an advanced epoxy resin polymeric composition having the following chemical structure:(formula) I where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); R′1—R′4 are independently hydrogen, an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent, for example, a nitro, an isocyanate, or an alkyloxy group; additionally, any two of R′1-R′4 may form fused ring independently; and X is cycloalkylene group, including substituted cycloalkylene group, where the substituent groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halide, a cyano, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
    • 一种涂料组合物,其包含具有以下化学结构的高级环氧树脂聚合物组合物:(式)I,其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基(饱和二价脂族烃基); R'1-R'4独立地为氢,烷基,环烷基,芳基或芳烷基或其它取代基,例如硝基,异氰酸酯基或烷氧基; 此外,R'1-R'4中的任何两个可以独立地形成稠环; 并且X是亚环烷基,包括取代的亚环烷基,其中取代基包括烷基,环烷基,芳基或芳烷基或其它取代基,例如卤素,氰基,硝基,封端异氰酸酯或 烷氧基 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。
    • 9. 发明申请
    • COATING COMPOSITION AND ARTICLES MADE THEREFROM
    • 涂料组合物及其制品
    • US20110171481A1
    • 2011-07-14
    • US13039138
    • 2011-03-02
    • Bernhard KainzCharles F. DiehlTimothy J. YoungDavid L. MalotkyDenise Lindenmuth
    • Bernhard KainzCharles F. DiehlTimothy J. YoungDavid L. MalotkyDenise Lindenmuth
    • B32B27/36C08L67/00C09D167/00B05D3/00B05D5/00B05D7/24
    • C08J7/047C08J3/05C08J2367/00C08J2423/00C08L67/00C08L2205/02C09D167/00Y10T428/31786C08L2666/18
    • The instant invention provides an aqueous dispersion, a coating composition, coating layers and coated article made therefrom. The coating composition according to the present invention comprises: (1) the inventive aqueous dispersion comprising the melt blending product of: (a) from 50 to 99 percent by weight of one or more first polyesters, based on the total solid content of the dispersion, wherein said one or more first polyesters have an acid number in the range of from less than 15, for example less than 10, or in the alternative less than 5, based on the total solid content of the one or more first polyesters; (b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number equal to or greater than 15, for example greater than 20, based on the solid content of the second polyester; (c) one or more neutralizing agents; and (d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion; wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion; and (2) one or more cross-linking agents.
    • 本发明提供一种水性分散体,一种涂料组合物,由其制成的涂层和涂层制品。 根据本发明的涂料组合物包括:(1)本发明的水性分散体,其包含熔融共混产物:(a)50至99重量%的一种或多种第一聚酯,基于分散体的总固体含量 ,其中所述一种或多种第一聚酯的酸值在小于15,例如小于10,或者以小于5为基准,基于一种或多种第一聚酯的总固体含量; (b)1至50重量%的一种或多种包含至少一种第二聚酯的稳定剂,基于分散体的总固体含量,其中所述第二聚酯具有羧酸基,酸值等于或大于 基于第二聚酯的固体含量,例如大于20,例如大于20; (c)一种或多种中和剂; 和(d)基于分散体的总重量的15至90重量%的水; 其中所述分散体的固体含量为10至85%,基于分散体的总重量; 和(2)一种或多种交联剂。