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1. 发明授权

US4886916A Process for preparing sulfone compounds 失效
标题翻译：砜类化合物的制备方法
公开(公告)号：US4886916A
公开(公告)日：1989-12-12
申请号：US168408
申请日：1988-03-15
申请人： Takashi Onishi , Shigeaki Suzuki , Toshiki Mori , Hiroshi Fujii , Yoshiji Fujita
发明人： Takashi Onishi , Shigeaki Suzuki , Toshiki Mori , Hiroshi Fujii , Yoshiji Fujita
IPC分类号： C07C20060101 , C07C317/04 , C07C317/14
CPC分类号： C07C317/00
摘要： A process for preparing an allylic sulfone of the following general formula (I), ##STR1## wherein, R is a hydrogen atom or a lower alkyl group, and containing both cis and trans isomers, by a reaction of a compound selected from the group consisting of geranyl chloride, neryl chloride, and linalyl chloride with a phenyl sulfinate of the following general formula (III), ##STR2## wherein, R is a hydrogen atom, or a lower alkyl group, and M is a sodium atom or potassium atom, in the presence of (i) tetralkylammonium iodide in an anhydrous condition or (ii) a zinc halide and an iodide.

2. 发明授权

US4827056A Process for preparing chlorinated olefins 失效
标题翻译：氯化烯烃的制备方法
公开(公告)号：US4827056A
公开(公告)日：1989-05-02
申请号：US164917
申请日：1988-03-07
申请人： Shigeaki Suzuki , Toshiki Mori , Takashi Onishi , Yoshiji Fujita
发明人： Shigeaki Suzuki , Toshiki Mori , Takashi Onishi , Yoshiji Fujita
IPC分类号： C07C17/00 , C07C17/02 , C07C17/10 , C07C21/04 , C07C21/19 , C07C22/04 , C07C41/00 , C07C41/22 , C07C43/17 , C07C43/174 , C07C67/00 , C07C67/287 , C07C69/025
CPC分类号： C07C17/00 , C07C41/22 , C07C67/287 , C07C67/58
摘要： Chlorinated olefins of general formula (I), ##STR1## wherein R is an alkyl, aralkyl, or alkenyl group substituted or not substituted by a lower acyloxy, lower alkyloxy, alkenyloxy or benzyloxy group, are prepared by the reaction of hypochlorous acid, generated by the reaction of sodium hypochlorite with a strong mineral acid, and olefins of general formula (II), ##STR2## wherein R is the same as defined above, in a two-phase system of water phase and organic solvent phase, not being miscible with water.

3. 发明授权

US4924030A Process for preparing cyclic terpenoids 失效
标题翻译：制备环状萜类化合物的方法
公开(公告)号：US4924030A
公开(公告)日：1990-05-08
申请号：US164909
申请日：1988-03-07
申请人： Takashi Onishi , Shigeaki Suzuki , Toshiki Mori , Yoshiji Fujita
发明人： Takashi Onishi , Shigeaki Suzuki , Toshiki Mori , Yoshiji Fujita
IPC分类号： C07C315/04 , C07B37/08 , C07C20060101 , C07C67/00 , C07C313/00 , C07C315/06 , C07C317/14
CPC分类号： C07C317/00
摘要： A present invention provides a process for preparing a mixture of cyclic terpenoids of general formula (I), ##STR1## wherein R is a hydrogen atom or a lower alkyl group, and general formula (II), ##STR2## wherein R is defined as above, containing (I) predominant over (II) by the reaction of an acid with a cyclic terpenoid of general formula (II), or a mixture of cyclic terpenoids of general formulas (I) and (II), containing (II) predominant over (I).

4. 发明授权

US4603208A Certain polyprenyl intermediates 失效
标题翻译：某些聚异戊烯中间体
公开(公告)号：US4603208A
公开(公告)日：1986-07-29
申请号：US465483
申请日：1983-02-10
申请人： Takashi Onishi , Shigeaki Suzuki , Fumio Mori , Tetsuo Takigawa , Yoshiji Fujita , Masao Mizuno , Takashi Nishida
发明人： Takashi Onishi , Shigeaki Suzuki , Fumio Mori , Tetsuo Takigawa , Yoshiji Fujita , Masao Mizuno , Takashi Nishida
IPC分类号： C07C69/767 , C07C317/00 , C07C317/24 , C07D213/70 , C07D213/71 , C07D309/12 , C07D317/18 , C07D405/12 , C07D417/12 , C07F7/18 , C07C69/78 , C07C147/103
CPC分类号： C07D405/12 , C07C317/00 , C07C321/00 , C07D309/12 , C07D317/18 , C07D417/12 , C07F7/1852
摘要： Novel polyprenyl compounds have the general formula: ##STR1## represents a cis-isoprene unit, n is an integer of 11-19, Z.sup.1 is --CH.sub.2 OH or a functional precursor thereof, and either one of R.sup.1 and R.sup.2 is a hydrogen atom and the other is --S(O).sub.m R.sup.3 in which m is an integer of 0 (zero), 1 or 2 and R.sup.3 is a phenyl, naphthyl, pyridyl or thiazolinyl group or such group substituted with at least one lower alkyl and/or halogen substituent. The topic novel polyprenyl compounds can be synthesized from derivatives of the polyprenol which is obtainable from leaves of Ginkgo biloba or Cedrus deodara, among others, by extraction, if necessary followed by hydrolytic treatment. The novel polyprenyl compounds can be converted to mammalian dolichols or precursors thereof by reductive elimination of the --S(O).sub.m R.sup.3 group.
摘要翻译：新颖的聚异戊二烯化合物具有以下通式：其中n为11〜19的整数，Z 1为-CH 2 OH的整数，或其功能性前体，R 1和R 2中的任一个是氢原子，另一个是-S（O）m R 3，其中m是0（0），1或2的整数，并且R 3是苯基，萘基，吡啶基或噻唑啉基或该基团被至少一个低级烷基和/或卤素取代基取代。主题新颖的聚异戊二烯基化合物可以由聚乙二醇的衍生物合成，其可以通过提取，如果需要然后进行水解处理，可以从银杏叶或塞德斯酵母的叶获得。新的聚异戊烯基化合物可以通过-S（O）m R 3基团的还原性消除而转化为哺乳动物多烯醇或其前体。

5. 发明授权

US4745229A Process for preparing .alpha., .beta.-unsaturated aldehydes 失效
标题翻译：制备α，β-不饱和醛的方法
公开(公告)号：US4745229A
公开(公告)日：1988-05-17
申请号：US15095
申请日：1987-02-13
申请人： Junzo Otera , Shigeaki Suzuki , Takashi Onishi , Yoshiji Fujita
发明人： Junzo Otera , Shigeaki Suzuki , Takashi Onishi , Yoshiji Fujita
IPC分类号： C07C45/27 , C07C45/28 , C07C45/56 , C07C47/21 , C07C69/145
CPC分类号： C07C47/21 , C07C45/27 , C07C45/28 , C07C45/56 , C07C67/29
摘要： A process for preparing .alpha.,.beta.-unsaturated aldehydes of the general formula (I) ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are independently a hydrogen atom, or an alkyl or alkenyl group with or without being substituted with a lower acyloxy group. The aldehyde of the general formula (I) is prepared by reaction between an allylic chloride of the following general formula (IIa) ##STR2## in which R.sup.1, R.sup.2 and R.sup.3 have, respectively, the same meanings as defined above, and an amine oxide selected from the group consisting of tri(lower alkyl)amine N-oxides of the formula,R.sub.3.sup.4 N.sup.+ O.sup.-,in which R.sup.4 represents a lower alkyl group having from 2 to 4 carbon atoms, and N-lower alkylmorpholine N-oxides of the following formula ##STR3## in which R.sup.5 represents a lower alkyl group having from 1 to 4 carbon atoms. Alternatively, the aldehyde of the formula (I) is obtained by reaction between an allylic chloride of the following general formula (IIb) ##STR4## in which R.sup.1, R.sup.2 and R.sup.3 have, respectively, the same meanings as defined above, and an amine oxide selected from the group consisting of tri(lower alkyl)amine N-oxides of the formula,R.sub.3.sup.4 N.sup.+ O.sup.-,in which R.sup.4 has the same meaning as defined above, and N-lower alkylmorpholine N-oxides of the following formula ##STR5## in which R.sup.5 has the same meaning as defined above, in the presence of an alkali metal iodide or a copper halide.
摘要翻译：制备通式（I）的α，β-不饱和醛的方法，其中R 1，R 2和R 3独立地为氢原子，或具有或不具有低级烷基或烯基的烷基或烯基酰氧基。通式（I）的醛通过以下通式（IIa）的烯丙基氯与其中R 1，R 2和R 3分别具有与上述相同的含义和选自下列的三（低级烷基）胺N-氧化物的氧化胺，其中R 4表示具有2至4个碳原子的低级烷基的式R 34 N + O-，和N-低级烷基吗啉N- 下式“IMAGE”的氧化物，其中R 5表示具有1至4个碳原子的低级烷基。或者，式（I）的醛通过以下通式（IIb）的烯丙基氯（IIb）（其中R1，R2和R3分别具有与上述相同的含义）和选自下式的三（低级烷基）胺N-氧化物的氧化胺，其中R 4具有与上述相同的含义的R 34 N + O-，以及下述的N-低级烷基吗啉N-氧化物在碱金属碘化物或卤化铜存在下，其中R 5具有与上述相同的含义的式“IMAGE”。

6. 发明授权

US5053552A Process for producing .alpha.,.beta.-unsaturated aldehyde 失效
标题翻译：生产（ALPHA），（BETA） - 饱和二醛的方法
公开(公告)号：US5053552A
公开(公告)日：1991-10-01
申请号：US537617
申请日：1990-06-14
申请人： Toshiki Mori , Shigeaki Suzuki , Takashi Onishi , Kazuo Yamamoto
发明人： Toshiki Mori , Shigeaki Suzuki , Takashi Onishi , Kazuo Yamamoto
IPC分类号： C07D521/00 , B01J31/02 , C07B61/00 , C07C45/27 , C07C45/54 , C07C45/72 , C07C47/21 , C07C47/225 , C07C47/232 , C07C47/277 , C07C47/38 , C07C69/07
CPC分类号： C07C45/27 , C07C45/54
摘要： The present invention provides a novel process for producing .alpha.,.beta.-unsaturated aldehydes including industrial important fragrances such as citral and sinensal, starting materials for preparing pharmaceutical drugs such as senecioaldehyde, farnesal, 8-acetoxy-2,6-dimethyl-2,6-octadienal and the like, directly and in high yield, from formic acid esters of allylic alcohols in the presence of a catalytic amount of aluminum alkoxide by the oxidation of the corresponding alehyde.

7. 发明授权

US4947001A Process for producing halogenated sulfone 失效
标题翻译：卤代砜生产工艺
公开(公告)号：US4947001A
公开(公告)日：1990-08-07
申请号：US364154
申请日：1989-06-12
申请人： Takashi Onishi , Toshiki Mori , Shigeaki Suzuki , Michio Takigawa , Kazuo Yamamoto
发明人： Takashi Onishi , Toshiki Mori , Shigeaki Suzuki , Michio Takigawa , Kazuo Yamamoto
IPC分类号： C07C315/04 , C07C20060101 , C07C317/08 , C07C317/22 , C07C403/06 , C07C403/22
CPC分类号： C07C403/22 , C07C403/08 , C07C403/12 , C07C2101/16
摘要： The present invention provides a process for preparing halogenated sulfones by reacting a halogenating agent with a salt of a hydroxysulfone. The halogenated sulfones are useful as an intermediate for vitamin A or its carboxylic acid esters employed as medicines or feed additives.

8. 发明授权

US4942262A Process for producing vitamin A or its carboxylic acid esters 失效
标题翻译：生产维生素A或其羧酸酯的方法
公开(公告)号：US4942262A
公开(公告)日：1990-07-17
申请号：US368800
申请日：1989-06-20
申请人： Toshiki Mori , Shigeaki Suzuki , Takashi Onishi
发明人： Toshiki Mori , Shigeaki Suzuki , Takashi Onishi
IPC分类号： C07C20060101 , C07C317/14 , C07C403/06 , C07C403/08 , C07C403/12
CPC分类号： C07C403/08 , C07C403/12 , C07C403/22 , C07C2101/16
摘要： The invention provides a process for producing vitamin A or its carboxylic acid ester by treating inexpensive and readily available industrial starting materials with potassium hydroxide which is widely employed industrially and is inexpensive.

9. 发明授权

US5118833A Process for producing .alpha.-keto-carboxylic acid ester 失效
标题翻译：制备（ALPHA） - 羧酸 - 羧酸酯的方法
公开(公告)号：US5118833A
公开(公告)日：1992-06-02
申请号：US537647
申请日：1990-06-14
申请人： Toshiki Mori , Shigeaki Suzuki , Takashi Onishi , Kazuo Yamamoto
发明人： Toshiki Mori , Shigeaki Suzuki , Takashi Onishi , Kazuo Yamamoto
IPC分类号： B01J31/02 , C07B41/06 , C07B61/00 , C07C67/313 , C07C69/716 , C07C69/738
CPC分类号： C07C69/716 , C07C67/313 , C07C69/738
摘要： The invention provides a novel process for produing .alpha. -keto-carboxylic acid esters that are useful as intermediates for the preparation of pharmaceutical drugs in high yield by oxidizing .alpha. -hydroxycarbocylic acid esters with hypochlorous acid in the presence of nitroxy radical.

10. 发明授权

US5312978A Process for producing vitamin A acid 失效
标题翻译：生产维生素A酸的方法
公开(公告)号：US5312978A
公开(公告)日：1994-05-17
申请号：US34910
申请日：1993-03-19
申请人： Toshiki Mori , Hiroshi Fujii , Takashi Onishi , Yoshin Tamai
发明人： Toshiki Mori , Hiroshi Fujii , Takashi Onishi , Yoshin Tamai
IPC分类号： B01J27/16 , C07B61/00 , C07C51/29 , C07C403/20
CPC分类号： C07C403/14 , C07C403/20 , C07C2101/16
摘要： A process for producing vitamin A acid, having useful biological activity, which comprises oxidizing vitamin A aldehyde with an aqueous solution of an alkali metal chlorite in the presence of an acid.
摘要翻译：一种生产具有有用生物活性的维生素A酸的方法，其包括在酸存在下用亚氯酸碱金属盐水溶液氧化维生素A醛。

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