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1. 发明申请

US20090291845A1 CONVERSION OF A PRECATALYST TO A CATALYTICALLY ACTIVE SILVER-VANADIUM OXIDE BRONZE 审中-公开
标题翻译：预处理对催化活性银 - 氧化钒的转化
公开(公告)号：US20090291845A1
公开(公告)日：2009-11-26
申请号：US12158858
申请日：2006-12-20
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck , Jürgen Zühlke
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck , Jürgen Zühlke
IPC分类号： B01J21/18
CPC分类号： B01J23/682 , B01J23/002 , B01J23/96 , B01J27/198 , B01J35/0006 , B01J35/002 , B01J37/0018 , B01J37/0219 , B01J37/0223 , B01J37/08 , B01J2523/00 , C01G31/006 , C01P2002/72 , C01P2006/12 , C07C51/265 , C07C51/313 , Y02P20/584 , C07C63/16 , B01J2523/18 , B01J2523/3712 , B01J2523/55
摘要： A process is described for converting a precatalyst which comprises an inert support, an organic carbon source and a multimetal oxide comprising silver and vanadium to a gas phase oxidation catalyst which comprises the inert support and a catalytically active silver vanadium oxide bronze, by treating the precatalyst thermally at a temperature of at least 350° C. in a gas atmosphere which comprises less than 10% by volume of oxygen, wherein, before the thermal treatment, the amount of the carbon source in the precatalyst is adjusted to a value below a critical amount The carbon content is reduced by burning-off at a temperature of from 80 to 200° C. in an oxygenous atmosphere with decomposition of a portion of the carbon source. The catalysts obtained serve for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides.
摘要翻译：描述了一种将包含惰性载体，有机碳源和包含银和钒的多金属氧化物的预催化剂转化成气相氧化催化剂的方法，该催化剂包含惰性载体和催化活性银钒氧化物青铜，通过处理预催化剂在包含小于10体积％氧气的气体气氛中，在至少350℃的温度下进行热处理，其中在热处理之前，将预催化剂中的碳源的量调节至低于临界值量在碳源的一部分分解的氧气氛中，在80〜200℃的温度下，通过烧成而降低碳含量。获得的催化剂用于将芳烃气相部分氧化成醛，羧酸和/或羧酸酐。

2. 发明授权

US07462727B2 Multimetal oxide containing silver, vanadium and a promoter metal and use thereof 失效
标题翻译：含有银，钒和助催化剂金属的多金属氧化物及其用途
公开(公告)号：US07462727B2
公开(公告)日：2008-12-09
申请号：US10566019
申请日：2004-07-23
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
IPC分类号： C07D307/89 , C07C51/255 , C07C51/16 , B01J23/00
CPC分类号： C07C51/313 , B01J23/002 , B01J23/682 , B01J23/688 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C01G31/006 , C07C51/265 , C07C63/16 , B01J2523/18 , B01J2523/3712 , B01J2523/55 , B01J2523/72 , B01J2523/47
摘要： A multimetal oxide of the formula I, Aga-cQbMcV2Od*e H2O, I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)≧0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.
摘要翻译：式I的多金属氧化物，<？in-line-formula description =“In-Line Formulas”end =“lead”→> Aga-cQbMcV2Od * e H2O，I <？in-line-formula description =“In- 其中a为0.3〜1.9，Q为选自P，As，Sb和/或Bi的元素，为0〜0.3，M为选自Nb， Ce，W，Mn，Ta，Pd，Pt，Ru和/或Rh，c为0.001至0.5，条件是（ac）> = 0.1，d为由化合价描述了式I中的氧以外的元素和e为0至20，并且还描述了由其制备的用于芳族烃的部分氧化的预催化剂和催化剂。

3. 发明申请

US20080019892A1 Multimetal Oxide Containing Silver, Vanadium And A Phosphor Group Element And The Use Thereof 审中-公开
标题翻译：包含银，钒和荧光体组元素的多金属氧化物及其用途
公开(公告)号：US20080019892A1
公开(公告)日：2008-01-24
申请号：US11629379
申请日：2005-06-14
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck , Jurgen Zuhlke
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck , Jurgen Zuhlke
IPC分类号： C01G31/00 , B01J23/00
CPC分类号： C01G31/00 , B01J23/002 , B01J23/682 , B01J27/198 , B01J2523/00 , C01P2002/72 , C01P2002/74 , C01P2006/12 , B01J2523/18 , B01J2523/51 , B01J2523/55
摘要： Multimetal oxides corresponding to the general formula (I), processes for their preparation, precatalysts containing such oxides and catalysts made therefrom for gas phase partial oxidation of hydrocarbons: Aga-cQbMcV12Od.eH2O (I)wherein a represents a number having a value of 5 to 9; Q represents an element selected from the group consisting of P, As, Sb, Bi and mixtures thereof; b represents a number having a value of 0.2 to 3; M represents a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni, Ce, Mn, Nb, W, Ta, Mo and mixtures thereof; c represents a number having a value of less than 1; d represents a number having a value of which is determined by the valency and frequency of Ag, Q, M and V in the formula (I); and e represents a number having a value of 0 to 20; wherein the multimetal oxide has a crystal structure wherein its powder X-ray diffractogram includes reflections at at least 5 interplanar spacings selected from the group of 7.13 Å, 5.52 Å, 5.14 Å, 3.57 Å, 3.25 Å, 2.83 Å, 2.79 Å, 2.73 Å, 2.23 Å and 1.71 Å, each interplanar spacing value±0.04 Å.
摘要翻译：对应于通式（I）的多金属氧化物，其制备方法，含有此类氧化物的预催化剂和由其制备的催化剂用于烃的气相部分氧化：<？in-line-formula description =“In-line Formulas”end =“ 导线“>> Ag C C 其中a表示数值为5〜9的数字，其中a表示0〜5的整数。 Q表示选自P，As，Sb，Bi及其混合物的元素; b表示数值为0.2〜3的数; M表示选自Li，Na，K，Rb，Cs，Tl，Mg，Ca，Sr，Ba，Cu，Zn，Cd，Pb，Cr，Au，Al，Fe，Co，Ni， Ce，Mn，Nb，W，Ta，Mo及其混合物; c表示小于1的数字; d表示数值，其数值由式（I）中Ag，Q，M和V的化合价和频率决定; e表示0〜20的数，其中所述多金属氧化物具有晶体结构，其中其粉末X射线衍射图包括选自7.13，5.52，5.14，3.57，3.25，2.83，2.79，2.73的至少5个面间距的反射 Å，2.23Å和1.71Å，每个晶面间距值±0.04Å。

4. 发明申请

US20060247446A1 Multi-metal oxide containing silver, vanadium and a promoter metal and use thereof 失效
标题翻译：含有银，钒和助催化剂金属的多金属氧化物及其用途
公开(公告)号：US20060247446A1
公开(公告)日：2006-11-02
申请号：US10566019
申请日：2004-07-23
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
IPC分类号： C07D307/89 , C07C51/255 , C07C51/16
CPC分类号： C07C51/313 , B01J23/002 , B01J23/682 , B01J23/688 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C01G31/006 , C07C51/265 , C07C63/16 , B01J2523/18 , B01J2523/3712 , B01J2523/55 , B01J2523/72 , B01J2523/47
摘要： A multimetal oxide of the formula I, Aga-cQbMcV2Od*eH2O, I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)≧0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.
摘要翻译：式I的多金属氧化物，<？in-line-formula description =“In-line Formulas”end =“lead”？> Ag ？V V V V V * O O O O O，，------------------------------------- 其中a为0.3〜1.9，Q为选自P，As，Sb和/或Bi的元素，为0〜0.3，M为选自Nb， Ce，W，Mn，Ta，Pd，Pt，Ru和/或Rh，c为0.001至0.5，条件是（ac）> = 0.1，d为由化合价描述了式I中的氧以外的元素和e为0至20，并且还描述了由其制备的用于芳族烃的部分氧化的预催化剂和催化剂。

5. 发明授权

US07071363B2 Structured catalyst bed 失效
标题翻译：结构催化剂床
公开(公告)号：US07071363B2
公开(公告)日：2006-07-04
申请号：US10617859
申请日：2003-07-14
申请人： Hartmut Hibst , Sebastian Storck , Dirk Demuth , Wolfram Stichert , Jens Klein , Stephan A. Schunk , Andreas Sundermann
发明人： Hartmut Hibst , Sebastian Storck , Dirk Demuth , Wolfram Stichert , Jens Klein , Stephan A. Schunk , Andreas Sundermann
IPC分类号： C07C45/00 , B01J23/48 , B01J23/50
CPC分类号： C07C45/34 , B01J8/0453 , B01J23/002 , B01J23/50 , B01J23/66 , B01J23/8885 , B01J27/1806 , B01J35/0006 , B01J2208/025 , B01J2523/00 , C07C45/58 , C07C47/21 , B01J2523/18 , B01J2523/31 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/11 , B01J2523/51
摘要： The invention relates to a novel structured catalyst bed which optionally comprises at least one part bed comprising at least one catalytically active mixture of oxides of the main group metals and transition metals and additionally comprises at least one catalytically active part bed comprising at least silver, at least one alkali metal and a porous support material and finally and necessarily at least one catalytically active part bed comprising at least one alkali metal phosphate and at least one sheet silicate.
摘要翻译：本发明涉及一种新颖的结构化催化剂床，其任选地包含至少一部分床，其包含至少一种主要金属和过渡金属的氧化物的催化活性混合物，并且还包含至少一种至少包含银的催化活性部分床，至少一种碱金属和多孔载体材料，最后并且必需至少一种包含至少一种碱金属磷酸盐和至少一种片状硅酸盐的催化活性部分床。

6. 发明授权

US07495132B2 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US07495132B2
公开(公告)日：2009-02-24
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
IPC分类号： C07C45/65 , B01J23/42
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

7. 发明申请

US20070167318A1 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US20070167318A1
公开(公告)日：2007-07-19
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Rossler , Hartmut Hibst , Joaquim Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Rossler , Hartmut Hibst , Joaquim Teles , Sebastian Storck , Jens Klein
IPC分类号： B01J23/00
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

8. 发明申请

US20050277546A1 Process for the preparation of a multimetal oxide material 审中-公开
标题翻译：制备多金属氧化物材料的方法
公开(公告)号：US20050277546A1
公开(公告)日：2005-12-15
申请号：US11139657
申请日：2005-05-31
申请人： Hartmut Hibst , Frieder Borgmeier , Frank Rosowski , Klaus Muller-Engel
发明人： Hartmut Hibst , Frieder Borgmeier , Frank Rosowski , Klaus Muller-Engel
IPC分类号： B01J23/00 , B01J23/28 , B01J23/31 , B01J23/887 , B01J27/057 , B01J35/00 , B01J37/02 , B01J37/03 , B01J37/10 , C01G1/02 , C01G31/02 , C01G39/00 , C01G39/02 , C01G51/00 , C01G53/00
CPC分类号： C01G53/006 , B01J23/002 , B01J23/28 , B01J23/31 , B01J23/8877 , B01J27/0576 , B01J35/002 , B01J37/0223 , B01J37/03 , B01J37/10 , B01J2523/00 , C01G1/02 , C01G39/00 , C01G39/006 , C01G45/006 , C01G47/006 , C01G51/006 , C01G55/002 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2004/03 , C01P2004/10 , C01P2006/12 , B01J2523/55 , B01J2523/68 , B01J2523/64 , B01J2523/54 , B01J2523/53 , B01J2523/56 , B01J2523/39 , B01J2523/845 , B01J2523/847
摘要： A process for the hydrothermal preparation of Mo- and V-comprising multimetal oxide materials, substantially exclusively sources from the group consisting of oxides, hydrated oxides, oxygen acids and hydroxides being used as sources of the elemental constituents of the multimetal oxide material, and a portion of the sources comprising the elemental constituent contained with an oxidation number which is below its maximum oxidation number.
摘要翻译：一种用于水热制备含Mo和V的多金属氧化物材料的方法，其基本上仅来源于氧化物，水合氧化物，氧酸和氢氧化物，其作为多金属氧化物材料的元素成分的来源，以及源的部分包含含有低于其最大氧化数的氧化数的元素成分。

9. 发明申请

US20120071671A1 CATALYST AND METHOD FOR PARTIALLY OXIDIZING HYDROCARBONS 审中-公开
标题翻译：催化剂和部分氧化氢氧化物的方法
公开(公告)号：US20120071671A1
公开(公告)日：2012-03-22
申请号：US13375019
申请日：2010-05-28
申请人： Andrey Karpov , Hartmut Hibst , Christine Deißler , Cornelia Katharina Dobner , Frank Rosowski , Nadine Brem , Stephan Schunk
发明人： Andrey Karpov , Hartmut Hibst , Christine Deißler , Cornelia Katharina Dobner , Frank Rosowski , Nadine Brem , Stephan Schunk
IPC分类号： C07D307/89 , B01J27/199 , B01J23/68
CPC分类号： B01J23/686 , B01J23/002 , B01J23/687 , B01J23/8993 , B01J27/199 , B01J37/0045 , B01J2523/00 , C07C51/265 , C07C63/16 , C07C63/26 , B01J2523/18 , B01J2523/305 , B01J2523/55 , B01J2523/68 , B01J2523/51 , B01J2523/3712 , B01J2523/53 , B01J2523/54 , B01J2523/17 , B01J2523/69 , B01J2523/15 , B01J2523/56 , B01J2523/842
摘要： The invention relates to a catalyst for partially oxidizing hydrocarbons in the gas phase, containing a multi-metal oxide of the general formula (I), AgaMObVcMdOe.f H2O (I), wherein M stands for at least one element selected from among Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Si, Sn, Pb, P, Sb, Bi, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Au, Zn, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and U, a has a value of 0.5 to 1.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, a+b+c has the value 3, d has a value of less than 1, e means a number that is determined by the valence and frequency of the elements other than oxygen in the formula (I), f has a value of 0 to 20, which multi-metal oxide exists in a crystal structure, the X-ray powder diffractogram of which is characterized by diffraction reflections at a minimum of 5 lattice distances selected from among d=4.53, 3.38, 3.32, 3.23, 2.88, 2.57, 2.39, 2.26, 1.83, 1.77 AA (+−0.04 AA).
摘要翻译：本发明涉及一种用于部分氧化气相中的烃的催化剂，其含有通式（I）的多金属氧化物，AgaMObVcMdOe.fH 2 O（I），其中M代表至少一种选自Li， Na，K，Rb，Cs，Be，Mg，Ca，Sr，Ba，B，Al，Ga，In，Si，Sn，Pb，P，Sb，Bi，Y，Ti，Zr，Hf， Ta，Cr，W，Mn，Re，Fe，Ru，Os，Co，Rh，Ir，Ni，Pd，Pt，Cu，Au，Zn，Cd，La，Ce，Pr，Nd，Sm，Eu， Tb，Dy，Ho，Er，Tm，Yb，Lu和U，a的值为0.5〜1.5，b为0.5〜1.5，c为0.5〜1.5，a + b + c为值3，d的值小于1，e表示式（I）中除氧以外的元素的化合价和频率所决定的数，f为0〜20，金属氧化物存在于晶体结构中，其X射线粉末衍射图的特征在于从d = 4.53,3.33,3.32,3.23,28.88,2.57,2.39,2.26,1中的至少5个晶格距离的衍射反射 .83,1.77AA（±0.04A）。

10. 发明申请

US20090118531A1 NOVEL SUPPORTED CATALYST FOR AMMOXIDATION 审中-公开
标题翻译：新型支持的氧化催化剂
公开(公告)号：US20090118531A1
公开(公告)日：2009-05-07
申请号：US12298806
申请日：2007-04-23
申请人： Hartmut Hibst , Sabine Huber , Frank Rosowski
发明人： Hartmut Hibst , Sabine Huber , Frank Rosowski
IPC分类号： C07C253/28 , B01J23/22
CPC分类号： B01J23/22 , B01J21/04 , B01J23/002 , B01J23/30 , B01J35/023 , B01J37/0201 , B01J37/0205 , B01J2523/00 , C07C253/28 , B01J2523/15 , B01J2523/53 , B01J2523/55 , B01J2523/69 , C07C255/51 , C07C255/50
摘要： Supported catalysts comprising a support having a mean diameter of ≦78 μm, a vanadium oxide, an antimony oxide, one or more alkali metal or alkaline earth metal oxides, and one or more oxides of tungsten, molybdenum, titanium, iron, cobalt, nickel, manganese, potassium, copper or mixtures thereof; processes for preparing said catalysts; and processes for preparing an aromatic or heteroaromatic nitrile in the presence of such a supported catalyst.
摘要翻译：包含平均直径<=78μm，氧化钒，氧化锑，一种或多种碱金属或碱土金属氧化物的载体和一种或多种钨，钼，钛，铁，钴，镍，锰，钾，铜或其混合物; 制备所述催化剂的方法; 以及在这种负载催化剂存在下制备芳族或杂芳族腈的方法。

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