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1. 发明授权

US5179121A Thiobutyric acid derivatives 失效
标题翻译：三氢酸衍生物
公开(公告)号：US5179121A
公开(公告)日：1993-01-12
申请号：US745567
申请日：1991-08-15
申请人： Peter Maienfisch , Manfred Boger , Eginhard Steiner
发明人： Peter Maienfisch , Manfred Boger , Eginhard Steiner
IPC分类号： A01N37/02 , A01N37/36 , A01N43/08 , C07C327/06 , C07C327/22 , C07D307/38
CPC分类号： C07C327/22 , A01N37/02 , A01N37/36 , A01N43/08
摘要： Novel 4-chloro-4,4-difluorothiobutyric acid derivatives of the formula I ##STR1## in which R.sub.1 and R.sub.2 are, independently of one another, hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 halogenoalkyl and R.sub.3 is hydrogen or an organic radical can be employed as pest-control agents. Control of insects and arachnids is possible and preferable.
摘要翻译：式I（I）的新型4-氯-4,4-二氟硫代丁酸衍生物，其中R 1和R 2彼此独立地为氢，C 1 -C 4烷基或C 1 -C 4卤代烷基，R 3为氢或有机自由基可以作为害虫防治剂使用。昆虫和蜘蛛的控制是可能的并且是优选的。

2. 发明授权

US4511571A N-(2-Pyridyloxyphenyl)-N'-benzoyl ureas, pesticidal compositions containing same and pesticidal methods of use 失效
标题翻译： N-（2-吡啶氧基苯基）-N'-苯甲酰脲，含有相同的杀虫组合物和杀虫剂的使用方法
公开(公告)号：US4511571A
公开(公告)日：1985-04-16
申请号：US433763
申请日：1982-10-12
申请人： Manfred Boger , Josef Ehrenfreund , Pierre Martin , Eginhard Steiner
发明人： Manfred Boger , Josef Ehrenfreund , Pierre Martin , Eginhard Steiner
IPC分类号： A01N47/34 , C07D213/64 , C07D213/643 , A01N43/40
CPC分类号： C07D213/643 , A01N47/34
摘要： Novel substituted N-(2-pyridyloxyphenyl)-N'-benzoylureas of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are each hydrogen, methyl or halogen,R.sub.5 is the radical --CHF.sub.2, or a C.sub.2 -C.sub.10 -alkyl group which is uniformly or nonuniformly substituted by 1 to 21 halogen atoms, andR.sub.6 is halogen,processes and starting products for producing these compounds, as well as compositions containing these, for use in combating pests, particularly for combating insects which infest plants and animals. The novel compounds have a specially high ovolarvicidal and ovicidal action against insects that damage plants.
摘要翻译：式（Ia）的新型取代的N-（2-吡啶氧基苯基）-N'-苯甲酰脲其中R 1，R 2，R 3和R 4彼此独立地为氢，甲基或卤素，R 5为基团-CHF 2或C 2 -C 1 -C 10烷基，其被1至21个卤素原子均匀或不均匀地取代，并且R 6是卤素，用于制备这些化合物的方法和起始产物，以及含有这些化合物的组合物，用于防治害虫，特别是用于防治害虫感染植物和动物。这些新型化合物对于损害植物的昆虫具有特别高的抗紫外线和杀卵作用。

3. 发明授权

US5008302A Titanocenes, the use thereof, and N-substituted pyrroles 失效
标题翻译：钛菁，其用途和N-取代的吡咯
公开(公告)号：US5008302A
公开(公告)日：1991-04-16
申请号：US273522
申请日：1988-11-21
申请人： Rinaldo Husler , Bernd Klingert , Manfred Rembold , Eginhard Steiner
发明人： Rinaldo Husler , Bernd Klingert , Manfred Rembold , Eginhard Steiner
IPC分类号： G03F7/028 , C07D207/32 , C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F7/08 , C07F7/28 , C07F17/00 , C08F2/50 , C08F4/76 , C09D4/00 , C09D11/10 , G03F7/029
CPC分类号： C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F17/00 , C07F7/0814 , C08F2/50 , G03F7/029 , Y10S430/121 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl groups, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as a further substituent, unsubstituted or substituted 1-pyrryl, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
摘要翻译：含有两个5元环二烯基的二茂钛，例如环戊二烯基，以及一个或两个6元碳环或5元或6元杂环芳环，它们被两个邻位中的至少一个中的氟原子取代作为另外的取代基，含有未取代的或取代的1-吡咯基，作为光引发剂适用于烯键式不饱和化合物的辐射诱导聚合。

4. 发明授权

US4033942A Chromium complex dye, including azo and azo methine dye compounds 失效
标题翻译：铬络合染料，包括偶氮次甲基染料化合物
公开(公告)号：US4033942A
公开(公告)日：1977-07-05
申请号：US680640
申请日：1976-04-27
申请人： Fabio Beffa , Gerhard Back , Eginhard Steiner
发明人： Fabio Beffa , Gerhard Back , Eginhard Steiner
IPC分类号： C09B45/04 , C09B45/00 , C09B45/48 , C09B55/00 , C09B56/02 , D06P1/10 , D06P1/13 , C09B45/26 , C09B45/06
CPC分类号： C09B45/00 , C09B55/001 , D06P1/10 , D06P1/13
摘要： 1:2 Chromium complex dyes of an azo compound of the formula ##STR1## and an azomethine compound of the formula ##STR2## COMPLEXED TO A CHROMIUM ATOM, WHEREIN A is an ortho-phenylene or -- naphthylene diazo component radical; B is an ortho-phenylene or -- naphthylene coupling component radical; X is --O-- or --CO--O--; X' is --O--, --NH--, --N(lower alkyl)--, --N(aralkyl)-- or --N(aryl)--; R is an aliphatic radical; the benzene ring "a" is unsubstituted or substituted by a fused benzene ring, halo, nitro alkyl or alkoxy; the molecule containing 0-5 water solubilizing groups and optionally a group of the formula --N=N--Ar--N=N--Ar' and/or -N=N--Ar" wherein Ar, Ar' and Ar" represent an aromatic or carbocyclic radical.
摘要翻译： 1：2下式的偶氮化合物的铬络合物染料和与铬酸盐复合的式“IMAGE”的偶氮甲碱化合物，其中A是邻 - 亚苯基或 - 亚萘基重氮组分基团; B是邻 - 亚苯基或亚萘基偶合成分基; X是-O-或-CO-O-; X'是-O - ， - NH - ， - N（低级烷基） - ， - N（芳烷基） - 或-N（芳基） - 。 R是脂族基团; 苯环“a”未被取代或被稠合的苯环，卤素，硝基烷基或烷氧基取代; 含有0-5个水溶性基团和任选的式-N = N-Ar-N = N-Ar'和/或-N = N-Ar“的分子，其中Ar，Ar'和Ar”表示芳族或碳环基。

5. 发明授权

US4577028A 5-Haloalkyl-pyridines 失效
标题翻译： 5-卤代烷基 - 吡啶
公开(公告)号：US4577028A
公开(公告)日：1986-03-18
申请号：US434433
申请日：1982-10-14
申请人： Pierre Martin , Eginhard Steiner
发明人： Pierre Martin , Eginhard Steiner
IPC分类号： C07C45/63 , C07C45/69 , C07C47/14 , C07D213/61 , C07D213/26
CPC分类号： C07D213/61 , C07C45/63 , C07C45/69 , C07C47/14
摘要： Novel 5-haloalkyl-pyridines suitable for producing pesticidal compositions, particularly insecticides, and corresponding to the formula ##STR1## wherein R is a C.sub.2 -C.sub.10 -alkyl group which is uniformly or nonuniformly substituted by 1 to 21 halogen atoms, and X is halogen;processes for producing them, as well as to the novel starting products and intermediates used or intermediately produced or formed in the production processes.
摘要翻译：适用于生产杀虫剂组合物，特别是杀虫剂的新型5-卤代烷基 - 吡啶类化合物，对应于式（Ⅰ）其中R是C2-C10烷基，其被1-22个卤素原子均匀或不均匀地取代，X是卤素 ; 生产方法，以及在生产过程中使用或中间生产或形成的新型起始产品和中间体。

6. 发明授权

US4245098A Process for producing 2,3,5-trichloropyridine, 2,4,4-trichloro-4-formyl-butyronitrile as a novel compound and a process for producing it 失效
标题翻译：制备2,3,5-三氯吡啶，2,4,4-三氯-4-甲酰基 - 丁腈作为新化合物的方法及其制备方法
公开(公告)号：US4245098A
公开(公告)日：1981-01-13
申请号：US098017
申请日：1979-11-28
申请人： Eginhard Steiner , Pierre Martin , Daniel Bellus
发明人： Eginhard Steiner , Pierre Martin , Daniel Bellus
IPC分类号： C07C255/17 , C07D213/61
CPC分类号： C07C255/00 , C07D213/61
摘要： A novel process for producing 2,3,5-trichloropyridine is described. The process comprises the addition reaction of trichloroacetaldehyde with acrylonitrile in the presence of a catalyst, and the subsequent cyclization of the intermediately formed 2,4,4-trichloro-4-formylbutyronitrile, with the splitting-off of water, to give 2,3,5-trichloropyridine.2,4,4-Trichloro-4-formylbutyronitrile occurring as an intermediate product in the process according to the invention is a novel compound. It can be produced by the addition reaction of trichloroacetaldehyde with acrylonitrile in the presence of a catalyst.2,3,5-Trichloropyridine can be used as intermediate for the production of herbicidal active substances.
摘要翻译：描述了一种制备2,3,5-三氯吡啶的新方法。该方法包括在催化剂存在下三氯乙醛与丙烯腈的加成反应，随后将中间形成的2,4,4-三氯-4-甲酰基丁腈与水分离，得到2,3 ，5-三氯吡啶。作为本发明方法中间产物的2,4,4-三氯-4-甲酰基丁腈是一种新型化合物。它可以通过三氯乙醛与丙烯腈在催化剂存在下的加成反应来制备。 2,3,5-三氯吡啶可用作生产除草活性物质的中间体。

7. 发明授权

US4242278A Process for the preparation of 2-(2',2',2'-trihalogenoethyl)-4-halogenocyclobutan-1-ones 失效
标题翻译：制备2-（2'，2'，2'-三卤代乙基）-4-卤代环丁烷-1-酮的方法
公开(公告)号：US4242278A
公开(公告)日：1980-12-30
申请号：US948126
申请日：1978-10-03
申请人： Pierre Martin , Hans Greuter , Eginhard Steiner , Daniel Bellus
发明人： Pierre Martin , Hans Greuter , Eginhard Steiner , Daniel Bellus
IPC分类号： C07C51/60 , C07C51/62 , C07C53/50 , C07C61/15 , C07C61/40 , C07C45/45 , C07C49/105 , C07C49/115
CPC分类号： C07C45/45 , C07C45/67 , C07C51/60 , C07C51/62 , C07C53/50 , C07C61/15 , C07C61/40
摘要： A process for the preparation of 2-(2',2',2',-trihalogenoethyl)-4-halogenocyclobutan-1-ones of the formula ##STR1## in which one of the radicals R.sub.1 and R.sub.2 is methyl and the other is hydrogen or methyl, or R.sub.1 and R.sub.2 together are an alkylene group having 2 to 4 carbon atoms, and X and Y are each chlorine or bromine, comprising reacting a 2,4,4,4-tetrahalogenobutyric acid chloride in the presence of an organic base with an ethylene compound which is disubstituted in 1-position by the radicals R.sub.1 and R.sub.2, as defined above, to form a 2-(2',2',2'-trihalogenoethyl)-2-halogenocyclobutan-1-one and then rearranging the latter, in the presence of a catalyst, into a 2-(2',2',2'-trihalogenoethyl)-4-halogenocyclobutan-1-one of the above formula; said 2-(2',2',2'-trihalogenoethyl)-4-halogenocyclobutan-1-ones being valuable intermediates for the preparation of 2-(2',2'-dihalogenovinyl)-cyclopropanecarboxylic acid and its insecticidally active esters; as well as the 2-(2',2',2'-trihalogenoethyl)-4-halogenocyclobutan-1-ones of the above formula and the intermediates utilized for their preparation.
摘要翻译：一种制备式（IMAGE）的2-（2'，2'，2'， - 三卤代乙基）-4-卤代环丁烷-1-酮的方法，其中R 1和R 2之一是甲基，另一个是氢或甲基，或R 1和R 2一起是具有2至4个碳原子的亚烷基，X和Y各自为氯或溴，包括在有机物存在下使2,4,4,4-四卤代丁酰氯反应与如上定义的基团R 1和R 2在1位被二取代的亚乙基化合物反应形成2-（2'，2'，2'-三卤代乙基）-2-卤代环丁烷-1-酮，然后在催化剂存在下将其重新排列成上式的2-（2'，2'，2'-三卤代乙基）-4-卤代环丁烷-1-酮; 所述2-（2'，2'，2'-三卤代乙基）-4-卤代环丁烷-1-酮是制备2-（2'，2'-二卤代乙酰基） - 环丙烷羧酸及其杀虫活性酯的有价值的中间体; 以及上述式的2-（2'，2'，2'-三卤代乙基）-4-卤代环丁烷-1-酮和用于其制备的中间体。

8. 发明授权

US4116952A Unsymmetrical azo - azo methine 1:2 chromium complex dyes 失效
标题翻译：不对称AZO - AZO甲1：2铬复合染料
公开(公告)号：US4116952A
公开(公告)日：1978-09-26
申请号：US788217
申请日：1977-04-18
申请人： Fabio Beffa , Gerhard Back , Eginhard Steiner
发明人： Fabio Beffa , Gerhard Back , Eginhard Steiner
IPC分类号： C09B45/00 , C09B55/00 , D06P1/10 , D06P1/13 , C09B45/06 , C09B45/26 , D06P3/32
CPC分类号： C09B45/00 , C09B55/001 , D06P1/10 , D06P1/13
摘要： 1:2 Chromium complex dyes which contain one molecule of an azo or azomethine compound of the formula ##STR1## and one molecule of the azomethine compound of the formula ##STR2## COMPLEXED TO A CHROMIUM ATOM, IN WHICH FORMULAE A represents the radical of a diazo component of the benzene or naphthalene series, which carries the complex-forming group XH in ortho-position to the azo group,B represents the radical of a coupling component which couples in ortho-position to HX' or the radical of an aromatic o-hydroxyaldehyde,Z represents a nitrogen atom or the -CH group,X represents an oxygen atom or a -CO-O group,X' represents an oxygen atom, a NH group, a low molecular N-alkyl, N-aralkyl or N-aryl group, andR represents a substituted or unsubstituted aliphatic or cycloaliphatic radical,And the benzene ring a can carry a further fused benzene ring or can be substituted by halogen, nitro, alkyl and alkoxy, in particular by low molecular alkyl and alkoxy, and these compounds contain together 0 to 5 water-solubilizing groups and optionally a group of the formula--N.dbd.N--Ar--N.dbd.N--Ar' (3)and/or one to two groups of the formula--N.dbd.N--Ar" (4)wherein Ar, Ar' and Ar" represent an aromatic, carbocyclic or heterocyclic radical. These dyes are primarily suitable for dyeing natural and synthetic polyamide material.

9. 发明授权

US5192642A Oxygen-containing titanocenes, and the use thereof 失效
标题翻译：含氧含钛，以及其使用
公开(公告)号：US5192642A
公开(公告)日：1993-03-09
申请号：US527988
申请日：1990-05-23
申请人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , C09D4/00 , G03F7/029
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/124 , Y10S430/148 , Y10S526/943
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by an acyloxy group are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译：其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代并且被酰氧基取代的芳族基团的式I化合物（I）的十六碳烯是合适的作为烯属不饱和化合物的光聚合的光引发剂。

10. 发明授权

US5026625A Titanocenes, the use thereof, and n-substituted fluoroanilines 失效
标题翻译：钛合金，其用途和n-取代的氟代苯胺
公开(公告)号：US5026625A
公开(公告)日：1991-06-25
申请号：US273526
申请日：1988-11-21
申请人： Martin Riediker , Eginhard Steiner , Harry Beyeler , Franciszek Sitek , Rinaldo Husler
发明人： Martin Riediker , Eginhard Steiner , Harry Beyeler , Franciszek Sitek , Rinaldo Husler
IPC分类号： C07C211/52 , C07C217/08 , C07C233/12 , C07C233/15 , C07C233/59 , C07C233/66 , C07C233/88 , C07C233/91 , C07C235/06 , C07C255/24 , C07C255/30 , C07C255/45 , C07C271/06 , C07C311/21 , C07C335/16 , C07C381/06 , C07D205/08 , C07D207/40 , C07D207/404 , C07D207/408 , C07D207/448 , C07D209/48 , C07D209/76 , C07D307/14 , C07D521/00 , C07F7/10 , C07F7/28 , C07F17/00 , C08F2/50 , G03F7/029
CPC分类号： C07D207/404 , C07C211/52 , C07C217/08 , C07C233/15 , C07C233/66 , C07C233/88 , C07C311/21 , C07D205/08 , C07D207/408 , C07D209/48 , C07D209/76 , C07D307/14 , C07F17/00 , C07F7/10 , C08F2/50 , G03F7/029 , C07C2101/14 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl gropus, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as further substituents, a substituted amino radical, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
摘要翻译：含有两个5元环二烯gropus，例如环戊二烯基，和一个或两个六元碳环或5元或它们被氟原子在两个邻位的至少一种取代的6元杂环芳环二茂钛钛 - 碳键并含有作为其它取代基的取代的氨基，适用作用于烯属不饱和化合物的辐射诱导聚合的光引发剂。

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