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1. 发明授权

US08002970B2 Zeolitic catalyst with a controlled doping element content, and improved process for processing hydrocarbon feeds 有权
标题翻译：具有受控掺杂元素含量的沸石催化剂，以及用于处理烃进料的改进方法
公开(公告)号：US08002970B2
公开(公告)日：2011-08-23
申请号：US11722610
申请日：2005-12-13
申请人： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
发明人： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
IPC分类号： C10G47/00
CPC分类号： B01J37/0009 , B01J21/12 , B01J29/146 , B01J29/166 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J2229/20 , B01J2229/42 , C10G47/14 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素，在24.40×10-10 m至24.15×10-10m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝，。

2. 发明申请

US20060070915A1 Doped catalyst and improved process for treatment of hydrocarbon feedstocks 有权
标题翻译：掺杂催化剂和用于处理烃原料的改进方法
公开(公告)号：US20060070915A1
公开(公告)日：2006-04-06
申请号：US11221416
申请日：2005-09-08
申请人： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
发明人： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
IPC分类号： B01J21/12 , B01J27/187 , B01J21/02 , B01J27/182 , C10G47/02
CPC分类号： B01J37/28 , B01J21/02 , B01J21/12 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J23/8885 , B01J23/8993 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/03 , B01J37/10 , B01J37/20 , B01J37/30 , C10G49/04 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
摘要翻译：本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素以及含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的二氧化硅 - 氧化铝基底的非沸石基材。

3. 发明授权

US07563743B2 Doped catalyst and improved process for treatment of hydrocarbon feedstocks 有权
标题翻译：掺杂催化剂和用于处理烃原料的改进方法
公开(公告)号：US07563743B2
公开(公告)日：2009-07-21
申请号：US11221416
申请日：2005-09-08
申请人： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
发明人： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
IPC分类号： B01J27/00 , B01J21/00 , B01J23/00 , B01J23/10 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/56 , B01J20/00 , C07C4/02 , C10G11/00 , C10G11/02
CPC分类号： B01J37/28 , B01J21/02 , B01J21/12 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J23/8885 , B01J23/8993 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/03 , B01J37/10 , B01J37/20 , B01J37/30 , C10G49/04 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
摘要翻译：本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素和具有二氧化硅 - 氧化铝基底的非沸石基材，其含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量。

4. 发明申请

US20090118556A1 ZEOLITIC CATALYST WITH A CONTROLLED DOPING ELEMENT CONTENT, AND IMPROVED PROCESS FOR PROCESSING HYDROCARBON FEEDS 有权
标题翻译：具有控制元素含量的新兴催化剂，以及加工油料进料的改进方法
公开(公告)号：US20090118556A1
公开(公告)日：2009-05-07
申请号：US11722610
申请日：2005-12-13
申请人： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
发明人： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
IPC分类号： B01J29/14 , B01J29/08 , C07C5/10
CPC分类号： B01J37/0009 , B01J21/12 , B01J29/146 , B01J29/166 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J2229/20 , B01J2229/42 , C10G47/14 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素，在24.40×10 -10 m至24.15×10 -10 m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝。

5. 发明授权

US07790019B2 Zeolitic catalyst, substrate based on a silica-alumina matrix and zeolite, and hydrocracking process for hydrocarbon feedstocks 有权
标题翻译：沸石催化剂，基于二氧化硅 - 氧化铝基质和沸石的底物，以及烃原料的加氢裂化方法
公开(公告)号：US07790019B2
公开(公告)日：2010-09-07
申请号：US10584144
申请日：2004-12-16
申请人： Patrick Euzen , Patrick Bourges , Hugues Dulot , Christophe Gueret
发明人： Patrick Euzen , Patrick Bourges , Hugues Dulot , Christophe Gueret
IPC分类号： C10G47/24 , C10G47/02 , B01J29/06
CPC分类号： B01J29/70 , B01J21/12 , B01J23/883 , B01J27/1853 , B01J27/19 , B01J29/064 , B01J29/076 , B01J29/084 , B01J29/74 , B01J29/78 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J2229/42 , C10G45/64 , C10G47/12 , C10G65/12
摘要： The invention relates to a catalyst including at least one hydro-dehydrogenating element chosen from the group formed by the group VIB and group VIII elements of the periodic table and a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite.The invention also relates to a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite.The invention also relates to hydrocracking and/or hydroconversion processes and hydrotreating processes utilizing a catalyst according to the invention.
摘要翻译：本发明涉及一种催化剂，其包括至少一种选自由元素周期表VIB族和VIII族元素形成的加氢脱氢元素，以及基于二氧化硅 - 氧化铝基质的底物，其中含有大量的大孔大于5重量％且小于或等于95重量％的二氧化硅（SiO 2）并且基于至少一种沸石。本发明还涉及一种基于二氧化硅 - 氧化铝基质的底物，其具有含量大于5重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的大孔含量，并基于至少一种沸石。本发明还涉及利用根据本发明的催化剂的加氢裂化和/或加氢转化方法和加氢处理方法。

6. 发明授权

US07270738B2 Catalyst and process for hydrocracking hydrocarbon-containing feedstocks 有权
标题翻译：用于加氢裂化含烃原料的催化剂和方法
公开(公告)号：US07270738B2
公开(公告)日：2007-09-18
申请号：US10696561
申请日：2003-10-30
申请人： Patrick Euzen , Carole Bobin , Magalie Roy-Auberger , Eric Benazzi , Patrick Bourges , Christophe Gueret
发明人： Patrick Euzen , Carole Bobin , Magalie Roy-Auberger , Eric Benazzi , Patrick Bourges , Christophe Gueret
IPC分类号： C01G47/00 , C01G45/00 , C01G17/00 , B01J23/00 , B01J21/00
CPC分类号： B01J35/10 , B01J21/12 , B01J23/24 , B01J23/42 , B01J23/74 , B01J23/85 , B01J23/888 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0009 , C10G47/12 , C10G47/14 , C10G47/16 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018 , C10G2300/70
摘要： This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 Å, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 160 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 200 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 500 Å, of less than 0.01 ml/g, an X diffraction diagram contains at least the main lines that are characteristic of at least one of the transition aluminas contained in the group that consists of the alpha, rho, chi, eta, gamma, kappa, theta and delta aluminas.
摘要翻译：本发明涉及硅铝基板，催化剂以及使用它们的加氢裂化和加氢处理方法。该催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和非沸石二氧化硅 - 氧化铝基底物的含氢量超过5的氢脱氢元件重量百分比和小于或等于95重量％的二氧化硅（SiO 2/2），并具有以下特征：通过水银孔率法测量的平均孔径包含在20和140之间，a 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，包括在 100和550m 2 / g，通过水银孔率法测量的孔体积包含在直径大于140埃，小于0.1ml / g的孔中，孔体积由包含在直径大于160埃，小于0的孔中的水银孔率法。 1毫升/克，通过水银孔率测定法测量的孔体积，直径大于200埃，小于0.1毫升/克，通过水银孔率法测定的孔体积，包含在直径为大于500埃，小于0.01ml / g，X衍射图至少包含由α，rho，chi，eta等组成的组中包含的至少一种过渡氧化铝的特征的主线， γ，κ，θ和δ氧化铝。

7. 发明申请

US20070108102A1 Method for treating a hydrocarbon feedstock including resin removal 有权
标题翻译：用于处理包括树脂去除的烃原料的方法
公开(公告)号：US20070108102A1
公开(公告)日：2007-05-17
申请号：US10584048
申请日：2004-12-13
申请人： Christophe Gueret , Raphael Huyghe , Hugues Dulot , Patrick Euzen
发明人： Christophe Gueret , Raphael Huyghe , Hugues Dulot , Patrick Euzen
IPC分类号： C10G7/00 , B01D3/00
CPC分类号： C10G21/14 , C10G47/00 , C10G67/049 , C10G2300/107 , C10G2300/1077 , C10G2300/301 , C10G2300/44
摘要： The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage. Drawing to be published.
摘要翻译：本发明涉及一种方法，包括除去树脂，用于处理烃装料，其中至少80％的化合物具有高于或等于340℃的沸点，其中所述装料送入分馏阶段，在此阶段，回收发生至少一个重馏分和至少一个轻馏分，至少部分重馏分被送至萃取阶段，在此阶段萃取所述重馏分中所含的树脂，以及回收纯化的馏分，制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物，将得到的混合物送入裂化阶段。绘图出版。

8. 发明授权

US07582204B2 Method for treating a hydrocarbon feedstock including resin removal 有权
标题翻译：用于处理包括树脂去除的烃原料的方法
公开(公告)号：US07582204B2
公开(公告)日：2009-09-01
申请号：US10584048
申请日：2004-12-13
申请人： Christophe Gueret , Raphaël Huyghe , Hugues Dulot , Patrick Euzen
发明人： Christophe Gueret , Raphaël Huyghe , Hugues Dulot , Patrick Euzen
IPC分类号： C10G7/00 , C10G21/00 , B01D3/00
CPC分类号： C10G21/14 , C10G47/00 , C10G67/049 , C10G2300/107 , C10G2300/1077 , C10G2300/301 , C10G2300/44
摘要： The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage.
摘要翻译：本发明涉及一种方法，包括除去树脂，用于处理烃装料，其中至少80％的化合物具有高于或等于340℃的沸点，其中所述装料送入分馏阶段，在此阶段，回收发生至少一个重馏分和至少一个轻馏分，至少部分重馏分被送至萃取阶段，在此阶段萃取所述重馏分中所含的树脂，以及回收纯化的馏分，制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物，将得到的混合物送入裂化阶段。

9. 发明授权

US07655136B2 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a doped catalyst based on mesoporous alumina-silica with a controlled macropore content 有权
标题翻译：通过使用基于具有受控大孔含量的介孔氧化铝 - 二氧化硅的掺杂催化剂从费 - 托方法加氢异构化和加氢裂化原料来生产中间馏分的方法
公开(公告)号：US07655136B2
公开(公告)日：2010-02-02
申请号：US11475259
申请日：2006-06-27
申请人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
发明人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
IPC分类号： C10G11/02
CPC分类号： B01J21/12 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/85 , B01J27/1856 , B01J35/0066 , B01J35/0093 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G47/18 , C10G65/12 , C10G65/14 , C10G2400/04 , C10G2400/06
摘要： The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises: at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table; 0.01% to 6% of phosphorus as a doping element; and a non-zeolitic support based on mesoporous alumina-silica.
摘要翻译：本发明涉及一种使用加氢裂化/加氢异构化催化剂由费 - 托合成生产的链烷烃进料生产中间馏分的方法，所述加氢裂化/加氢异构化催化剂包括：至少一种选自由周期性的VIB族和VIII族的元素形成的加氢元素表; 0.01〜6％的磷作为掺杂元素; 和基于介孔氧化铝 - 二氧化硅的非沸石载体。

10. 发明授权

US07160436B2 Method for two-step hydrocracking of hydrocarbon feedstocks 有权
标题翻译：碳氢化合物原料两步加氢裂化方法
公开(公告)号：US07160436B2
公开(公告)日：2007-01-09
申请号：US10343218
申请日：2001-07-26
申请人： Eric Benazzi , Jean-Marie Deves , Pierre Marion , Christophe Gueret , Alain Billon , Patrick Bourges
发明人： Eric Benazzi , Jean-Marie Deves , Pierre Marion , Christophe Gueret , Alain Billon , Patrick Bourges
IPC分类号： C10G65/12 , C10G37/02
CPC分类号： C10G47/20 , C10G65/12 , C10G2300/207 , C10G2300/301 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： An improved hydrocracking process of hydrocarbon charges, in two stages with an intermediate separation, in which the second-stage of hydrocracking is carried out in the presence of an added nitrogen content which is greater than 150 ppm by weight, preferably about 500 ppm by weight, and preferably in the presence of a Y zeolite catalyst, produces high yields of middle distillate.
摘要翻译：改进的烃电荷的加氢裂化方法，分两个阶段进行中间分离，其中第二阶段的加氢裂化在加入的氮含量大于150重量ppm，优选约500重量ppm的条件下进行，并且优选在Y沸石催化剂的存在下，产生高产率的中间馏分。

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