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1. 发明授权

US5760112A Water-borne autodepositing coating compositions 失效
标题翻译：水性自沉积涂料组合物
公开(公告)号：US5760112A
公开(公告)日：1998-06-02
申请号：US696958
申请日：1996-08-23
申请人： Mutsumi Hirota , Takumi Honda , Norifumi Hatano , Shoichi Sangenya , Shunjiro Saiki
发明人： Mutsumi Hirota , Takumi Honda , Norifumi Hatano , Shoichi Sangenya , Shunjiro Saiki
IPC分类号： B01F17/00 , C09D5/08 , C08K5/42
CPC分类号： B01F17/0057 , C09D5/088
摘要： A water-borne autodepositing coating composition that has a pH of 1.6 to 5 and contains as essential components a water-dispersible or water-soluble organic coating-forming resin, a liquid dispersion of carbon black, acid, and oxidizing agent, and that may contain metal ions as an optional component, has an excellent storage stability and produces a strongly adherent and highly corrosion-resistant coating when the liquid dispersion of carbon black is an aqueous dispersion in which carbon black is dispersed using as a dispersant a naphthalenesulfonate-formaldehyde condensate.
摘要翻译： PCT No.PCT / US95 / 01935 Sec。 371日期：1996年8月23日 102（e）日期1996年8月23日PCT提交1995年2月22日PCT公布。 WO95 / 23038 PCT公开日期1995年8月31日水性自动沉积涂料组合物，其pH为1.6〜5，作为必要成分含有水分散性或水溶性有机涂层形成性树脂，炭黑，酸性和氧化性的液体分散体并且可以含有金属离子作为任选的组分，具有优异的储存稳定性，并且当炭黑的液体分散体是其中使用分散剂分散炭黑的水性分散体时，产生强粘附和高度耐腐蚀的涂层萘磺酸盐 - 甲醛缩合物。

2. 发明授权

US6033492A Composition and process for autodeposition with modifying rinse of wet autodeposited coating film 失效
标题翻译：用湿法自动沉积涂膜改性冲洗自动沉积的组成和工艺
公开(公告)号：US6033492A
公开(公告)日：2000-03-07
申请号：US298
申请日：1998-01-26
申请人： Takumi Honda , Mutsumi Hirota , Norifumi Hatano
发明人： Takumi Honda , Mutsumi Hirota , Norifumi Hatano
IPC分类号： B05D7/14 , C23C8/00
CPC分类号： B05D7/144
摘要： The uniformity of gloss of a dried autodeposited resin film on a metal surface can be increased by rinsing the wet autodeposited film initially formed with an aqueous modifying rinse having a pH from 6 to 11 and comprising from 0.2 to 10.0 g/L in total of polymers of carboxylic acid monomers having an ethylenic double bond and salts thereof.
摘要翻译： PCT No.PCT / US96 / 11833 Sec。 371日期1998年1月26日 102（e）1998年1月26日PCT PCT 1996年7月24日PCT公布。出版物WO97 / 04880 日期1997年2月13日通过用pH为6〜11的水性改性漂洗液冲洗初始形成的湿自动沉积膜，可以增加金属表面上干燥的自动沉积树脂膜的光泽均匀性，并且包含0.2至10.0g / 总共有具有烯属双键的羧酸单体的聚合物及其盐。

3. 发明授权

US5688560A Process for coating metal surfaces 失效
标题翻译：金属表面涂层工艺
公开(公告)号：US5688560A
公开(公告)日：1997-11-18
申请号：US640956
申请日：1996-05-09
申请人： Takumi Honda , Kazuhisa Naito , Mutsumi Hirota
发明人： Takumi Honda , Kazuhisa Naito , Mutsumi Hirota
IPC分类号： B05D7/14 , C09D5/08 , B05D3/10 , B05D3/00
CPC分类号： C09D5/088 , B05D7/144
摘要： A process for coating metal surfaces in which an uncured resin coating is formed on the surface of a metal by contacting the metal surface with an autodepositing coating composition that contains acid, oxidizing agent, and water-dispersible or water-soluble organic film-forming resin, and the uncured coating is thereafter dried, produces a strongly adherent, highly corrosion-resistant autodeposited coating when the uncured coating is brought, prior to its drying, into contact with an aqueous solution that has a pH adjusted to 7 to 11 and that contains at least one selection from the following inorganic acids and salts thereof: molybdic acid, tungstic acid, polyphosphoric acid, and polysilicic acid.
摘要翻译： PCT No.PCT / US94 / 12221 Sec。 371日期：1996年5月9日 102（e）日期1996年5月9日PCT 1994年11月1日PCT PCT。出版物WO95 / 13145 日期1995年5月18日一种通过使金属表面与含有酸，氧化剂和水分散性或水溶性有机物的自动沉积涂料组合物接触而在金属表面上涂覆未固化的树脂涂层的金属表面的方法然后干燥未固化的涂层，当未固化的涂层在其干燥之前与pH调节至7至约的水溶液接触时，产生强粘附的，高度耐腐蚀的自沉积涂层 11，其含有下列无机酸及其盐的至少一种选择：钼酸，钨酸，多磷酸和聚硅酸。

4. 发明授权

US5510410A Autodeposition coating composition 失效
标题翻译：自动沉积涂料组合物
公开(公告)号：US5510410A
公开(公告)日：1996-04-23
申请号：US256913
申请日：1994-07-29
申请人： Takumi Honda , Kazuhisa Naito , Mitsuyuki Koga
发明人： Takumi Honda , Kazuhisa Naito , Mitsuyuki Koga
IPC分类号： C09D5/08 , C23C22/44 , C08K3/10 , C08K5/04 , C08K5/51
CPC分类号： C23C22/44 , C09D5/088
摘要： The invention is an aqueous autodeposition coating composition that produces a film that has a better adherence and corrosion resistance than the films formed by the prior-art coating compositions, but which does so without a rinse treatment (for example, a chromium containing solution, rinse) prior to film curing. The aqueous autodeposition coating composition has a pH of 1.6 to 5.0 and contains(i) water-dispersible or water-soluble organic film-forming resin,(ii) at least one of fluoride ions or fluoride ions and complex fluoride ions,(iii) hexavalent chromium ion or hexavalent chromium ion+trivalent chromium ion, and(iv) tungstate ion and/or molybdate ion.
摘要翻译： PCT No.PCT / US93 / 00138 Sec。 371日期1994年7月29日第 102（e）日期1994年7月29日PCT 1993年1月15日PCT公布。公开号WO93 / 15155 日期：1993年8月5日。本发明是一种水性自沉积涂料组合物，其产生比现有技术的涂料组合物形成的膜具有更好的粘合性和耐腐蚀性，但是没有进行冲洗处理（例如，，含铬溶液，冲洗）。水性自沉淀涂料组合物的pH为1.6〜5.0，含有（i）水分散性或水溶性有机成膜树脂，（ii）氟离子或氟离子和配位氟离子中的至少一种，（iii）六价铬离子或六价铬离子+三价铬离子，以及（iv）钨酸根离子和/或钼酸根离子。

5. 发明授权

US06736908B2 Composition and process for treating metal surfaces and resulting article 有权
标题翻译：用于处理金属表面和所得制品的组合物和方法
公开(公告)号：US06736908B2
公开(公告)日：2004-05-18
申请号：US10169478
申请日：2002-11-12
申请人： Ryosuke Sako , Keiichi Ueno , Takumi Honda
发明人： Ryosuke Sako , Keiichi Ueno , Takumi Honda
IPC分类号： C23C2200
CPC分类号： C09D161/14 , C08L61/14 , C23C22/34 , C23C22/40 , C23C22/44 , Y10T428/31678
摘要： A metal treating composition comprising at least a specific type of dissolved and/or dispersed organic resin, a dissolved vanadium compound in which the valence of vanadium is from 3 to 5, and a dissolved compound that contains at least one of the metals Zr, Ti, Mo, W, Mn, and Ce can provide metal surfaces with superior corrosion resistance, alkali resistance, and fingerprint resistance. The composition contains no chromium to cause pollution problems and/or require pollution abatement.
摘要翻译：一种金属处理组合物，其至少包含一种特定类型的溶解和/或分散的有机树脂，其中钒的价数为3至5的溶解的钒化合物和包含至少一种金属Zr，Ti ，Mo，W，Mn和Ce可以为金属表面提供优异的耐腐蚀性，耐碱性和耐指纹性。该组合物不含铬，导致污染问题和/或需要减少污染。

6. 发明授权

US5646211A Autodeposition coating composition 失效
标题翻译：自动沉积涂料组合物
公开(公告)号：US5646211A
公开(公告)日：1997-07-08
申请号：US634132
申请日：1996-04-19
申请人： Takumi Honda , Kazuhisa Naito
发明人： Takumi Honda , Kazuhisa Naito
IPC分类号： C09D5/08 , C23C22/44 , C08K3/10
CPC分类号： C09D5/088 , C23C22/44
摘要： An aqueous autodeposition coating composition that is essentially free of chromium compounds and which produces a film with a much better adherence and corrosion resistance than heretofore obtained, but which does so without a rinse treatment with a chromium-containing solution prior to film curing. The aqueous autodeposition coating composition has a pH of about 1.6 to about 5 and contains(i) water-dispersible or water-soluble organic film-forming resin;(ii) at least one of fluoride ions and flouride ions and complex fluoride ions;(iii) ions of at least one metal selected from zinc, cobalt, manganese, nickel, iron, and aluminum; and(iv) tungstate ion and/or molybdate ion.
摘要翻译：一种基本上不含铬化合物的水性自沉积涂料组合物，其产生具有比迄今为止获得的更好的粘合性和耐腐蚀性的膜，但是在膜固化之前没有用含铬溶液进行漂洗处理。水性自沉淀涂料组合物的pH为约1.6至约5，并含有（i）水分散性或水溶性有机成膜树脂; （ii）氟离子和氟离子中的至少一种和复合氟离子; （iii）选自锌，钴，锰，镍，铁和铝中的至少一种金属的离子; 和（iv）钨酸根离子和/或钼酸根离子。

7. 发明授权

US5141575A Surface treatment for zinciferous surfaces 失效
标题翻译：锌表面的表面处理
公开(公告)号：US5141575A
公开(公告)日：1992-08-25
申请号：US505337
申请日：1990-04-05
申请人： Noriaki Yoshitake , Kenshi Saeki , Takumi Honda , Takao Ogino
发明人： Noriaki Yoshitake , Kenshi Saeki , Takumi Honda , Takao Ogino
IPC分类号： C07D311/22 , A61K31/35 , A61K31/352 , A61K47/32 , A61K47/38 , A61P29/00 , C23C22/33
CPC分类号： C23C22/33 , C23C2222/20
摘要： Zinciferous surfaces, particularly those of galvanized steel, may be effectively protected against corrosion, either as treated or after painting, while remaining easy to weld, by contact with an aqueous solution containing chromium in both +6 and +3 valence states, phosphate, a tertiary alcohol or similar oxidation stable, water soluble organic compound as a wetting agent, and a silane coupling agent, followed by drying with a film from the solution still in place on the surface. A thin coating containing 10-200 mg/m.sup.2 of chromium is formed on the surface to provide a protective layer that is also an excellent base for paint.
摘要翻译：通过与含有+6和+3价态的铬的水溶液接触，可以有效地防止含锌表面，特别是镀锌钢的表面，防止被处理或涂漆后的腐蚀，同时保持容易焊接，磷酸盐，叔醇或类似的氧化稳定性，水溶性有机化合物作为润湿剂，和硅烷偶联剂，然后用溶液从表面干燥。在表面上形成含有10-200mg / m 2的铬的薄涂层，以提供也是漆的优良基材的保护层。

8. 发明授权

US06211283B1 Electrically insulated metallic surfaces with interior corners and methods and compositions therefor 失效
标题翻译：具有内角的电绝缘金属表面及其方法和组合物
公开(公告)号：US06211283B1
公开(公告)日：2001-04-03
申请号：US09125847
申请日：1998-08-21
申请人： Takumi Honda , Kenji Takahashi
发明人： Takumi Honda , Kenji Takahashi
IPC分类号： C08J300
CPC分类号： B05D7/144 , B05D7/142 , C09D5/088
摘要： An effective electrically insulating film on the surface of a metal object, such as a common type of electric motor core assembly, in which the surface includes an interior comer on which insulation is desired, can be formed by autodeposition with an adequate thickness in the interior corner without need for excessive thickness on other parts of the surface that are more readily covered by prior art methods of applying an insulating coating. If the autodeposition composition used includes as its primary film-forming component a copolymer of certain acrylic monomers, a very high volume resistivity can be achieved.
摘要翻译：在金属物体表面上的有效的电绝缘膜，例如常见类型的电动机芯组件，其中表面包括需要绝缘的内角，可以通过在内部具有足够的厚度自动沉积而形成角部，而不需要通过施加绝缘涂层的现有技术方法更容易地覆盖的表面的其它部分上的过厚。如果使用的自沉积组合物包括某些丙烯酸类单体的共聚物作为其初始成膜组分，则可以实现非常高的体积电阻率。

9. 发明授权

US06395336B1 Process for improving the corrosion resistance of a metal surface 失效
标题翻译：提高金属表面耐腐蚀性的工艺
公开(公告)号：US06395336B1
公开(公告)日：2002-05-28
申请号：US09600368
申请日：2000-07-14
申请人： Takumi Honda , Mutsumi Yanagi
发明人： Takumi Honda , Mutsumi Yanagi
IPC分类号： B05D136
CPC分类号： B05D7/142 , B05D7/144 , C09D5/088
摘要： A resin coating is formed on a metal surface using an aqueous autodepositing resin composition that contains oxidizing agent, acid, and carboxyl-functional and/or hydroxyl-functional water-dispersible or water-soluble resin and, optionally, metal ions; the resulting coating, while still in its uncured condition, is subject to post-treatment with an aqueous solution containing from 0.5 to 5.0 g/L of amine and from 10 to 100 g/L (solids) of water-soluble amino resin molecules that bear at least two alkoxymethylamino, methylolamino, and/or imino groups; and the coating is then dried and cured. This provides a highly anticorrosive coating on the metal, and contrary to an analogous process in which the post-treatment solution contains amino resin but not amine, the post-treatment solution remains stable and provides continuing high quality coating performance even after a considerable amount of metal surface per unit volume of post-treatment solution has been processed.
摘要翻译：使用包含氧化剂，酸和羧基官能和/或羟基官能的水分散性或水溶性树脂和任选的金属离子的水性自动沉积树脂组合物在金属表面上形成树脂涂层; 所得到的涂层当仍处于未固化状态时，用含有0.5-5.0g / L胺和10-100g / L（固体）水溶性氨基树脂分子的水溶液进行后处理，该水溶液含有至少两个烷氧基甲基氨基，羟甲基氨基和/或亚氨基; 然后将涂层干燥并固化。这提供了金属上的高度防腐涂层，与后处理溶液含有氨基树脂而不是胺类似的方法相反，后处理溶液保持稳定，并且即使在相当量的金属表面每单位体积的后处理溶液已经被处理。

10. 发明授权

US4959277A Process for treating plated steel sheet 失效
标题翻译：镀钢板的处理方法
公开(公告)号：US4959277A
公开(公告)日：1990-09-25
申请号：US444664
申请日：1989-12-01
申请人： Kenshi Saeki , Takao Ogino , Noriaki Yoshitake , Takumi Honda , Akira Nishihara , Hiroshi Okita , Yukio Tsuge , Haruo Iizuka
发明人： Kenshi Saeki , Takao Ogino , Noriaki Yoshitake , Takumi Honda , Akira Nishihara , Hiroshi Okita , Yukio Tsuge , Haruo Iizuka
IPC分类号： C09D5/44 , C08G18/10 , C08G18/64 , C08K3/36 , C09D175/00 , C09D175/04 , C09D175/12
CPC分类号： C08K3/36 , C08G18/10 , C08G18/643 , C09D175/12 , Y10T428/12542 , Y10T428/12549 , Y10T428/12556 , Y10T428/12569 , Y10T428/12611 , Y10T428/12799 , Y10T428/12972
摘要： The present invention relates to a process for surface treatment for cathodic electrodeposit coating of a zinc-plated or zinc alloy-plated steel sheet comprising coating and drying a protective coating material on said steel sheet chromate-treated beforehand, to form a protective film before subjecting the sheet to the cathodic electrodeposit coating, which comprises coating a protective coating material having as a principal constituent of film-forming organic component a block isocyanate-containing prepolymer containing in one and the same molecule respectively at least one blocked isocyanate group, hydroxyl group, and tertiary amono group and containing 10-100 parts by weight of silica sol relative to 100 parts by weight of said prepolymer, in an amount of 0.3 g-4 g/m.sup.2, and then heat-drying the same.

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