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1. 发明授权

US3970037A Coating composition vaporizer 失效
标题翻译：涂料组合物蒸发器
公开(公告)号：US3970037A
公开(公告)日：1976-07-20
申请号：US533609
申请日：1974-12-17
申请人： John F. Sopko
发明人： John F. Sopko
IPC分类号： C03C17/00 , C03C17/245 , C23C16/453 , C23C16/54 , C23C13/12
CPC分类号： C03C17/245 , C03C17/002 , C23C16/453 , C23C16/545 , C03C2217/21 , C03C2217/217 , C03C2217/219 , C03C2217/23 , C03C2218/152
摘要： A metal reactant, dissolved in a volatile solvent, is sprayed into converging reactive carrier gas streams, is vaporized and is carried past a heater for ultimate discharge against a heated substrate whereupon the metal reactant and a portion of the reactive gas streams react to form an adherent coating on the substrate.
摘要翻译：溶解在挥发性溶剂中的金属反应物被喷射到会聚的反应性载气流中，被蒸发并被运送通过加热器以最终排放到加热的基底上，于是金属反应物和一部分反应气流反应形成基材上的粘附涂层。

2. 发明授权

US06436541B1 Conductive antireflective coatings and methods of producing same 有权
标题翻译：导电抗反射涂层及其制造方法
公开(公告)号：US06436541B1
公开(公告)日：2002-08-20
申请号：US09287305
申请日：1999-04-07
申请人： John F. Sopko , Michael O. Okoroafor , Huawen Li , George A. Neuman
发明人： John F. Sopko , Michael O. Okoroafor , Huawen Li , George A. Neuman
IPC分类号： B32B900
CPC分类号： G02B1/116 , G02B1/16 , Y10T428/24942 , Y10T428/24975 , Y10T428/265
摘要： This invention relates to a two layers or more anti-static film coating deposited on a substrate. Selected layers of the films may have anti-static and/or electromagnetic properties. In one embodiment, the film farthest from the substrate has an index of refraction lower than the underlying film. In another embodiment, the surface of the film is roughened to provide a graded index of refraction.
摘要翻译：本发明涉及沉积在基底上的两层或多层抗静电膜涂层。所选择的膜层可具有抗静电和/或电磁特性。在一个实施例中，距衬底最远的膜的折射率低于下面的膜。在另一个实施例中，膜的表面被粗糙化以提供渐变的折射率。

3. 发明授权

US4401695A Method of and apparatus for applying powder coating reactants 失效
标题翻译：粉末涂料反应物的应用方法和设备
公开(公告)号：US4401695A
公开(公告)日：1983-08-30
申请号：US383644
申请日：1982-06-01
申请人： John F. Sopko
发明人： John F. Sopko
IPC分类号： B05D1/12 , B05D7/00 , C03C17/00 , C03C17/23 , C23C20/08
CPC分类号： B05D1/12 , C03C17/002 , C03C17/23 , C03C2217/211 , C03C2217/229 , C03C2217/23 , C03C2218/17
摘要： A method is disclosed for depositing a coating from a gaseous stream of a powder coating reactant, wherein the carrier gas is supplied at a high volume rate (at least 100 cubic ft./min) and low pressure (not greater than one psi).
摘要翻译：公开了一种从粉末涂料反应物的气流中沉积涂层的方法，其中载气以高体积速率（至少100立方英尺/分钟）和低压（不大于1psi）供应。

4. 发明授权

US5356718A Coating apparatus, method of coating glass, compounds and compositions for coating glasss and coated glass substrates 失效
标题翻译：涂布装置，玻璃涂覆方法，用于涂覆玻璃和涂覆的玻璃基板的化合物和组合物
公开(公告)号：US5356718A
公开(公告)日：1994-10-18
申请号：US17930
申请日：1993-02-16
申请人： Patricia R. Athey , Douglas S. Dauson , David E. Lecocq , George A. Neuman , John F. Sopko , Royann L. Stewart-Davis
发明人： Patricia R. Athey , Douglas S. Dauson , David E. Lecocq , George A. Neuman , John F. Sopko , Royann L. Stewart-Davis
IPC分类号： B32B9/00 , B32B17/06 , C03C17/00 , C03C17/23 , C03C17/245 , C03C17/30 , C03C17/34 , C07C7/04 , C23C16/40 , C23C16/44 , C23C16/453 , C23C16/455 , C23C16/54
CPC分类号： C03C17/245 , C03C17/002 , C03C17/2453 , C03C17/3417 , C23C16/401 , C23C16/4412 , C23C16/453 , C23C16/545 , C03C2217/211 , C03C2217/212 , C03C2217/213 , C03C2217/215 , C03C2217/216 , C03C2217/218 , C03C2217/219 , C03C2217/228 , C03C2217/23 , C03C2217/241 , C03C2217/244 , C03C2218/152
摘要： An apparatus for coating a glass ribbon has an exhaust on each side of a coating unit at different distances therefrom. With this arrangement, portions of the ribbon upstream and downstream of the coating unit are exposed to coating vapors from the coating unit for different periods of time. A coating mixture includes tin containing precursors and a silicon containing precursor. The silicon containing precursor has the structural formula ##STR1## where R.sub.1 is a group which does not have an oxygen available to form a peroxide, R.sub.2 is a functional group giving the silicon containing precursor the ability to be easily converted to silicon oxide coating, R.sub.3 is a bridging group to provide for multiple silicon atoms and R.sub.4 completes the bonding on the foundation silicon atom. An accelerant e.g. a phosphorus containing precursor may be used with the metal containing precursors to increase the deposition rate of the coating. The coating deposited on the glass has regions of continuously varying weight percent of silicon oxide and tin oxide as the distance from the glass-coating interface increases, with the surface of the coating farthest from the glass-coating interface being predominantly tin oxide. The regions within the coating provide the coating with different indices of refraction to eliminate iridescence resulting from increased thickness of the tin oxide at the outer coating surface and to provide the coated glass article with a neutral color. When phosphorus is used as the accelerant, the percent of crystallinity is reduced and approaches O, thereby reducing or eliminating the coating haze.
摘要翻译：用于涂覆玻璃带的设备在与其不同的距离处的涂布单元的每一侧上具有排气。通过这种布置，涂层单元的上游和下游的部分部分暴露于来自涂覆单元的涂覆蒸气不同的时间段。涂料混合物包括含锡前体和含硅前体。含硅前体具有结构式“IMAGE”，其中R1是不具有可用于形成过氧化物的氧的基团，R2是赋予含硅前体的能够容易地转化为氧化硅涂层的功能，R3 是提供多个硅原子的桥接基团，R4完成了在基础硅原子上的键合。加速剂例如可以将含磷前体与含金属的前体一起使用以增加涂层的沉积速率。随着玻璃 - 涂层界面的距离增加，沉积在玻璃上的涂层具有连续变化重量百分比的氧化硅和氧化锡的区域，其中最远离玻璃 - 涂层界面的涂层的表面主要是氧化锡。涂层中的区域为涂层提供不同的折射率，以消除由外涂层表面上的氧化锡厚度增加而产生的虹彩，并为涂覆的玻璃制品提供中性色。当磷用作促进剂时，结晶度的百分比降低并接近O，从而减少或消除涂层雾度。

5. 发明授权

US4259371A Method for improving the alkali durability of metal oxide films formed by pyrolysis 失效
标题翻译：提高通过热解形成的金属氧化物膜的耐碱性的方法
公开(公告)号：US4259371A
公开(公告)日：1981-03-31
申请号：US060318
申请日：1979-07-25
申请人： Dennis S. Postupack , John F. Sopko
发明人： Dennis S. Postupack , John F. Sopko
IPC分类号： C03C17/25 , C03C17/23 , B05D3/02
CPC分类号： C03C17/23 , C03C2217/229 , C03C2218/112
摘要： A method is disclosed for improving the uniformity and durability of a pyrolytically deposited metal oxide film on glass by cooling the coating solution and/or the atomizing air prior to the application of the coating composition to the hot glass surface.
摘要翻译：公开了一种通过在将涂料组合物施加到热玻璃表面之前冷却涂覆溶液和/或雾化空气来提高玻璃上热解沉积的金属氧化物膜的均匀性和耐久性的方法。

6. 发明授权

US08197940B2 Aqueous suspension for pyrolytic spray coating 有权
标题翻译：用于热解喷涂的水悬浮液
公开(公告)号：US08197940B2
公开(公告)日：2012-06-12
申请号：US12179669
申请日：2008-07-25
申请人： John F. Sopko , Patricia R. Athey
发明人： John F. Sopko , Patricia R. Athey
IPC分类号： B32B15/00
CPC分类号： C03C17/25 , C03C2217/217 , C03C2217/219 , C03C2217/23 , C03C2218/112
摘要： The durability of a transparent pyrolytic spray applied coating is improved by providing a spray solution of metal acetylacetonates having different particle size distribution. More particularly, the particle size distribution of each of the metal acetylacetonates is a function of its melting temperature, and optionally of its melting temperature and solubility.
摘要翻译：通过提供具有不同粒度分布的金属乙酰丙酮化物的喷雾溶液来改善透明热解喷涂涂层的耐久性。更具体地，每个金属乙酰丙酮化物的粒度分布是其熔融温度，以及任选其熔融温度和溶解度的函数。

7. 发明授权

US3951100A Chemical vapor deposition of coatings 失效
标题翻译：化学气相沉积涂层
公开(公告)号：US3951100A
公开(公告)日：1976-04-20
申请号：US507656
申请日：1974-09-18
申请人： John F. Sopko , Krishna Simhan
发明人： John F. Sopko , Krishna Simhan
IPC分类号： C03C17/00 , C03C17/245 , C23C16/40 , C23C16/453 , C23C16/54 , C23C13/08
CPC分类号： C23C16/545 , C03C17/00 , C03C17/002 , C03C17/245 , C23C16/40 , C23C16/453 , C03C2217/21 , C03C2217/217 , C03C2217/219 , C03C2217/23 , C03C2218/152
摘要： A metal oxide coating is applied to a hot glass surface by contacting the surface with a mixture of carrier air, vaporized solvent and a vaporized metal containing reactant. The mixture is directed against the glass through an elongated, converging slot-nozzle, the interior surfaces of which have an increasing radius of curvature towards the exit end, nozzle at a Reynolds number exceeding 2500 with the nozzle-to-glass spacing at least 1.25 times the characteristic dimension of the nozzle.
摘要翻译：通过使表面与载体空气，蒸发溶剂和含有气化金属的反应物的混合物接触，将金属氧化物涂层施加到热玻璃表面。混合物通过细长的会聚狭缝喷嘴引导抵靠玻璃，其内表面朝向出口端具有增加的曲率半径，雷诺数超过2500的喷嘴，喷嘴间距至少为1.25 倍于喷嘴的特征尺寸。

8. 发明授权

US08557328B2 Non-orthogonal coater geometry for improved coatings on a substrate 有权
标题翻译：用于改善衬底上涂层的非正交涂布机几何形状
公开(公告)号：US08557328B2
公开(公告)日：2013-10-15
申请号：US12572317
申请日：2009-10-02
申请人： James W. McCamy , John F. Sopko
发明人： James W. McCamy , John F. Sopko
IPC分类号： C23C16/448 , C23C16/40
CPC分类号： C23C16/4401 , C23C16/4412 , C23C16/45502 , C23C16/45563 , C23C16/45578 , C23C16/45587 , C23C16/54
摘要： A coating apparatus includes non-orthogonal coater geometry to improve coatings on a glass ribbon, and to improve yields of such coatings. The apparatus includes a first arrangement to move the ribbon along a first imaginary straight line through a coating zone provided in a glass forming chamber. The coater has a coating nozzle and an exhaust slot, each have a longitudinal axis. The coating nozzle directs coating vapors toward the coating zone, and the exhaust slot removes vapors from the coating zone. A second arrangement mounts the coater in spaced relation to the path with the coating nozzle and the exhaust slot facing the coating zone. A second imaginary straight line is normal to the longitudinal axis of the coating nozzle, and the first imaginary line and the second imaginary line subtend an angle in the range of greater than zero degrees to 90 degrees.
摘要翻译：涂覆设备包括非正交涂布机几何形状以改善玻璃带上的涂层，并提高这种涂层的产量。该装置包括第一装置，用于沿着第一假想直线穿过设置在玻璃形成室中的涂布区域移动色带。涂布机具有涂覆喷嘴和排气槽，每个具有纵向轴线。涂层喷嘴将涂层蒸气引导到涂层区域，排气槽从涂层区域去除蒸汽。第二布置将涂布机以与涂布喷嘴和排气槽相对的涂布区域的路径间隔开来安置。第二假想直线垂直于涂覆喷嘴的纵向轴线，并且第一假想线和第二假想线对准大于零度至90度范围内的角度。

9. 发明申请

US20110081486A1 NON-ORTHOGONAL COATER GEOMETRY FOR IMPROVED COATINGS ON A SUBSTRATE 有权
标题翻译：用于改善基材上涂层的非正交涂层几何
公开(公告)号：US20110081486A1
公开(公告)日：2011-04-07
申请号：US12572317
申请日：2009-10-02
申请人： James W. McCamy , John F. Sopko
发明人： James W. McCamy , John F. Sopko
IPC分类号： C23C16/448 , C23C16/40
CPC分类号： C23C16/4401 , C23C16/4412 , C23C16/45502 , C23C16/45563 , C23C16/45578 , C23C16/45587 , C23C16/54
摘要： A coating apparatus includes non-orthogonal coater geometry to improve coatings on a glass ribbon, and to improve yields of such coatings. The apparatus includes a first arrangement to move the ribbon along a first imaginary straight line through a coating zone provided in a glass forming chamber. The coater has a coating nozzle and an exhaust slot, each have a longitudinal axis. The coating nozzle directs coating vapors toward the coating zone, and the exhaust slot removes vapors from the coating zone. A second arrangement mounts the coater in spaced relation to the path with the coating nozzle and the exhaust slot facing the coating zone. A second imaginary straight line is normal to the longitudinal axis of the coating nozzle, and the first imaginary line and the second imaginary line subtend an angle in the range of greater than zero degrees to 90 degrees.
摘要翻译：涂覆设备包括非正交涂布机几何形状以改善玻璃带上的涂层，并提高这种涂层的产量。该装置包括第一装置，用于沿着第一假想直线穿过设置在玻璃形成室中的涂布区域移动色带。涂布机具有涂覆喷嘴和排气槽，每个具有纵向轴线。涂层喷嘴将涂层蒸气引导到涂层区域，排气槽从涂层区域去除蒸汽。第二布置将涂布机以与涂布喷嘴和排气槽相对的涂布区域的路径间隔开来安置。第二假想直线垂直于涂覆喷嘴的纵向轴线，并且第一假想线和第二假想线对准大于零度至90度范围内的角度。

10. 发明申请

US20100021746A1 AQUEOUS SUSPENSION FOR PYROLYTIC SPRAY COATING 有权
标题翻译：水性喷雾涂料的水性悬浮液
公开(公告)号：US20100021746A1
公开(公告)日：2010-01-28
申请号：US12179669
申请日：2008-07-25
申请人： John F. Sopko , Patricia R. Athey
发明人： John F. Sopko , Patricia R. Athey
IPC分类号： C23C14/54 , B01F13/00
CPC分类号： C03C17/25 , C03C2217/217 , C03C2217/219 , C03C2217/23 , C03C2218/112
摘要： The durability of a transparent pyrolytic spray applied coating is improved by providing a spray solution of metal acetylacetonates having different particle size distribution. More particularly, the particle size distribution of each of the metal acetylacetonates is a function of its melting temperature, and optionally of its melting temperature and solubility.
摘要翻译：通过提供具有不同粒度分布的金属乙酰丙酮化物的喷雾溶液来改善透明热解喷涂涂层的耐久性。更具体地，每个金属乙酰丙酮化物的粒度分布是其熔融温度，以及任选其熔融温度和溶解度的函数。

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