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1. 发明授权

US08551609B2 Method of depositing niobium doped titania film on a substrate and the coated substrate made thereby 有权
标题翻译：在衬底上沉积掺铌的二氧化钛膜的方法和由此制成的涂覆的衬底
公开(公告)号：US08551609B2
公开(公告)日：2013-10-08
申请号：US12767910
申请日：2010-04-27
申请人： Songwei Lu , James W. McCamy , James J. Finley
发明人： Songwei Lu , James W. McCamy , James J. Finley
IPC分类号： C03C17/34
CPC分类号： C03C17/3417 , C03C17/002 , C03C17/2456 , C03C17/256 , C03C2217/212 , C03C2217/218 , C03C2217/24 , C03C2217/94 , C03C2218/112 , C03C2218/152
摘要： A coated article includes a pyrolytic applied transparent electrically conductive oxide film of niobium doped titanium oxide. The article can be made by using a coating mixture having a niobium precursor and a titanium precursor. The coating mixture is directed toward a heated substrate to decompose the coating mixture and to deposit a transparent electrically conductive niobium doped titanium oxide film on the surface of the heated substrate. In one embodiment of the invention, the method is practiced using a vaporized coating mixture including a vaporized niobium precursor; a vaporized titanium precursor, and a carrier gas to deposit a niobium doped titanium oxide film having a sheet resistance greater than 1.2 and an index of refraction of 2.3 or greater. The chemical formula for the niobium doped titanium oxide is Nb:TiOX where X is in the range of 1.8-2.1.
摘要翻译：涂覆制品包括掺铌掺杂的氧化钛的热解涂覆的透明导电氧化物膜。该制品可以通过使用具有铌前体和钛前体的涂料混合物来制备。涂层混合物指向加热的基底以分解涂层混合物并在被加热的基底的表面上沉积透明导电的掺铌的氧化钛膜。在本发明的一个实施方案中，该方法是使用包括蒸发的铌前体的蒸发涂层混合物来实施的; 蒸发的钛前体和载气，以沉积具有大于1.2的薄层电阻并且折射率为2.3或更大的掺铌氧化钛膜。掺杂铌的氧化钛的化学式是Nb：TiOX，其中X在1.8-2.1的范围内。

2. 发明授权

US08535501B2 Electrical contact arrangement for a coating process 有权
标题翻译：涂层工艺的电接触布置
公开(公告)号：US08535501B2
公开(公告)日：2013-09-17
申请号：US13015626
申请日：2011-01-28
申请人： Benjamin Kabagambe , James W. McCamy , Donald W. Boyd
发明人： Benjamin Kabagambe , James W. McCamy , Donald W. Boyd
IPC分类号： C25D13/12
CPC分类号： C25D13/22 , C25D13/12 , F16B2/10
摘要： A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.
摘要翻译：通过偏置具有可延展导电材料层的导电构件（例如，导电构件），将保护涂层施加到太阳能反射镜的反射涂层的导电表面。在导电表面上移动可电沉积涂料组合物时，将其粘贴到导电表面的一部分上。可电沉积涂料组合物在导电表面上的移动包括通过可电沉积涂料组合物的流动幕移动太阳镜，并将太阳镜浸没在可电沉积涂料组合物的池中。在导电构件和导电表面之间使用可延展的导电材料层补偿了在涂覆过程期间接触的导电表面中的不规则性，从而降低了电接触区域处的电流密度。

3. 发明申请

US20120097546A1 ELECTROCURTAIN COATING PROCESS FOR COATING SOLAR MIRRORS 有权
标题翻译：用于涂层太阳镜的电镀涂层工艺
公开(公告)号：US20120097546A1
公开(公告)日：2012-04-26
申请号：US12911189
申请日：2010-10-25
申请人： Benjamin Kabagambe , Donald W. Boyd , Michael J. Buchanan , Patrick Kelly , Luke A. Kutilek , James W. McCamy , Douglas A. McPheron , Gary R. Orosz , Raymond D. Limbacher
发明人： Benjamin Kabagambe , Donald W. Boyd , Michael J. Buchanan , Patrick Kelly , Luke A. Kutilek , James W. McCamy , Douglas A. McPheron , Gary R. Orosz , Raymond D. Limbacher
IPC分类号： C25D7/08 , C25D17/00
CPC分类号： G02B1/14 , C09D5/24 , C09D5/4488 , C25D5/02 , C25D5/08 , C25D7/08 , C25D13/04 , F24S23/77 , F24S23/79 , F24S23/82 , G02B1/10 , G02B1/105 , H01L31/0547 , Y02E10/40 , Y02E10/52
摘要： An electrically conductive protective coating or film is provided over the surface of a reflective coating of a solar mirror by flowing or directing a cation containing liquid and an anion containing liquid onto the conductive surface. The cation and the anion containing liquids are spaced from, and preferably out of contact with one another on the surface of the reflective coating as an electric current is moved through the anion containing liquid, the conductive surface between the liquids and the cation containing liquid to coat the conductive surface with the electrically conductive coating.
摘要翻译：通过将含阳离子的液体和含阴离子的液体流动或引导到导电表面上，在太阳镜的反射涂层的表面上提供导电保护涂层或膜。阳离子和含阴离子的液体在反射涂层的表面上彼此隔开并且优选地彼此不接触，因为电流通过含阴离子的液体，液体和含阳离子的液体之间的导电表面转移到用导电涂层涂覆导电表面。

4. 发明授权

US5386798A Method for continuous control of composition and doping of pulsed laser deposited films 失效
标题翻译：脉冲激光沉积膜的组成和掺杂的连续控制方法
公开(公告)号：US5386798A
公开(公告)日：1995-02-07
申请号：US132528
申请日：1993-10-06
申请人： Douglas H. Lowndes , James W. McCamy
发明人： Douglas H. Lowndes , James W. McCamy
IPC分类号： C23C14/00 , C23C14/06 , C03B31/20
CPC分类号： C23C14/0617 , C23C14/0021 , Y10S148/064 , Y10S438/925
摘要： A method for growing a deposit upon a substrate of semiconductor material involves the utilization of pulsed laser deposition techniques within a low-pressure gas environment. The substrate and a target of a first material are positioned within a deposition chamber and a low-pressure gas atmosphere is developed within the chamber. The substrate is then heated, and the target is irradiated, so that atoms of the target material are ablated from the remainder of the target, while atoms of the gas simultaneously are adsorbed on the substrate/film surface. The ablated atoms build up upon the substrate, together with the adsorbed gas atoms to form the thin-film deposit on the substrate. By controlling the pressure of the gas of the chamber atmosphere, the composition of the formed deposit can be controlled, and films of continuously variable composition or doping can be grown from a single target of fixed composition.
摘要翻译：用于在半导体材料的衬底上生长沉积物的方法涉及在低压气体环境中利用脉冲激光沉积技术。衬底和第一材料的靶材位于沉积室内，并且室内形成低压气体气氛。然后加热基板，照射目标物，使目标材料的原子从目标物的其余部分烧蚀，同时气体的原子同时吸附在基片/薄膜表面上。烧蚀的原子与吸附的气体原子一起堆积在衬底上，以在衬底上形成薄膜沉积物。通过控制室气体的气体压力，可以控制形成的沉积物的组成，并且可以从固定组合物的单个目标生长连续可变组成或掺杂的膜。

5. 发明申请

US20110305906A1 METHOD FOR DEPOSITING AN ELECTRODEPOSITABLE COATING COMPOSITION ONTO A SUBSTRATE USING A PLURALITY OF LIQUID STREAMS 有权
标题翻译：将电沉积涂层组合物沉积在使用多种液体流的基板上的方法
公开(公告)号：US20110305906A1
公开(公告)日：2011-12-15
申请号：US12813537
申请日：2010-06-11
申请人： Gary Orosz , Donald W. Boyd , Benjamin Kabagambe , James W. McCamy , Douglas A. McPheron
发明人： Gary Orosz , Donald W. Boyd , Benjamin Kabagambe , James W. McCamy , Douglas A. McPheron
IPC分类号： C25D13/00 , B32B27/18
CPC分类号： C25D13/00 , C09D5/44 , Y10T428/31504
摘要： The present invention is directed to a method for coating a substrate wherein the substrate is electrically conductive, the method comprising simultaneously applying a plurality of electrically conductive liquid materials to different portions of the substrate wherein at least one of the electrically conductive liquid materials comprises an ionic compound; and applying an electrical current to at least one of the liquid materials thereby depositing the ionic compound onto the substrate.
摘要翻译：本发明涉及一种用于涂覆基底的方法，其中基底是导电的，该方法包括同时将多种导电液体材料施加到基底的不同部分，其中至少一种导电液体材料包含离子复合; 以及向至少一种液体材料施加电流，从而将所述离子化合物沉积到所述基底上。

6. 发明申请

US20130003206A1 REFLECTIVE ARTICLE HAVING A SACRIFICIAL CATHODIC LAYER 有权
标题翻译：具有真实阴极层的反射物品
公开(公告)号：US20130003206A1
公开(公告)日：2013-01-03
申请号：US13171509
申请日：2011-06-29
申请人： Benjamin Kabagambe , Michael J. Buchanan , Matthew S. Scott , Brian K. Rearick , Paul A. Medwick , James W. McCamy
发明人： Benjamin Kabagambe , Michael J. Buchanan , Matthew S. Scott , Brian K. Rearick , Paul A. Medwick , James W. McCamy
IPC分类号： G02B5/08
CPC分类号： C03C17/38 , C03C17/42 , C03C2217/445 , C03C2217/465 , C03C2217/479 , G02B5/0808 , H01L31/0547 , Y02E10/52
摘要： The present invention relates to reflective articles, such as solar mirrors, that include a sacrificial cathodic layer. The reflective article, more particularly includes a substrate, such as glass, having a multi-layered coating thereon that includes a lead-free sacrificial cathodic layer. The sacrificial cathodic layer includes at least one transition metal, such as a particulate transition metal, which can be in the form of flakes (e.g., zinc flakes). The sacrificial cathodic layer can include an inorganic matrix formed from one or more organo-titanates. Alternatively, the sacrificial cathodic layer can include an organic polymer matrix (e.g., a crosslinked organic polymer matrix formed from an organic polymer and an aminoplast crosslinking agent). The reflective article also includes an outer organic polymer coating, that can be electrodeposited over the sacrificial cathodic layer.
摘要翻译：本发明涉及包括牺牲阴极层的反射制品，例如太阳镜。反射制品更具体地包括其上具有多层涂层的诸如玻璃的基底，其包括无铅牺牲阴极层。牺牲阴极层包括至少一种过渡金属，例如粒状过渡金属，其可以是片状（例如锌片）的形式。牺牲阴极层可以包括由一种或多种有机钛酸盐形成的无机基质。或者，牺牲阴极层可以包括有机聚合物基质（例如，由有机聚合物和氨基塑料交联剂形成的交联的有机聚合物基质）。反射制品还包括可以电沉积在牺牲阴极层上的外部有机聚合物涂层。

7. 发明授权

US08277626B2 Method for depositing an electrodepositable coating composition onto a substrate using a plurality of liquid streams 有权
标题翻译：使用多个液体流将电沉积涂料组合物沉积在基材上的方法
公开(公告)号：US08277626B2
公开(公告)日：2012-10-02
申请号：US12813537
申请日：2010-06-11
申请人： Gary Orosz , Donald W. Boyd , Benjamin Kabagambe , James W. McCamy , Douglas A. McPheron
发明人： Gary Orosz , Donald W. Boyd , Benjamin Kabagambe , James W. McCamy , Douglas A. McPheron
IPC分类号： C25D13/00
CPC分类号： C25D13/00 , C09D5/44 , Y10T428/31504
摘要： The present invention is directed to a method for coating a substrate wherein the substrate is electrically conductive, the method comprising simultaneously applying a plurality of electrically conductive liquid materials to different portions of the substrate wherein at least one of the electrically conductive liquid materials comprises an ionic compound; and applying an electrical current to at least one of the liquid materials thereby depositing the ionic compound onto the substrate.
摘要翻译：本发明涉及一种用于涂覆基底的方法，其中基底是导电的，该方法包括同时将多种导电液体材料施加到基底的不同部分，其中至少一种导电液体材料包含离子复合; 以及向至少一种液体材料施加电流，从而将所述离子化合物沉积到所述基底上。

8. 发明申请

US20110262757A1 METHOD OF DEPOSITING NIOBIUM DOPED TITANIA FILM ON A SUBSTRATE AND THE COATED SUBSTRATE MADE THEREBY 有权
标题翻译：在底物上沉积铌酸钡薄膜的方法及其涂覆的基板
公开(公告)号：US20110262757A1
公开(公告)日：2011-10-27
申请号：US12767910
申请日：2010-04-27
申请人： Songwei Lu , James W. McCamy , James J. Finley
发明人： Songwei Lu , James W. McCamy , James J. Finley
IPC分类号： B32B17/06 , B05D5/12 , H01B1/02
CPC分类号： C03C17/3417 , C03C17/002 , C03C17/2456 , C03C17/256 , C03C2217/212 , C03C2217/218 , C03C2217/24 , C03C2217/94 , C03C2218/112 , C03C2218/152
摘要： A coated article includes a pyrolytic applied transparent electrically conductive oxide film of niobium doped titanium oxide. The article can be made by using a coating mixture having a niobium precursor and a titanium precursor. The coating mixture is directed toward a heated substrate to decompose the coating mixture and to deposit a transparent electrically conductive niobium doped titanium oxide film on the surface of the heated substrate. In one embodiment of the invention, the method is practiced using a vaporized coating mixture including a vaporized niobium precursor; a vaporized titanium precursor, and a carrier gas to deposit a niobium doped titanium oxide film having a sheet resistance greater than 1.2 and an index of refraction of 2.3 or greater. The chemical formula for the niobium doped titanium oxide is Nb:TiOX where X is in the range of 1.8-2.1.
摘要翻译：涂覆制品包括掺铌掺杂的氧化钛的热解涂覆的透明导电氧化物膜。该制品可以通过使用具有铌前体和钛前体的涂料混合物来制备。涂层混合物指向加热的基底以分解涂层混合物并在被加热的基底的表面上沉积透明导电的掺铌的氧化钛膜。在本发明的一个实施方案中，该方法是使用包括蒸发的铌前体的蒸发涂层混合物来实施的; 蒸发的钛前体和载气，以沉积具有大于1.2的薄层电阻并且折射率为2.3或更大的掺铌氧化钛膜。掺杂铌的氧化钛的化学式是Nb：TiOX，其中X在1.8-2.1的范围内。

9. 发明授权

US09758426B2 Reflective article having a sacrificial cathodic layer 有权
公开(公告)号：US09758426B2
公开(公告)日：2017-09-12
申请号：US13171509
申请日：2011-06-29
申请人： Benjamin Kabagambe , Michael J. Buchanan , Matthew S. Scott , Brian K. Rearick , Paul A. Medwick , James W. McCamy
发明人： Benjamin Kabagambe , Michael J. Buchanan , Matthew S. Scott , Brian K. Rearick , Paul A. Medwick , James W. McCamy
IPC分类号： G02B5/08 , C03C17/38 , C03C17/42 , H01L31/054
CPC分类号： C03C17/38 , C03C17/42 , C03C2217/445 , C03C2217/465 , C03C2217/479 , G02B5/0808 , H01L31/0547 , Y02E10/52
摘要： The present invention relates to reflective articles, such as solar mirrors, that include a sacrificial cathodic layer. The reflective article, more particularly includes a substrate, such as glass, having a multi-layered coating thereon that includes a lead-free sacrificial cathodic layer. The sacrificial cathodic layer includes at least one transition metal, such as a particulate transition metal, which can be in the form of flakes (e.g., zinc flakes). The sacrificial cathodic layer can include an inorganic matrix formed from one or more organo-titanates. Alternatively, the sacrificial cathodic layer can include an organic polymer matrix (e.g., a crosslinked organic polymer matrix formed from an organic polymer and an aminoplast crosslinking agent). The reflective article also includes an outer organic polymer coating, that can be electrodeposited over the sacrificial cathodic layer.

10. 发明授权

US08557328B2 Non-orthogonal coater geometry for improved coatings on a substrate 有权
标题翻译：用于改善衬底上涂层的非正交涂布机几何形状
公开(公告)号：US08557328B2
公开(公告)日：2013-10-15
申请号：US12572317
申请日：2009-10-02
申请人： James W. McCamy , John F. Sopko
发明人： James W. McCamy , John F. Sopko
IPC分类号： C23C16/448 , C23C16/40
CPC分类号： C23C16/4401 , C23C16/4412 , C23C16/45502 , C23C16/45563 , C23C16/45578 , C23C16/45587 , C23C16/54
摘要： A coating apparatus includes non-orthogonal coater geometry to improve coatings on a glass ribbon, and to improve yields of such coatings. The apparatus includes a first arrangement to move the ribbon along a first imaginary straight line through a coating zone provided in a glass forming chamber. The coater has a coating nozzle and an exhaust slot, each have a longitudinal axis. The coating nozzle directs coating vapors toward the coating zone, and the exhaust slot removes vapors from the coating zone. A second arrangement mounts the coater in spaced relation to the path with the coating nozzle and the exhaust slot facing the coating zone. A second imaginary straight line is normal to the longitudinal axis of the coating nozzle, and the first imaginary line and the second imaginary line subtend an angle in the range of greater than zero degrees to 90 degrees.
摘要翻译：涂覆设备包括非正交涂布机几何形状以改善玻璃带上的涂层，并提高这种涂层的产量。该装置包括第一装置，用于沿着第一假想直线穿过设置在玻璃形成室中的涂布区域移动色带。涂布机具有涂覆喷嘴和排气槽，每个具有纵向轴线。涂层喷嘴将涂层蒸气引导到涂层区域，排气槽从涂层区域去除蒸汽。第二布置将涂布机以与涂布喷嘴和排气槽相对的涂布区域的路径间隔开来安置。第二假想直线垂直于涂覆喷嘴的纵向轴线，并且第一假想线和第二假想线对准大于零度至90度范围内的角度。

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