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    • 7. 发明授权
    • Unsymmetrical polyureaurethane fertilizer encapsulation
    • 不对称聚脲氨酯肥料封装
    • US6001147A
    • 1999-12-14
    • US121376
    • 1998-07-23
    • Peter H. MarkuschJames W. Rosthauser
    • Peter H. MarkuschJames W. Rosthauser
    • C05G3/00C08G18/32C09D175/00C05G5/00
    • C09D175/00C05G3/0029C08G18/3271C08G18/3275
    • This invention relates to processes for the production of unsymmetrical polyurea-urethane coated granular fertilizer products, and to the unsymmetrical polyurea-urethane coated granular fertilizer products produced by these processes. These processes comprise coating fertilizer granules with compounds which react to form unsymmetrical polyurea-urethane coatings, then the compounds are polymerized. Suitable compounds comprise a) an organic polyisocyanate component, and b) an alkanolamine component containing at least one primary or secondary amine group and at least one hydroxyl group. These compounds are present in sufficient quantities that the NCO to active hydrogen group is from about 0.5:1.0 up to about 1.5:1.0. It is necessary that sufficient amounts of these compounds are applied to the fertilizer granules such that the unsymmetrical polyurea-urethane coated granular fertilizer particles contain from about 0.5 to about 15% by weight of polyurea-urethane, based on the total weight of the encapsulated fertilizer particles.
    • 本发明涉及生产不对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品的方法以及由这些方法生产的不对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品。 这些方法包括用化合物包覆肥料颗粒,反应形成不对称的聚脲 - 氨基甲酸酯涂层,然后化合物聚合。 合适的化合物包括a)有机多异氰酸酯组分,和b)含有至少一个伯或仲胺基和至少一个羟基的链烷醇胺组分。 这些化合物以足够的量存在,使活性氢基团的NCO为约0.5:1.0至约1.5:1.0。 需要将足量的这些化合物施加到肥料颗粒上,使得不对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料颗粒含有约0.5至约15重量%的聚脲 - 氨基甲酸酯,基于包封肥料的总重量 粒子。
    • 8. 发明授权
    • Polyurethane contact adhesives with improved temperature resistance
properties
    • 具有改善耐温性能的聚氨酯接触粘合剂
    • US5733966A
    • 1998-03-31
    • US787066
    • 1997-01-22
    • Robert L. ClineJames W. RosthauserPeter H. Markusch
    • Robert L. ClineJames W. RosthauserPeter H. Markusch
    • C08G18/48C08G18/72C09J175/08C08J3/00C08G18/00C08K3/20C08L75/00
    • C08G18/725C08G18/4812C09J175/08C08G2170/40Y02P20/582
    • The present invention relates to highly elastic polyurethane contact adhesives, a process to coat substrates with these contact adhesives, and the coated substrates produced by this process. This invention requires a) a polyisocyanate with a functionality of less than about 4 and b) a polyol blend comprising 1) about 90 to 100% polyethers with molecular weights from about 1,800 to 12,000 and average functionality from about 1.5 to about 4, and 2) up to about 10% of chain extenders with molecular weights from about 60 to 400 and average functionality from about 1.5 to about 3. The functionalities and amounts of components a) and b) are such that the molecular weight between crosslinks is from about 7,000 to about 16,000 and the equivalent ratio of isocyanate groups to isocyanate-reactive groups is from about 80:100 to about 120:100 and the urethane group content is from about 1 to about 8%. It is preferred that at least one of components a) and b) have a functionality of greater than about 2.2.
    • 本发明涉及高弹性聚氨酯接触粘合剂,用这些接触粘合剂涂覆基材的方法以及通过该方法生产的涂布基材。 本发明要求a)具有小于约4的官能度的多异氰酸酯和b)多元醇共混物,其包含1)约90至100%分子量为约1,800至12,000的聚醚,平均官能度为约1.5至约4,和2 )至多约10%的分子量为约60至400且平均官能度为约1.5至约3的扩链剂。组分a)和b)的官能度和量使得交联之间的分子量为约7,000 至约16,000,异氰酸酯基与异氰酸酯反应性基团的当量比为约80:100至约120:100,氨基甲酸酯基含量为约1至约8%。 组分a)和b)中的至少一种优选具有大于约2.2的官能度。
    • 9. 发明授权
    • Aqueous polyurea dispersions prepared by an emulsion polymerization
process
    • 通过乳液聚合方法制备的水性聚脲分散体
    • US5367017A
    • 1994-11-22
    • US877686
    • 1992-05-01
    • James W. RosthauserRobin E. Tirpak
    • James W. RosthauserRobin E. Tirpak
    • C08G18/08C08G18/50C08G18/66C08G18/70C08G18/80C08J3/00C08K3/20C08L75/00
    • C08G18/6685C08G18/0819C08G18/5024C08G18/706C08G18/8064
    • The present invention is directed to a aqueous polyurea dispersion for the preparation of an aqueous polyurea dispersion byI) dispersing in water at an NCO:NH equivalent ratio of 0.5:1.0 to 2.0:1.0a) a polyisocyanate which has an average functionality of 1.5 to 4.0 and an isocyanate content of at least 12% by weight andb) a polyamine component containingi) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups and a molecular weight of at least 1000 andii) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups, a molecular weight of less than 400 and at least one anionic or potential anionic group andII) allowing the polyisocyanate and polyamine component to react to form an aqueous polyurea dispersion.The present invention is also directed to the aqueous polyurea dispersion prepared by this aqueous polyurea dispersion.
    • 本发明涉及一种用于制备聚脲水分散体的水性聚脲分散体,其通过I)以0.5: 1.0至2.0:1.0的NCO:NH当量比分散在水中,a)多异氰酸酯的平均官能度为1.5 至4.0,异氰酸酯含量为至少12重量%,b)多胺组分,其含有i)30至70摩尔%的具有至少两个伯和/或仲氨基并且分子量至少为1000的多胺;以及 ii)30-70摩尔%的具有至少两个伯和/或仲氨基,分子量小于400和至少一个阴离子或潜在阴离子基团的多胺,和II)允许多异氰酸酯和多胺组分与 形成聚脲水分散体。 本发明还涉及由该聚脲分散体水溶液制备的聚脲水溶液。