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1. 发明申请

US20110034628A1 BRANCHED POLYOLS CONTAINING ON AVERAGE TWO OR MORE HYDROXYL GROUPS PER MOLECULE,THEIR PREPARATION AND USE 审中-公开
标题翻译：包含平均每分子两个或多个羟基的分支的多元醇，其制备和使用
公开(公告)号：US20110034628A1
公开(公告)日：2011-02-10
申请号：US12300535
申请日：2007-05-09
申请人： Gunther Ott , Bjorn Feldmann , Sabine Holtschulte , Andreas Janssen , Christin Sobbe , Karl-Heinz Joost
发明人： Gunther Ott , Bjorn Feldmann , Sabine Holtschulte , Andreas Janssen , Christin Sobbe , Karl-Heinz Joost
IPC分类号： C08G18/72 , C08L75/04
CPC分类号： C08G18/792 , C08G18/0823 , C08G18/2825 , C08G18/3212 , C08G18/4063 , C08G18/4283 , C09D175/04
摘要： Disclosed are branched polyols (A) having two or more hydroxyl groups per molecule prepared by providing a polyisocyanate (A1) containing per molecule two or more isocyanate groups and either two or more hard segments (a11) which as part of a thermoset three-dimensional network raise its glass transition temperature, or two or more soft segments which as part of a thermoset three-dimensional network lower its glass transition temperature; and reacting the polyisocyanate (A1) with a polyol (A2) in a molar ratio (A2):(A1) of ≧2 and an equivalent ratio of [X+OH]:NCO≧2; wherein polyol (A2) has the general formula I: X [—R(—OH)n]m, and the variables have the following definitions: n is a number from 1 to 5, m is 1 or 2, X is an isocyanate-reactive functional group, and R is a divalent to pentavalent organic radical, with the proviso that R comprises at least one hard segment (a11) if (A1) comprises soft segments.
摘要翻译：公开了每分子具有两个或多个羟基的支化多元醇（A），其通过提供每分子含有两个或更多个异氰酸酯基团和两个或更多个硬链段（a11）制备的多异氰酸酯（A1），所述硬链段作为热固性三维网络提高其玻璃化转变温度，或两个或更多软段，作为热固性三维网络的一部分降低其玻璃化转变温度; 并使多异氰酸酯（A1）与摩尔比（A2）：（A1）= 2的多元醇（A2）和当量的[X + OH]:NCO≥2的比例反应; 其中多元醇（A2）具有通式I：X [-R（-OH）n] m，并且变量具有以下定义：n为1至5的数，m为1或2，X为异氰酸酯 - 反应性官能团，R是二价至五价有机基团，条件是如果（A1）包含软链段，R包含至少一个硬链段（a11）。

2. 发明申请

US20100273975A1 POLYOLS BASED ON MODIFIED AMINO RESINS, THEIR PREPARATION AND 失效
标题翻译：基于改性氨基树脂的多元醇及其制备方法
公开(公告)号：US20100273975A1
公开(公告)日：2010-10-28
申请号：US12160348
申请日：2007-02-09
申请人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
发明人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
IPC分类号： C08G12/40
CPC分类号： C08G12/44 , C08G6/02 , C09D161/32
摘要： Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I)>N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).
摘要翻译：本文公开了一种基于改性氨基树脂的多元醇（A），其通过使包含通式（I）的三个缩醛化或醚化的N-羟甲基的氨基树脂（B）与N-CHR-OR1反应制备，其中R为氢原子，1〜6个碳原子的烷基或6〜10个碳原子的芳基，R 1为1〜6个碳原子的烷基; 与通式（II）的多元醇（C）R 2（-OH）n，其中n是2至6的数，R 2是二价至六价的有机基团; 其中缩醛化或醚化的N-羟甲基与多元醇（C）的当量比为0.5:1至1.2:1; 从氨基树脂（B）中除去至少50mol％的通式R 1 -OH的一元醇（D），其中R 1如上定义。

3. 发明授权

US08153752B2 Polyols based on modified amino resins, process for their preparation and their use 失效
标题翻译：基于改性氨基树脂的多元醇，其制备方法及其用途
公开(公告)号：US08153752B2
公开(公告)日：2012-04-10
申请号：US12160348
申请日：2007-02-09
申请人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
发明人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
IPC分类号： C08G12/30 , C08G12/32 , C08G12/00
CPC分类号： C08G12/44 , C08G6/02 , C09D161/32
摘要： Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I) >N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).
摘要翻译：本文公开了一种基于改性氨基树脂的多元醇（A），其通过使包含通式（I）的三个缩醛化或醚化的N-羟甲基的氨基树脂（B）与N-CHR-OR1反应制备，其中R为氢原子，1〜6个碳原子的烷基或6〜10个碳原子的芳基，R 1为1〜6个碳原子的烷基; 与通式（II）的多元醇（C）R 2（-OH）n，其中n是2至6的数，R 2是二价至六价的有机基团; 其中缩醛化或醚化的N-羟甲基与多元醇（C）的当量比为0.5:1至1.2:1; 从氨基树脂（B）中除去至少50mol％的通式R 1 -OH的一元醇（D），其中R 1如上定义。

4. 发明授权

US5879754A Polyether urethane, process for its preparation, flow-out agent and use of the polyether urethane 失效
标题翻译：聚醚尿烷，其制备方法，流出剂和聚醚聚氨酯的使用
公开(公告)号：US5879754A
公开(公告)日：1999-03-09
申请号：US293906
申请日：1994-08-22
申请人： Michael Geist , Gunther Ott , Helmut Fobbe , Klaus Arlt , Udo Strauss , Klaus Cibura
发明人： Michael Geist , Gunther Ott , Helmut Fobbe , Klaus Arlt , Udo Strauss , Klaus Cibura
IPC分类号： C08G18/83 , C08G18/10 , C08G18/28 , C08G18/32 , C08G18/48 , C09D5/44 , C09D7/47 , B05D1/04 , H05C1/00 , B29C71/02 , C08L75/00
CPC分类号： C09D7/06 , C08G18/10 , C08G18/4825 , C09D5/4492
摘要： The invention relates to a polyether urethane of the general formula ##STR1## wherein R.sup.1 denotes H or an alkyd (sic) radical of 1 to 8 carbon atoms,R.sup.2 denotes an alkylene radical of 2 to 10 carbon atoms or a cycloalkylene radical of 6 to 20 carbon atoms or an arylene radical of 6 to 20 carbon atoms,R.sup.3, R.sup.4 denote an optionally substituted alkyl radical of 1 to 8 carbon atoms or a joint ring whose members are R.sup.3 and R.sup.4,n denotes 2 to 1800m denotes 1 to 15.The invention further relates to a process for its preparation, to a flow-out agent for water-borne paints and to the use of the polyether urethanes as flow-out agents in water-borne, cathodically depositable electro-coating paints.
摘要翻译：本发明涉及通式为：其中R 1表示H或1至8个碳原子的醇酸（sic）基团的聚醚氨基甲酸酯，R 2表示2至10个碳原子的亚烷基或 6至20个碳原子的亚环烷基或6至20个碳原子的亚芳基，R 3，R 4表示任选取代的1至8个碳原子的烷基或其成员是R 3和R 4的连接环，n表示2至1800 m表示1〜15。本发明还涉及其制备方法，用于水性涂料的流出剂，以及在水性阴极可沉积的电解质中使用聚醚氨酯作为流出剂，涂料涂料。

5. 发明授权

US5451305A Process for coating electrically conductive substrates, a water-based coating and a crosslinking agent containing masked NCO groups 失效
标题翻译：用于涂覆导电基材，水性涂料和含有掩蔽的NCO基团的交联剂的方法
公开(公告)号：US5451305A
公开(公告)日：1995-09-19
申请号：US955703
申请日：1994-02-09
申请人： Gunther Ott , Udo Reiter , Walter Jouck
发明人： Gunther Ott , Udo Reiter , Walter Jouck
IPC分类号： C08G18/80 , C09D5/44 , C25D13/10
CPC分类号： C08G18/8064 , C08G18/8009 , C09D5/4496
摘要： The invention relates to a cathodic electro-dipping process wherein the electro-dipping primer employed contains a crosslinking agent which can be obtained by reactinga) a diol and/or a triol or a mixture of diols and/or a mixture of triols,b) diphenylmethane 4,4'-diisocyanate the melting point of which has been depressed, by partial reaction with a monool and/or polyol or a mixture of monools and/or a mixture of polyols, so far that it is liquid at room temperature andc) a masking agent or a mixture of masking agentsto give a crosslinking agent which is free from isocyanate groups.
摘要翻译： PCT No.PCT / EP91 / 01012 Sec。 371日期1994年2月9日 102（e）1994年2月9日PCT PCT 1991年5月31日PCT公布。出版物WO92 / 00358 日本1992年1月9日。本发明涉及一种阴极电浸法，其中所用的电浸渍底物含有交联剂，其可通过使a）二醇和/或三醇或二醇和/ 或三醇的混合物，b）二苯基甲烷4,4'-二异氰酸酯，其熔点已经被抑制，通过与一元醇和/或多元醇或单醇和/或多元醇的混合物的混合物的部分反应，至目前为止在室温下为液体，c）掩蔽剂或掩蔽剂混合物，得到不含异氰酸酯基团的交联剂。

6. 发明授权

US5262465A Process for coating electrically conductive substrates, aqueous coating composition, process for the preparation of a cationic, amine-modified epoxy resin and cationic, amine-modified epoxy resin prepared according to this process 失效
标题翻译：用于涂覆导电基材的方法，水性涂料组合物，用于制备阳离子，胺改性的环氧树脂和阳离子，根据该方法制备的胺改性的环氧树脂的方法
公开(公告)号：US5262465A
公开(公告)日：1993-11-16
申请号：US777339
申请日：1991-12-11
申请人： Gunther Ott , Ulrich Heimann , David J. Santure , Udo Reiter
发明人： Gunther Ott , Ulrich Heimann , David J. Santure , Udo Reiter
IPC分类号： C08G18/58 , C08G18/10 , C08G59/14 , C08G59/40 , C09D5/44 , C09D163/00 , C09D175/00 , C08L63/02
CPC分类号： C09D5/4434 , C08G18/10 , C09D163/00
摘要： The invention relates to a cathodic electro-dipcoating process, wherein the electro-dipcoating composition used contains a cationic, amine-modified epoxy resin, which is obtainable by reacting(A) a polyepoxide,(B) an amine and(C) an adduct, which is obtainable by . . . (sic)(c1) a polyether- or polyester-polyol,(c2) a polyisocyanate and(c3) a compound which contains at least one hydrogen atom which is reactive towards isocyanate groups and at least one ketimine group in the molecule, and/or(D) a hydrolysis product of (C)with one another in a relative proportion such that 20 to 90% of the epoxy groups of component (A) are reacted with component (B) and the remaining epoxy groups are reacted with component (C) and/or (D), and--if still necessary--at least partially protonating the reaction product thus obtained.
摘要翻译： PCT No.PCT / EP90 / 00843 Sec。 371日期1991年12月11日 102（e）日期1991年12月11日PCT 1990年5月25日PCT PCT。出版物WO90 / 15108 日本1990年12月13日。本发明涉及一种阴极电沉积工艺，其中所用的电沉积涂料组合物含有阳离子胺改性环氧树脂，其可通过使（A）聚环氧化物，（B）胺和（C）加合物，其可通过以下方式获得。。。（c1）（c1）聚醚或聚酯多元醇，（c2）多异氰酸酯和（c3）含有至少一个对分子中的异氰酸酯基团和至少一个酮亚胺基具有反应性的氢原子的化合物和/ 或（D）（C）的水解产物相对比例使得组分（A）的20-90％的环氧基与组分（B）反应，剩余的环氧基与组分（ C）和/或（D），以及 - 如果仍然是必要的 - 至少部分质子化由此获得的反应产物。

7. 发明授权

US5086090A Process for the preparation of binder dispersions capable of being cathodically deposited using crosslinking agents based on polyisocyantes blocked by hydroxyl groups 失效
标题翻译：使用基于通过羟基组合阻滞的聚异氰酸酯的交联剂来严格沉积的粘合剂分散体的制备方法
公开(公告)号：US5086090A
公开(公告)日：1992-02-04
申请号：US466437
申请日：1990-06-13
申请人： Michael Geist , Klaus Cibura , Walter Jouck , Gunther Ott , Jurgen Sadlowski , Manfred Dangschaft , Manfred Reimann
发明人： Michael Geist , Klaus Cibura , Walter Jouck , Gunther Ott , Jurgen Sadlowski , Manfred Dangschaft , Manfred Reimann
IPC分类号： C08G18/58 , C08G18/64 , C08G18/80 , C08G18/81 , C08G59/14 , C08J3/07 , C09D5/44 , C09D163/00 , C09D175/00
CPC分类号： C08J3/07 , C08G18/6407 , C08G18/8064 , C08G18/8183 , C09D5/443 , C09D5/4434 , C08J2363/00
摘要： The invention relates to a process for the preparation of aqueous dispersions to be further processed to electrocoating paints with baking temperatures below 160.degree. C. and baking times.ltoreq.30 minutes, which dispersions contain modified epoxide-amine adducts as binders and polyisocyanates blocked by hydroxyl groups as cross-linking agents.In this process polyepoxides and compounds containing one or more, preferably 2, hydroxyl groups per molecule are reacted at elevated temperatures in the presence of catalysts to furnish epoxide-containing intermediates.A solvent or a mixture of solvents is then added with external cooling ahd the solution is boiled under reflux, if necessary in vacuo, until the temperature of the solution drops to 95.degree. C. to 20.degree. C.Amines are then added onto the epoxide groups which are still present in a free state in the epoxy resin and a dispersion is prepared by adding a water/acid mixture after adding the crosslinking agent or the dispersion is first prepared and the crosslinking agent is added subsequently.
摘要翻译： PCT No.PCT / EP88 / 00998 Sec。 371日期1990年6月13日 102（e）日期1990年6月13日PCT提交1988年11月3日PCT公布。出版物WO89 / 04353 日本1989年5月18日。本发明涉及一种制备水性分散体的方法，以进一步加工成具有低于160℃的烘烤温度和烘烤时间<30分钟的电涂料，该分散体含有改性的环氧胺 - 胺加合物作为粘合剂和被羟基封端的多异氰酸酯作为交联剂。在该方法中，每个分子中含有一个或多个，优选2个羟基的聚环氧化物和化合物在升高的温度下在催化剂的存在下反应以提供含环氧化物的中间体。然后加入溶剂或溶剂混合物进行外部冷却，将溶液在回流下煮沸，如果需要，在真空中直至溶液的温度降至95℃至20℃。然后将胺加入到环氧化物在环氧树脂中仍然以游离状态存在的基团，并且通过在加入交联剂之后加入水/酸混合物或首先制备分散体并随后添加交联剂来制备分散体。

8. 发明授权

US4818356A Process for multicoat cathodic wet-on-wet painting of metallic conductive substrates 失效
标题翻译：多金属阴极湿式湿法涂覆金属导电基材的工艺
公开(公告)号：US4818356A
公开(公告)日：1989-04-04
申请号：US905333
申请日：1986-09-25
申请人： Michael Geist , Gunther Ott , Georg Schon , Arnold Dobbelstein , Wolfgang Batzill
发明人： Michael Geist , Gunther Ott , Georg Schon , Arnold Dobbelstein , Wolfgang Batzill
IPC分类号： B05D7/14 , B05D1/00 , B05D7/00 , C09D5/44 , C09D5/46 , C25D13/00 , C25D13/06 , C25D13/10 , C25D13/22
CPC分类号： B05D7/542 , B05D7/577 , C09D5/44 , C25D13/22 , B05D1/007 , Y10S524/901
摘要： The invention relates to a process for coating an electrically conductive substrate, the said substrate being immersed in an aqueous bath based on a cationic synthetic resin binder which is at least in part neutralized with acids and contains amino and/or hydroxyl groups. The said bath contains a mixture of crosslinking agents as well as pigments, fillers, corrosion inhibitors, paint auxiliary substances, and, if appropriate, catalysts, as well as organic solvents in an amount of up to 15% by weight based on the total weight of the coating, the said substrate being cathodically connected. By the action of direct current, a film is deposited on the substrate, after which the said substrate is removed from the bath and the film is cured by stoving, the mixture of crosslinking agents comprising at least two crosslinking agents of different reactivities based on activated esters and/or polyisocyanates blocked by different blocking agents. The expression "different reactivities" means that the crosslinking reaction commences by heating to temperatures which are separated by at least 10.degree. C. and that crosslinking agent which is first to react is present in an amount of 15 to 60 mol %, based on the mixture of the crosslinking agents. This first coat is rinsed and one or more further cathodic coats are deposited before stoving. After each coat has been rinsed, all the coats are cured together.
摘要翻译： PCT No.PCT / EP85 / 00694 Sec。 371日期1986年9月25日第 102（e）日期1986年9月25日PCT提交1985年12月11日PCT公布。公开号WO86 / 03791 日本1986年7月3日。本发明涉及一种涂覆导电基材的方法，所述基材基于阳离子合成树脂粘合剂浸渍在水浴中，所述阳离子合成树脂粘合剂至少部分地被酸中和并含有氨基和/ 或羟基。所述浴包含交联剂以及颜料，填料，腐蚀抑制剂，涂料辅助物质以及适当的催化剂以及基于总重量的至多15重量％的有机溶剂的混合物的涂层，所述衬底被阴极连接。通过直流电的作用，将膜沉积在基底上，然后将所述基底从浴中除去，并且通过烘烤使膜固化，交联剂的混合物包含基于活化的不同反应性的至少两种交联剂酯和/或多异氰酸酯被不同的封闭剂阻断。表述“不同的反应性”是指通过加热至至少10℃分离的温度开始交联反应，并且首先反应的交联剂的存在量为15至60mol％，基于交联剂的混合物。冲洗第一层涂层，并在烘烤之前沉积一层或多层其它阴极涂层。每件外套已经冲洗完毕后，所有的外套都被固化在一起。

9. 发明授权

US4622117A Self-crosslinking, heat-curable grinding resin 失效
标题翻译：自交联，热固化研磨树脂
公开(公告)号：US4622117A
公开(公告)日：1986-11-11
申请号：US699149
申请日：1985-02-07
申请人： Michael Geist , Gunther Ott
发明人： Michael Geist , Gunther Ott
IPC分类号： C08G59/00 , C08G59/50 , C08G59/52 , C08G59/58 , C08G59/62 , C09D5/44 , C09D17/00 , C09D163/00 , C09D201/02 , C09D201/06 , C25D13/06 , C08G59/14 , C08G59/16
CPC分类号： C08G59/625 , C08G59/58 , C09D163/00 , C09D17/00 , C09D5/4446 , C09D5/4488 , Y10T428/31529 , Y10T428/31681 , Y10T428/31699
摘要： The invention relates to a self-crosslinking heat-curable binder, in particular for electrocoating finishes, based on an organic synthetic resin which contains primary and/or secondary hydroxyl groups, esterified carboxyl groups and quaternary ammonium groups and can be diluted with water as a result of partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which has a negative inductive effect.
摘要翻译：本发明涉及一种自交联热固化性粘合剂，特别是电泳涂料，其基于含有伯和/或仲羟基，酯化羧基和季铵基团的有机合成树脂，并且可以用水稀释部分或完全用酸中和的结果。酯化的羧基在醇组分中通过具有负诱导作用的取代基活化。

10. 发明授权

US4566963A Water-dispersible binders based on modified epoxide/amine adducts, and their preparation and use 失效
标题翻译：基于改性环氧化物/胺加合物的水分散性粘合剂及其制备和用途
公开(公告)号：US4566963A
公开(公告)日：1986-01-28
申请号：US705311
申请日：1985-02-25
申请人： Gunther Ott , Arnold Dobbelstein , Michael Geist , Georg Schon , Klaas Ahlers
发明人： Gunther Ott , Arnold Dobbelstein , Michael Geist , Georg Schon , Klaas Ahlers
IPC分类号： C08G59/00 , C08G59/06 , C08G59/14 , C08G59/40 , C08G59/56 , C08G59/62 , C09D5/02 , C09D5/44 , C09D163/00 , H01B3/40 , C25D13/00
CPC分类号： C08G59/066 , C08G59/40 , C08G59/56 , C08G59/625 , C09D5/4434 , H01B3/40
摘要： This application discloses water-dispersible binders which are based on modified epoxide/amine adducts and are the reaction products ofA. polyepoxides having an epoxide equivalent greater than 1 and a mean molecular weight M.sub.n of 140 to 5,000 withB. diphenylolalkanoate esters andC. amines.
摘要翻译：该申请公开了基于改性的环氧化物/胺加合物的水分散性粘合剂，并且是环氧当量大于1且平均分子量＆Upbar＆Mn为140至5,000的A.多环氧化物与B.二苯基酯基烷酸酯和C的反应产物胺。

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