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1. 发明授权

US4900795A Polymer ammonium salts 失效
标题翻译：聚合物铵盐
公开(公告)号：US4900795A
公开(公告)日：1990-02-13
申请号：US200951
申请日：1988-06-02
申请人： Gerhard Hoffmann , Wolfgang Huemmer , Horst Koch , Dieter Littmann
发明人： Gerhard Hoffmann , Wolfgang Huemmer , Horst Koch , Dieter Littmann
IPC分类号： C08F8/00 , C08F2/48 , C08F8/44 , C08F290/00 , C08F299/00
CPC分类号： C08F8/44
摘要： In polymer ammonium salts which are formed from a copolymer (A) which can be modified by a polymer-analogous reaction and from one or more amines (B), the copolymer (A) is obtainable by copolymerization of a monomer mixture of(a.sub.1) ethylene,(a.sub.2) acrylic acid and/or methacrylic acid, and(a.sub.3) one or more further monomers from the group consisting of the vinyl esters, vinyl ethers, acrylates, methacrylates, acrylamides and methacrylamides, and the amines (B) are selected from the group consisting of the(b.sub.1) cyclic amines of the general formula I ##STR1## and/or from the group consisting of the (b.sub.2) open-chain amines of the general formula II ##STR2## and/or from the group consisting of (b.sub.3) 1,4-thiazine, N,N',N"-trisvinylmelamine and N,N',N"-triallylmelamine, Z, R.sup.1, R.sup.2 and R.sup.3 having the meanings stated in the description.
摘要翻译：在由可通过聚合物 - 类似反应改性的共聚物（A）和一种或多种胺（B）形成的聚合物铵盐中，共聚物（A）可通过（a1）的单体混合物共聚获得，乙烯，（a2）丙烯酸和/或甲基丙烯酸，和（a3）选自乙烯基酯，乙烯基醚，丙烯酸酯，甲基丙烯酸酯，丙烯酰胺和甲基丙烯酰胺和胺（B）的一种或多种其它单体从由通式I的（b1）环胺和/或由通式II II的（b2）开链胺和/或由由（b3）1,4-噻嗪，N，N'，N“ - 三乙烯基三聚氰胺和N，N'，N” - 三烯丙基三聚氰胺组成的组，Z，R 1，R 2和R 3具有说明书中所述的含义。

2. 发明授权

US5102773A Photosensitive recording material comprising carboxyl-containing polymeric binder having ethylenically unsaturated side groups and .beta.-amino alcohols 失效
标题翻译：包含含有乙烯基不饱和基团和（BETA） - 氨基醇的含羧基聚合物粘结剂的感光性记录材料
公开(公告)号：US5102773A
公开(公告)日：1992-04-07
申请号：US424690
申请日：1989-10-20
申请人： Dieter Littmann , Thomas Telser , Horst Koch , Wolfgang Huemmer , Martin Meister
发明人： Dieter Littmann , Thomas Telser , Horst Koch , Wolfgang Huemmer , Martin Meister
IPC分类号： G03F7/027 , C08F2/46 , C08F2/48 , C08F2/50 , G03F7/00 , G03F7/031 , G03F7/032
CPC分类号： G03F7/031 , Y10S430/119 , Y10S430/12
摘要： A photosensitive recording material contains a mixture of carboxyl-containing polymers having ethylenically unsaturated side groups, one or more ethylenically unsaturated monomeric compounds, a photoinitiator and a .beta.-aminoalcohol.It is suitable for the production of printing plates.
摘要翻译：感光记录材料含有具有烯属不饱和侧基的含羧基聚合物，一种或多种烯属不饱和单体化合物，光引发剂和β-氨基醇的混合物。适用于生产印版。

3. 发明授权

US5176986A Liquid cleaner composition for removing polymeric materials from a surface 失效
标题翻译：用于从表面去除聚合材料的液体清洁剂组合物
公开(公告)号：US5176986A
公开(公告)日：1993-01-05
申请号：US356933
申请日：1989-05-25
申请人： Thomas Telser , Wolfgang Huemmer , Horst Koch , Karl-Rudolf Kurtz , Heinz-Ulrich Werther , Beinhard Schneider
发明人： Thomas Telser , Wolfgang Huemmer , Horst Koch , Karl-Rudolf Kurtz , Heinz-Ulrich Werther , Beinhard Schneider
IPC分类号： G03F7/00 , C11D3/43 , C11D10/02 , C11D17/00 , G03F7/30 , G03F7/32
CPC分类号： G03F7/32 , C11D3/43
摘要： A new liquid cleaner composition is provided for the mild and gentle removal of polymeric materials from sufaces without leaving any residues. The said new cleaner composition is an emulsion of the water-in-oil type comprising an aqueous phase finely dispersed in a continuous phase selected from the group consisting of nonflammable, fire-retardant, high-boiling, and fire-retardant and high-boiling organic phases, the volume ratio of the finely dispersed aqueous phase to the continuous organic phase being in the range of from 90:10 to 10:90. The new liquid cleaner composition can contain alcohols, surface-active agents and further useful additives. The new liquid cleaner composition is most preferably used in the process for preparing photopolymerized flexographic relief printing plates as the developer for washing out the non-irradiated and thus non-photopolymerized areas of the imagewise irradiated relief-forming recording layers of the said flexographic relief printing plates.
摘要翻译：提供了一种新的液体清洁剂组合物，用于从表面温和和温和地除去聚合材料，而不留下任何残留物。所述新型清洁剂组合物是油包水型的乳液，其包含精细分散在连续相中的水相，所述连续相选自不可燃，阻燃，高沸点，阻燃和高沸点有机相，细分散水相与连续有机相的体积比在90:10至10:90的范围内。新的液体清洁剂组合物可以含有醇，表面活性剂和其它有用的添加剂。新的液体清洗剂组合物最优选用于制备光聚合柔版印刷印版的方法，作为用于洗出所述柔性印版印刷的图像照射的浮雕形成记录层的未经照射且因此非光聚合区域的显影剂盘子

4. 发明授权

US5055377A Light-sensitive recording element and process of forming a relief image wherein the recording element contains lecithin as an additive 失效
标题翻译：感光记录元素和记录元素形成缓冲图像的过程包含作为添加剂的LECITHIN
公开(公告)号：US5055377A
公开(公告)日：1991-10-08
申请号：US404280
申请日：1989-09-07
申请人： Dieter Littmann , Horst Koch
发明人： Dieter Littmann , Horst Koch
IPC分类号： G03F7/004 , G03F7/027
CPC分类号： G03F7/027
摘要： A novel light-sensitive recording element for preparing relief plates or relief printing plates comprises a dimensionally stable base and at least one photopolymerizable recording layer (A) consisting essentially of at least one polymer as binder, at least one photopolymerization initiator, at least one photopolymerizable olefinically unsaturated compound (monomer) which is compatible with the polymeric binder, and/or photopolymerizable olefinically unsaturated radicals which are linked internally and/or terminally to the polymeric binder, and at least one additive, the said additive or at least one of the said additives being selected from the group consisting of the lecithins of the general formulae I and II ##STR1## where R.sup.1 and R.sup.2, which may be identical to or different from each other, are each C.sub.11 -C.sub.18 -alkyl or C.sub.11 -C.sub.18 -alkenyl, with the proviso that at least one of R.sub.1 and R.sub.2 is C.sub.11 -C.sub.18 alkenyl, the photopolymerizable recording layer (A) preferably containing from 0.1 to 10% by weight, based on the recording layer (A), of the lecithins of the general structures I and II.
摘要翻译：一种用于制备浮雕印版或凸版印刷版的新型光敏记录元件包括尺寸稳定的基底和至少一个可光聚合的记录层（A），该至少一个可光聚合记录层（A）主要由至少一种作为粘合剂的聚合物，至少一种光聚合引发剂，至少一种可光聚合的与聚合物粘合剂相容的烯属不饱和化合物（单体）和/或在聚合物粘合剂内部和/或末端连接的可光聚合的烯属不饱和基团和至少一种添加剂，所述添加剂或所述添加剂选自通式I和II的卵磷脂，其中可以相同或不同的R 1和R 2各自为C 11 -C 18 - 烷基或C 11 -C 18 - 烯基，条件是R 1和R 2中的至少一个是C 11 -C 18烯基，光聚合记录层（A）优选含有0.1〜基于记录层（A）的10重量％的一般结构I和II的卵磷脂。

5. 发明授权

US5124237A Production of photopolymerized relief printing plates having a non-tacky surface 失效
标题翻译：生产具有非粘性表面的光聚合凸版印刷版
公开(公告)号：US5124237A
公开(公告)日：1992-06-23
申请号：US476900
申请日：1990-02-08
申请人： Dieter Littmann , Horst Koch
发明人： Dieter Littmann , Horst Koch
IPC分类号： G03F7/00 , G03F7/038 , G03F7/40
CPC分类号： G03F7/405 , G03F7/40
摘要： A relief printing plate whose photopolymerized relief layer has a non-tacky surface is produced by (1) imagewise exposure of a photopolymerizable relief-forming recording layer which contains one or more polymeric binders containing acid groups, (2) washing out (development) of the unexposed and therefore non-photopolymerized parts of the imagewise exposed relief-forming recording layer with a developer and (3) aftertreatment of the resulting photopolymerized relief layer with a basic aftertreatment solution.
摘要翻译：通过（1）成像曝光含有一种或多种含有酸基团的聚合物粘合剂的光聚合性浮雕形成记录层，（2）洗涤（显影）图像曝光的浮雕形成记录层的未曝光和非光致聚合部分与显影剂和（3）用碱性后处理溶液对得到的光聚合缓冲层进行后处理。

6. 发明授权

US4849307A Photosensitive recording materials having a novel graft copolymer binder 失效
标题翻译：具有新型接枝共聚物粘合剂的感光记录材料
公开(公告)号：US4849307A
公开(公告)日：1989-07-18
申请号：US130216
申请日：1987-12-08
申请人： Gerhard Hoffmann , Horst Koch , Guenther Schulz
发明人： Gerhard Hoffmann , Horst Koch , Guenther Schulz
IPC分类号： G03F7/032 , C08G65/32 , G03F7/00 , G03F7/033
CPC分类号： G03F7/033 , Y10S430/11
摘要： The invention relates to a novel photosensitive recording material which can be developed in aqueous solvents after its imagewise irradiation with actinic light and which consists essentially of a dimensionally stable base (A) and of a photosensitive recording layer (B). The said photosensitive recording layer (B) contains from about 48 to about 85% by weight, based on the photosensitive recording layer (B) of one or more elastomeric graft copolymers (B1) which are selected from the group consisting of polyalkylene oxide - vinyl ester - graft copolymers whose vinyl ester structural units have been hydrolyzed to a degree of not less 50 mol.-% from about 0.01 to about 10% by weight, based on the photosensitive recording layer (B), of one or more photoinitiators (B2), and from about 5 to about 30% by weight, based on the photosensitive recording layer (B), of one or more photopolymerizable monomers (B3). In addition to these components, the photosensitive recording layer (B) might contain further assistants or additives. The novel photosensitive recording material is especially well suited for the production of lithographic printing plates, resists and relief plates, in particular relief printing plates. The invention is furthermore related to a process for preparing the novel photosensitive recording material by polymerizing vinylesters in the presence of polyalkylene oxides to yield polyalkylene oxide - vinylester - graft copolymers, hydrolyzing or transesterifying said polyalkylene oxide - vinylester - graft copolymers to yield the said elastomeric graft copolymer (B1), mixing the said elastomeric graft copolymers (B1) with the other components of the photosensitive recording layer (B), and forming the said photosensitive recording layer (B) from the mixture consisting of its components on the dimensionally stable base (A).
摘要翻译：本发明涉及一种新颖的光敏记录材料，其可以在其光化学光照成像照射之后在水性溶剂中显影，并且其基本上由尺寸稳定的基底（A）和感光记录层（B）组成。基于一种或多种弹性体接枝共聚物（B1）的感光记录层（B），所述感光记录层（B）含有约48至约85重量％，所述弹性体接枝共聚物（B1）选自聚环氧烷 - 乙烯基酯基 - 接枝共聚物的乙烯基酯结构单元已经被水解至一个或多个光引发剂（B2）的基于感光记录层（B）的约0.01至约10重量％的不少于50摩尔％的程度）和约5至约30重量％的基于感光记录层（B）的一种或多种可光聚合单体（B3）。除了这些组分之外，光敏记录层（B）可能还含有助剂或添加剂。新型光敏记录材料特别适用于制造平版印刷版，抗蚀剂和浮雕版，特别是凸版印刷版。本发明还涉及通过在聚环氧烷存在下聚合乙烯基酯以制备新的感光记录材料的方法，以产生聚环氧烷 - 乙烯基酯 - 接枝共聚物，水解或酯交换所述聚环氧烷 - 乙烯基酯 - 接枝共聚物以产生所述弹性体接枝共聚物（B1），将所述弹性体接枝共聚物（B1）与感光记录层（B）的其它组分混合，并从由其组分组成的混合物形成所述感光记录层（B）（一个）。

7. 发明授权

US5262486A Modified emulsion polymers, in particular for photopolymerizable recording materials which can be developed in water and aqueous solvents 失效
标题翻译：改性乳液聚合物，特别是可在水和含水溶剂中显影的可光聚合记录材料
公开(公告)号：US5262486A
公开(公告)日：1993-11-16
申请号：US730766
申请日：1991-07-16
申请人： Thomas Telser , Martin Meister , Horst Koch
发明人： Thomas Telser , Martin Meister , Horst Koch
IPC分类号： C08F8/14 , C08F8/44 , C08F220/04 , C08F222/02 , C08F236/04 , C08F279/00 , C08F279/02 , G03F7/027 , G03F7/033 , G03F7/038 , C08F4/00
CPC分类号： C08F8/14 , C08F8/44 , G03F7/033 , C08F2810/30 , Y10S525/902 , Y10S525/919
摘要： Modified polymers in acid form or in the form of their salts consist ofA) a carboxyl-containing copolymer prepared by emulsion polymerization andB) side radicals introduced therein by partial grafting onto the carboxyl groups and of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.5 -alkyl, X is oxygen, sulfur or imino, Y is an ester, amide, ether or C.sub.1 -C.sub.10 -alkylene group and 1
摘要翻译：酸形式或其盐形式的改性聚合物由A）通过乳液聚合制备的含羧基的共聚物和B）通过部分接枝进入羧基和通式I的侧基自由基 R 1和R 2各自为氢或C 1 -C 5 - 烷基，X为氧，硫或亚氨基，Y为酯，酰胺，醚或C 1 -C 10亚烷基，并且对于平均数n为1

8. 发明授权

US4940650A Preparation of recording layers and their use for the production of flexographic printing plates 失效
标题翻译：记录层的制备及其用于生产柔版印刷版的用途
公开(公告)号：US4940650A
公开(公告)日：1990-07-10
申请号：US331392
申请日：1989-03-31
申请人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
发明人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
IPC分类号： C08F291/02 , C08F291/00 , C08K5/00 , C08K5/01 , C08L21/00 , G03F7/00 , G03F7/004 , G03F7/027
CPC分类号： G03F7/027 , Y10S430/108
摘要： A flexographic printing plate which is resistant to ozone cracking and where the flexible recording layer has an anisotropy factor AF of
摘要翻译：柔性版印刷版耐臭氧裂纹，柔性记录层的各向异性因子AF小于1.5，由（A）一种或多种弹性粘合剂组成的感光性混合物，（B）（B1） 5至20重量％的一种或多种与（A）相容并含有两个或多个烯属双键的可光聚合有机化合物和（B2）1至15重量％的一种或多种单烯属不饱和有机化合物，它们是与（A）相容，其均聚物的玻璃化转变温度低于室温，（C）0.1至10重量％的一种或多种光引发剂和（D）0至27重量％的常规助剂和添加剂，柔性记录层的各向异性因子AF被定义为在制造过程中从柔性记录层冲裁的2×15cm的条带的100％伸长率的弹性模量的比率原料板一方面沿着所使用的感光性混合物的流动方向，另一方面与所述方向交叉，然后均匀地曝光。

9. 发明授权

US5147757A Optically transparent polymer alloy and its use in molding materials, moldings, films, coatings, adhesives and photosensitive recording elements 失效
标题翻译：光学透明聚合物合金及其在模塑材料，模具，薄膜，涂料，粘合剂和感光记录元素中的应用
公开(公告)号：US5147757A
公开(公告)日：1992-09-15
申请号：US759979
申请日：1991-09-17
申请人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser
发明人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser
IPC分类号： G02B1/04 , C08F2/44 , C08F2/50 , C08L23/08 , C08L23/16 , C08L33/02 , C09D123/02 , C09D123/16 , C09J123/16
CPC分类号： C08L23/08 , C08L23/16 , C08L33/02
摘要： A novel optically transparent polymer alloy comprisesA) at least one elastomer which contains ethylene and propylene as copolymerized units andB) at least one elastomer which contains ethylene and (meth)acrylic acid as copolymerized units,and is used as a molding material or for the production of molding materials, moldings, films, coatings, adhesives and photosensitive recording elements.
摘要翻译：一种新颖的光学透明聚合物合金包括A）至少一种含有乙烯和丙烯作为共聚单元的弹性体，以及B）至少一种含有乙烯和（甲基）丙烯酸作为共聚单元的弹性体，并且用作模塑材料或用作成型材料，模制品，薄膜，涂料，粘合剂和感光记录元件的生产。

10. 发明授权

US5112725A Preparation of recording layers and their use for the production of flexographic printing plates 失效
标题翻译：记录层的制备及其生产柔版印刷板的使用
公开(公告)号：US5112725A
公开(公告)日：1992-05-12
申请号：US668337
申请日：1991-03-14
申请人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
发明人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
IPC分类号： C08F291/02 , C08F291/00 , C08K5/00 , C08K5/01 , C08L21/00 , G03F7/00 , G03F7/004 , G03F7/027
CPC分类号： G03F7/027 , Y10S430/108
摘要： A flexographic printing plate which is resistant to ozone cracking and where the flexible recording layer has an anisotropy factor AF of

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