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1. 发明授权

US4316783A Process for modifying a shaped polyethylene 失效
标题翻译：改性成型聚乙烯的方法
公开(公告)号：US4316783A
公开(公告)日：1982-02-23
申请号：US48391
申请日：1979-06-14
申请人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara , Noboru Kasai , Kunio Araki , Takayuki Hirano
发明人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara , Noboru Kasai , Kunio Araki , Takayuki Hirano
IPC分类号： B29C35/08 , B29C71/04 , C08K5/17 , C08J3/28 , C08J3/24
CPC分类号： B29C71/04 , C08K5/17 , B29C2035/0877 , B29K2023/06
摘要： An improved process for cross-linking a shaped polyethylene is herein disclosed comprising irradiating it with electron beams using 0.2 to 2 parts by weight of amine alone or in combination with 0.2 to 1.0 part by weight of alcohol for 100 parts by weight of polyethylene to thereby improve the electrical, mechanical, thermal and other characteristics of the polyethylene.
摘要翻译：本文公开了一种用于交联成型聚乙烯的改进方法，其包括用电子束照射0.2至2重量份的胺单独使用或与0.2至1.0重量份的醇组合使用100重量份的聚乙烯，由此提高聚乙烯的电气，机械，热等特性。

2. 发明授权

US4116784A Method for cross-linking polyethylene with an ionizing radiation 失效
标题翻译：交联聚乙烯与电离辐射的方法
公开(公告)号：US4116784A
公开(公告)日：1978-09-26
申请号：US717866
申请日：1976-08-25
申请人： Fumio Hosoi , Miyuki Hagiwara , Kunio Araki
发明人： Fumio Hosoi , Miyuki Hagiwara , Kunio Araki
IPC分类号： B29C35/08 , B29C71/04 , C08F255/02 , C08K5/11 , C08L23/06 , C08F8/00
CPC分类号： C08F255/02 , B29C71/04 , C08K5/11 , C08L23/06 , B29C2035/0844 , B29C2035/085 , B29C2035/0872 , B29C2035/0877 , B29K2023/06 , B29K2105/0088
摘要： A method for cross-linking polyethylene, characterized in that polyethylene is blended with dipropargyl maleate and a copolymer selected from the group consisting of an ethylene-acrylonitrile copolymer, an ethylene-acrylic ester copolymer, an ethylene-substituted acrylic ester copolymer, ethylene-vinyl acetate copolymer, an ethylene-substituted vinyl acetate copolymer and mixtures thereof, and the resulting mixture being irradiated with an ionizing radiation.
摘要翻译：一种交联聚乙烯的方法，其特征在于将聚乙烯与马来酸二丙酯和共聚物共混，所述共聚物选自乙烯 - 丙烯腈共聚物，乙烯 - 丙烯酸酯共聚物，乙烯取代的丙烯酸酯共聚物，乙烯 - 乙烯基醋酸酯共聚物，乙烯取代的乙酸乙烯酯共聚物及其混合物，并将所得混合物用电离辐射照射。

3. 发明授权

US4393165A Polymer compositions 失效
标题翻译：聚合物组合物
公开(公告)号：US4393165A
公开(公告)日：1983-07-12
申请号：US406974
申请日：1982-08-09
申请人： Takashi Sasaki , Miyuki Hagiwara , Fumio Hosoi , Tohru Takagi
发明人： Takashi Sasaki , Miyuki Hagiwara , Fumio Hosoi , Tohru Takagi
IPC分类号： C08F2/00 , C08F2/54 , C08F283/00 , C08F291/00 , C08G59/00 , C08G59/40 , C08G81/00 , C08G81/02 , C08G63/76 , C08L67/00
CPC分类号： C08F283/00
摘要： A polymer composition is herein disclosed, which consists essentially of:(A) 90 to 50 wt % of a saturated polymer having in one molecule (1) at least two groups of at least one type selected from the group consisting of an epoxy group of the formula ##STR1## (R is hydrogen or methyl), an alcoholic or phenolic hydroxyl group and an alkoxymethyl-substituted acid amide group of the formula ##STR2## (R is an alkyl group of C.sub.1 to C.sub.4) and (2) a repeating unit made of a nonaromatic methylene group or methine group; and(B) 50 to 10 wt % of a nonfunctional radical polymerizable monomer mixture consisting of (a) a radical polymerizable monomer having in one molecule at least one functional group selected from the group consisting of a carboxyl group, an acid anhydride group, an alcoholic hydroxyl group, an alkoxymethyl-substituted acid amide group of the formula ##STR3## (R is an alkyl group of C.sub.1 to C.sub.4) and an amino group of the formula --NR.sub.1 R.sub.2 (R.sub.1 and R.sub.2 are each an alkyl group of C.sub.1 to C.sub.8) and an ethylenic double bond, and (b) a radical polymerizable monomer having one epoxy ring and one ethylenic double bond in one molecule.
摘要翻译：本文公开了一种聚合物组合物，其基本上由以下组成：（A）90至50重量％的在一分子中具有至少两个选自以下组中的至少一种的饱和聚合物：（1）至少一种选自下组的环氧基：式（IMA）（R是氢或甲基），醇或酚羟基和具有下式的烷氧基甲基取代的酰胺基（R是C1至C4的烷基）和（2）重复的由非芳族亚甲基或次甲基组成的单元; 和（B）50〜10重量％的由以下组成的非功能性自由基聚合性单体混合物：（a）在1分子中具有至少一个选自羧基，酸酐基，醇羟基，式IMAMA的烷氧基甲基取代的酰胺基（R为C1至C4的烷基）和式-NR1R2的氨基（R1和R2各自为C1至C8的烷基））和烯属双键，和（b）在一个分子中具有一个环氧环和一个烯属双键的自由基聚合单体。

4. 发明授权

US4405426A Self-curing irradiated blend of epoxy resin and salt of quaternary amino ester of unsaturated acid 失效
标题翻译：环氧树脂和不饱和酸季氨基酯盐的自固化照射混合物
公开(公告)号：US4405426A
公开(公告)日：1983-09-20
申请号：US369612
申请日：1982-04-19
申请人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara
发明人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara
IPC分类号： C08G59/00 , C08F2/54 , C08F283/00 , C08F283/10 , C08F299/02 , C08G59/20 , C08G59/34 , C08G59/40 , C08G59/50 , C08G59/52 , C08G59/68 , C08J3/07 , C08J3/28 , C08L63/00 , C08F220/34
CPC分类号： C08J3/28 , C08F299/028 , C08G59/50 , C08G59/52 , C08G59/686 , C08J3/07 , C08J2363/00
摘要： A self-curing modified epoxy resin composition produced by irradiating with electron beams a mixture of an epoxy resin, a quaternary salt of .alpha.,.beta.-unsaturated carboxylic acid ester having one quaternized amine nitrogen in the ester group, and optionally a monomer having one ethylenically unsaturated bond in the molecule, as well as an aqueous dispersion of such resin composition is herein disclosed.
摘要翻译：通过用电子束照射环氧树脂，在酯基中具有一个季铵化胺氮的α，β-不饱和羧酸季铵盐和任选地具有一个烯键式的单体的混合物制备的自固化改性环氧树脂组合物本文公开了分子中的不饱和键，以及这种树脂组合物的水分散体。

5. 发明授权

US4486280A Self-curing modified epoxy resin composition and aqueous dispersion thereof 失效
标题翻译：自固化改性环氧树脂组合物及其水分散体
公开(公告)号：US4486280A
公开(公告)日：1984-12-04
申请号：US508564
申请日：1983-06-28
申请人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara , Shigenori Egusa , Kiyoshi Nanishi
发明人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara , Shigenori Egusa , Kiyoshi Nanishi
IPC分类号： C08G59/00 , C08F2/52 , C08F283/10 , C08G59/02 , C08G59/17 , C08G59/40 , C08L63/00 , C08L63/10
CPC分类号： C08F283/10
摘要： A self-curing epoxy resin composition is, herein, disclosed produced by irradiating with an electron beam a mixture of 85 to 97 wt % of an epoxy resin and 3 to 15 wt % of a quaternary alkyl ammonium salt of .alpha.,.beta.-unsaturated carboxylic acid or a neutralized product of an .alpha.,.beta.-unsaturated carboxylic acid and a tertiary amine.
摘要翻译：本文公开了一种自固化环氧树脂组合物，其通过用电子束照射85-97重量％的环氧树脂和3-15重量％的α，β-不饱和羧酸的季烷基铵盐，酸或α，β-不饱和羧酸和叔胺的中和产物。

6. 发明授权

US4134812A Method of manufacturing shaped articles of cross-linked poly-.alpha.-olefin composition by irradiation of electron beam 失效
标题翻译：通过电子束照射制造交联聚{{
公开(公告)号：US4134812A
公开(公告)日：1979-01-16
申请号：US860569
申请日：1977-12-14
申请人： Takashi Sasaki , Kunio Araki , Miyuki Hagiwara , Hayao Ishitani , Eisuke Saito , Kyoji Komatsu
发明人： Takashi Sasaki , Kunio Araki , Miyuki Hagiwara , Hayao Ishitani , Eisuke Saito , Kyoji Komatsu
IPC分类号： C08L23/00 , B29C35/08 , B29C71/04 , C08J7/00 , C08K5/01 , C08K5/10 , C08K5/13 , C08K5/134 , H01B3/44 , C08F8/00
CPC分类号： H01B3/441 , B29C71/04 , C08K5/01 , C08K5/10 , C08K5/1345 , B29C2035/0872 , B29K2023/00
摘要： A method of manufacturing shaped articles of cross-linked poly-.alpha.-olefin composition by irradiation of electron beam which comprises the steps of blending a poly-.alpha.-olefin with a compound miscible therewith which is expressed by the general formula:X--Ym(where X is a group free from acetylenic linkage, Y is a group containing acetylenic linkage and m is an integer of 1 or over) and tetrakis-[methylene-(3,5-di-t-butyl-4-hydroxy-hydrocinnamate)]-methane; molding the blended mass into a desired shape; and cross-linking said shaped articles by irradiation of electron beam.
摘要翻译：通过电子束照射制造交联聚-α-烯烃组合物的成型制品的方法，该方法包括以下步骤：将聚-α-烯烃与可混合的化合物混合，所述化合物由下式表示：

7. 发明授权

US4226687A Method of preventing fine cracks from occuring in rubber or plastic insulation of an insulated wire or cable exposed to electron beam irradiation 失效
标题翻译：防止电子束照射的绝缘电线或电缆的橡胶或塑料绝缘中发生细裂纹的方法
公开(公告)号：US4226687A
公开(公告)日：1980-10-07
申请号：US944782
申请日：1978-09-22
申请人： Takashi Sasaki , Miyuki Hagiwara , Kunio Araki , Hayao Ishitani , Eisuke Saito , Kyozi Komatsu
发明人： Takashi Sasaki , Miyuki Hagiwara , Kunio Araki , Hayao Ishitani , Eisuke Saito , Kyozi Komatsu
IPC分类号： B29C35/00 , B29C35/08 , B29C71/04 , C08F2/54 , C08J7/00 , G21K5/10 , H01B13/00 , H01B13/14 , C08F2/46 , C08F8/00
CPC分类号： G21K5/10 , B29C71/04 , H01B13/003 , B29C2035/0877 , B29K2021/00 , B29L2031/3462
摘要： A method of manufacturing an electric wire or cable having an improved rubber or plastic insulation layer which has the maximum wall thickness of beam penetration of 4mm or over and whose properties are improved by irradiation with an electron beam, wherein the wire or cable runs under the scanner of an electron beam accelerator while being rotated about the axis of the wire or cable at such a speed as causes the same portion of the wire or cable to be irradiated with the electron beam at least twice during a period of less than 10 seconds; and the electron beam accelerator directs on the insulation layer of the wire or cable an electron beam which is accelerated to an energy of 1 MeV or over and whose maximum penetration range in the said insulation layer is larger than its thickness.
摘要翻译：一种制造具有改进的橡胶或塑料绝缘层的电线或电缆的方法，其具有4mm或更大的光束穿透的最大壁厚，并且通过用电子束照射改善其性能，其中电线或电缆在电子束加速器的扫描仪，同时绕着电线或电缆的轴线旋转，以使电线或电缆的相同部分在少于10秒的时间内用电子束照射至少两次; 并且电子束加速器引导电线或电缆的绝缘层，电子束被加速至1MeV以上的能量，并且其绝缘层中的最大穿透范围大于其厚度。

8. 发明授权

US4062998A Heat-resistant, resin coated electric wire characterized by three resin coatings, the outer of which is less highly cross-linked than the coating next adjacent thereto 失效
标题翻译：耐热树脂涂层电线，其特征在于三层树脂涂层，其外表面与邻近的涂层交联度较低
公开(公告)号：US4062998A
公开(公告)日：1977-12-13
申请号：US675252
申请日：1976-04-09
申请人： Miyuki Hagiwara , Masayoshi Sohara , Kunio Araki , Tsutomu Kagiya
发明人： Miyuki Hagiwara , Masayoshi Sohara , Kunio Araki , Tsutomu Kagiya
IPC分类号： H01B3/44 , H01B7/295 , B32B15/02 , B32B15/08
CPC分类号： H01B7/295 , H01B3/443 , Y10T428/2942 , Y10T428/2947
摘要： Electric wire coated by a non-flammable resin, characterized in that the resin is composed of two layers, the degrees of crosslinking of which are different from each other, and the gel percent of the outer portion of the resin is lower than that of the inner portion of the resin is disclosed.
摘要翻译：由不可燃树脂涂覆的电线，其特征在于，树脂由交联度不同的两层组成，树脂外部的凝胶百分比低于公开了树脂的内部。

9. 发明授权

US4113595A Process for producing molded product composed of crosslinked resin or crosslinked-resin coated material on a substrate by means of electron beam 失效
标题翻译：通过电子束在基板上制造由交联树脂或交联树脂涂覆材料构成的成型体的方法
公开(公告)号：US4113595A
公开(公告)日：1978-09-12
申请号：US639066
申请日：1975-12-09
申请人： Miyuki Hagiwara , Kunio Araki , Shingo Matsuoka , Syunichi Fujimura
发明人： Miyuki Hagiwara , Kunio Araki , Shingo Matsuoka , Syunichi Fujimura
IPC分类号： C08L23/00 , C08F8/32 , C08F255/00 , C08J3/28 , C08J7/00 , C08K5/10 , C08L101/00 , H01B3/44 , C08F8/00
CPC分类号： C08F8/32 , C08F255/00
摘要： A process for producing molded product composed of crosslinked resin or coated material composed of crosslinked resin on a substrate which comprises blending a polyolefin-series resin, a compound represented by the formulaX -- Y.sub.m Iwherein X is a group not containing an acetylenic linkage, Y is a group containing an acetylenic linkage and m is an integer of 1 or more, which is compatible with the resin at a room temperature or an elevated temperature, and a compound selected from the group consisting of an amino compound represented by the formula ##STR1## wherein each of R.sub.1 and R.sub.2 is independently substituted or non-substituted aliphatic hydrocarbon, substituted or non-substituted alicyclic hydrocarbon, or substituted or non-substituted aromatic hydrocarbon, provided that at least one of R.sub.1 or R.sub.2 is substituted or non-substituted aromatic hydrocarbon, an amino compound represented by the formula ##STR2## wherein each of R.sub.3, R.sub.4 and R.sub.5 is independently substituted or non-substituted aliphatic hydrocarbon, substituted or non-substituted alicyclic hydrocarbon, or substituted or non-substituted aromatic hydrocarbon, provided that at least one of R.sub.3, R.sub.4 and R.sub.5 is substituted or non-substituted aromatic hydrocarbon; and mixtures thereof which are compatible with the resin at a room temperature or an elevated temperature; and molding the mixture or coating the mixture on a substrate and irradiating the resulting molded material or the resulting coated material by means of an electron beam.
摘要翻译：一种制造由交联树脂或由交联树脂构成的涂布材料的成型体的方法，该方法包括将聚烯烃类树脂，式X-Ym I表示的化合物，其中X为不含炔键的基团， Y是含有炔键的基团，m是在室温或高温下与树脂相容的整数1以上的整数，以及选自由式其中R 1和R 2各自独立地为取代或未取代的脂族烃，取代或未取代的脂环烃，或取代或未取代的芳烃，条件是R 1或R 2中的至少一个为取代或未取代的芳族烃，取代的芳族烃，由式（III）表示的氨基化合物，其中R3，R4和R5各自独立地被取代或不代替脂族烃，取代或未取代的脂环烃，或取代或未取代的芳族烃，条件是R 3，R 4和R 5中的至少一个是取代或未取代的芳族烃; 和它们的混合物，其在室温或高温下与树脂相容; 并将该混合物成型或将该混合物涂覆在基材上，并通过电子束照射所得模制材料或所得到的涂覆材料。

10. 发明授权

US4373046A Flame-retardant and radiation-resistant polymer composition and a resin molded product prepared therefrom 失效
标题翻译：阻燃和耐辐射聚合物组合物和由其制备的树脂模制产品
公开(公告)号：US4373046A
公开(公告)日：1983-02-08
申请号：US233134
申请日：1981-02-10
申请人： Miyuki Hagiwara , Yousuke Morita
发明人： Miyuki Hagiwara , Yousuke Morita
IPC分类号： C08L101/00 , C08K5/03 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L65/00 , C08L67/00 , C08L77/00 , C09K15/04 , C09K21/08 , C08L57/08
CPC分类号： C08K5/03
摘要： A flame-retardant and radiation-resistant polymer composition comprising a polymer and a halogenated acenaphthylene condensate having a structural unit of the formula (I) or (II): ##STR1## (wherein X is chlorine or bromine, n and n' are each an integer of 2 to 6, R is a substituent other than halogen, m and m' are each an integer of 0 to 4, n (or N')+m(or m').ltoreq.6, and when m or m' is 2 or more, each R may be the same or different) and a flame-retardant and radiation-resistant resin molded product prepared therefrom are herein disclosed.
摘要翻译：包含具有式（I）或（II）结构单元的聚合物和卤代苊缩合物的阻燃和耐辐射聚合物组合物：其中X是氯或溴，n和n'各自为2至6的整数，R为除卤素以外的取代基，m和m'各自为0至4的整数，n（或N'）+ m（或m'）为当m或m'为2或更大时，每个R可以相同或不同），并且本文公开了由其制备的阻燃和耐辐射树脂模制产品。

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