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1. 发明授权

US08158572B2 Linear polydimethylsiloxane-polyether copolymers with amino and/or quaternary ammonium groups and use thereof 有权
标题翻译：具有氨基和/或季铵基团的线性聚二甲基硅氧烷 - 聚醚共聚物及其用途
公开(公告)号：US08158572B2
公开(公告)日：2012-04-17
申请号：US13015852
申请日：2011-01-28
申请人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheuermann , Bernard William Kluesener , Rajan Keshav Panadiker
发明人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheuermann , Bernard William Kluesener , Rajan Keshav Panadiker
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C08G77/388 , C08G77/46 , C08L83/12 , C11D3/001
摘要： Household care compositions having a linear polydimethylsiloxane-polyether copolymers with amino and/or quaternary ammonium groups, obtainable by the reaction of organopolysiloxanes functionalized with secondary aminoalkyl groups with the reaction products formed from compounds containing epoxy groups and amines, the use thereof and process for preparation thereof.
摘要翻译：具有具有氨基和/或季铵基团的直链聚二甲基硅氧烷 - 聚醚共聚物的家用护理组合物，其通过用仲氨基烷基官能化的有机聚硅氧烷与由含有环氧基和胺的化合物形成的反应产物的反应获得，其用途和制备方法其中。

2. 发明申请

US20110190190A1 Novel Linear Polydimethylsiloxane-Polyether Copolymers with Amino and/or Quaternary Ammonium Groups and Use Thereof 有权
标题翻译：具有氨基和/或季铵基团的新型线性聚二甲基硅氧烷 - 聚醚共聚物及其用途
公开(公告)号：US20110190190A1
公开(公告)日：2011-08-04
申请号：US13015852
申请日：2011-01-28
申请人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheuermann , Bernard William Kluesener , Rajan Keshav Panadiker
发明人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheuermann , Bernard William Kluesener , Rajan Keshav Panadiker
IPC分类号： C11D3/60 , C08G77/04
CPC分类号： C11D3/3742 , C08G77/388 , C08G77/46 , C08L83/12 , C11D3/001
摘要： Household care compositions having a linear polydimethylsiloxane-polyether copolymers with amino and/or quaternary ammonium groups, obtainable by the reaction of organopolysiloxanes functionalized with secondary aminoalkyl groups with the reaction products formed from compounds containing epoxy groups and amines, the use thereof and process for preparation thereof.
摘要翻译：具有具有氨基和/或季铵基团的直链聚二甲基硅氧烷 - 聚醚共聚物的家用护理组合物，其通过用仲氨基烷基官能化的有机聚硅氧烷与由含有环氧基和胺的化合物形成的反应产物的反应获得，其用途及其制备方法其中。

3. 发明授权

US08957009B2 Linear polydimethylsiloxane-polyether copolymers having amino and/or quaternary ammonium groups and use thereof 有权
标题翻译：具有氨基和/或季铵基团的线性聚二甲基硅氧烷 - 聚醚共聚物及其用途
公开(公告)号：US08957009B2
公开(公告)日：2015-02-17
申请号：US13520091
申请日：2010-12-29
申请人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheuermann , Bernard William Kluesener , Rajan Keshav Panandiker
发明人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheuermann , Bernard William Kluesener , Rajan Keshav Panandiker
IPC分类号： C08G77/388 , C08G77/46 , A61K8/898 , A61Q19/00 , D06M15/643 , D06M15/647 , A61Q5/00
CPC分类号： C08G77/46 , A61K8/898 , A61Q5/00 , A61Q19/00 , C08G77/388 , D06M15/6436 , D06M15/647
摘要： Linear polydimethylsiloxane-polyether copolymers with amino and/or quaternary ammonium groups, obtainable by the reaction of organopolysiloxanes functionalized with secondary aminoalkyl groups with the reaction products formed from compounds containing epoxy groups and amines, the use thereof and process for preparation thereof.
摘要翻译：具有氨基和/或季铵基团的线性聚二甲基硅氧烷 - 聚醚共聚物，其可通过用仲氨基烷基官能化的有机聚硅氧烷与由含有环氧基和胺的化合物形成的反应产物的反应获得，其用途及其制备方法。

4. 发明申请

US20120308494A1 NOVEL LINEAR POLYDIMETHYLSILOXANE-POLYETHER COPOLYMERS HAVING AMINO AND/OR QUATERNARY AMMONIUM GROUPS AND USE THEREOF 有权
标题翻译：具有氨基和/或季铵基团的新型线性聚二甲基硅氧烷聚合物共聚物及其用途
公开(公告)号：US20120308494A1
公开(公告)日：2012-12-06
申请号：US13520091
申请日：2010-12-29
申请人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheurmann , Bernhard William Kluesener , Rajan Keshav Panandiker
发明人： Frank Schubert , Wilfried Knott , Michael Ferenz , Klaus-Dieter Klein , Tobias Maurer , Ralph Scheurmann , Bernhard William Kluesener , Rajan Keshav Panandiker
IPC分类号： C08G77/388 , A61Q19/10 , A61Q5/12 , A61Q5/06 , D06M15/647 , A61Q5/10 , A61Q15/00 , A61K47/34 , A61Q17/02 , A61K8/898 , A61Q17/04
CPC分类号： C08G77/46 , A61K8/898 , A61Q5/00 , A61Q19/00 , C08G77/388 , D06M15/6436 , D06M15/647
摘要： Linear polydimethylsiloxane-polyether copolymers with amino and/or quaternary ammonium groups, obtainable by the reaction of organopolysiloxanes functionalized with secondary aminoalkyl groups with the reaction products formed from compounds containing epoxy groups and amines, the use thereof and process for preparation thereof.
摘要翻译：具有氨基和/或季铵基团的线性聚二甲基硅氧烷 - 聚醚共聚物，可通过用仲氨基烷基官能化的有机聚硅氧烷与由含有环氧基和胺的化合物形成的反应产物的反应获得，其用途及其制备方法。

5. 发明授权

US07612158B2 Equilibration of siloxanes 有权
标题翻译：硅氧烷的平衡
公开(公告)号：US07612158B2
公开(公告)日：2009-11-03
申请号：US11456379
申请日：2006-07-10
申请人： Georg Burkhart , Juergen Droese , Horst Dudzik , Klaus-Dieter Klein , Wilfried Knott , Volker Moehring
发明人： Georg Burkhart , Juergen Droese , Horst Dudzik , Klaus-Dieter Klein , Wilfried Knott , Volker Moehring
IPC分类号： C08G77/08
CPC分类号： C08G77/46 , C08G77/08 , C08G77/10
摘要： The invention relates to a process for the preparation of equilibration products of organosiloxanes by rearrangement of the siloxane bond to a cation exchange resin, the organopolysiloxanes thus obtainable and the use thereof.
摘要翻译：本发明涉及通过将硅氧烷键重排为阳离子交换树脂，由此得到的有机聚硅氧烷及其用途来制备有机硅氧烷的平衡产物的方法。

6. 发明授权

US06489498B2 Silanes with hydrophilic groups, their synthesis and use as surfactants in aqueous media 失效
标题翻译：具有亲水基团的硅烷，它们的合成和用作水性介质中的表面活性剂
公开(公告)号：US06489498B2
公开(公告)日：2002-12-03
申请号：US09818419
申请日：2001-03-27
申请人： Klaus-Dieter Klein , Wilfried Knott , Götz Koerner , Manfred Krakenberg
发明人： Klaus-Dieter Klein , Wilfried Knott , Götz Koerner , Manfred Krakenberg
IPC分类号： C07F708
CPC分类号： B01F17/0071 , C07F7/081
摘要： Silanes of the general formula are prepared, wherein R1, R2 and R3 in the molecule are the same or different and represent aliphatic or aromatic hydrocarbon groups, R4 is a divalent hydrocarbon group with 4 to 12 carbon atoms and a lateral hydroxyl group, wherein the hydrocarbon group can be interrupted by an ether oxygen, R5 is a hydrophilic, ionic group. A method for synthesizing these compounds is described. The silanes greatly lower the surface tension of aqueous solutions, the surface tension being reduced to values of about 23 mN/m. The silanes are biologically degradable and have pronounced surfactant properties.
摘要翻译：制备通式的硅烷，其中分子中的R 1，R 2和R 3相同或不同并且表示脂族或芳族烃基，R 4是具有4至12个碳原子和侧羟基的二价烃基，其中烃组可以被醚氧中断，R5是亲水的离子基团。对这些化合物的合成方法进行说明。硅烷大大降低了水溶液的表面张力，表面张力降低到约23mN / m。硅烷是生物可降解的并且具有显着的表面活性剂性质。

7. 发明授权

US07754778B2 Linear polydimethylsiloxane-polyoxyalkylene block copolymers linked via Si-C groups and via carboxylic ester groups, a process for preparing them and their use 失效
标题翻译：通过Si-C基团和羧酸酯基团连接的线性聚二甲基硅氧烷 - 聚氧化烯嵌段共聚物，其制备方法及其用途
公开(公告)号：US07754778B2
公开(公告)日：2010-07-13
申请号：US12179944
申请日：2008-07-25
申请人： Wilfried Knott , Oliver Thum , Klaus-Dieter Klein , Dagmar Windbiel , Claudia Hierath
发明人： Wilfried Knott , Oliver Thum , Klaus-Dieter Klein , Dagmar Windbiel , Claudia Hierath
IPC分类号： C08G77/06 , C08G77/04 , C08J9/00
CPC分类号： C08G77/46
摘要： The invention provides linear polydimethylsiloxane-polyoxyalkylene block copolymers containing Si—C groups and carboxylic ester groups and having repeating (A1BA2B) units where A1 and A2 are two different polydimethylsiloxane units of the general formula (I) with a number of Si atoms N=(n+2) of 15≦N≦30 and NA1≠NA2 and B is a unit of the formula (II) —CH2—CH2—(CH2)a—CO[O—CH2—CH(R)]c—O-[D-O]e—[—CH2—CH(R)—O]d—OC—(CH2)b—CH2—CH2— (II) where R independently at each occurrence is H, —CH3 or —C2H5, a and b independently of one another are 0 to 20, c and d independently of one another are values≧1, e is 0 or 1 and D is a hydrocarbon radical having 2 to 10 C atoms, the overall molar weight of the unit of the formula II being from 600 to 10 000 g/mol, with the proviso that the average mixed molar weight of the polydimethylsiloxane units (A1+A2) is from >1665 to 0% to ≦50% by weight, based on the overall weight of [O—CH2—CH(R)] in B, a process for preparing them and their use.
摘要翻译：本发明提供含有Si-C基团和羧酸酯基并具有重复（A1BA2B）单元的线性聚二甲基硅氧烷 - 聚氧化烯嵌段共聚物，其中A1和A2是通式（I）的两种不同聚二甲基硅氧烷单元，其数量为Si原子N =（（II）-CH 2 -CH 2 - （CH 2）a -CO [O-CH 2 -CH（R）] c-O-（CH 2）n - [DO] e - [ - CH 2 -CH（R）-O] d-OC-（CH 2）b -CH 2 -CH 2 - （II）其中R各自独立地为H，-CH 3或-C 2 H 5，a和b 彼此独立地为0至20，c和d彼此独立地为值≧1，e为0或1，D为具有2至10个C原子的烃基，式II的单元的总摩尔量是从600至10000g / mol，条件是聚二甲基硅氧烷单元（A1 + A2）的平均混合摩尔数为> 1665至<1998g / mol，[O-CH 2 -CH（R ）]，其中R = H为> 0％至＆lt; nlE; 50％为重量 ht，基于B中[O-CH 2 -CH（R）]的总重量，其制备方法及其用途。

8. 发明申请

US20060241270A1 EQUILIBRATION OF SILOXANES 有权
标题翻译：硅氧烷的平衡
公开(公告)号：US20060241270A1
公开(公告)日：2006-10-26
申请号：US11456379
申请日：2006-07-10
申请人： Georg Burkhart , Jurgen Drose , Horst Dudzik , Klaus-Dieter Klein , Wilfried Knott , Volker Mohring
发明人： Georg Burkhart , Jurgen Drose , Horst Dudzik , Klaus-Dieter Klein , Wilfried Knott , Volker Mohring
IPC分类号： C08G77/10 , C08L83/04
CPC分类号： C08G77/46 , C08G77/08 , C08G77/10
摘要： The invention relates to a process for the preparation of equilibration products of organosiloxanes by rearrangement of the siloxane bond to a cation exchange resin, the organopolysiloxanes thus obtainable and the use thereof.
摘要翻译：本发明涉及通过将硅氧烷键重排为阳离子交换树脂，由此得到的有机聚硅氧烷及其用途来制备有机硅氧烷的平衡产物的方法。

9. 发明授权

US06291622B1 Process and apparatus for continuous hydrosilylation 有权
标题翻译：连续氢化硅烷化的方法和装置
公开(公告)号：US06291622B1
公开(公告)日：2001-09-18
申请号：US09470533
申请日：1999-12-22
申请人： Jürgen Dröse , Hubertus Geisler , Wolfgang Hiersche , Klaus-Dieter Klein , Wilfried Knott , Andreas Mehrwald , Dagmar Windbiel
发明人： Jürgen Dröse , Hubertus Geisler , Wolfgang Hiersche , Klaus-Dieter Klein , Wilfried Knott , Andreas Mehrwald , Dagmar Windbiel
IPC分类号： C08G7706
CPC分类号： C08G77/46 , C08G77/38
摘要： A continuous process for preparing organomodified polysiloxanes by the transition metal-catalyzed addition of polysiloxanes containing SiH groups onto substances containing C—C multiple bonds, in particular a process for the continuous hydrosilylation of substances containing C—C multiple bonds, which comprises introducing the reactants, in the presence or absence of a homogeneous or heterogeneous catalyst, into a loop-like, heatable and coolable reaction circuit which has a static mixing element and/or a dynamic mixing element to mix starting materials and product formed, leaving the reaction mixture in the reaction circuit until a predetermined degree of conversion has been reached and subsequently transferring the reaction mixture still containing starting materials to a tube reactor to complete the reaction and taking it off via a receiver. In addition, a suitable industrial apparatus for carrying out the process of the invention is described.
摘要翻译：通过过渡金属催化加成含有SiH基团的聚硅氧烷到含有多个CC的物质的物质，特别是含有CC多键的物质的连续氢化硅烷化方法，用于制备有机改性聚硅氧烷的连续方法，其包括在存在下引入反应物或不存在均相或多相催化剂，形成环状，可加热和可冷却的反应回路，其具有静态混合元件和/或动态混合元件以混合起始材料和形成的产物，将反应混合物留在反应回路中直到已经达到预定的转化率，随后将仍含有原料的反应混合物转移到管式反应器中以完成反应，并通过接收器将其取出。此外，描述了用于实施本发明的方法的合适的工业设备。

10. 发明授权

US5475127A Organosilyl and organosiloxanyl derivatives of glycerin ethers and their use 失效
标题翻译：甘油醚的有机甲硅烷基和有机硅氧烷基衍生物及其用途
公开(公告)号：US5475127A
公开(公告)日：1995-12-12
申请号：US415974
申请日：1995-04-03
申请人： Klaus-Dieter Klein , Wilfried Knott
发明人： Klaus-Dieter Klein , Wilfried Knott
IPC分类号： B01F17/54 , C07F7/08 , C08G77/38 , C08G77/50 , C11D1/82
CPC分类号： B01F17/0071 , C07F7/0818 , C07F7/0852 , C07F7/0856 , C08G77/38 , C08G77/50 , C11D1/82 , Y10S516/01 , Y10S516/03 , Y10S516/05
摘要： The invention relates to novel organosilyl and organosiloxanyl derivatives of glycerin ethers of the general formula ##STR1## wherein R represents --OH or the --OCH.sub.2 --CH.dbd.CH--(CH.sub.2).sub.3 --CH.dbd.CH.sub.2 group or the --(R.sup.5).sub.a --R.sup.6 group or the --OCH.sub.2 --CH.dbd.CH--(CH.sub.2).sub.5 --R.sub.4 group.
摘要翻译：本发明涉及通式为（I）的甘油醚的新的有机甲硅烷基和有机硅氧烷基衍生物，其中R表示-OH或-OCH 2 -CH = CH-（CH 2）3 -CH = CH 2基团或 - （R 5 ）a-R6基团或-OCH2-CH = CH-（CH2）5-R4基团。

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