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1. 发明授权

US07960445B2 Dual cure compositions employing free radical and RTV cure 有权
标题翻译：使用自由基和RTV固化的双重固化组合物
公开(公告)号：US07960445B2
公开(公告)日：2011-06-14
申请号：US11572738
申请日：2005-07-22
申请人： Anthony F. Jacobine , John G. Woods , Steven T. Nakos , Thomas Fay-Oy Lim
发明人： Anthony F. Jacobine , John G. Woods , Steven T. Nakos , Thomas Fay-Oy Lim
IPC分类号： C03C25/10 , C08L83/00 , C08F8/30
CPC分类号： C08J3/243 , C08G18/10 , C08G18/672 , C08G18/755 , C08G63/6854 , C08G63/6954 , C08G63/914 , C08G2190/00 , C09J167/07 , C08G18/48 , C08G18/718
摘要： The present invention relates to dual curing compositions, which cure with moisture and photo radiation, such as UV light, and methods for preparing and using same. In particular, the compositions of the present invention contain a polyether or polyester backbone, photocurable portion(s) and moisture curable portion(s). The photo curable portion is a urethane or carbamate linkage terminated with a (meth)acryloxyalkyl group. The moisture curable portion is either: (1) a portion terminated with a polyalkoxysilyl group; or (2) a portion having a urea linkage terminated with an alkylpolyalkoxysilyl group.
摘要翻译：本发明涉及用水分和光辐射固化的双重固化组合物，例如UV光，以及制备和使用它们的方法。特别地，本发明的组合物含有聚醚或聚酯骨架，可光固化部分和湿气可固化部分。光固化部分是用（甲基）丙烯酰氧基烷基封端的氨基甲酸酯或氨基甲酸酯键。湿气固化部分是：（1）以多烷氧基甲硅烷基封端的部分; 或（2）具有用烷基聚烷氧基甲硅烷基封端的脲键的部分。

2. 发明申请

US20080139687A1 Vinyl Ether/Acrylate Block Resins, Compositions and Methods of Making Same 审中-公开
标题翻译：乙烯基醚/丙烯酸酯嵌段树脂，组合物和制备方法
公开(公告)号：US20080139687A1
公开(公告)日：2008-06-12
申请号：US11814584
申请日：2005-11-10
申请人： John G. Woods , Joel D. Schall , Steven T. Nakos , Anthony F. Jacobine
发明人： John G. Woods , Joel D. Schall , Steven T. Nakos , Anthony F. Jacobine
IPC分类号： C08G18/63
CPC分类号： C08G18/3212 , C08G18/227 , C08G18/4854 , C08G18/6715 , C08G18/672 , C09J175/16 , C08G18/48
摘要： The present invention relates to vinyl ether or acrylate terminated block resins, compositions incorporating same and methods for preparing same. In particular, the compositions of the present invention may contain a vinyl ether or acrylate terminated block resin, such as a polyurethane block copolymer, a reactive diluent having vinyl ether or 1-alkenyl ether and (meth)acrylate functionality and a curing initiator. The compositions may be exposed to an energy source, e.g., photoradiation, to impart tack-free surface cure.
摘要翻译：本发明涉及乙烯基醚或丙烯酸酯封端的嵌段树脂，其组合物及其制备方法。特别地，本发明的组合物可以含有乙烯基醚或丙烯酸酯封端的嵌段树脂，如聚氨酯嵌段共聚物，具有乙烯基醚或1-链烯基醚和（甲基）丙烯酸酯官能团的反应性稀释剂和固化引发剂。组合物可以暴露于能量源，例如光辐射，以赋予无粘性表面固化。

3. 发明授权

US08519023B2 Fast,curing two part anaerobic adhesive composition 有权
标题翻译：快速，固化两部分厌氧胶组合物
公开(公告)号：US08519023B2
公开(公告)日：2013-08-27
申请号：US13187299
申请日：2011-07-20
申请人： Steven T. Nakos , Andrew D. Messana , Anthony F. Jacobine , John G. Woods
发明人： Steven T. Nakos , Andrew D. Messana , Anthony F. Jacobine , John G. Woods
IPC分类号： C09J4/00
CPC分类号： C09J4/00 , C08K5/46 , C08K5/56
摘要： The present invention concerns improved polymerizable anaerobic compositions which contain (meth)acrylic ester monomers, peroxy polymerization initiators, saccharin a saccharin derivative or a related sulfimide derivative and an activator containing a ferrocene moiety.
摘要翻译：本发明涉及含有（甲基）丙烯酸酯单体，过氧化聚合引发剂，糖精，糖精衍生物或相关的硫酰亚胺衍生物和含有二茂铁部分的活化剂的改进的可聚合厌氧组合物。

4. 发明授权

US08197989B2 UV-curable fuel cell sealants and fuel cells formed therefrom 有权
标题翻译：可UV固化的燃料电池密封剂和由其形成的燃料电池
公开(公告)号：US08197989B2
公开(公告)日：2012-06-12
申请号：US12161237
申请日：2007-01-16
申请人： Anthony F. Jacobine , John G. Woods , Steven T. Nakos , Matthew P. Burdzy , Brian R. Einsla , Kevin J. Welch
发明人： Anthony F. Jacobine , John G. Woods , Steven T. Nakos , Matthew P. Burdzy , Brian R. Einsla , Kevin J. Welch
IPC分类号： H01M8/02 , B29C45/14
CPC分类号： H01M8/0284 , H01M8/0258 , H01M8/0273 , H01M8/0276 , H01M8/0297 , H01M8/2404 , H01M8/241 , H01M8/249
摘要： A fuel cell, having improved sealing against leakage, includes a fuel cell component having a cured sealant, wherein the cured sealant includes a telechelic-functional polyisobutylene, an organhydrogenosilane crosslinker, a platinum catalyst and a photoinitiator. The fuel cell component may be a cathode flow field plate, an anode flow field plate, a resin frame, a gas diffusion layer, an anode catalyst layer, a cathode catalyst layer, a membrane electrolyte, a membrane-electrode-assembly frame, and combinations thereof. A method for forming such a fuel cell includes the steps of providing a fuel cell component including a substrate; providing a mold having a cavity; positioning the mold so that the cavity is in fluid communication with the substrate; applying a curable liquid sealant composition into the cavity, wherein the curable sealant composition includes a telechelic-functional polyisobutylene, an organhydrogenosilane crosslinker, a platinum catalyst and a photoinitiator; and curing the composition with actinic radiation.
摘要翻译：具有改进的泄漏密封性的燃料电池包括具有固化的密封剂的燃料电池部件，其中固化的密封剂包括遥爪功能聚异丁烯，有机氢硅烷交联剂，铂催化剂和光引发剂。燃料电池部件可以是阴极流场板，阳极流场板，树脂框架，气体扩散层，阳极催化剂层，阴极催化剂层，膜电解质，膜 - 电极 - 组装框架，以及其组合。一种形成这种燃料电池的方法包括以下步骤：提供包括基板的燃料电池部件; 提供具有空腔的模具; 定位模具使空腔与衬底流体连通; 将可固化液体密封剂组合物施加到空腔中，其中可固化密封剂组合物包括遥爪功能性聚异丁烯，有机氢硅烷交联剂，铂催化剂和光引发剂; 并用光化辐射固化组合物。

5. 发明授权

US07705064B2 Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same 有权
标题翻译：感光性化合物，包含其的光聚合性组合物及其制备和使用方法
公开(公告)号：US07705064B2
公开(公告)日：2010-04-27
申请号：US11781317
申请日：2007-07-23
申请人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
发明人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
IPC分类号： C08F2/50 , C08F222/10 , C07C69/587 , C08G16/00
CPC分类号： C08F2/50 , C07C67/347 , C07C255/22 , C08G18/10 , C08G18/672 , C07C69/716 , C08G18/3206 , C08G18/3838 , C08G18/42
摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.
摘要翻译：本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基，和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。

6. 发明申请

US20090030106A1 Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same 有权
标题翻译：光敏化合物，包括其的可光聚合组合物及其制备和使用方法
公开(公告)号：US20090030106A1
公开(公告)日：2009-01-29
申请号：US11781317
申请日：2007-07-23
申请人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
发明人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
IPC分类号： C08F2/48 , C07C45/00
CPC分类号： C08F2/50 , C07C67/347 , C07C255/22 , C08G18/10 , C08G18/672 , C07C69/716 , C08G18/3206 , C08G18/3838 , C08G18/42
摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.
摘要翻译：本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基，和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。

7. 发明申请

US20090012202A1 Acrylated Urethanes, Processes for Making the Same and Curable Compositions Including the Same 审中-公开
标题翻译：丙烯酸聚氨酯，制造相同的方法和包含其的可固化组合物
公开(公告)号：US20090012202A1
公开(公告)日：2009-01-08
申请号：US11772843
申请日：2007-07-03
申请人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , David M. Glaser
发明人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , David M. Glaser
IPC分类号： C08G18/04 , C08F2/46 , C08G18/09
CPC分类号： C08F2/48 , C08G18/3212 , C08G18/3275 , C08G18/3281 , C08G18/3876 , C08G18/4277 , C08G18/44 , C08G18/4854 , C08G18/6208 , C08G18/672 , C08G18/755 , C08G18/758 , C08G18/8019 , C08G18/8041 , C08G18/8175 , C09D175/16 , C09J175/16 , C08G18/42 , C08G18/62 , C08G18/48
摘要： The present invention is directed to acrylated urethanes including the reaction product of: (1)(a) at least one urethane having at least two isocyanate groups and at least one acrylate group; and (b) at least one alcohol compound having at least two hydroxyl groups; or (2) (a) at least one isocyanate functional urethane which is the reaction product of at least one alcohol compound selected from the group consisting of amino alcohols, thioether alcohols, phosphino alcohols and mixtures thereof and at least one polyisocyanate; and (b) at least one hydroxy-functional material having at least one acrylate group; curable compositions including the same and processes for making the same.
摘要翻译：本发明涉及丙烯酸酯化的聚氨酯，其包括以下反应产物：（1）（a）至少一种具有至少两个异氰酸酯基团和至少一个丙烯酸酯基团的氨基甲酸酯; 和（b）至少一种具有至少两个羟基的醇化合物; 或（2）（a）至少一种异氰酸酯官能氨基甲酸酯，其是至少一种选自氨基醇，硫醚醇，膦醇及其混合物的醇化合物与至少一种多异氰酸酯的反应产物; 和（b）至少一种具有至少一个丙烯酸酯基团的羟基官能材料; 包括其的可固化组合物及其制备方法。

8. 发明申请

US20110272095A1 FAST,CURING TWO PART ANAEROBIC ADHESIVE COMPOSITION 有权
标题翻译：快速，固化两部分厌氧胶粘剂组合物
公开(公告)号：US20110272095A1
公开(公告)日：2011-11-10
申请号：US13187299
申请日：2011-07-20
申请人： Steven T. Nakos , Andrew D. Messana , Anthony F. Jacobine , John G. Woods
发明人： Steven T. Nakos , Andrew D. Messana , Anthony F. Jacobine , John G. Woods
IPC分类号： B32B37/12 , C09J133/08
CPC分类号： C09J4/00 , C08K5/46 , C08K5/56
摘要： The present invention concerns improved polymerizable anaerobic compositions which contain (meth)acrylic ester monomers, peroxy polymerization initiators, saccharin a saccharin derivative or a related sulfimide derivative and an activator containing a ferrocene moiety.
摘要翻译：本发明涉及含有（甲基）丙烯酸酯单体，过氧化聚合引发剂，糖精，糖精衍生物或相关的硫酰亚胺衍生物和含有二茂铁部分的活化剂的改进的可聚合厌氧组合物。

9. 发明授权

US5558937A Optical fiber primary coatings and fibers coated therewith 失效
公开(公告)号：US5558937A
公开(公告)日：1996-09-24
申请号：US433722
申请日：1995-05-03
申请人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
发明人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
IPC分类号： B29C67/00 , C03C25/10 , C07D263/42 , C08F2/50 , C08F6/02 , C08F8/34 , C08F8/42 , C08G65/332 , C08G73/02 , C08G75/04 , C09D4/00 , G02B6/44 , G03F7/00 , G03F7/027 , G02B6/00 , C08G75/12 , D02G3/00
CPC分类号： G02B6/443 , B29C67/0066 , C03C25/106 , C07D263/42 , C08F6/02 , C08G65/332 , C08G73/028 , C08G75/045 , C09D4/00 , G03F7/0037 , G03F7/0275 , Y10T428/2938
摘要： A curable thiol-ene composition specially adapted for use as a primary coating on optical fibers comprises a polythiol and a compound having a plurality of norbornene groups thereon, are characterized in that one of either the compound having the plurality of norbornene groups or the polythiol has a backbone of a poly(tetramethylene oxide), or is an oligomer thereof, and the poly(tetramethylene oxide) has a molecular weight of between 250 and 5,000. The formulations are relatively low viscosity liquids at practical application temperatures and cure substantially completely with very low irradiation fluence. The formulations cure in ambient air. There is no need to exclude oxygen or to control humidity. The formulations of the invention can be cured using low intensity UV lamps which do not generate significant amounts of heat. The cured products have excellent low temperature flexibility, good humidity and water absorbtion resistance and good thermal oxidative stability. The formulations may be applied to optical fibers using conventional techniques and cured with UV-vis or EB irradiation.

10. 发明授权

US5459175A Optical fiber primary coatings and fibers coated therewith 失效
标题翻译：光纤初级涂层和涂覆的纤维
公开(公告)号：US5459175A
公开(公告)日：1995-10-17
申请号：US80748
申请日：1993-06-22
申请人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
发明人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
IPC分类号： B29C67/00 , C03C25/10 , C07D263/42 , C08F2/50 , C08F6/02 , C08F8/34 , C08F8/42 , C08G65/332 , C08G73/02 , C08G75/04 , C09D4/00 , G02B6/44 , G03F7/00 , G03F7/027
CPC分类号： G02B6/443 , B29C67/0066 , C03C25/106 , C07D263/42 , C08F6/02 , C08G65/332 , C08G73/028 , C08G75/045 , C09D4/00 , G03F7/0037 , G03F7/0275 , Y10T428/2938
摘要： A curable thiol-ene composition specially adapted for use as a primary coating on optical fibers comprises a polythiol and a compound having a plurality of norbornene groups thereon, are characterized in that one of either the compound having the plurality of norbornene groups or the polythiol has a backbone of a poly(tetramethylene oxide), or is an oligomer thereof, and the poly(tetramethylene oxide) has a molecular weight of between 250 and 5,000. The formulations are relatively low viscosity liquids at practical application temperatures and cure substantially completely with very low irradiation fluence. The formulations cure in ambient air. There is no need to exclude oxygen or to control humidity. The formulations of the invention can be cured using low intensity UV lamps which do not generate significant amounts of heat. The cured products have excellent low temperature flexibility, good humidity and water absorbtion resistance and good thermal oxidative stability. The formulations may be applied to optical fibers using conventional techniques and cured with UV-vis or EB irradiation.
摘要翻译：特别适用于光纤上的初级涂层的可固化硫醇烯组合物包括多硫醇和其上具有多个降冰片烯基团的化合物，其特征在于具有多个降冰片烯基团的化合物或多硫醇中的一种具有聚（四氢呋喃）氧化物的骨架或其低聚物，并且聚（四氢呋喃）的分子量为250-5,000。制剂在实际应用温度下是相对低粘度的液体，并且以非常低的照射能量密度完全固化。配方在环境空气中固化。不需要排除氧气或控制湿度。本发明的配方可以使用不产生大量热量的低强度UV灯来固化。固化产物具有优异的低温柔韧性，良好的湿度和吸水性，良好的热氧化稳定性。可以使用常规技术将制剂施用于光纤并用UV-vis或EB辐照固化。

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