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1. 发明授权

US4683266A Compositions thickened through urethane reaction 失效
标题翻译：组合物通过氨基甲酸酯反应增稠
公开(公告)号：US4683266A
公开(公告)日：1987-07-28
申请号：US796031
申请日：1985-11-07
申请人： Anthony C. Palermo , Roger M. Christenson , Glenn L. Mazza
发明人： Anthony C. Palermo , Roger M. Christenson , Glenn L. Mazza
IPC分类号： C08F279/02 , C08G18/63 , C08G18/69 , C08F8/00 , C08L75/00
CPC分类号： C08G18/696 , C08F279/02 , C08G18/635 , C08G18/69 , C08G18/692
摘要： A thickened composition which is cured by free-radical initiated polymerization is composed of a compound containing at least two ethylenically unsaturated double bonds per molecule; an active hydrogen-containing homopolymer or copolymer of a diene having a number average molecular weight of from 500 to 15,000; the active hydrogens being derived from hydroxyl, amino, or mercapto groups; and an organic polyisocyanate present in an amount sufficient to thicken said composition without gelation.
摘要翻译：通过自由基引发聚合固化的增稠组合物由每分子含有至少两个烯属不饱和双键的化合物组成; 数均分子量为500〜15000的二烯的活性含氢均聚物或共聚物; 活性氢源自羟基，氨基或巯基; 和有机多异氰酸酯的存在量足以增稠所述组合物而没有凝胶化。

2. 发明授权

US4403085A Polyurethane crosslinkers, and the process for preparing and using the same 失效
标题翻译：聚氨酯交联剂，以及其制备和使用方法
公开(公告)号：US4403085A
公开(公告)日：1983-09-06
申请号：US330290
申请日：1981-12-14
申请人： Roger M. Christenson , Thomas R. Hockswender
发明人： Roger M. Christenson , Thomas R. Hockswender
IPC分类号： C08G18/08 , C08G18/10 , C08G18/66 , C08G18/80 , C08G18/81 , C08G18/32 , C08G18/60
CPC分类号： C08G18/8061 , C08G18/0823 , C08G18/10 , C08G18/6625 , C08G2390/00 , Y10T428/31605
摘要： A polyurethane crosslinker is provided by reacting a partially-blocked diisocyanate and a hydroxyl-terminated, carboxyl group-containing polyurethane precursor. The precursor is a reaction product of a diol containing a carboxyl group and another diol of high molecular weight, and a diisocyanate. The instant crosslinkers are particularly useful in water-based coating compositions for metal containers.
摘要翻译：通过使部分封端的二异氰酸酯和含羟基封端的含羧基的聚氨酯前体反应来提供聚氨酯交联剂。前体是含有羧基的二醇和高分子量的另一种二醇的二异氰酸酯的反应产物。即时交联剂特别适用于金属容器的水性涂料组合物。

3. 发明授权

US4316784A Process for electrodeposition of Michael adducts of polymeric materials 失效
标题翻译：电沉积聚合材料迈克尔加合物的方法
公开(公告)号：US4316784A
公开(公告)日：1982-02-23
申请号：US247582
申请日：1981-03-26
申请人： Stephen L. Buchwalter , Joseph F. Bosso , Roger M. Christenson
发明人： Stephen L. Buchwalter , Joseph F. Bosso , Roger M. Christenson
IPC分类号： C09D5/44 , C09D161/06 , C09D163/10 , C25D13/06
CPC分类号： C09D5/4434 , C09D161/06 , C09D163/10
摘要： Resinous compositions which are the Michael adducts of primary and/or secondary amines and polymers containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties are disclosed. The compositions are depositable on substrates to form films. The films are amenable to oxidative and aminoplast cures and cure with light color. The compositions are desirable for use in cationic electrodeposition.
摘要翻译：公开了作为初级和/或仲胺的迈克尔加合物和含有α，β-烯键式不饱和部分与羰基部分缀合的聚合物的树脂组合物。组合物可沉积在基材上以形成薄膜。这些胶片适合于氧化和氨基塑料固化并用浅色固化。组合物用于阳离子电沉积中是理想的。

4. 发明授权

US4302561A Pigment dispersants for coating compositions 失效
标题翻译：用于涂料组合物的颜料分散剂
公开(公告)号：US4302561A
公开(公告)日：1981-11-24
申请号：US178207
申请日：1980-08-14
申请人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
发明人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
IPC分类号： C08F8/00 , C09B67/46 , C09D7/45 , C08F220/34
CPC分类号： C09D7/02 , C08F8/00 , C09B67/0091
摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acids, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.
摘要翻译：用于涂料组合物的颜料分散剂，其中分散剂是（i）烷基中具有3-8个碳原子的甲基丙烯酸烷基酯的聚合产物，（ii）选自苯乙烯，甲基丙烯酸甲酯，甲基丙烯酸乙酯及其混合物，（iii）选自丙烯酸，甲基丙烯酸，衣康酸，巴豆酸，马来酸，富马酸及其混合物的烯属不饱和羧酸或具有双键α-烯烃的单体，当与水，醇，胺或酸酐反应时提供羧基官能团，（iv）具有羰基和至少一个羟基的双键α-β的单体或提供这种基团的单体当与酸或环氧化物进一步反应时，和（v）提供胺或胺盐官能部分的化合物。分散剂可用于将颜料分散在含有多种成膜树脂的涂料组合物中。

5. 发明授权

US4225480A Addition interpolymers having improved stability and two-package compositions comprising such interpolymers and polyepoxides 失效
标题翻译：具有改进的稳定性的加成互聚物和包含这种互聚物和聚环氧化物的双组分组合物
公开(公告)号：US4225480A
公开(公告)日：1980-09-30
申请号：US929882
申请日：1978-07-31
申请人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
发明人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
IPC分类号： C08L33/02 , C08L63/00 , C09D133/02 , C09D157/04 , C08F8/30 , C08F8/32 , C08F8/44 , C08L31/02
CPC分类号： C09D133/02 , C08L33/02 , C08L63/00 , C09D157/04
摘要： Amine group-containing addition interpolymers having improved stability under conditions of storage and use are prepared by interpolymerizing at least one polymerizable ethylenically unsaturated carboxylic acid monomer and at least one polymerizable ethylenically unsaturated aminolysis-resistant organic monomer to form an addition interpolymer containing carboxyl groups pendent to the polymer chain and aminolysis-resistant organic groups pendent to the polymer chain, following which a portion of the pendent carboxyl groups of the addition interpolymer are reacted with an alkylenimine to form pendent amine groups and a portion of the pendent carboxyl groups of the addition interpolymer are neutralized with a basic compound to form pendent anionic salt groups. The addition interpolymer is preferably reducible with organic solvents, water or a mixture thereof, and can be utilized as pigment grinding vehicles or they can be formulated with conventional additives to form useful coating compositions. A preferred use for these interpolymers is in combination with a polyepoxide to provide two-package cocurable polymeric compositions for coatings and other uses.
摘要翻译：通过将至少一种可聚合的烯键式不饱和羧酸单体和至少一种可聚合的烯属不饱和的抗氨基有机单体共聚以形成含有羧基的加成互聚物来制备在储存和使用条件下具有改进的稳定性的含胺基的加成互聚物，聚合物链和耐氨基的有机基团聚合到聚合物链上，随后将一部分加成互聚物的侧基羧基与亚烷基亚胺反应以形成侧挂胺基团和一部分加成互聚物的侧挂羧基用碱性化合物中和以形成悬垂的阴离子盐基团。添加互聚物优选可以用有机溶剂，水或其混合物还原，并且可以用作颜料研磨载体，或者可以用常规添加剂配制以形成有用的涂料组合物。这些互聚物的优选用途是与聚环氧化物组合，以提供用于涂料和其它用途的双包封可共聚的聚合物组合物。

6. 发明授权

US4221885A Addition interpolymers having improved stability and two-package compositions comprising such interpolymers and polyepoxides 失效
标题翻译：具有改进的稳定性的加成互聚物和包含这种互聚物和聚环氧化物的双组分组合物
公开(公告)号：US4221885A
公开(公告)日：1980-09-09
申请号：US939950
申请日：1978-09-06
申请人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
发明人： Karl F. Schimmel , Roger M. Christenson , Jerome A. Seiner , James A. Claar
IPC分类号： C08F8/32 , C08F8/44 , C08F8/30
CPC分类号： C08F8/32 , C08F8/44
摘要： Amine group-containing addition interpolymers having improved stability under conditions of storage and use are prepared by interpolymerizing at least one polymerizable ethylenically unsaturated carboxylic acid monomer and at least one polymerizable ethylenically unsaturated aminolysis-resistant organic monomer to form an addition interpolymer containing carboxyl groups pendent to the polymer chain and aminolysis-resistant organic groups pendent to the polymer chain, following which a portion of the pendent carboxyl groups of the addition interpolymer are reacted with an alkylenimine to form pendent amine groups and a portion of the pendent carboxyl groups of the addition interpolymer are neutralized with a basic compound to form pendent anionic salt groups.
摘要翻译：通过将至少一种可聚合的烯键式不饱和羧酸单体和至少一种可聚合的烯属不饱和的抗氨基有机单体共聚以形成含有羧基的加成互聚物来制备在储存和使用条件下具有改进的稳定性的含胺基的加成互聚物，聚合物链和耐氨基的有机基团聚合到聚合物链上，随后将一部分加成互聚物的侧基羧基与亚烷基亚胺反应以形成侧挂胺基团和一部分加成互聚物的侧挂羧基用碱性化合物中和以形成悬垂的阴离子盐基团。

7. 发明授权

US4153545A Method for cleaning membrane filter 失效
标题翻译：膜过滤器的清洗方法
公开(公告)号：US4153545A
公开(公告)日：1979-05-08
申请号：US825734
申请日：1977-08-18
申请人： Robert R. Zwack , Roger M. Christenson
发明人： Robert R. Zwack , Roger M. Christenson
IPC分类号： B01D65/06 , C09D5/44 , C11D1/00 , B01D13/00
CPC分类号： B01D61/20 , B01D65/02 , B01D2321/162
摘要： A method of cleaning a membrane such as an ultrafilter which has been used in the treatment of a cataphoretic paint is disclosed. The method involves treating the membrane with an aqueous solution of an acid, a fatty amine and a water-soluble organic solvent.
摘要翻译：公开了一种清洁已经用于治疗阴天漆的超滤器等膜的方法。该方法包括用酸，脂肪胺和水溶性有机溶剂的水溶液处理膜。

8. 发明授权

US4711917A Cationic coating compositions for electrodeposition over rough steel 失效
标题翻译：用于电沉积在粗钢上的阳离子涂料组合物
公开(公告)号：US4711917A
公开(公告)日：1987-12-08
申请号：US879709
申请日：1986-06-27
申请人： Gregory J. McCollum , Roger L. Scriven , Roger M. Christenson , George W. Mauer , Robert R. Zwack
发明人： Gregory J. McCollum , Roger L. Scriven , Roger M. Christenson , George W. Mauer , Robert R. Zwack
IPC分类号： C08G18/08 , C08G18/64 , C08G18/80 , C09D5/44 , C08L63/00
CPC分类号： C08G18/0814 , C08G18/643 , C08G18/8064 , C09D5/443 , Y10S524/901
摘要： A method of cationic electrodeposition, electrocoated articles and novel electrocoating compositions are disclosed. The compositions comprise a cationic resin containing blocked isocyanate functionality and are capable of being electrodeposited over rough steel and producing extremely smooth films upon curing.
摘要翻译：公开了一种阳离子电沉积方法，电涂制品和新型电涂组合物。组合物包含含有封端异氰酸酯官能团的阳离子树脂，并且能够电沉积在粗糙的钢上并在固化时产生非常光滑的膜。

9. 再颁专利

USRE31022E Michael adducts of polymeric materials useful in coating applications 失效
标题翻译：用于涂料应用的聚合物材料的迈克尔加合物
公开(公告)号：USRE31022E
公开(公告)日：1982-08-31
申请号：US247584
申请日：1981-03-26
申请人： Stephen L. Buchwalter , Joseph F. Bosso , Roger M. Christenson
发明人： Stephen L. Buchwalter , Joseph F. Bosso , Roger M. Christenson
IPC分类号： C08G18/08 , C08G18/67 , C09D5/44 , C09D161/06 , C09D163/10
CPC分类号： C08G18/0814 , C08G18/6705 , C09D161/06 , C09D163/10 , C09D5/4434 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529
摘要： Resinous compositions which are the Michael adducts of primary and/or secondary amines and polymers containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties are disclosed. The compositions are depositable on substrates to form films. The films are amenable to oxidative and aminoplast cures and cure with light color. The compositions are desirable for use in cationic electrodeposition.

10. 发明授权

US4289674A Base-solubilized acrylic polymers and aqueous resinous dispersions of acrylic polymers and epoxy resins 失效
标题翻译：丙烯酸聚合物和环氧树脂的碱溶性丙烯酸聚合物和水性树脂分散体
公开(公告)号：US4289674A
公开(公告)日：1981-09-15
申请号：US55937
申请日：1979-07-09
申请人： Roger M. Christenson , Rudolf Maska , Rostyslawa Dowbenko , Thomas R. Hockswender
发明人： Roger M. Christenson , Rudolf Maska , Rostyslawa Dowbenko , Thomas R. Hockswender
IPC分类号： C08L63/00 , C09D133/02 , C09D133/26 , C09D157/10 , C09D157/12 , C08L33/02
CPC分类号： C09D157/10 , C09D133/02 , C09D133/26 , C09D157/12 , C08L63/00 , Y10T428/31529 , Y10T428/31699
摘要： An aqueous resinous dispersion and a method of coating employing the aqueous resinous dispersion are disclosed. The aqueous resinous dispersions are solubilized with base and comprise an acrylic polymer containing N-ethoxymethylacrylamide or methacrylamide moieties and an epoxy resin. The dispersion is useful for coating metal containers particularly as a coating for the interior of containers which are used for alcoholic beverages, for example, beer cans.
摘要翻译：公开了一种水性树脂分散体和使用该水性树脂分散体的涂布方法。水性树脂分散体用碱溶解并且包含含有N-乙氧基甲基丙烯酰胺或甲基丙烯酰胺部分的丙烯酸聚合物和环氧树脂。该分散体可用于涂覆金属容器，特别是用作用于酒精饮料（例如啤酒罐）的容器内部的涂层。

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