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    • 9. 发明公开
    • 내열성 탄화수소 흡착촉매와 그 제조방법
    • 耐热烃捕​​获催化剂及其制备方法
    • KR1020030097230A
    • 2003-12-31
    • KR1020020034511
    • 2002-06-20
    • 현대자동차주식회사
    • 인치범
    • B01J33/00
    • B01J33/00B01J20/16
    • PURPOSE: A heat resistant hydrocarbon trap catalyst is provided which is capable of purifying hydrocarbons efficiently by laying up diffusion barrier formed of porous silica (SiO2) at upper and lower sides of zeolite layer that is hydrocarbon trap layer, and a preparation method of the catalyst is provided. CONSTITUTION: In a hydrocarbon trap catalyst for purifying exhaust gas comprising zeolite layer that is a hydrocarbon trap layer, and three way catalyst layer formed at an upper side of the zeolite layer, the heat resistant hydrocarbon trap catalyst is characterized in that diffusion barrier of porous silica having a specific surface area of 100 to 300 m¬2/g is formed on upper and lower sides of the zeolite layer so that the diffusion barrier forms upper and lower layers of the zeolite layer. In a preparation method of hydrocarbon trap catalyst for purifying exhaust gas comprising a step (a) of laying up zeolite layer that is a hydrocarbon trap layer on a ceramic supporter; and a step (b) of laying up three way catalyst on the zeolite layer, the preparation method of heat resistant hydrocarbon trap catalyst comprises the steps of first laying up diffusion barrier by drying and calcining the supported porous silica powder after supporting porous silica powder having a specific surface area of 100 to 300 m¬2/g before laying up the zeolite layer; laying up the zeolite layer on the diffusion barrier; and laying up another diffusion barrier on the zeolite layer by drying and calcining the supported porous silica powder after supporting porous silica powder having a specific surface area of 100 to 300 m¬2/g onto the zeolite layer.
    • 目的:提供一种耐热烃陷阱催化剂,其能够通过在作为烃阱层的沸石层的上侧和下侧放置由多孔二氧化硅(SiO 2)形成的扩散阻挡层来有效地净化烃,以及催化剂的制备方法 被提供。 构成:在用于净化排气的碳氢捕集催化剂中,其包含作为烃捕集层的沸石层和在沸石层的上侧形成的三元催化剂层,其特征在于,多孔 在沸石层的上侧和下侧形成比表面积为100〜300m2 / g的二氧化硅,使得扩散阻挡层形成沸石层的上层和下层。 在一种用于净化废气的烃捕获催化剂的制备方法中,包括在陶瓷载体上铺设作为烃阱层的沸石层的步骤(a) 和在沸石层上铺设三元催化剂的步骤(b),耐热烃捕集催化剂的制备方法包括以下步骤:首先在支撑多孔二氧化硅粉末之后通过干燥和煅烧负载的多孔二氧化硅粉末来铺设扩散阻挡层, 在铺设沸石层之前,比表面积为100-300m2 / g; 在扩散阻挡层上铺设沸石层; 并通过在将比表面积为100-300m2 / g的多孔二氧化硅粉末支撑在沸石层上之后干燥和煅烧负载的多孔二氧化硅粉末,在沸石层上铺设另一个扩散阻挡层。
    • 10. 发明公开
    • 열 잠재성 촉매, 그 제조 방법, 및 상기의 촉매에 의하여제조되는 수지
    • 热催化剂,其制备方法和使用相同催化剂生产的树脂
    • KR1020030021540A
    • 2003-03-15
    • KR1020010054851
    • 2001-09-06
    • 주식회사 엠엔비그린어스
    • 김진환김우석이종두김성택김은기
    • B01J33/00
    • B01J33/00B01J31/0267B01J37/04
    • PURPOSE: Provided are thermal latent catalyst with high reaction temperature, a method for fabricating the same and resin produced by using the same catalyst. CONSTITUTION: The method comprises the steps of agitating general catalyst and 16 to 66 wt.% of polymer in the presence of solvent at room temperature; and putting the solvent obtained during the first step into a vacuum oven for the purpose of removing the solvent, wherein the polymer is selected from polyvinylpyrrolidone (PVP.), poly(methyl methacrylate)(PMMA) and polystyrene, and wherein the catalyst is selected from the group consisting of triphenyl phosphine, tetraphenyl phosphine tetraphenylborate, 2-methyl imidazolium, 1,8-diazobicyclo£5,4,0|undec-7-ene and their derivatives.
    • 目的:提供具有高反应温度的热潜催化剂,其制备方法和使用相同催化剂制备的树脂。 方案:该方法包括在室温下在溶剂存在下搅拌一般催化剂和16至66重量%的聚合物的步骤; 并将第一步中获得的溶剂放入真空烘箱中以除去溶剂,其中聚合物选自聚乙烯吡咯烷酮(PVP),聚(甲基丙烯酸甲酯)(PMMA)和聚苯乙烯,并且其中选择催化剂 由三苯基膦,四苯基膦四苯基硼酸盐,2-甲基咪唑鎓,1,8-二氮杂双环[5,4,0]十一碳-7-烯及其衍生物组成的组。