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    • 1. 发明公开
    • 알칼리 수전해용 수소 정제 제어방법
    • 用于控制碱性水电解的氢气净化方法
    • KR1020140067213A
    • 2014-06-05
    • KR1020120134182
    • 2012-11-26
    • 여영진
    • 여영진
    • C01B3/16C01B3/02C25C3/00
    • Y02P20/52C01B3/508B01D53/02B01D2256/16B01D2257/80C01B2203/0425C01B2203/043C01B2203/1614
    • The present invention relates to a method for controlling hydrogen purification for alkali water electrolysis that can improve the purification efficiency of a hydrogen gas by catalyst-reacting an impurity-including raw material gas that is supplied from an alkali water electrolysis device and by alternately performing a moisture adsorption reaction for a catalyst reactive gas including moisture and a reproduction reaction for desorbing adsorbed moisture in a plurality of adsorption reactors. To this end, the method of the present invention comprises the steps of: producing moisture by means of an oxygen catalyst reaction that is performed on oxygen included in a raw material gas by feeding a hydrogen gas that is supplied from an alkali water electrolysis device into a catalyst reactor; supplying the produced moisture to a first adsorption reactor; supplying the produced moisture to a second adsorption reactor and a recycled gas to the first adsorption reactor if an adhesive layer of the first adsorption reaction is saturated; and controlling an adsorption reaction and a reproduction reaction alternately in the first adsorption reactor and second adsorption reactor until a hydrogen gas having desired purity is obtained.
    • 本发明涉及用于控制碱水电解的氢气净化的方法,其可以通过使从碱水电解装置供给的含杂质原料气体进行催化反应,并且通过交替地进行 包括水分的催化剂活性气体的吸湿反应和用于解吸多个吸附反应器中的吸附水分的再生反应。 为此,本发明的方法包括以下步骤:通过将从碱水电解装置供给的氢气供给到原料气体中所含的氧进行氧催化剂反应来生成水分, 催化剂反应器; 将产生的水分供应到第一吸附反应器; 如果第一吸附反应的粘合剂层饱和,则将产生的水分供应到第二吸附反应器和再循环气体到第一吸附反应器; 并且在第一吸附反应器和第二吸附反应器中交替地控制吸附反应和再生反应,直到获得具有所需纯度的氢气。
    • 2. 发明公开
    • 고순도 수소생산방법
    • 高纯度氢生成方法
    • KR1020130130972A
    • 2013-12-03
    • KR1020120054666
    • 2012-05-23
    • 한국에너지기술연구원
    • 류호정박영철조성호이창근진경태선도원배달희박재현이승용문종호이동호
    • C01B3/16B01J19/24B01J20/04
    • Y02P20/584C01B3/16C01B2203/0283C01B2203/0425C01B2203/1076C01B2203/148
    • The present invention relates to a method for consecutively producing high purity hydrogen from synthetic gas generated by the gasification of hydrocarbon fuel by a sorption enhanced water gas shift (SEWGS) reaction using a water gasification catalyst and a carbon dioxide absorption agent. The method for producing high purity hydrogen comprises: a first step of promoting hydrogen production through the reduction of the partial pressure of carbon dioxide due to the adsorption of the carbon dioxide among synthetic gas by supplying the synthetic gas produced by the gasification of fuel and bring the water gasification catalyst of a fluidized state into contact with the carbon dioxide absorption agent at the same time; a second step of moving the water gasification catalyst and carbon dioxide absorption agent while separating the hydrogen gas generated in the first step; a third step of separating carbon dioxide absorbed on the carbon dioxide absorption agent and releasing the carbon dioxide by bring regenerative gas into contact with the water gasification catalyst and carbon dioxide absorption agent; and a fourth step of returning the water gasification catalyst and regenerated carbon dioxide absorption agent to the first step. The first step through the fourth step are successively performed.
    • 本发明涉及一种通过使用水气化催化剂和二氧化碳吸收剂的吸附增强水煤气变换(SEWGS)反应,通过烃燃料气化产生的合成气体连续生产高纯度氢的方法。 生产高纯度氢的方法包括:通过提供由燃料气化产生的合成气体,由于二氧化碳在合成气体中的吸附而减少二氧化碳分压而促进氢生产的第一步骤,并带来 流化状态的水气化催化剂同时与二氧化碳吸收剂接触; 在分离第一步骤中产生的氢气的同时移动水气化催化剂和二氧化碳吸收剂的第二步骤; 分离吸收在二氧化碳吸收剂上的二氧化碳并通过使再生气体与水气化催化剂和二氧化碳吸收剂接触释放二氧化碳的第三步骤; 以及将水气化催化剂和再生二氧化碳吸收剂返回到第一工序的第四工序。 依次执行第四步骤的第一步骤。
    • 6. 发明公开
    • 석탄을 연료 전지 품질의 수소 및 즉시 격리가능한이산화탄소로 전환시키는 방법
    • 将燃料转化为燃料电池质量氢和顺序二氧化碳的方法
    • KR1020030011693A
    • 2003-02-11
    • KR1020020044953
    • 2002-07-30
    • 제너럴 일렉트릭 캄파니
    • 라이언리처드케이
    • C01B3/02C01B32/50
    • C10J3/725B01J8/0055B01J8/26B01J8/388B01J2208/00292B01J2208/00513B01J2208/025C01B3/56C01B2203/0425C01B2203/0475C10J3/463C10J3/56C10J2300/093C10J2300/0956C10J2300/0983C10J2300/0996C10J2300/16C10J2300/1646F23C2900/99008Y02C10/08Y02E20/346Y02P30/30C01B3/02C01B32/50
    • PURPOSE: A process for burning coal to produce hydrogen for fuel cells, oxygen depleted air for powering gas turbines, and sequestration-ready CO2 is provided. CONSTITUTION: The process for converting coal(22) into fuel cell quality hydrogen and sequestration-ready carbon dioxide using unmixed combustion comprises the steps of charging a first fluidized bed reactor(10) with coal(22) and high temperature steam which oxidizes a portion of the coal(22) and produces substantially pure hydrogen gas and carbon dioxide; circulating a mixture of solids among the first reactor(10) and second and third reactors(12,14) containing coal(22), calcium compounds present as CaO, CaCO3, and mixtures thereof, and iron compounds present as FeO, Fe2O3 and mixtures thereof; reacting the CaO present in the first reactor(10) with carbon dioxide to form CaCO3; reacting the CaCO3 in the second reactor(12) to regenerate CaO while reacting coal(22) and/or coal char with Fe2O3 to form FeO and carbon dioxide; oxidizing the FeO present in the third reactor(14) to regenerate Fe2O3 and produce oxygen depleted air at an elevated temperature; and withdrawing substantially pure hydrogen, carbon dioxide and depleted air in separate streams(26,28,30) from the first, second and third reactors(10,12,14).
    • 目的:提供燃煤燃煤电池氢气,耗氧空气,燃气轮机供电和封存二氧化碳的工艺。 构成:使用未混合燃烧将煤(22)转化为燃料电池质量的氢和螯合就绪二氧化碳的方法包括以下步骤:向第一流化床反应器(10)加入煤(22)和将部分氧化的高温蒸汽 的煤(22),并产生基本上纯的氢气和二氧化碳; 在含有煤(22)的第一反应器(10)和第二和第三反应器(12,14)之间循环固体混合物,以CaO,CaCO 3及其混合物存在的钙化合物和以FeO,Fe 2 O 3和混合物存在的铁化合物 物; 使第一反应器(10)中存在的CaO与二氧化碳反应形成CaCO 3; 使第二反应器(12)中的CaCO 3使煤再生,同时使煤(22)和/或煤焦与Fe2O3反应形成FeO和二氧化碳; 氧化存在于第三反应器(14)中的FeO以再生Fe 2 O 3并在高温下产生贫氧空气; 以及从与所述第一,第二和第三反应器(10,12,14)分开的流(26,28,30)中抽出基本上纯的氢,二氧化碳和贫化空气。